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Title: The effects of glucose and fatty acids on enhanced biological phosphorus removal using a sequencing batch reactor.
Creator: Khouri, Tarek Zaki, Randall, Andrew A., Engineering
Abstract / Description: University of Central Florida College of Engineering Thesis; Two anaerobic/aerobic sequencing batch reactors (SBRs) were used to evaluate enhanced biological phosphorus removal (EBPR). The first SBR, designated the Glucose SBR, was run for a period of four months. It received a synthetic wastewater plus glucose as a supplemental carbon source. The second SBR, the Isovaleric SBR, was run for three months. During the first month, isovaleric acid was its supplemental carbon source while for the...
Show moreUniversity of Central Florida College of Engineering Thesis; Two anaerobic/aerobic sequencing batch reactors (SBRs) were used to evaluate enhanced biological phosphorus removal (EBPR). The first SBR, designated the Glucose SBR, was run for a period of four months. It received a synthetic wastewater plus glucose as a supplemental carbon source. The second SBR, the Isovaleric SBR, was run for three months. During the first month, isovaleric acid was its supplemental carbon source while for the remaining time period, no supplemental carbon source was added to the feed. Steady-state data from the SBR receiving isovalerate yielded the highest phosphorus (P) removals observed during the study, with a mixed liquor volatile suspended solid (MLVSS) P content of 7.2%. The next highest removals were observed when prefermented glucose was received, which yielded a MLVSS P content of 6.4%. The lowest removals were observed when no supplemental carbon source was added to the SBR influent, with at 4.4% MLVSS P content. Batch experiments were also conducted to quantify the effect of EBPR of glucose and the volatile fatty acids (VFAs) acetic acid, propionic acid, valeric acid, and isovaleric acid. Compounds giving the largest anaerobic P release ultimately yielded the lowest effluent P concentrations. At 0.80 mmoles/l, isovaleric acid resulted in anaerobic P released 9.5 mg/l greater than an equal amount of glucose or propionic acid, but ultimately gave effluent P values roughly 4 mg/l lower than either. Ratios of aerobic P uptake/anaerobic P release were found to be roughly equal for all the VFAs when the VFAs were compared on a molar basis. Propionic acid had aerobic P uptake/anaerobic P release ratios similar to the other VFAs. It also behaved the same as all the other VFAs with respect to the effect of concentrations added to the batch experiment; however, the magnitude of its removal was significantly lower than all the other substrates. Glucose, on the other hand, behaved differently from all the VFAs. Glucose aerobic P uptake/anaerobic P release ratios varied with concentration, which was not the case for the others substrates. Also, glucose P net removals decreased at concentrations higher than 0.60 mmoles/l. Glucose also resulted in net P removals roughly 2mg/l higher than propionic acid, but ultimately gave lower net P removal than isovaleric, valeric and acetic acids.
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Date Issued: 1996
Identifier: CFR0010871, ucf:53053
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFR0010871

Title: EVALUATION OF PREFERMENTATION AS A UNIT PROCESS UPON BIOLOGICAL NUTRIENT REMOVAL INCLUDING BIOKINETIC AND WASTEWATER PARAMETERS.
Creator: McCue, Terrence, Randall, Andrew, University of Central Florida
Abstract / Description: The objective of this dissertation was to provide a controlled comparison of identical continuous flow BNR processes both with and without prefermentation in order to provide a stronger, more quantitative, technical basis for design engineers to evaluate the potential benefits of prefermentation to EBPR in treating domestic wastewater. In addition, the even less understood effect of prefermentation on denitrification kinetics and anoxic phosphorus (P) uptake was studied and quantified. Other...
Show moreThe objective of this dissertation was to provide a controlled comparison of identical continuous flow BNR processes both with and without prefermentation in order to provide a stronger, more quantitative, technical basis for design engineers to evaluate the potential benefits of prefermentation to EBPR in treating domestic wastewater. In addition, the even less understood effect of prefermentation on denitrification kinetics and anoxic phosphorus (P) uptake was studied and quantified. Other aspects of BNR performance, which might change due to use of prefermentation, will also be addressed, including anaerobic stabilization. Potential benefits to BNR processes derived from prefermentation are compared and contrasted with the more well-known benefits of primary clarification. Finally, some biokinetic parameters necessary to successfully model both the activated sludge systems and the prefermenter were determined and compared for the prefermented versus the non-prefermented system. Important findings developed during the course of this dissertation regarding the impact of prefermentation upon the performance of activated sludge treatment systems are summarized below: • For a septic COD-limited (TCOD:TP < 40:1) wastewater, prefermentation was found to enhance EPBR by 27.7% at a statistical significance level of alpha=0.05 (95% confidence level). • For septic P-limited (TCOD:TP > 40:1) wastewaters, prefermentation was not found to improve EBPR at a statistical significance level of alpha=0.05 (95% confidence level). • The increased anaerobic P release and aerobic P uptakes due to prefermentation correlated with greater PHA formation and glycogen consumption during anaerobiosis of prefermented influent. • Improvements in biological P removal of septic, non-P limited wastewater occurred even when all additional VFA production exceeded VFA requirements using typical design criteria (e.g. 6 g VFA per 1 g P removal). • Prefermentation increased RBCOD content by an average of 28.8% and VFA content by an average of 18.8%, even for a septic domestic wastewater. • Prefermentation increased specific anoxic denitrification rates for both COD-limited (14.6%) and P-limited (5.4%) influent wastewaters. This increase was statistically significant at alpha=0.05 for COD-limited wastewater, but not for P-limited wastewater.
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Date Issued: 2006
Identifier: CFE0001418, ucf:47052
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001418

Title: THE EFFECTS OF PH ON ENHANCED BIOLOGICAL PHOSPHORUS REMOVAL (EBPR) WITH PROPIONIC ACID AS THE DOMINANT VOLATILE FATTY ACID (VFA).
Creator: malekjahani, seyed, Randall, Andrew, University of Central Florida
Abstract / Description: pH control is a tool to improve some aspects of Enhanced Biological Phosphorus Removal (EBPR) process. Filipe et al (2001a, 2001b, and 2001c) found strong evidence that the stability of EBPR systems can be improved by increasing the pH of the anaerobic zone, thereby creating conditions where phosphorus-accumulating organisms (PAOs) are able to take up acetate faster than glycogen-accumulating organisms (GAOs). They explained this observation by comparing the growth rate of phosphorus...
Show morepH control is a tool to improve some aspects of Enhanced Biological Phosphorus Removal (EBPR) process. Filipe et al (2001a, 2001b, and 2001c) found strong evidence that the stability of EBPR systems can be improved by increasing the pH of the anaerobic zone, thereby creating conditions where phosphorus-accumulating organisms (PAOs) are able to take up acetate faster than glycogen-accumulating organisms (GAOs). They explained this observation by comparing the growth rate of phosphorus-accumulating organisms (PAOs) and glycogen-accumulating organisms (GAOs) and found that pH has little effect on PAOs growth rate but adversely affects GAOs growth rate when it increases (at pH values greater than 7.25, PAOs would take acetate faster than GAOs would). They used synthetic wastewater rich in acetic acid. In this study, we used real wastewater and the dominant volatile fatty acid available to microorganisms was propionic acid in continuous EBPR system. It was found that lower anaerobic zone pH (6.5 vs. 7.2) reduced the anaerobic P release both on an MLVSS specific basis and also on a non-specific (absolute value for the process) basis. In addition, the observed yield was significantly decreased. Aerobic P uptake was lower in the low-pH system (on a non-specific basis) due to the lower observed yield, and thus lower MLVSS concentration. Net P uptake was hard to interpret because of the effect of P release in the secondary clarifier of Train 2 (high pH). However, on a specific basis it was clear that net P uptake was either equal or better in the low-pH system regardless of how the secondary clarifier data was interpreted. Carbon transformations were not impacted in as consistent a fashion as anaerobic P release was. On a specific basis, PHA content remained unchanged although the PHV/PHB ratio was impacted with much lower PHV content in the low-pH system. Glycogen content and the amount of labile glycogen (delta glycogen) were higher in the low-pH system, in spite of the fact that MLVSS P content did not decrease. However, due to the impact of the low observed yield at low pH, absolute values resulted in higher PHA content for the process reactors as a whole, higher glycogen content, and unchanged labile glycogen. Low pH resulted in increased biomass P content, however the lower observed yield offset this on a process basis so that effluent P levels were nearly equal. So low pH improved P removal on a specific basis, but not on a process basis. Since it is unknown if the low observed yield is repeatable, and due to the impact of the secondary clarifier in the high pH system, it cannot be concluded that the effect of low pH on net P removal would be similar in other EBPR systems.
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Date Issued: 2006
Identifier: CFE0001433, ucf:47042
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001433

Title: EFFECTS OF REDUCED RAS AND VOLUME ON ANAEROBIC ZONE PERFORMANCE FOR A SEPTIC WASTEWATER BIOLOGICAL PHOSPHOROUS REMOVAL SYSTEM.
Creator: Magro, Daniel, Randall, Andrew, University of Central Florida
Abstract / Description: Enhanced Biological Phosphorous Removal (EBPR) performance was found to be adequate with reduced Return Activated Sludge (RAS) flows (50% of available RAS) to the anaerobic tank and smaller than typical anaerobic zone volume (1.08 hours hydraulic retention time or HRT). Three identical parallel biological nutrient removal (BNR) pilot plants were fed with strong, highly fermented (160 mg/L VFAs), domestic/industrial wastewater from a full scale wastewater treatment facility (WWTF). The pilot...
Show moreEnhanced Biological Phosphorous Removal (EBPR) performance was found to be adequate with reduced Return Activated Sludge (RAS) flows (50% of available RAS) to the anaerobic tank and smaller than typical anaerobic zone volume (1.08 hours hydraulic retention time or HRT). Three identical parallel biological nutrient removal (BNR) pilot plants were fed with strong, highly fermented (160 mg/L VFAs), domestic/industrial wastewater from a full scale wastewater treatment facility (WWTF). The pilot plants were operated at 100%, 50%, 40% and 25% RAS (percent of available RAS) flows to the anaerobic tank with the remaining RAS to the anoxic tank. In addition, varying anaerobic HRT (1.08 and 1.5 hours), and increased hydraulic loading (35% increase) was examined. The study was divided in four Phases, and the effect of these process variations on EBPR were studied by having one different variable between two identical systems. The most significant conclusions were that only bringing part of the RAS to the anaerobic zone did not decrease EBPR performance, instead changing the location of P release and uptake. Bringing less RAS to the anaerobic and more to the anoxic tank decreased anaerobic P release and increased anoxic P release (or decreased anoxic P uptake). Equally important is that with VFA rich influent wastewater, excessive anaerobic volume was shown to hurt overall P removal even when it resulted in increased anaerobic P release. Computer modeling with BioWin and UCTPHO was found to predict similar results to the pilot test results. Modeling was done with reduced RAS flows to the anaerobic zone (100%, 50%, and 25% RAS), increased anaerobic volume, and increased hydraulic loading. The most significant conclusions were that both models predicted EBPR did not deteriorate with less RAS to the anaerobic zone, in fact, improvements in EBPR were observed. Additional scenarios were also consistent with pilot test data in that increased anaerobic volume did not improve EBPR and increased hydraulic loading did not adversely affect EBPR.
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Date Issued: 2005
Identifier: CFE0000329, ucf:46285
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000329

Title: BENCH SCALE ANALYSIS OF EXPERIMENTAL FOULING-RESISTENT LOW PRESSURE REVERSE OSMOSIS MEMBRANES USING HIGH ORGANIC SURFACE WATER AND SYNTHETIC COLLOIDAL WATER.
Creator: Doan, Matthew, Randall, Andrew, University of Central Florida
Abstract / Description: The utilization of membrane treatment for the production of potable water has become more prevalent in today's industry. As drinking water regulations become more stringent this trend is expected to continue. Widespread use is also a result of membrane treatment being the best available treatment in many cases. While membrane treatment is a proven technology that can produce a consistently superior product to conventional treatment methods, membrane fouling and concentrate disposal are...
Show moreThe utilization of membrane treatment for the production of potable water has become more prevalent in today's industry. As drinking water regulations become more stringent this trend is expected to continue. Widespread use is also a result of membrane treatment being the best available treatment in many cases. While membrane treatment is a proven technology that can produce a consistently superior product to conventional treatment methods, membrane fouling and concentrate disposal are issues that drive up the cost of membrane treatment and can effectively eliminate it from consideration as a treatment alternative. This research focused on membrane fouling. A series of filtration experiments were conducted on various membranes to investigate the physical and chemical factors that influence fouling. The effects of both organic and colloidal fouling were explored by conducting research on various commercial membranes and experimental membranes by Saehan Industries, Inc. (Saehan). Saehan's membranes were in various stages of development in their process of creating a more fouling resistant membrane (FRM). Various hydrodynamic and chemical conditions were used to characterize the evolution of the Saehan commercial products to the experimental FRMs. The developmental stage of the membrane tested included analysis of the various trade secret coating techniques termed single, double, and special. A proprietary post-treatment process was also utilized in combination with each of the coating techniques. The developmental membranes were also compared to commercially available FRMs. The existing FRMs showed better fouling resistance than Saehan's commercially available products in high organic surficial groundwater testing. Synthetic colloidal water testing demonstrated the superior performance of the FRMs, but was not acute enough to differentiate the fouling performance within the group of FRMs or Saehan products. Average roughness decreased slightly as coating technique progressed from single to double to special. Post-treatment increased roughness in single coated membranes and reduced the roughness in double and special coated membranes. The relative charge differences in the developmental membranes were exhibited among non post-treated membranes. Post-treatment membranes did not demonstrate relative surface charge differences consistent with the manufacturer. Initial mass transfer coefficient, determined by clean water testing, increased as coating moved from single to double to special. Clean water testing showed increased initial mass transfer coefficient for membranes with post-treatment. Single coated membranes showed the best salt rejection capability among non post-treated membranes. Post-treatment increased selectivity for all membrane coating techniques. The coating effect on fouling potential had an inverse relationship between single coated versus double and special coated membranes. The post-treatment increased fouling resistance for the single coated membranes, but decreased fouling resistance of double and special coated membranes. The SN7 membranes showed the best performance of the developmental membranes.
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Date Issued: 2006
Identifier: CFE0001508, ucf:47123
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001508

Title: COMPARISON OF THM FORMATION DURING DISINFECTION: FERRATE VERSUS FREE CHLORINE FOR DIFFERENT SOURCE WATERS.
Creator: Mukattash, Adhem, Randall, Andrew, University of Central Florida
Abstract / Description: The objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition...
Show moreThe objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition samples were tested for Total Coliform Escherichia coli (TC/E.coli), and heterotrophic bacteria using HPC by spreadplating on R2A agar. Dissolved organic carbon (DOC) was measured as well. Dosages of 2, 5, and 10 ppm of hypochlorite and ferrate were used for Lake Claire and Atlantic Ocean water, while 1, 2, and 5 ppm dosages were used for wastewater treatment effluent. Ferrate resulted in 48.3% ± 11.2% less THM produced for the same level of disinfection (i.e. approximately 3 logs reduction in HPC). Oxidation of DOC was relatively small with a 6.1 to 11.6 % decrease in DOC being observed for ferrate doses from 2 to 10 mg/L. Free chlorine oxidation of DOC was negligible.
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Date Issued: 2007
Identifier: CFE0001734, ucf:47324
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001734

Title: BIOSTABILITY IN DRINKING WATER DISTRIBUTION SYSTEMS IN A CHANGING WATER QUALITY ENVIRONMENT USING CORROSION INHIBITORS.
Creator: Zhao, Bingjie, Randall, Andrew, University of Central Florida
Abstract / Description: In this study, the bacterial growth dynamics of 14 pilot drinking water distribution systems were studied in order to observe water quality changes due to corrosion inhibitor addition. Empirical models were developed to quantity the effect of inhibitor type and dose on bacterial growth (biofilm and bulk water). Water and pipe coupon samples were taken and examined during the experiments. The coupons were exposed to drinking water at approximately 20 °C for at least 5 weeks to allow the...
Show moreIn this study, the bacterial growth dynamics of 14 pilot drinking water distribution systems were studied in order to observe water quality changes due to corrosion inhibitor addition. Empirical models were developed to quantity the effect of inhibitor type and dose on bacterial growth (biofilm and bulk water). Water and pipe coupon samples were taken and examined during the experiments. The coupons were exposed to drinking water at approximately 20 °C for at least 5 weeks to allow the formation of a measurable quasi- steady-state biofilm. Bulk water samples were taken every week. In this study, two simple but practical empirical models were created. Sensitivity analysis for the bulk HPC model (for all 14 of the PDSs) showed that maintaining a chloramine residual at 2.6 mg/L instead of 1.1 mg/L would decrease bulk HPC by anywhere from 0.5 to 0.9 log, which was greater than the increase in bulk HPC from inhibitor addition at 0.31 to 0.42 log for Si and P based inhibitors respectively. This means that maintaining higher residual levels can counteract the relatively modest increases due to inhibitors. BF HPC was affected by pipe material, effluent residual and temperature in addition to a small increase due to inhibitor addition. Biofilm density was most affected by material type, with polyvinyl chloride (PVC) biofilm density consistently much lower than other materials (0.66, 0.92, and 1.22 log lower than lined cast iron (LCI), unlined cast iron (UCI), and galvanized steel (G), respectively). Temperature had a significant effect on both biofilm and bulk HPC levels but it is not practical to alter temperature for public drinking water distribution systems so temperature is not a management tool like residual. This study evaluated the effects of four different corrosion inhibitors (i.e. based on either phosphate or silica) on drinking water distribution system biofilms and bulk water HPC levels. Four different pipe materials were used in the pilot scale experiments, polyvinyl chloride (PVC), lined cast iron (LCI), unlined cast iron (UCI), and galvanized steel (G). Three kinds of phosphate based and one silica based corrosion inhibitors were added at concentrations typically applied in a drinking water distribution system for corrosion control. The data showed that there was a statistically significant increase of 0.34 log in biofilm bacterial densities (measured as HPC) with the addition of any of the phosphate based inhibitors (ortho-phosphorus, blended ortho-poly-phosphate, and zinc ortho-phosphate). A silica based inhibitor resulted in an increase of 0.36 log. The biological data also showed that there was a statistically significant increase in bulk water bacterial densities (measured as heterotrophic plates count, HPC) with the addition of any of the four inhibitors. For bulk HPC this increase was relatively small, being 15.4% (0.42 log) when using phosphate based inhibitors, and 11.0% (0.31 log) for the silica based inhibitor. Experiments with PDS influent spiked with phosphate salts, phosphate based inhibitors, and the silicate inhibitor showed that the growth response of P17 and NOx in the AOC test was increased by addition of these inorganic compounds. For this source water and the PDSs there was more than one limiting nutrient. In addition to organic compounds phosphorus was identified as a nutrient stimulating growth, and there was also an unidentified nutrient in the silica based inhibitor. However since the percentage increases due to inhibitors were no greater than 15% it is unlikely that this change would be significant for the bulk water microbial quality. In addition it was shown that increasing the chloramines residual could offset any additional growth and that the inhibitors could help compliance with the lead and copper rule. However corrosion inhibitors might result in an increase in monitoring and maintenance requirements, particularly in dead ends, reaches with long HRTs, and possibly storage facilities. In addition it is unknown what the effect of corrosion inhibitors are on the growth of coliform bacteria and opportunistic pathogens relative to ordinary heterotrophs. A method was developed to monitor precision for heterotrophic plate count (HPC) using both blind duplicates and lab replicates as part of a project looking at pilot drinking water distribution systems. Precision control charts were used to monitor for changes in assay variability with time just as they are used for chemical assays. In adapting these control charts for the HPC assay, it was determined that only plate counts ≥ 30 cfu per plate could be used for Quality Assurance (QA) purposes. In addition, four dilutions were used for all known Quality Control (QC) samples to insure counts usable for QC purposes would be obtained. As a result there was a 50% increase in the required labor for a given number of samples when blind duplicates and lab replicates were run in parallel with the samples. For bulk water HPCs the distributions of the duplicate and replicate data were found to be significantly different and separate control charts were used. A probability based analysis for setting up the warning limit (WL) and control limit (CL) was compared with the method following National Institute of Standard and Technology (NIST) guidelines.
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Date Issued: 2007
Identifier: CFE0001947, ucf:47452
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001947

Title: BIOSTABILITY IN DRINKING WATER DISTRIBUTION SYSTEMS: STUDY AT PILOT-SCALE.
Creator: LE PUIL, Michael, Randall, Andrew A., University of Central Florida
Abstract / Description: Biostability and related issues (e.g. nitrification) were investigated for 18 months in 18 pilot distribution systems, under various water quality scenarios. This study specifically investigated the impact of steady-state water changes on HPC levels in chlorinated and chloraminated distribution systems. Chlorination was more effective than chloramination in reducing HPC levels (1-2 log difference). There was a rapid increase in HPC corresponding to the change in steady-state water quality,...
Show moreBiostability and related issues (e.g. nitrification) were investigated for 18 months in 18 pilot distribution systems, under various water quality scenarios. This study specifically investigated the impact of steady-state water changes on HPC levels in chlorinated and chloraminated distribution systems. Chlorination was more effective than chloramination in reducing HPC levels (1-2 log difference). There was a rapid increase in HPC corresponding to the change in steady-state water quality, which was observed in all PDS. Modeling effort demonstrated that HPC levels reached a maximum within five days after water quality change and return to initial level ten days after the change. Since alkalinity was used as a tracer of the steady-state water quality change, time to reach maximum HPC was related to a mixing model using alkalinity as a surrogate that confirmed alkalinity transition was complete in approximately eight days.Biostability was assessed by HPC levels, since no coliform were ever detected. It was observed that HPC levels would be above four logs if residual droped below 0.1-0.2 mg/L as Cl2, which is below the regulatory minimum of 0.6 mg/L as Cl2. Therefore bacterial proliferation is more likely to be controlled in distribution systems as long as residual regulatory requirements are met. An empirical modeling effort showed that residual, pipe material and temperature were the most important parameters in controlling HPC levels in distribution systems, residual being the only parameter that can be practically used by utilities to control biological stability in their distribution systems. Use of less reactive (i.e. with less chlorine demand) pipes is recommended in order to prevent residual depletion and subsequent bacterial proliferation.This study is investigated biofilm growth simultaneously with suspended growth under a wide range of water quality scenarios and pipe materials. It was found that increasing the degree of treatment led to reduction of biofilm density, except for reverse osmosis treated groundwater, which exerted the highest biofilm density of all waters. Biofilm densities on corrodible, highly reactive materials (e.g. unlined cast iron and galvanized steel) were significantly greater than on PVC and lined cast iron. Biofilm modeling showed that attached bacteria were most affected by temperature and much less by HRT, bulk HPC and residual. The model predicts biofilms will always be active for environments common to drinking water distribution systems. As American utilities do not control biofilms with extensive and costly AOC reduction, American utilities must maintain a strong residual to maintain biological integrity and stability in drinking water distribution systems.Nitrite and nitrate were considered the most suitable indicators for utilities to predict onset of a nitrification episode in the distribution system bulk liquid. DO and ammonia were correlated to production of nitrite and nitrate and therefore could be related to nitrification. However since ammonia and DO consumptions can be caused by other phenomena than nitrification (e.g. oxidation by disinfectant to nitrite and reduction at the pipe wall, respectively), these parameters are not considered indicators of nitrification.Ammonia-Oxidizing Bacteria (AOB) densities in the bulk phase correlated well with nitrite and nitrate production, reinforcing the fact that nitrite and nitrate are good monitoring tools to predict nitrification. Chloramine residual proved to be helpful in reducing nitrification in the bulk phase but has little effect on biofilm densities. As DO has been related to bacterial proliferation and nitrification, it can be a useful and inexpensive option for utilities in predicting biological instability, if monitored in conjunction with residual, nitrite and nitrate. Autotrophic (i.e. AOB) and heterotrophic (i.e. HPC) organisms were correlated in the bulk phase and biofilms.
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Date Issued: 2004
Identifier: CFE0000111, ucf:46183
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000111

Title: DEGRADATION OF HALOGENATED ALIPHATIC COMPOUNDS IN SEQUENTIAL ANAEROBIC/AEROBIC METHANOGENIC AND HOMOACETOGENIC ENVIRONMENTS.
Creator: Hoxworth, Scott, Randall, Andrew, University of Central Florida
Abstract / Description: The objective of this study was to utilize an alternating anaerobic/aerobic sequence to biologically transform perchloroethylene to non-hazardous end products such as ethylene, CO2 and H2 using a single microbial consortia in a methanogenic and/or a homoacetogenic environment followed by a aerobic methanotrophic environment. Reductive dechlorination of PCE and TCE to cDCE and VC in an anaerobic environment is typically carried out by methanogens, sulfidogens, or homoacetogens but often (e.g....
Show moreThe objective of this study was to utilize an alternating anaerobic/aerobic sequence to biologically transform perchloroethylene to non-hazardous end products such as ethylene, CO2 and H2 using a single microbial consortia in a methanogenic and/or a homoacetogenic environment followed by a aerobic methanotrophic environment. Reductive dechlorination of PCE and TCE to cDCE and VC in an anaerobic environment is typically carried out by methanogens, sulfidogens, or homoacetogens but often (e.g. in-situ) leads to an accumulation of daughter compounds (cDCE, VC) which are more toxic than their parent compounds (PCE, TCE). Furthermore, PCE is resistant to degradation in aerobic environments while VC and cDCE are readily oxidized co-metabolically by aerobic methanotrophic bacteria, among others. In order to achieve complete mineralization of chlorinated solvents using a biotic system, an anaerobic/aerobic treatment strategy was investigated. This strategy has been accomplished successfully at a lab scale with anaerobic and aerobic reactors in series, and in-situ anaerobic zones with downgradient aerobic zones have been proposed in the field. In contrast, the focus of this research was to expose single mixed microbial consortia to sequential anaerobic/aerobic treatments in order to determine if reductive dechlorination could be sustained following aerobic phases of treatment. If possible this would imply that the anaerobic and aerobic zones (in-situ) or reactors (ex-situ) would not necessarily have to be spatially separated. In pure or dilute cultures where soil material is not present strict anaerobes would typically not resume metabolic activity if exposed to frequent aerobic phases of treatment. However in aquifer material or reactors with large floc/granules it might be possible due to the protection of anaerobic micro-environments as a result of diffusion limitations. Microcosms contained in sealed 120-mL serum bottles were used to generate experimental data including autoclaved abiotic controls with mercuric chloride. Inocula for these microcosms come from a several sources, including anaerobic digester sludge, soils, and contaminated aquifers. Once an experimental microcosm showed signs of reductive dechlorination, an aerobic treatment was implemented. The anaerobic phase of the microcosm was interrupted with a short duration aerobic phase. Headspace air or hydrogen peroxide addition was used to supply oxygen. Analytical data from the experiments indicated that anaerobic reductive dechlorination was readily accomplished during anaerobic phase experiments as PCE was sequentially dechlorinated to TCE and then to cDCE as reported in previous research reported by others in the literature. Additionally, a few mixed consortia microcosms showed evidence of further reductive dechlorination to VC and ethylene. During the sequential environment experiments, analytical data also indicated that reductive dechlorination also resumed after an aerobic sequence utilizing hydrogen peroxide as an oxidizer in the microcosm. No conclusive evidence was observed to indicate that aerobic degradation of cDCE during any of the aerobic phase treatments. This was probably due to the inocula not containing methanotrophs.
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Date Issued: 2004
Identifier: CFE0000282, ucf:46238
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000282

Title: EFFECTIVENESS AND KINETICS OF FERRATE AS ADISINFECTANT FOR BALLAST WATER.
Creator: Jessen, Andrea, Randall, Andrew, University of Central Florida
Abstract / Description: The introduction of aquatic nuisance species (ANS) and bacterial pathogens from discharge of ballast water by sea-faring vessels is an ongoing problem that threatens ecosystems and human health. This study investigates the disinfecting capability of ferrate in a marine environment on several organisms listed in international standards for ballast water management. Organisms were grown in a saline solution and were treated with dosages of ferrate ranging from 0.25-5.0 mg/l. A ferrate dose of 5...
Show moreThe introduction of aquatic nuisance species (ANS) and bacterial pathogens from discharge of ballast water by sea-faring vessels is an ongoing problem that threatens ecosystems and human health. This study investigates the disinfecting capability of ferrate in a marine environment on several organisms listed in international standards for ballast water management. Organisms were grown in a saline solution and were treated with dosages of ferrate ranging from 0.25-5.0 mg/l. A ferrate dose of 5 mg/l resulted in almost complete kill for all organisms tested. Smaller dosages have also been very effective, particularly if all organic material from the nutrient broth used to cultivate them is removed by washing the cells with saline solution. Ferrate appears to act very quickly, with tailing occurring after about 5-15 minutes. Analyses of the data with the CT approach, the Chick-Watson and Hom's models, and an oxidant demand equation derived from equations recommended by the Water Environment Federation (WEF) are in good agreement that ferrate concentration is more important than contact time. The Hom's model appeared to most accurately represent the action of ferrate on these organisms. Salinity and pH did not adversely affect results, and regrowth was not a problem. Two measures to reduce clumping did not eliminate the observed tailing effect, suggesting a different mechanism for this phenomena. These preliminary tests indicate that ferrate could be a very effective disinfectant in the treatment of ballast water, and the short half-life of ferrate is an advantage, since the ballast water is subsequently released into the environment.
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Date Issued: 2006
Identifier: CFE0001287, ucf:46891
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001287

Title: DECOLORIZATION OF AN AZO AND ANTHRAQUINONE TEXTILE DYE BY A MIXTURE OF LIVING AND NON-LIVING TRAMETES VERSICOLOR FUNGUS.
Creator: Dykstra, Christine, Randall, Andrew, University of Central Florida
Abstract / Description: Wastewater from the textile industry is difficult to treat effectively due to the prevalent use and wide variety of synthetic dyes that are resistant to conventional treatment methods. White-rot fungi, such as Trametes versicolor, have been found to be effective in decolorizing many of these synthetic dyes and current research is focusing on their application to wastewater treatment. Although numerous studies have been conducted on the ability of both living and nonliving Trametes versicolor...
Show moreWastewater from the textile industry is difficult to treat effectively due to the prevalent use and wide variety of synthetic dyes that are resistant to conventional treatment methods. White-rot fungi, such as Trametes versicolor, have been found to be effective in decolorizing many of these synthetic dyes and current research is focusing on their application to wastewater treatment. Although numerous studies have been conducted on the ability of both living and nonliving Trametes versicolor to separately decolorize textile dyes, no studies were found to have investigated the use of a mixture of live and dead fungus for decolorization. This study explored potential interactions between live and dead, autoclaved Trametes versicolor biomass in a mixed system by utilizing a series of batch tests with two structurally different synthetic textile dyes. Samples were analyzed by spectrophotometer and compared with controls to determine the effect of any interactions on decolorization. The results of this study indicate that an interaction between living and nonliving biomass occurred that affected the specific dye removal for both Reactive Blue 19, an anthraquinone textile dye, and Reactive Orange 16, an azo textile dye. This interaction was seen to improve the specific dye removal during the first 10-46 hours of experimentation but then diminish the specific dye removal after this period. This effect could be due to hydrophobins, which are surface-active proteins excreted by live fungi that may alter hydrophobicity. Additionally, the presence of adsorptive dead biomass could affect dye contact with degrading enzymes released from the live fungus. By expanding current knowledge of the interactions that take place in a fungal bioreactor and their effect on textile dye decolorization, this research aims to inspire more effective and less costly bioreactor designs for the treatment of textile wastewater.
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Date Issued: 2011
Identifier: CFH0003823, ucf:44720
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH0003823

Title: Evaluation of Biosorption Activated Media Under Roadside Swales for Stormwater Quality Improvement & Harvesting.
Creator: Hood, Andrew, Chopra, Manoj, Wanielista, Martin, Randall, Andrew, University of Central Florida
Abstract / Description: Stormwater runoff from highways is a source of pollution to surface water bodies and groundwater. This project develops a bio-detention treatment and harvesting system that is incorporated into roadside swales. The bio-detention system uses Bold & Gold(TM), a type of biosorption activated media (BAM), to remove nutrients from simulated highway runoff and then store the water in underground vaults for infiltration, controlled discharge, and/or irrigation and other non-potable applications. In...
Show moreStormwater runoff from highways is a source of pollution to surface water bodies and groundwater. This project develops a bio-detention treatment and harvesting system that is incorporated into roadside swales. The bio-detention system uses Bold & Gold(TM), a type of biosorption activated media (BAM), to remove nutrients from simulated highway runoff and then store the water in underground vaults for infiltration, controlled discharge, and/or irrigation and other non-potable applications. In order to design a bio-detention system, media characteristics and media/water quality relationships are required. Media characteristics determined through testing include: specific gravity, permeability, infiltration, maximum dry density, moisture content of maximum dry density, and particle-size distribution. One of the goals of this experiment is to compare the nitrogen and phosphorous species concentrations in the effluent of BAM to sandy soil for simulated highway runoff. Field scale experiments are done on an elevated test bed that simulates a typical roadway with a swale. The swale portion of the test bed is split into halves using BAM and sandy soil. The simulated stormwater flows over a concrete section, which simulates a roadway, and then over either sod covered sandy soil or BAM. One, one and a half, and three inch storms are each simulated three times with a duration of 30 minutes each. During the simulated storm event, initial samples of the runoff (influent) are taken. The test bed is allowed to drain for two hours after the rainfall event and then samples of each of the net effluents are taken. In addition to the field scale water quality testing, column tests are also preformed on the sandy soil and Bold & Gold(TM) without sod present. Sod farms typically use fertilizer to increase production, thus it is reasonable to assume that the sod will leach nutrients into the soils on the test bed, especially during the initial test runs. The purpose of the column tests is to obtain a general idea of what percentage removals of total phosphorus and total nitrogen are obtained by the sandy soil and Bold & Gold(TM). It is shown that the Bold & Gold(TM) media effluent has significantly lower concentrations of total nitrogen and total phosphorus compared to the effluent of the sandy soil based on an 80% confidence level. The Bold & Gold(TM) has a 41% lower average effluent concentration of total nitrogen than the sandy soil. The Bold & Gold(TM) media has a 78% lower average effluent concentration of total phosphorus than the sandy soil. Using both the column test data in combination with the field scale data, it is determined that the Bold & Gold(TM) BAM system has a total phosphorus removal efficiency of 71%. The removal efficiency is increased when stormwater harvesting is considered. A total phosphorus reduction of 94% is achieved in the bio-detention & harvesting swale system sample design problem.
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Date Issued: 2012
Identifier: CFE0004312, ucf:52869
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004312

Title: An Assessment of Biosorption Activated Media for the Removal of Pollutants in Up-Flow Stormwater Treatment Systems.
Creator: Hood, Andrew, Randall, Andrew, Wanielista, Martin, Chopra, Manoj, O'Reilly, Andrew, Moore, Sean, University of Central Florida
Abstract / Description: Nitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical...
Show moreNitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical in ultra-urban environments where above ground space is limited. Upflow filters utilizing biosorption activated media (BAM) that can be placed underground offer a small footprint alternative. Additionally, BAM upflow filters can be installed at the discharge point of traditional stormwater ponds to provide further treatment. This research simulated stormwater that had already been treated for solids removal; thus, most of the nutrients and solids in the influent were assumed to be as non-settable suspended solids or dissolved solids. Three different BAM mixtures in an upflow filter configuration were compared for the parameters of nitrogen, phosphorus, total coliform, E. coli, and heterotrophic plate count (HPC). Additionally, genetic testing was conducted using Polymerase Chain Reaction (PCR), in conjunction with a nitrogen mass balance, to determine if Anammox was a significant player in the nitrogen removal. The columns were run at both 22-minute and 220-minute Empty Bed Contact Times (EBCTs). All the BAM mixtures analyzed were shown to be capable at the removal of nitrogen, phosphorus, and total coliform during both the 22-minute and 220-minute EBCTs, with BAM #1 having the highest removal performance for all three parameters during both EBCTs. All BAM mixtures experienced an increase in HPC. Additionally, PCR analysis confirmed the presence of Anammox in the biofilm and via mass balance it was determined that the biological nitrogen removal was due to Anammox and endogenous denitrification with Anammox being a significant mechanism.
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Date Issued: 2019
Identifier: CFE0007817, ucf:52875
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007817

Title: Characterization of Florida Landfills with Elevated Temperatures.
Creator: Joslyn, Ryan, Reinhart, Debra, Lee, Woo Hyoung, Randall, Andrew, University of Central Florida
Abstract / Description: The occurrence of elevated temperatures within landfills is a very challenging issue for landfill operators to detect and correct. Little is known regarding the causes of elevated temperatures (ETs) and the number of landfills currently operating under such conditions. Therefore, the goal of this research was to determine which landfills within Florida have been impacted by ETs, and to develop a more complete understanding of the factors that may lead to these landfills becoming elevated...
Show moreThe occurrence of elevated temperatures within landfills is a very challenging issue for landfill operators to detect and correct. Little is known regarding the causes of elevated temperatures (ETs) and the number of landfills currently operating under such conditions. Therefore, the goal of this research was to determine which landfills within Florida have been impacted by ETs, and to develop a more complete understanding of the factors that may lead to these landfills becoming elevated temperature landfills (ETLFs). Historical landfill gas wellhead data, waste deposition reports, and landfill site geometry were collected for 27 landfill cells through the FDEP OCULUS database and from landfill operators and owners. These data were evaluated to quantify the statistical characteristics that result in landfills becoming 'elevated' in temperature. Gas data included landfill gas temperatures, methane content, carbon dioxide content, and balance gas readings. Waste deposition information was gathered through solid waste reports for each landfill. Landfill site geometry was found through landfill permits, topographical landfill diagrams, and annual operation reports. Furthermore, landfill maps were created in ArcGIS to observe spatial distribution of ETs in landfills over time.Upon analysis of the landfill gas wellhead data, it was discovered that 74% of studied landfill cells had ET readings; regulatory limits specify a maximum allowable gas temperature of 55 degrees C (131 degrees F). When studying the solid waste reports, it was discovered that 37% of landfill cells contained MSW ash; of these cells, 90% of them are considered ETLFs. Regarding site geometry, it was found that ETLF cells are on-average double the site area and approximately 20 feet deeper than the average non-ETLF cell. Furthermore, results suggest that heat propagation in most landfills is limited; however, heat propagation is possible if gas wells are turned off for an extensive time period.
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Date Issued: 2019
Identifier: CFE0007471, ucf:52690
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007471

Title: Harmful Algal Bloom Mitigation using Recycle Concrete Aggregate coated with Fixed-Quat.
Creator: Ezeodurukwe, Ikenna, Lee, Woo Hyoung, Randall, Andrew, Sadmani, A H M Anwar, University of Central Florida
Abstract / Description: Human activities generate surplus nutrients which may lead to algal bloom events in water resources along with serious ecological problems and thus substantial economic losses. Particularly, harmful algal blooms (HABs) represent toxic cyanobacterial blooms which produce cyanotoxins. The primary concerns of HABs are the exposures to a wide variety of cyanotoxins via ingestion of contaminated drinking water, inhalation during recreational activities, and consumption of contaminated fish and...
Show moreHuman activities generate surplus nutrients which may lead to algal bloom events in water resources along with serious ecological problems and thus substantial economic losses. Particularly, harmful algal blooms (HABs) represent toxic cyanobacterial blooms which produce cyanotoxins. The primary concerns of HABs are the exposures to a wide variety of cyanotoxins via ingestion of contaminated drinking water, inhalation during recreational activities, and consumption of contaminated fish and shellfish. However, conventional physical and chemical methods are not always possible to efficiently handle these HABs events. It is urgent to develop viable and rapid solutions to control HABs in field and mitigate the effects of HABs in fresh water, particularly in those that serve as sources of drinking water supply.(&)nbsp;Quaternary ammonium compounds (Quats) represent a wide range of cationic compounds with different formulation that constitutes products for agriculture, domestic and medical and industry. As organic antimicrobial compounds, Quats can be used as alternatives to existing chemical-based technique for HABs control due to its less toxicity and its affinity to variety of surface. In this study, recycled concrete aggregate (RCA) from a regional construction and demolition (C(&)D) waste recycling facility was used as a sustainable and environmentally friendly substrate and coated with a composite of silica-quaternary ammonium compounds (Fixed-Quat).(&)nbsp;Then, the algistatic capabilities of imparting antimicrobial properties of Quats to the RCA surface, which involve the covalent attachment of the biocides to the surfaces (sol-gel technique), were evaluated with HABs-causing algal species, Microcystis aeruginosa. Chlorophyll-a was measured to determine the efficiency of HABs mitigation using Fixed-Quat coated RCA in terms of photosynthetic inactivation of the selected algae. OD660 and pH were measured as key parameters to monitor algal cell growth and cement hydration. Notably, a 61% reduction of chlorophyll-a within 6 hours and complete removal of chlorophyll-a within 8 hours were achieved, indicating that Fixed-Quat coated RCA would be efficient in growth inhibition of Microcystis aeruginosa. Overall, with an appropriate design for field application and further evaluations like lifetime of Quat coating and potential recovery of treated algae, the Fixed-Quat antimicrobial coated RCA would be a promising and sustainable(&)nbsp;alternative to conventional HABs mitigation methods in various aquatic systems.
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Date Issued: 2018
Identifier: CFE0007400, ucf:52066
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007400

Title: Disinfection By-Product Reduction Study of a Small Central Florida Public Water System.
Creator: Staubus, Paul, Duranceau, Steven, Sadmani, A H M Anwar, Randall, Andrew, University of Central Florida
Abstract / Description: The disinfection of water for potabilization has proven to be one of the most significant public achievements of the 20th century. Although chemical disinfectants are successfully utilized to inactivate acute pathogenic organisms, they may react with natural organic matter (NOM) to produce potentially-harmful disinfection by-products (DBPs). As a result, the United States Environmental Protection Agency regulates DBPs such as total trihalomethanes (TTHMs) and haloacetic acids (HAAs). The...
Show moreThe disinfection of water for potabilization has proven to be one of the most significant public achievements of the 20th century. Although chemical disinfectants are successfully utilized to inactivate acute pathogenic organisms, they may react with natural organic matter (NOM) to produce potentially-harmful disinfection by-products (DBPs). As a result, the United States Environmental Protection Agency regulates DBPs such as total trihalomethanes (TTHMs) and haloacetic acids (HAAs). The research herein is focused on the formation, removal, and control of TTHMs and HAAs in a small public water system (PWS) in Polk County, Florida (County). Pilot-scale tests were implemented to determine the efficacy of stripping TTHMs using single-pass spray and recirculating tray aeration systems, both operating at flows of 3 gallons per minute. In the spray aerator evaluation, an average TTHM reduction of 29.5% was recorded. With tray aeration, a 46.7% reduction of TTHMs was observed after a single pass through the assembly. The benefits of additional recirculation appeared to decrease significantly after four passes, at a TTHM removal of 85.5%. A raw water blending effort was conducted to model bypass around granular activated carbon (GAC) adsorption vessels. The results demonstrated the feasibility of a 50% blend in full-scale treatment operations. With this blend, chlorine residuals and HAA concentrations were able to be controlled throughout 48 hours of incubation at 30(&)deg;C. From the data collected, a water quality plan was developed for the County's Waverly PWS. The plan to control the formation of DBPs integrated a recirculating tray aeration process for TTHM stripping complemented with GAC adsorption process for removing DBP precursors.The estimated conceptual operating cost was approximated at $24,000 annually. This cost considered carbon replacement as well as the recirculation pump operation. If the recommended 50% GAC bypass is applied, the conceptual operating cost reduces to approximately $15,250 annually.
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Date Issued: 2018
Identifier: CFE0007249, ucf:52175
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007249

Title: Construction and Demolition Debris Recovery and Recycling in Orange County, FL.
Creator: Toth, Michael, Reinhart, Debra, Behzadan, Amir, Randall, Andrew, University of Central Florida
Abstract / Description: In 2008, the State of Florida established a recycling goal of 75% to be achieved by 2020. In response to the Florida goal Orange County (OC), Florida has made the development and implementation of an efficient strategy for landfill diversion of its solid waste a top priority. The Florida Department of Environmental Protection (FDEP) estimated that 23% of municipal solid waste was generated by construction and demolition (C&D) activities in 2009, with only 30 percent of C&D debris being...
Show moreIn 2008, the State of Florida established a recycling goal of 75% to be achieved by 2020. In response to the Florida goal Orange County (OC), Florida has made the development and implementation of an efficient strategy for landfill diversion of its solid waste a top priority. The Florida Department of Environmental Protection (FDEP) estimated that 23% of municipal solid waste was generated by construction and demolition (C&D) activities in 2009, with only 30 percent of C&D debris being recycled. Therefore, OC decided to create a solid waste integrated resource plan (SWIRP) initially focused on the recovery and recycling of C&D materials (2010). For SWIRP development, OC decision makers need the best available data regarding C&D debris generation and composition and an understanding of the potential markets available for recycled materials. In this investigation debris generation was estimated over the period of 2001 to 2009 for the largest single governing body within OC, unincorporated OC (UOC), representing 65 percent of county population. The debris generation model was constructed for years 2001-2010 using area values for C&D activities in six sectors obtained from building permits and debris generation multipliers obtained from literature values. The benefit of the model is that as building permit information is received, debris generation estimations can also be expediently updated. Material composition fractions obtained from waste characterization studies of landfills in the Central Florida area were applied to the debris generation model resulting in a material composition for all sectors for years 2001-2010. The material composition of the debris stream was found to be, on average, concrete (53%) drywall (20%), wood (12%), a miscellaneous fraction (8%), asphalt roofing material (4%), metal (2%), cardboard (1%) and carpet and padding (1%). A market analysis was performed for concrete, drywall, wood, asphalt roofing shingles and residual screened materials (RSM). It was found that statewide, markets existed for 100 percent of the materials studied and could replace significant amounts of natural material feedstocks, but that the development of more local markets was vital to meeting OC's diversion goal to minimize the cost of transporting recyclables.
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Date Issued: 2012
Identifier: CFE0004241, ucf:52871
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004241

Title: Cost and Environmental Impacts of Leachate Nitrogen/Phosphorus Management Approaches.
Creator: Alanezi, Alaa, Reinhart, Debra, Randall, Andrew, Sadmani, A H M Anwar, University of Central Florida
Abstract / Description: Landfill leachate is a challenging wastewater to discharge into municipal wastewater treatment plants (WWTPs), the most common approach for leachate management, due to the presence of contaminants that may affect the performance of the treatment plant. Treatment, disposal, and transportation of leachate are expensive and therefore a concern. Currently, sidestream treatment is becoming increasingly common in WWTPs prior to returning the liquid to the plant influent. For this research, a new...
Show moreLandfill leachate is a challenging wastewater to discharge into municipal wastewater treatment plants (WWTPs), the most common approach for leachate management, due to the presence of contaminants that may affect the performance of the treatment plant. Treatment, disposal, and transportation of leachate are expensive and therefore a concern. Currently, sidestream treatment is becoming increasingly common in WWTPs prior to returning the liquid to the plant influent. For this research, a new treatment scheme is introduced combining centrate and leachate to reduce contaminants, recover phosphorous and nitrogen through struvite precipitation, and reduce energy requirements through anaerobic ammonium oxidation (Anammox). By combining the two waste streams, the respective limited nutrients (nitrogen in centrate and nitrogen in leachate) can be removed in a low cost chemical treatment resources can be recovered. Carbon contaminants and remaining nutrients can be removed in subsequent innovative biological treatment units. The objective of this thesis is to conduct a cost analysis and environmental assessment of the proposed novel treatment approach and to compare it to more traditional landfill on-site leachate treatment approaches (e.g., membrane bioreactors (MBR) and sequencing batch reactors (SBR)). The study was completed with the use of spreadsheet-based models. Spreadsheets have been developed to evaluate treatment costs (Capital + O(&)M) for both the proposed nutrient recovery/biological and traditional on-site leachate treatments. Transportation costs of leachate to the WWTP have been studied and analyzed by the use of a spreadsheet model as a function of distance. Results suggest that treatment using Struvite (-) Aerobic Granular Sludge (-) Anammox (SGA) was higher in cost compared to traditional approaches. However, positive outcomes from this process include: lower N_2 O emissions, lower power consumption, struvite fertilizer, and overall recovery of nitrogen and phosphorus with the combination of centrate and leachate.
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Date Issued: 2018
Identifier: CFE0007147, ucf:52310
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007147

Title: Electrochemical Microsensors for In Situ Monitoring of Chemical Compounds in Engineered and Natural Aquatic Systems.
Creator: Church, Jared, Lee, Woo Hyoung, Randall, Andrew, Duranceau, Steven, University of Central Florida
Abstract / Description: The adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20(&)#181;m) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using...
Show moreThe adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20(&)#181;m) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using conventional analytical tools. However, their applications have been primarily limited to understanding mass transport dynamics and kinetics in biofilms. With the advancement of sensor fabrication and utilization techniques, their potential applications can surpass conventional biofilm processes. In this dissertation, microsensors were utilized to elucidate mass transport and chemical reactions in multidisciplinary research areas including biological nutrient uptake, oily wastewater treatment, photocatalytic disinfection, and plant disease management, which have not yet explored using this emerging technology. The main objective of this work was to develop novel microsensors and use them for better understanding various natural and engineered aquatic systems. These include; 1) investigating localized photo-aeration and algal-bacterial symbiotic interaction in an advanced algal-bacterial biofilm process for nutrient removal from wastewater, 2) characterizing oil-in-water emulsions for better understanding bilge water emulsion stability, 3) evaluating sun-light driven photocatalytic reactions using a novel MoS2 nanofilm for water disinfection and microcystins-LR removal, 4) developing a zinc ion-selective microsensor and applying them for monitoring the transport of zinc in citrus trees, and 5) integrating heavy metal detection using anodic stripping voltammetry (ASV) in a microelectrode platform for plant applications.
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Date Issued: 2018
Identifier: CFE0007565, ucf:52576
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007565

Title: CO Florida 2012, A MOVES-Based, Near-Road, Screening Model.
Creator: Ritner, Mark, Cooper, Charles, Radwan, Ahmed, Randall, Andrew, University of Central Florida
Abstract / Description: Citizens in the United States are fortunate to have an excellent system of roadways and the affluence with which to afford automobiles. The flexibility of travel on demand for most allows for a variety of lifestyles, assists with conducting business, and contributes to the feeling of freedom that most citizens enjoy. The current vehicle fleet, which is primarily powered by internal combustion engines burning fossil fuels, does however contribute to the deterioration of air quality. This...
Show moreCitizens in the United States are fortunate to have an excellent system of roadways and the affluence with which to afford automobiles. The flexibility of travel on demand for most allows for a variety of lifestyles, assists with conducting business, and contributes to the feeling of freedom that most citizens enjoy. The current vehicle fleet, which is primarily powered by internal combustion engines burning fossil fuels, does however contribute to the deterioration of air quality. This effect is particularly significant in metropolitan areas. Motor vehicle exhausts contain several combustion bi-products that pose harmful effects to the environment and human health, in particular. The United States Environmental Protection Agency (EPA) and the Federal Highway Administration (FHWA) have selected carbon monoxide (CO) as the air pollutant on which it has based its guidelines for assessing potential air quality impacts from roadway construction (EPA 1992).The design of roadway networks must consider traffic flows, Level of Service (LOS), cost, and National Ambient Air Quality Standards (NAAQS) requirements. In light of the environmental standards it is necessary to model to estimate potential future near-road concentrations of CO. This modeling has two aspects, first determining the rate of pollutant emissions, and second determining how those pollutants disperse near the road. Obtaining a precise, realistic estimate of the near-road CO concentrations under a wide variety of weather and traffic patterns is a potentially huge undertaking. With budgetary constraints in mind, the development of a screening model is appropriate. CO Florida 2012 (COFL2012) is such a model that uses conservative assumptions to predict worst-case, near-road CO concentration. Projects that pass a COFL2012 model run do not require additional air quality modeling. Projects that fail a COFL2012 model run, however, may still be viable, but will require additional, detailed modeling and possibly project modifications.COFL2012 uses tables of emission factors (EFs) that were derived from numerous runs of the EPA's MOtor Vehicle Emission Simulator (MOVES2010a), which is indicated as the preferred model for near-road modeling of CO.(EPA 2009) COFL2012 then inputs the EFs, along with assumed link configurations, geographical assumptions, and user-inputted traffic information into input files that are run through CAL3QHC Version 2.0 (CAL3QHC2), the EPA's approved near-road dispersion model (EPA 1995).COFL2012 is a brand new Florida CO screening model, written from scratch. This author has written the computer code for COFL2012 in Visual Basic, using Microsoft Visual Studios 2010. Visual Studios utilizes the .net Framework 4. COFL2012 is easy to learn, quick to operate, and has been written to allow for future updates simply and easily, whenever the EPA releases updates to the databases that feed MOVES2010a.
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Date Issued: 2012
Identifier: CFE0004233, ucf:49011
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004233

drinking water (4)	+ -
wastewater (4)	+ -
BAM (3)	+ -
BMP (3)	+ -
Phosphorus (3)	+ -

biomass (3)	+ -
phosphorus removal (3)	+ -
Biosorption Activated Media (2)	+ -
Bold & Gold (2)	+ -
CAL3QHC (2)	+ -
Corrosion (2)	+ -
Dissolved Organic Nitrogen (2)	+ -
E. coli (2)	+ -
EBPR (2)	+ -
Gasification (2)	+ -
HAA (2)	+ -
HPC (2)	+ -
LID (2)	+ -
Landfill leachate (2)	+ -
MOVES (2)	+ -
Nanofiltration (2)	+ -
Nitrogen (2)	+ -
Recycling (2)	+ -
Reverse Osmosis (2)	+ -
Stormwater management (2)	+ -
THM (2)	+ -
THMs (2)	+ -
biofilm (2)	+ -
biological nutrient removal (2)	+ -
conventional treatment (2)	+ -

ETD Collection (58)	+ -
Honors Collection (1)	+ -

University of Central Florida (58)	+ -
Randall, Andrew (56)	+ -
Duranceau, Steven (20)	+ -
Chopra, Manoj (9)	+ -
Lee, Woo Hyoung (9)	+ -

Yestrebsky, Cherie (9)	+ -
Cooper, Charles (7)	+ -
Wang, Dingbao (7)	+ -
Reinhart, Debra (6)	+ -
Wanielista, Martin (5)	+ -
Beazley, Melanie (4)	+ -
Cooper, David (4)	+ -
Sadmani, A H M Anwar (4)	+ -
Clausen, Christian (3)	+ -
Legron-Rodriguez, Tamra (3)	+ -
Zhang, Husen (3)	+ -
Zou, Shengli (3)	+ -
Bolyard, Stephanie (2)	+ -
Chang, Ni-bin (2)	+ -
Church, Jared (2)	+ -
Hood, Andrew (2)	+ -
Jimenez, Jose (2)	+ -
Mackie, Kevin (2)	+ -
Radwan, Ahmed (2)	+ -
Randall, Andrew A. (2)	+ -
Salamah, Sultan (2)	+ -
Santra, Swadeshmukul (2)	+ -
Alanezi, Alaa (1)	+ -
Almutairi, Adibah (1)	+ -
Bartlett, Joseph (1)	+ -

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