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Title: Mid-infrared plasmonics.
Creator: Khalilzadeh Rezaie, Farnood, Peale, Robert, Ishigami, Masa, Schoenfeld, Winston, Buchwald, Walter, Abdolvand, Reza, University of Central Florida
Abstract / Description: This dissertation reports investigations into materials for, and applications of, infrared surface plasmon polaritons (SPP). SPPs are inhomogeneous electromagnetic waves that are bound to the surface of a conductor. Tight confinement of electromagnetic energy, the primary virtue of SPPs for so-called (")plasmonic(") applications, requires plasma frequencies for the conductor near the intended infrared operational frequencies. This requires carrier concentrations that are much less than those...
Show moreThis dissertation reports investigations into materials for, and applications of, infrared surface plasmon polaritons (SPP). SPPs are inhomogeneous electromagnetic waves that are bound to the surface of a conductor. Tight confinement of electromagnetic energy, the primary virtue of SPPs for so-called (")plasmonic(") applications, requires plasma frequencies for the conductor near the intended infrared operational frequencies. This requires carrier concentrations that are much less than those of usual metals such as gold and silver. I have investigated the optical properties and SPP excitation resonances of two materials having infrared plasma frequencies, namely the semimetal bismuth and the transparent conducting fluorine-doped tin-oxide (FTO). The complex permittivity spectra for evaporated films of Bi were found to be distinctly different than earlier reports for crystal or polycrystalline films, and SPP excitation resonances on Bi-coated gratings were found to be disappointingly broad. Permittivity spectra for chemical spray deposited FTO were obtained to long-wave IR wavelengths for the first time, and nano-crystalline FTO-coated silicon lamellar gratings show remarkable conformity. SPP excitation resonances for FTO are more promising than for Bi. Thus, FTO appears to be a promising SPP host for infrared plasmonics, e.g. a planer waveguide plasmonic spectral sensor, whose design was elaborated and investigated as part of my research and which requires SPP-host coating on deep vertical side walls of a trench-like analyte interaction region. Additionally, FTO may serve as a useful conducting oxide for a near-IR plasmonic spectral imager that I have investigated theoretically.
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Date Issued: 2015
Identifier: CFE0006222, ucf:51080
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006222

Title: The Consequences of a Reduced Superlattice Thickness on Quantum Cascade LASER Performance.
Creator: Figueiredo, Pedro, Lyakh, Arkadiy, Peale, Robert, Klemm, Richard, Fathpour, Sasan, University of Central Florida
Abstract / Description: Coherent infrared radiation sources are essential for the operability of a wide range of scientific, industrial, military and commercial systems. The importance of the mid-infrared spectral region cannot be understated. Numerous molecules have some vibrational band in this range, allowing for identification of species by means of absorption, emission or some other form of spectroscopy. As such, spectroscopy alone has numerous applications ranging from industrial process control to disease...
Show moreCoherent infrared radiation sources are essential for the operability of a wide range of scientific, industrial, military and commercial systems. The importance of the mid-infrared spectral region cannot be understated. Numerous molecules have some vibrational band in this range, allowing for identification of species by means of absorption, emission or some other form of spectroscopy. As such, spectroscopy alone has numerous applications ranging from industrial process control to disease diagnosis utilizing breath analysis. However, despite the discovery of the LASER in the 60s, to this day the amount of coherent sources in this range is limited. It is for this reason that the quantum cascade laser has gained such momentum over the past 23 years.Quantum Cascade LASERS (QCL) are semiconductor LASERS which are based on the principle of bandgap engineering. This incredible technique is a testament to the technological maturity of the semiconductor industry. It has been demonstrated that by having precise control of individual material composition (band gap control), thicknesses on the order of monolayers, and doping levels for each individual layer in a superlattice, we have unprecedented flexibility in designing a LASER or detector in the infrared. And although the technology has matured since it's discovery, there still remain fundamental limitations on device performance. In particular, active region overheating limits QCL performance in a high duty cycle mode of operation.In this dissertation, along with general discussion on the background of the QCL, we propose a solution of where by limiting the growth of the superlattice to a fraction of typical devices, we allow for reduction of the average superlattice temperature under full operational conditions. The consequences of this reduction are explored in theory, experiment and system level applications.
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Date Issued: 2017
Identifier: CFE0006592, ucf:51273
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006592

Title: Multidimensional Room-Temperature Fluorescence Microscopy for the Nondestructive Analysis of Forensic Trace Textile Fibers.
Creator: Mujumdar, Nirvani, Campiglia, Andres, Sigman, Michael, Harper, James, Rex, Matthew, Peale, Robert, University of Central Florida
Abstract / Description: The purpose of this dissertation is to advance nondestructive methodology for forensic fiber examination. Non-destructive techniques that can either discriminate between similar fibers or match a known to a questioned fiber (-) and still preserve the physical integrity of the fibers for further court examination - are highly valuable in forensic science. A challenging aspect of forensic fiber examinations involves the comparison of fibers colored with visually indistinguishable dyestuffs....
Show moreThe purpose of this dissertation is to advance nondestructive methodology for forensic fiber examination. Non-destructive techniques that can either discriminate between similar fibers or match a known to a questioned fiber (-) and still preserve the physical integrity of the fibers for further court examination - are highly valuable in forensic science. A challenging aspect of forensic fiber examinations involves the comparison of fibers colored with visually indistinguishable dyestuffs. This is not an uncommon situation, as there are numerous indistinguishable fibers pre-dyed with commercial dyes of virtually identical colors. Minimal chemical structural variations are actually encouraged by the dye patent process and commercial competition.The common denominator to forensic methodology is the fact that fiber analysis primarily focuses on the dyes used to color the fibers and do not investigate other potential discriminating components present in the fiber. This dissertation explores a different aspect of fiber analysis as it focuses on the total fluorescence emission of fibers. In addition to the contribution of the textile dye (or dyes) to the fluorescence spectrum of the fiber, we consider the contribution of intrinsic fluorescence impurities (-) i.e. impurities imbedded into the fibers during fabrication of garments - as a reproducible source of fiber comparison. Although fluorescence microscopy is used in forensic labs for single fiber examination, measurements are made with the aid of band-pass filters that provide very limited information on the spectral profiles of fibers. We take the non-destructive nature of fluorescence microscopy to a higher level of selectivity with the collection of room-temperature fluorescence excitation emission matrices (RTF-EEMs). The information contained in the EEMs was first used to select the best excitation wavelength for recording first order data, i.e. two-dimensional fluorescence spectra. Pairwise comparisons involved the following visually indistinguishable fibers: nylon 361 pre-dyed with acid yellow (AY) 17 and AY 23, acrylic 864 pre-dyed with basic green (BG) 1 and BG 4, acetate satin 105B pre-dyed with disperse blue (DB) 3 and DB 14, and polyester 777 pre-dyed with disperse red (DR) 1 and DR 19. With the exception of acrylic 864 fibers dyed with BG1 and BG4, the comparison of two-dimensional spectra via principal component analysis (PCA) provided accurate fiber identification for all the analyzed fibers. The same approach was later applied to the investigation of laundering effects on the comparison of textile fibers. The presence of brighteners and other detergent components adsorbed in the fibers provided spectral fingerprints that enhanced the fiber identification process.The full dimensionality of EEMs was then explored with the aid of parallel factor analysis (PARAFAC), a second order algorithm capable to determine the number of fluorescence components that contribute to an EEM along with their individual excitation and emission profiles. The application of PARAFAC was carried out unsupervised and supervised by linear discrimination analysis (LDA). The classification performances of PARAFAC and LDA-supervised PARAFAC were compared to the one obtained with supervised discriminant unfolded partial least squares (DU-PLS). The best discrimination was obtained with the supervised DU-PLS, which allowed the pairwise differentiation of the four pairs of investigated fibers.DU-PLS was then used to investigate weathering effects on the spectral features of cotton 400 pre-dyed with DB1, nylon 361 pre-dyed with AY17 and acrylic 864 pre-dyed with BG4. The investigated fibers were exposed to humid (Florida) and dry (Arizona) weathering conditions for three, six, nine and twelve months. In all cases, this algorithm was unable to differentiate non-exposed acrylic fibers from exposed acrylic fibers. DU-PLS was able to differentiate non-exposed cotton and nylon fibers from exposed fibers to Florida and Arizona weathering conditions. It was possible to determine the period of exposure to either Florida or Arizona conditions. It was also possible to discriminate between fibers exposed to Florida or Arizona weathering conditions for the same period of time. These results provide the foundation for future studies towards a non-destructive approach capable to provide information on the history of the fiber.
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Date Issued: 2016
Identifier: CFE0006838, ucf:51773
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006838

Title: Atomic-scale simulation of physical and chemical processes during space weathering and planet formation.
Creator: Quadery, Abrar, Schelling, Patrick, Britt, Daniel, Peale, Robert, Kara, Abdelkader, Sohn, Yongho, University of Central Florida
Abstract / Description: We investigate the mechanisms of space weathering and dust grain collisions, two topics of interests from planetary sciences, using atomic-scale simulations. Space weathering is the change in chemical and physical properties of minerals exposed to solar radiation and micrometeorite bombardment on surfaces of airless planetary bodies like the Moon and asteroids. An understanding of the connection between the surface evolution of the minerals and the underlying thermodynamic and kinetic factors...
Show moreWe investigate the mechanisms of space weathering and dust grain collisions, two topics of interests from planetary sciences, using atomic-scale simulations. Space weathering is the change in chemical and physical properties of minerals exposed to solar radiation and micrometeorite bombardment on surfaces of airless planetary bodies like the Moon and asteroids. An understanding of the connection between the surface evolution of the minerals and the underlying thermodynamic and kinetic factors is still missing. We address this issue and determine the time evolution of Frenkel defects in the silicate minerals olivine ((Mg,Fe)$_2$SiO$_4$) and orthopyroxene ((Mg,Fe)SiO$_3$) using molecular dynamics with a pair potential. Defect diffusion and clustering are observed in both the minerals. Cation diffusion occurs more readily in olivine than in orthopyroxene and leads to faster annealing in the former. In orthopyroxene, diffusion of anion defects, especially oxygen interstitials, occurs more rapidly and also exhibits anisotropy, which hinders the annealing process. This difference in defect evolution may explain the experimental observation that surface modifications due to irradiation is more pronounced in orthopyroxene than in olivine. Dust grain collision is the dominant process in the initial stage of planet formation, however, the mechanisms by which dust grains grow to larger aggregates and eventually to kilometer sized planetesimal is still not understood. We explore the role of surface chemistry in energy dissipation and grain adhesion during collision of amorphous silica (SiO$_2$) nanograins using molecular dynamics with a reactive potential, namely ReaxFF. We found nonhydroxylated amorphous silica nanoparticles stick with higher probability than their hydroxylated counterpart. This difference is attributed to the preponderance of unsatisfied dangling bonds on the dry silicate surface which facilitate bond formation during collision, and thereby provide a mechanism for energy dissipation. The speed below which sticking occurs in the dry nanograins is much higher than that found in Earth-based experiments, which suggests any experimental study of dust grain collision should take into account of the chemical environment. We probe into the nanograin collisions further and carry out atomistic simulatons of collisions of molten silica nanograins. We observed in the molten state, amorphous silica is more sticky than it is in the solid phase. This happens due to increased viscoelastic energy dissipation. The result may explain how rocky planets originated from the inner rings of the protoplanetay disks where temperatures were as high as $\sim$ 2000 K. In order to increase the range of materials that could be simulated with ReaxFF potential, and also to examine the different oxidation states of iron associated with nanophase iron formation during space weathering, we made attempt to develop ReaxFF potential for fayalite (Fe$_2$SiO$_4$). We found out fundamental limitations of ReaxFF model to describe three-component minerals. However, during the fitting process we developed a model for iron silicide (FeSi), and made attempt to improve the silica model to obtain better elastic properties. We report here the fitting processes and the observed limitations of ReaxFF model.
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Date Issued: 2017
Identifier: CFE0006907, ucf:51691
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006907

Title: Shock Tube and Mid-infrared Laser Absorption Measurements of Ignition Delay Times and Species Time-histories.
Creator: Koroglu, Batikan, Vasu Sumathi, Subith, Kapat, Jayanta, Kassab, Alain, Peale, Robert, University of Central Florida
Abstract / Description: Energy consumption has increased dramatically as the world advances and becomes more industrialized. Over the next twenty five years, the U.S. Department of Energy expects the energy demand to increase by 29% with majority of the new energy coming from natural gas (methane). Another promising fuel source for power generation and transportation is the biofuels. The biofuel use in the US is shown to have increased substantially in the last decade. There are serious environmental concerns...
Show moreEnergy consumption has increased dramatically as the world advances and becomes more industrialized. Over the next twenty five years, the U.S. Department of Energy expects the energy demand to increase by 29% with majority of the new energy coming from natural gas (methane). Another promising fuel source for power generation and transportation is the biofuels. The biofuel use in the US is shown to have increased substantially in the last decade. There are serious environmental concerns associated with greenhouse (e.g. carbon-dioxide) and toxic gas emissions (e.g. nitrogen oxides and aldehydes such as propanal) due to deriving energy from natural gas and biofuel combustion. In this doctoral study, a shock tube experimental setup was designed, assembled, and tested in order to study the ignition as well as thermal decomposition characteristics of two types of fuels: methane (the major natural gas component, which is also a major intermediate during higher order hydrocarbon ignition and pyrolysis) and propanal (an oxygenated hydrocarbon found in the exhaust emissions of biofuels). A laser diagnostics using semi-conductor type laser diodes in the infrared region for measurements of methane and propanal gas concentrations was developed and used with the shock tube. This diagnostics also enabled the interference-free detection of methane during the course of propanal pyrolysis. The experimental measurements highlighted the areas in which refinement of reaction kinetic models was required. The current research provided information on the ignition delay times as well as concentration time-histories of fuels (e.g. propanal or methane) and intermediates (e.g. methane). The knowledge gained during this doctoral study is vital for the accurate modeling of emissions due to combustion of fuels. The dissertation discusses the details of the four following items: 1) design, assembly, and testing of a shock tube setup as well as a laser diagnostics apparatus for studying ignition characteristics of fuels and associated reaction rates, 2) measurements of methane and propanal infrared spectra at room and high temperatures using a Fourier Transformed Infrared Spectrometer (FTIR) and a shock tube , 3) measurements of ignition delay times and reaction rates during propanal thermal decomposition and ignition, and 4) investigation of ignition characteristics of methane during its combustion in carbon-dioxide diluted bath gas. The main benefit and application of this work is the experimental data which can be used in future studies to constrain reaction mechanism development.
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Date Issued: 2016
Identifier: CFE0006533, ucf:51382
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006533

Title: Light Trapping in Thin Film Crystalline Silicon Solar Cells.
Creator: Boroumand Azad, Javaneh, Chanda, Debashis, Peale, Robert, Del Barco, Enrique, Flitsiyan, Elena, Schoenfeld, Winston, University of Central Florida
Abstract / Description: This dissertation presents numerical and experimental studies of a unified light trapping approach that is extremely important for all practical solar cells. A 2D hexagonal Bravais lattice diffractive pattern is studied in conjunction with the verification of the reflection mechanisms of single and double layer anti-reflective coatings in the broad range of wavelength 400 nm - 1100 nm. By varying thickness and conformity, we obtained the optimal parameters which minimize the broadband...
Show moreThis dissertation presents numerical and experimental studies of a unified light trapping approach that is extremely important for all practical solar cells. A 2D hexagonal Bravais lattice diffractive pattern is studied in conjunction with the verification of the reflection mechanisms of single and double layer anti-reflective coatings in the broad range of wavelength 400 nm - 1100 nm. By varying thickness and conformity, we obtained the optimal parameters which minimize the broadband reflection from the nanostructured crystalline silicon surface over a wide range of angle 0(&)deg;-65(&)deg;. While the analytical design of broadband, angle independent anti-reflection coatings on nanostructured surfaces remains a scientific challenge, numerical optimization proves a viable alternative, paving the path towards practical implementation of the light trapping solar cells. A 3 (&)#181;m thick light trapping solar cell is modeled in order to predict and maximize combined electron-photon harvesting in ultrathin crystalline silicon solar cells. It is shown that the higher charge carrier generation and collection in this design compensates the absorption and recombination losses and ultimately results in an increase in energy conversion efficiency. Further, 20 (&)#181;m and 100 (&)#181;m thick functional solar cells with the light trapping scheme are studied. The efficiency improvement is observed numerically and experimentally due to photon absorption enhancement in the light trapping cells with respect to a bare cell of same thickness.
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Date Issued: 2017
Identifier: CFE0006936, ucf:51654
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006936

Title: Exchange coupling in molecular magnets: Zero, one and three dimensions.
Creator: Amjad, Asma, Gonzalez Garcia, Enrique, Klemm, Richard, Peale, Robert, Hill, Stephen, University of Central Florida
Abstract / Description: Molecular magnets with different dimensionality, whether they are zero-dimensional single-molecule magnets (SMM) or one-dimensional single-chain magnets (SCM) are very interesting, since they allow probing the fundamental aspects bordering quantum and classical physics at the nanoscale level. This dissertation covers experimental studies of two Mn-based exchange-coupled molecule-based magnets and two Co-based single-chain magnets, using both dc Hall-effect magnetometry and electron paramagnet...
Show moreMolecular magnets with different dimensionality, whether they are zero-dimensional single-molecule magnets (SMM) or one-dimensional single-chain magnets (SCM) are very interesting, since they allow probing the fundamental aspects bordering quantum and classical physics at the nanoscale level. This dissertation covers experimental studies of two Mn-based exchange-coupled molecule-based magnets and two Co-based single-chain magnets, using both dc Hall-effect magnetometry and electron paramagnet resonance (EPR) techniques. In these multi-dimensional systems, the spin of the molecule exhibits quantum mechanical behavior at low temperature. It is quite interesting to observe the effect of magnetic exchange interactions on the magnetic properties of various complexes; hence they strongly affect the magnetic behavior.In this dissertation, the research is initiated with the study of low-magnetic-nuclearity molecules, starting with a spectroscopic study of a significantly anisotropic Mn(IV) monomer. At low temperature the molecule possesses easy-plane type anisotropy of a remarkable magnitude. Although the molecule is not a single-molecule magnet, the remarkable anisotropy can initiate synthesis of newer and better molecular magnets with Mn(IV) as the main building block. Furthermore, the interplay between the magnetic anisotropy and the inter-ion exchange interactions (J) within the molecule are probed for a dimer and a trimer where the magnetic core is comprised of two and three ions respectively. In the Mn-based case of the dimer, the low coupling between the atoms leads to significant state mixing, thus making it impossible to assign the individual spin states to the dimer or to the respective individual Mn(II) ions. In the case of the trimer, lowering of the symmetry achieved by fine tuning of the inter-ion exchange interactions leads to relieving of frustration in the antiferromagnetic (AF) triangular Mn(III) system, resulting in a well defined ground state and significant zero field splitting. Also a clear hysteretic behavior observed in this system demonstrates its SMM nature at low temperature. Finally, high-field high-frequency magnetic and spectroscopic studies performed on two cobalt-based SCMs reveal that formation of magnetic domains by exchange interactions within the chain are strongly influenced by thermal fluctuations. The chain possesses a uniaxial anisotropy with the quantization axis lying along the length of the chain. Moreover it is shown that modulation of the magnitude of inter- and intra-chain interactions results in a three-dimensional dynamics in one of the samples. Interestingly, detailed dc magnetic studies show a tunable crossover between one- and three-dimensional magnetic dynamics as a function of temperature and/or magnetic field sweep rate. Our voyage through several molecular systems of different dimensionality have allowed us to expand our understanding of the role of exchange interactions on the magnetic behavior in molecular magnetism.
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Date Issued: 2013
Identifier: CFE0004806, ucf:49723
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004806

Title: Characterization of gold black and its application in un-cooled infrared detectors.
Creator: Panjwani, Deep, Peale, Robert, Chow, Lee, Del Barco, Enrique, Schoenfeld, Winston, University of Central Florida
Abstract / Description: Gold black porous coatings were thermally evaporated in the chamber backfilled with inert gas pressure and their optical properties were studied in near-far-IR wavelengths. The porosities of coatings were found to be extremely high around ~ 99%. Different approaches of effective medium theories such as Maxwell-Garnett, Bruggeman, Landau-Lifshitz-Looyenga and Bergman Formalism were utilized to calculate refractive index (n) and extinction coefficient (k). The aging induced changes on...
Show moreGold black porous coatings were thermally evaporated in the chamber backfilled with inert gas pressure and their optical properties were studied in near-far-IR wavelengths. The porosities of coatings were found to be extremely high around ~ 99%. Different approaches of effective medium theories such as Maxwell-Garnett, Bruggeman, Landau-Lifshitz-Looyenga and Bergman Formalism were utilized to calculate refractive index (n) and extinction coefficient (k). The aging induced changes on electrical and optical properties were studied in regular laboratory conditions using transmission electron microscopy, Fourier transform infrared spectroscopy, and fore-probe electrical measurements. A significant decrease in electrical resistance in as deposited coating was found to be consistent with changes in the granular structure with aging at room temperature. Electrical relaxation model was applied to calculate structural relaxation time in the coatings prepared with different porosities. Interestingly, with aging, absorptance of the coatings improved, which is explained using conductivity form of Bergman Formulism. Underlying aim of this work was to utilize gold blacks to improve sensitivity in un-cooled IR sensors consist of pixel arrays. To achieve this, fragile gold blacks were patterned on sub-mm length scale areas using both stenciling and conventional photolithography. Infrared spectral imaging with sub-micron spatial resolution revealed the spatial distribution of absorption across the gold black patterns produced with both the methods. Initial experiments on VOx-Au bolometers showed that, gold black improved the responsivity by 42%. This work successfully establishes promising role of gold black coatings in commercial un-cooled infrared detectors.
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Date Issued: 2015
Identifier: CFE0005680, ucf:50197
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005680

Title: Two-photon absorption in bulk semiconductors and quantum well structures and its applications.
Creator: Pattanaik, Himansu, Vanstryland, Eric, Hagan, David, Delfyett, Peter, Schoenfeld, Winston, Peale, Robert, University of Central Florida
Abstract / Description: The purpose of this dissertation is to provide a study and possible applications of two-photon absorption (2PA), in direct-gap semiconductors and quantum-well (QW) semiconductor structures. One application uses extremely nondegenerate (END) 2PA, for mid-infrared (mid-IR) detection in uncooled semiconductors. The use of END, where the two photons have very different energies gives strong enhancement comapared to degenerate 2PA. This END-2PA enhanced detection is also applied to mid-IR imaging...
Show moreThe purpose of this dissertation is to provide a study and possible applications of two-photon absorption (2PA), in direct-gap semiconductors and quantum-well (QW) semiconductor structures. One application uses extremely nondegenerate (END) 2PA, for mid-infrared (mid-IR) detection in uncooled semiconductors. The use of END, where the two photons have very different energies gives strong enhancement comapared to degenerate 2PA. This END-2PA enhanced detection is also applied to mid-IR imaging and light detection and ranging (LIDAR) in uncooled direct-gap photodiodes. A theoretical study of degenerate 2PA (D-2PA) in quantum wells, QWs, is presented, along with a new theory of ND 2PA in QWs is developed. Pulsed mid-IR detection of femtosecond pulses is investigated in two different semiconductor p-i-n photodiodes (GaAs and GaN). With the smaller gap materials having larger ND-2PA, it is observed that they have better sensitivity to mid-IR detection, but unwanted background from D-2PA outweighs this advantage. A comparison of responsivity and signal-to-background ratio for GaAs and GaN in END-2PA based detection is presented. END-2PA enhancement is utilized for CW IR detection in uncooled GaAs and GaN p-i-n photodiodes. The pulsed mid-IR detection experiments are further extended to perform mid-IR imaging in uncooled GaN p-i-n photodetectors. A 3-D automated scanning gated imaging system is developed to obtain 3-D mid-IR images of various objects. The gated imaging system allows simultaneous 3-D and 2-D imaging of objects. The 3-D gated imaging system described in the dissertation could be used for examination of buried structures (microchannels, defects etc.) or laser written volumetric structures and could also be suitable for in-vivo imaging applications in biology in the mid-IR spectral region. As an example, 3-D imaging of buried semiconductor structures is presented.A theoretical study of D-2PA of QWs for transverse electric (TE) and transverse magnetic (TM) fields is carried out and an analytical expression for the D-2PA coefficient in QWs using second-order perturbation theory is derived. A theory for ND-2PA in QW semiconductor using second-order perturbation theory is developed for the first time and an analytical expression for the ND-2PA coefficient for TE, TM, and the mixed case of TE and TM is derived. The shape of the 2PA curve for the D-2PA and ND-2PA for QWs in the TE case is similar to that of bulk semiconductors. As governed by the selection rules both the D-2PA and ND-2PA curves for the TE case does not show a step-like signature for the density of states of the QWs whereas 2PA curve for the TM case shows such step like sharp features. The ND-2PA coefficient for TE, TM, and the mixed case is compared with that obtained for bulk semiconductors. Large enhancement in ND-2PA of QW semiconductors for the TM case over bulk semiconductors is predicted.
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Date Issued: 2015
Identifier: CFE0005684, ucf:50164
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005684

Title: TERAHERTZ AND SUB-TERAHERTZ TUNABLE RESONANT DETECTORS BASED ON EXCITATION OF TWO DIMENSIONAL PLASMONS IN InGaAs/InP HEMTs.
Creator: Nader Esfahani, Nima, Peale, Robert, Ishigami, Masa, Del Barco, Enrique, Buchwald, Walter, University of Central Florida
Abstract / Description: Plasmons can be generated in the two dimensional electron gas (2DEG) of grating-gated high electron mobility transistors (HEMTs). The grating-gate serves dual purposes, namely to provide the required wavevector to compensate for the momentum mismatch between the free-space radiation and 2D-plasmons, and to tune the 2DEG sheet charge density. Since the plasmon frequency at a given wavevector depends on the sheet charge density, a gate bias can shift the plasmon resonance. In some cases,...
Show morePlasmons can be generated in the two dimensional electron gas (2DEG) of grating-gated high electron mobility transistors (HEMTs). The grating-gate serves dual purposes, namely to provide the required wavevector to compensate for the momentum mismatch between the free-space radiation and 2D-plasmons, and to tune the 2DEG sheet charge density. Since the plasmon frequency at a given wavevector depends on the sheet charge density, a gate bias can shift the plasmon resonance. In some cases, plasmon generation results in a resonant change in channel conductance which allows a properly designed grating-gated HEMT to be used as a voltage-tunable resonant detector or filter. Such devices may find applications as chip-scale tunable detectors in airborne multispectral detection and target tracking.Reported here are investigations of InGaAs/InP-based HEMT devices for potential tunable resonant sub-THz and THz detectors. The HEMTs were fabricated from a commercial double-quantum well HEMT wafer by depositing source, drain, and semi-transparent gate contacts using standard photolithography processes. Devices were fabricated with metalized transmission gratings with multiple periods and duty cycles. For sub-THz devices, grating period and duty cycle were chosen to be 9 ?m and 22%, respectively; while they were chosen to be 0.5 ?m and 80% for the THz device. The gratings were fabricated on top of the gate region with dimensions of 250 ?m (&)#215; 195 ?m.The resonant photoresponse of the larger grating-period HEMT was investigated in the sub-THz frequency range of around 100 GHz. The free space radiation was generated by an ultra-stable Backward Wave Oscillator (BWO) and utilized in either frequency modulation (FM), or amplitude modulation (AM) experiments. The photoresponse was measured at 4K sample temperature as the voltage drop across a load resistor connected to the drain while constant source-drain voltages of different values, VSD, were applied. The dependence of such optoelectrical effect to polarization of the incident light, and applied VSD is studied. The results of AM and FM measurements are compared and found to be in agreement with the calculations of the 2D-plasmon absorption theory, however, a nonlinear behavior is observed in the amplitude and the line-shape of the photoresponse for AM experiments. For detection application, the minimum noise-equivalent-power (NEP) of the detector was determined to be 235 and 113 pW/Hz1/2 for FM and AM experiments, respectively. The maximum responsivity of the detector was also estimated to be ~ 200 V/W for the two experiments. The far-IR transmission spectra of the device with nanometer scale period was measured at 4 K sample temperature for different applied gate voltages to investigate the excitation of 2D-plasmon modes. Such plasmon resonances were observed, but their gate bias dependence agreed poorly with expectations.
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Date Issued: 2014
Identifier: CFE0005386, ucf:50461
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005386

Title: Field Theoretic Lagrangian Stencils from Off-Shell Supermultiplet Gauge Quotients.
Creator: Katona, Gregory, Klemm, Richard, Hubsch, Tristan, Peale, Robert, Shivamoggi, Bhimsen, University of Central Florida
Abstract / Description: Recent efforts to classify off-shell representations of supersymmetry without a central charge have focused upon directed, supermultiplet graphs of hypercubic topology known as Adinkras. These encodings of Super Poincare algebras, depict every generator of a chosen supersymmetry as a node-pair transformtion between fermionic / bosonic componentfields. This research thesis is a culmination of investigating novel diagrammatic sums of gauge quotients by supersymmetric images of other Adinkras,...
Show moreRecent efforts to classify off-shell representations of supersymmetry without a central charge have focused upon directed, supermultiplet graphs of hypercubic topology known as Adinkras. These encodings of Super Poincare algebras, depict every generator of a chosen supersymmetry as a node-pair transformtion between fermionic / bosonic componentfields. This research thesis is a culmination of investigating novel diagrammatic sums of gauge quotients by supersymmetric images of other Adinkras, and the correlated building of field theoretic worldline Lagrangians to accommodate both classical and quantum venues. We find Ref [40], that such gauge quotients do not yield other stand alone or (")proper(") Adinkras as afore sighted, nor can they be decomposed into supermultiplet sums, but are rather a connected (")Adinkraic network("). Their iteration, analogous to Weyl's construction for producing all finite-dimensional unitary representations in Lie algebras, sets off chains of algebraic paradigms in discrete-graph and continuous-field variables, the links of which feature distinct, supersymmetric Lagrangian templates. Collectively, these Adiankraic series air new symbolic genera for equation to phase moments in Feynman path integrals. Guided in this light, we proceed by constructing Lagrangians actions for the N = 3 supermultiplet YI /(iDI X) for I = 1, 2, 3, where YI and X are standard, Salam-Strathdee superfields: YI fermionic and X bosonic. The system, bilinear in the component fields exhibits a total of thirteen free parameters, seven of which specify Zeeman-like coupling to external background (magnetic) fluxes. All but special subsets of this parameter space describe aperiodic oscillatory responses, some of which are found to be surprisingly controlled by the golden ratio, ? ? 1.61803, Ref [52]. It is further determined that these Lagrangians allow an N = 3 ? 4 supersymmetric extension to the Chiral-Chiral and Chiral-twisted-Chiral multiplet, while a subset admits two inequivalent such extensions. In a natural progression, a continuum of observably and usefully inequivalent, finite-dimensional off-shellrepresentations of worldline N = 4 extended supersymmetry are explored, that are variatefrom one another but in the value of a tuning parameter, Ref [53]. Their dynamics turnsout to be nontrivial already when restricting to just bilinear Lagrangians. In particular, wefind a 34-parameter family of bilinear Lagrangians that couple two differently tuned supermultiplets to each other and to external magnetic fluxes, where the explicit parameter dependence is unremovable by any field redefinition and is therefore observable. This offers the evaluation of X-phase sensitive, off-shell path integrals with promising correlationsto group product decompositions and to deriving source emergences of higher-order background flux-forms on 2-dimensional manifolds, the stacks of which comprise space-time volumes. Application to nonlinear sigma models would naturally follow, having potential use in M- and F- string theories.
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Date Issued: 2013
Identifier: CFE0005011, ucf:50004
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005011

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