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Molecular Size Distributions of Heavy Metals in Lake Washington
Title
Molecular Size Distributions of Heavy Metals in Lake Washington.
Creator
Andrews, William B., Taylor, James S., Engineering
Abstract / Description
University of Central Florida College of Engineering Thesis; Four untreated and one magnesium treated water samples from Lake Washington, the potable water source for the city of Melbourne, Florida, were collected and analyzed for As, Cd, Cr, Cu, Fe, Pb, Ni, Zn, Mb, Ca, and color on the basis of molecular weight distribution. Molecular weight distributions of the samples were obtained using a Millipore ultrafiltration system and filters in the following sizes: 106, 105, 2.5 x 104, 104, and...
Show moreUniversity of Central Florida College of Engineering Thesis; Four untreated and one magnesium treated water samples from Lake Washington, the potable water source for the city of Melbourne, Florida, were collected and analyzed for As, Cd, Cr, Cu, Fe, Pb, Ni, Zn, Mb, Ca, and color on the basis of molecular weight distribution. Molecular weight distributions of the samples were obtained using a Millipore ultrafiltration system and filters in the following sizes: 106, 105, 2.5 x 104, 104, and 103 nominal molecular weight limits (nmwl). color causing materials in the untreated samples were found to be located in the molecular weight fraction greater than 2.5 x 104 nmwl. The majoity of the metals concentrations (approximately greater than 80%) were also found to be located in the molecular weight fraction greater than 2.5 x 104 nmwl. Analysis of the magnesium treated (for maximum color removal) sample showed higher concentrations of metals passing the respective filter sizes as opposed to the untreated samples indicating less complexation or smaller molecular complexes of the metals. Thus, a fairly strong correlation betwee heavy metals concentrations and colorin the Lake Washington samples was indicated.
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Date Issued
1979
Identifier
CFR0008138, ucf:52945
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFR0008138
The effect of varying temperature, flux and pretreatment on the microfiltration of Lake Michigan water
Title
The effect of varying temperature, flux and pretreatment on the microfiltration of Lake Michigan water.
Creator
Kopp, Karen Linda, Taylor, James S., Engineering
Abstract / Description
University of Central Florida College of Engineering Thesis; This study investigated microfiltration of Lake Michigan Water for the production of drinking water. A 60 gpm Memcor microfiltration pilot plant was operated for nine months at Manitowoc, Wisconsin to determine and model the performance characteristics of a microfiltration pilot plant for varying surface water conditions. Statistical regression and modeling was used to determine and develop quantitative relationships between time of...
Show moreUniversity of Central Florida College of Engineering Thesis; This study investigated microfiltration of Lake Michigan Water for the production of drinking water. A 60 gpm Memcor microfiltration pilot plant was operated for nine months at Manitowoc, Wisconsin to determine and model the performance characteristics of a microfiltration pilot plant for varying surface water conditions. Statistical regression and modeling was used to determine and develop quantitative relationships between time of operation and several operational variables for water quality and productivity. Modifications of Darcy's Law and flux decline data were used to develop a model relating temperature and flux to cleaning frequency. Statistical hypothesis testing and associated modeling were used to determine if relationships existed between the water quality and the independent operating variables affecting microfiltration. The study demonstrated that the filtered water turbidity or particle count did not carry with the flux or the influent water temperature and that the degree of turbidity or particle count removal was dependent on the raw water turbidity or particle count. Direct filtration of an alum pretreated feed water was found to greatly increase time of operation between cleanings for temperatures below 48°F. As expected the size exclusion membrane process was found to have no effect on dissolved of diffusion controlled solute rejection. the investigation found the turbidity and particle counts of the microfiltered water was less than the same for the finished water produced by the conventional alum coagulation, sedimentation and filtration process. The investigation demonstrated that microfiltration could be used to consistently produce a drinking water that met or exceeded state or federal requirements at Manitowoc. Based on the results of this investigation, a recommendation was made to use microfiltration as the treatment process of choice for the treatment of Lake Michigan Water.
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Date Issued
1997
Identifier
CFR0010872, ucf:53052
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFR0010872
WATER QUALITY VARIATIONS DURING NITRIFICATION IN DRINKING WATER DISTRIBUTION SYSTEMS
Title
WATER QUALITY VARIATIONS DURING NITRIFICATION IN DRINKING WATER DISTRIBUTION SYSTEMS.
Creator
Webb, David W, Taylor, James S., University of Central Florida
Abstract / Description
This thesis documents the relationship among the major water quality parametersduring a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilotdrinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1Cl2:NH3-N. Surface, ground and sea water were treated and disinfected withmonochloramines to produce finished water quality similar to regional utility water quality.PVC, galvanized, unlined cast iron and lined iron pipes were...
Show moreThis thesis documents the relationship among the major water quality parametersduring a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilotdrinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1Cl2:NH3-N. Surface, ground and sea water were treated and disinfected withmonochloramines to produce finished water quality similar to regional utility water quality.PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regionaldistribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSswere operated at a 5-day hydraulic residence time (HRT) and ambient temperatures.As seasonal temperatures increased the rate of monochloramine dissipation increaseduntil effluent PDS residuals were zero. PDSs effluent water quality parameters chloraminesresidual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogenspecies were monitored and found to vary as expected by stoichiometry associated withtheoretical biological reactions excepting alkalinity. Nitrification was confirmed in thePDSs. The occurrence in the PDSs was not isolated to any particular source water.Ammonia for nitrification came from degraded chloramines, which was common among allfinished waters. Consistent with nitrification trends of dissolved oxygen consumption,ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulkwater quality profiles. Trends of pH and alkalinity were less apparent. To controlnitrification: residual was increased to 4.5 mg/L as Cl2 at 5:1 Cl2:NH3-N dosing ratio, and theHRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achievedafter a 1 week free chlorine burn.
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Date Issued
2004
Identifier
CFE0000063, ucf:46118
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000063
EFFECT OF SOURCE WATER BLENDING ON COPPER RELEASE IN PIPE DISTRIBUTION SYSTEM: THERMODYNAMIC AND EMPIRICAL MODELS
Title
EFFECT OF SOURCE WATER BLENDING ON COPPER RELEASE IN PIPE DISTRIBUTION SYSTEM: THERMODYNAMIC AND EMPIRICAL MODELS.
Creator
Xiao, Weizhong, Taylor, James S., University of Central Florida
Abstract / Description
This dissertation focuses on copper release in drinking water. Qualitative and quantitative assessment of Cu and Fe corrosion by process water quality was assessed over one year in a field study using finished waters produced from seven different treatment process and eighteen pilot distribution systems (PDSs) that were made from unlined cast iron and galvanized steel pipes, and lined cement and PVC pipes taken from actual distribution systems. Totally seven different waters were studied,...
Show moreThis dissertation focuses on copper release in drinking water. Qualitative and quantitative assessment of Cu and Fe corrosion by process water quality was assessed over one year in a field study using finished waters produced from seven different treatment process and eighteen pilot distribution systems (PDSs) that were made from unlined cast iron and galvanized steel pipes, and lined cement and PVC pipes taken from actual distribution systems. Totally seven different waters were studied, which consisted of three source waters: groundwater, surface, and simulated brackish water designated as G1, S1, and RO. With certain pre-established blending ratios, these three waters were blended to form another three waters designated as G2, G3, and G4. Enhanced surface water treatment was CFS, ozonation and GAC filtration, which was designated as S1. The CFS surface water was nanofiltered, which is S2. All seven finished waters were stabilized and chloraminated before entering the PDSs. Corrosion potential was compared qualitatively and quantitatively for all seven waters by monitoring copper and iron release from the PDSs. This dissertation consists of four major parts.(1) Copper corrosion surface characterization in which the solid corrosion products formed in certain period of exposure to drinking water were tried to be identified with kinds of surface techniques. Surface characterization indicated that major corrosion products consists of cuprite (Cu2O) as major underneath corrosion layer and tenorite (CuO), cupric hydroxide (Cu(OH)2) on the top surface. In terms of dissolution/precipitation mechanism controlling the copper concentration in bulk solution, cupric hydroxide thermodynamic model was developed.(2) Theoretical thermodynamic models were developed to predict the copper release level quantitatively based on controlling solid phases identified in part (1). These models are compared to actual data and relative assessment is made of controlling solid phases. (3) Non-linear and linear regression models were developed that accommodated the release to total copper for varying water quality. These models were verified using independent data and provide proactive means of assessing and controlling copper release in a varying water quality environment. (4) Simulation of total copper release was conducted using all possible combinations of water quality produced by blending finished waters from ground, surface and saline sources, which involves the comparison of copper corrosion potentials among reverse osmosis, nanofiltration, enhanced coagulation, lime softening, and conventional drinking water treatment.
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Date Issued
2004
Identifier
CFE0000042, ucf:46069
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000042
MODELING OF MEMBRANE SOLUTE MASSTRANSFER IN RO/NF MEMBRANE SYSTEMS
Title
MODELING OF MEMBRANE SOLUTE MASSTRANSFER IN RO/NF MEMBRANE SYSTEMS.
Creator
Zhao, Yu, Taylor, James S., University of Central Florida
Abstract / Description
Five articles describing the impact of surface characteristics, and development of mass transfer models for diffusion controlled membrane applications are published in this dissertation. Article 1 (Chapter 3) describes the impact of membrane surface characteristics and NOM on membrane performance for varying pretreatment and membranes during a field study. Surface charge, hydrophobicity and roughness varied significantly among the four membranes used in the study. Membrane surface...
Show moreFive articles describing the impact of surface characteristics, and development of mass transfer models for diffusion controlled membrane applications are published in this dissertation. Article 1 (Chapter 3) describes the impact of membrane surface characteristics and NOM on membrane performance for varying pretreatment and membranes during a field study. Surface charge, hydrophobicity and roughness varied significantly among the four membranes used in the study. Membrane surface characteristics, NOM and SUVA measurements were used to describe mass transfer in a low pressure RO integrated membrane system. Inorganic and organic solute and water mass transfer coefficients were systematically investigated for dependence on membrane surface properties and NOM mass loading. Inorganic MTCs were accurately described by a Gaussian distribution curve. Water productivity, NOM rejection and inorganic rejection increased as membrane surface charge and NOM loading increased. Inorganic MTCs were also correlated to surface hydrophobicity and surface roughness. The permeability change of identical membranes was related to NOM loading, hydrophobicity and roughness. Organic fouling as measured by water, organic and inorganic mass transfer was less for membranes with higher hydrophilicity and roughness. Article 2 (Chapter 4) describes the development of a diffusion controlled solute mass transfer model to assess membrane performance over time. The changing mass transfer characteristics of four low-pressure reverse osmosis (LPRO) membranes was correlated to feed stream water quality in a 2000 hour pilot study. Solute mass transfer coefficients (MTCs) were correlated to initial solute MTCs, solute charge, feed water temperature, monochloramine loading and organic loading (UV254). The model can be used to predict cleaning frequency, permeate water quality and sensitivity of permeate water quality to variation of temperature, organic and monochloramine mass loading.Article 3 (Chapter 5) describes a comparison of the long standing method of assessing membrane performance (ASTM D 45160 and another approach using mass transfer coefficients (MTCs) from the homogenous solution diffusion model (HSDM) using a common data set, water productivity and standardized salt passage. Both methods were shown to provide identical assessments of water productivity, however different assessments of salt passage. ASTM D 4516 salt passage is normalized for pressure and concentration and does not show the effects of flux, recovery, temperature or specific foulants on salt passage. However the MTC HSDM method is shown to consider all those effects and can be easily used to predict membrane performance at different sites and times of operation, whereas ASTM D 45160 can not. The HSDM MTC method of membrane evaluation is more versatile for assessment of membrane performance at varying sites and changing operational conditions.Article 4 (Chapter 6) describes the development of a fully integrated membrane mass transfer model that considers concentration, recovery and osmotic pressure for prediction of permeate water quality and required feed stream pressures. Osmotic pressure is incorporated into the model using correction coefficients that are calculated from boundary conditions determined from stream osmotic pressures of the feed and concentrate streams. Comparison to homogenous solution diffusion model (HSDM) with and without consideration of osmotic pressure and verification of IOPM using independently developed data from full and pilot scale plants is presented. The numerical simulation and statistical assessment show that osmotic pressure corrected models are superior to none-osmotic pressure corrected models, and that IOPM improves model predictability.Article 5 (Chapter 7) describes the development and comparison of a modified solution diffusion model and two newly developed artificial neural network models to existing mechanistic or empirical model
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Date Issued
2004
Identifier
CFE0000026, ucf:52859
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000026