Current Search:   lifetime (x)

View All Items

  • CSV Spreadsheet
(1 - 10 of 10)
EFFECTS OF BOND COAT SURFACE PREPARATION ON THERMAL CYCLING LIFETIME AND FAILURE CHARACTERISTICS OF THERMAL BARRIER COATINGS
Title
EFFECTS OF BOND COAT SURFACE PREPARATION ON THERMAL CYCLING LIFETIME AND FAILURE CHARACTERISTICS OF THERMAL BARRIER COATINGS.
Creator
Liu, Jing, Sohn, Yong-ho, University of Central Florida
Abstract / Description
Thermal barrier coatings (TBCs) have been widely used in gas turbine engines to protect the underlying metal from high operating temperature so as to improve the durability of the components and enhance the engine efficiency. However, since the TBCs always operate in a demanding high-temperature environment of aircraft and industrial gas-turbine engines, a better understanding of this complex system is required to improve the durability and reliability.The objective of this study is to...
Show moreThermal barrier coatings (TBCs) have been widely used in gas turbine engines to protect the underlying metal from high operating temperature so as to improve the durability of the components and enhance the engine efficiency. However, since the TBCs always operate in a demanding high-temperature environment of aircraft and industrial gas-turbine engines, a better understanding of this complex system is required to improve the durability and reliability.The objective of this study is to investigate the effects of surface modification for the NiCoCrAlY bond coats on the thermal cycling lifetime and failure characteristics of TBCs. Parameters of modification for the bond coats included as-sprayed, barrel-finished, hand-polished and pre-oxidation heat treatment at 1100 C in =10-8 atm up to 4 hours, carried out prior to the electron beam physical vapor deposition (EB-PVD) of ZrO2-7wt% Y2O3 (7YSZ) ceramic topcoat. The resulting characteristics of the bond coat and the thermally grown oxide (TGO) scale were initially documented by surface roughness, phase constituents of the TGO scale, and residual stress of the TGO scale. The thermal cycling test consisted of 10-minute heat-up to 1121 C, 40-minute hold at 1121 C, and 10-minute forced air-quench. As-coated and thermally-cycled TBCs were characterized by optical profilometry (OPM), photo-stimulated luminescence spectroscopy (PSLS), optical microscopy, scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS), and scanning/transmission electron microscopy (TEM/STEM) equipped with high angle annular dark field (HAADF) and X-ray energy dispersive spectroscopy (XEDS). TBC specimens for TEM/STEM analysis were prepared by focused ion beam (FIB) in-situ lift-out (INLO) technique.Superior thermal cycling lifetime was observed for TBCs with as-sprayed bond coats regardless of pre-oxidation heat treatment, and TBCs with hand-polished bond coats only after pre-oxidation heat treatment. With pre-oxidation heat treatment, relative photostimulated luminescence intensity of the equilibrium ¦Á-Al2O3 increased. Thus, the improvement in TBC lifetime can be correlated with an increase in the amount of ¦Á-Al2O3 in the TGO scale, given a specific surface modification/roughness. The lifetime improvement due to pre-oxidation was particularly significant to TBCs with smooth hand-polished bond coats and negligible for TBCs with rough as-sprayed bond coats.Spallation-fracture paths depended on the lifetime of TBCs. Premature spallation of TBCs occurred at the interface between the YSZ and TGO. Longer durability can be achieved by restricting the fracture paths to the TGO/bond coat interface. Small particulate phase observed through the TGO scale was identified as Y2O3 (cubic) by diffraction analysis on TEM. While small addition of Y in the NiCoCrAlY bond coat helps the adhesion of the TGO scale, excessive alloying can lead to deleterious effects.
Show less
Date Issued
2004
Identifier
CFE0000097, ucf:46083
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000097
MODELING AND SIMULATION OF LONG TERM DEGRADATION AND LIFETIME OF DEEP-SUBMICRON MOS DEVICE AND CIRCUIT
Title
MODELING AND SIMULATION OF LONG TERM DEGRADATION AND LIFETIME OF DEEP-SUBMICRON MOS DEVICE AND CIRCUIT.
Creator
CUI, ZHI, Liou, Juin J., University of Central Florida
Abstract / Description
Long-term hot-carrier induced degradation of MOS devices has become more severe as the device size continues to scale down to submicron range. In our work, a simple yet effective method has been developed to provide the degradation laws with a better predictability. The method can be easily augmented into any of the existing degradation laws without requiring additional algorithm. With more accurate extrapolation method, we present a direct and accurate approach to modeling empirically the 0...
Show moreLong-term hot-carrier induced degradation of MOS devices has become more severe as the device size continues to scale down to submicron range. In our work, a simple yet effective method has been developed to provide the degradation laws with a better predictability. The method can be easily augmented into any of the existing degradation laws without requiring additional algorithm. With more accurate extrapolation method, we present a direct and accurate approach to modeling empirically the 0.18-ìm MOS reliability, which can predict the MOS lifetime as a function of drain voltage and channel length. With the further study on physical mechanism of MOS device degradation, experimental results indicated that the widely used power-law model for lifetime estimation is inaccurate for deep submicron devices. A better lifetime prediction method is proposed for the deep-submicron devices. We also develop a Spice-like reliability model for advanced radio frequency RF MOS devices and implement our reliability model into SpectreRF circuit simulator via Verilog-A HDL (Hardware Description Language). This RF reliability model can be conveniently used to simulate RF circuit performance degradation
Show less
Date Issued
2005
Identifier
CFE0000476, ucf:46360
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000476
MECHANISMS OF LIFETIME IMPROVEMENT IN THERMAL BARRIER COATINGS WITH HF AND/OR Y MODIFICATION OF CMSX-4 SUPERALLOY SUBSTRATES
Title
MECHANISMS OF LIFETIME IMPROVEMENT IN THERMAL BARRIER COATINGS WITH HF AND/OR Y MODIFICATION OF CMSX-4 SUPERALLOY SUBSTRATES.
Creator
Liu, Jing, Sohn, Yong ho, University of Central Florida
Abstract / Description
In modern turbine engines for propulsion and energy generation, thermal barrier coating (TBCs) protect hot-section blades and vanes, and play a critical role in enhancing reliability, durability and operation efficiency. In this study, thermal cyclic lifetime and microstructural degradation of electron beam physical vapor deposited (EB-PVD) Yttria Stabilized Zirconia (YSZ) with (Ni,Pt)Al bond coat and Hf- and/or Y- modified CMSX-4 superalloy substrates were examined. Thermal cyclic lifetime...
Show moreIn modern turbine engines for propulsion and energy generation, thermal barrier coating (TBCs) protect hot-section blades and vanes, and play a critical role in enhancing reliability, durability and operation efficiency. In this study, thermal cyclic lifetime and microstructural degradation of electron beam physical vapor deposited (EB-PVD) Yttria Stabilized Zirconia (YSZ) with (Ni,Pt)Al bond coat and Hf- and/or Y- modified CMSX-4 superalloy substrates were examined. Thermal cyclic lifetime of TBCs was measured using a furnace thermal cycle test that consisted of 10-minute heat-up, 50-minute dwell at 1135C, and 10-minute forced-air-quench. TBC lifetime was observed to improve from 600 cycles to over 3200 cycles with appropriated Hf- and/or Y alloying of CMSX-4 superalloys. This significant improvement in TBC lifetime is the highest reported lifetime in literature with similar testing parameters. Beneficial role of reactive element (RE) on the durability of TBCS were systematically investigated in this study. Photostimulated luminescence spectroscopy (PL) was employed to non-destructively measure the residual stress within the TGO scale as a function of thermal cycling. Extensive microstructural analysis with emphasis on the YSZ/TGO interface, TGO scale, TGO/bond coat interface was carried out by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning electron microscopy (STEM) as a funcion of thermal cycling including after the spallation failure. Focused ion beam in-situ lift-out (FIB-INLO) technique was employed to prepare site-specific TEM specimens. X-ray diffraction (XRD) and secondary ion mass spectroscopy (SIMS) were also employed for phase identification and interfacial chemical analysis. While undulation of TGO/bond coat interface (e.g., rumpling and ratcheting) was observed to be the main mechanism of degradation for the TBCs on baseline CMSX-4, the same interface remained relatively flat (e.g., suppressed rumpling and ratcheting) for durable TBCs on Hf- and/or Y-modified CMSX-4. The fracture paths changed from the YSZ/TGO interface to the TGO/bond coat interface when rumpling was suppressed. The geometrical incompatibility between the undulated TGO and EB-PVD YSZ lead to the failure at the YSZ/TGO interface for TBCs with baseline CMSX-4. The magnitude of copressive residual stress within the TGO scale measured by PL gradually decreased as a function of thermal cycling for TBCs with baseline CMSX-4 superalloy substrates. This gradual decrease corrsponds well to the undulation of the TGO scale that may lead to relaxation of the compressive residual stress within the TGO scale. For TBCs with Hf- and/or Y-modified CMSX-4 superalloy substrates, the magnitude of compressive residual stress within the TGO scale remained relatively constant throughout the thermal cycling, although PL corresponding to the stress-relief caused by localized cracks at the TGO/bond coat interface and within the TGO scale was observed frequently starting 50% of lifetime. A slightly smaller parabolic growth constant and grain size of the TGO scale was observed for TBCs with Hf- and/or Y- modified CMSX-4. Small monoclinic HfO2 precipitates were observed to decorate grain boundaries and the triple pointes within the alpha-Al2O3 scale for TBCs with Hf- and/or Y-modified CMSX-4 substrates. Segregation of Hf/Hf4+ at the TGO/bond coat interfaces was also observed for TBCs with Hf- and/or Y-modified CMSX-4 superalloys substrates. Adherent and pore-free YSZ/TGO interface was observed for TBCs with Hf- and/or Y-modified CMSX-4, while a significant amount of decohesion at the YSZ/TGO interface was observed for TBCs with baseline CMSX-4. The beta-NiAl(B2) phase in the (Ni,Pt)Al bond coat was observed to partially transform into gama prime-Ni3Al (L12) phase due to depletion of Al in the bond coat during oxidation. More importantly, the remaining beta-NiAl phase transformed into L10 martensitic phase upon cooling even though there was no significant difference in these phase transformations for all TBCs. Results from these microstructural observations are documented to elucidate mechanisms that suppress the rumpling of the TGO/bond coat interface, which is responsible for superior performance of EB-PVD TBCs with (Ni,Pt)Al bond coat and Hf- and/or Y-modified CMXS-4 superalloy.
Show less
Date Issued
2007
Identifier
CFE0001872, ucf:47382
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001872
INFLUENCE OF ELECTRON TRAPPING ON MINORITY CARRIER TRANSPORT PROPERTIES OF WIDE BAND GAP SEMICONDUCTORS
Title
INFLUENCE OF ELECTRON TRAPPING ON MINORITY CARRIER TRANSPORT PROPERTIES OF WIDE BAND GAP SEMICONDUCTORS.
Creator
Tirpak, Olena, Chernyak, Leonid, University of Central Florida
Abstract / Description
Minority carrier transport properties and the effects of electron irradiation/injection were studied in GaN and ZnO containing dopants known to form acceptor states deep within the materials' bandgap. Minority carrier diffusion length and lifetime changes were investigated using Electron Beam Induced Current (EBIC) method, cathodoluminescence spectroscopy, spectral photoresponse and persistent photoconductivity measurements. It is shown that electron irradiation by the beam of a scanning...
Show moreMinority carrier transport properties and the effects of electron irradiation/injection were studied in GaN and ZnO containing dopants known to form acceptor states deep within the materials' bandgap. Minority carrier diffusion length and lifetime changes were investigated using Electron Beam Induced Current (EBIC) method, cathodoluminescence spectroscopy, spectral photoresponse and persistent photoconductivity measurements. It is shown that electron irradiation by the beam of a scanning electron microscope results in a significant increase of minority carrier diffusion length. These findings are supported by the cathodoluminescence measurements that demonstrate the decay of near-band-edge intensity as a consequence of increasing carrier lifetime under continuous irradiation by the electron beam. Temperature-dependent measurements were used to determine the activation energies for the electron irradiation-induced effects. The latter energies were found to be consistent with the involvement of deep acceptor states. Based on these findings, the effects of electron irradiation are explained via the mechanism involving carrier trapping on these levels. Solid-state electron injection was also shown to result in a similar increase of minority carrier lifetime and diffusion length. Solid-state injection was carried out by applying the forward bias to a ZnO homojunction and resulted in a significant improvement of the peak photoresponse of the junction. This improvement was unambiguously correlated with the increase of the minority carrier diffusion length due to electron injection.
Show less
Date Issued
2007
Identifier
CFE0001710, ucf:47325
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001710
Fatigue Lifetime Approximation based on Quantitative Microstructural Analysis for Air Plasma Sprayed Thermal Barrier Coatings
Title
Fatigue Lifetime Approximation based on Quantitative Microstructural Analysis for Air Plasma Sprayed Thermal Barrier Coatings.
Creator
Bargraser, Carmen, Sohn, Yongho, An, Linan, Heinrich, Helge, University of Central Florida
Abstract / Description
The durability of thermal barrier coatings (TBCs) affects the life of the hot section engine components on which they are applied. Fatigue is the general failure mechanism for such components and is responsible for most unexpected failures; therefore it is desirable to develop lifetime approximation models to ensure reliability and durability.In this study, we first examined the microstructural degradation of air plasma sprayed ZrO2-8wt.%Y2O3 TBCs with a low-pressure plasma sprayed CoNiCrAlY...
Show moreThe durability of thermal barrier coatings (TBCs) affects the life of the hot section engine components on which they are applied. Fatigue is the general failure mechanism for such components and is responsible for most unexpected failures; therefore it is desirable to develop lifetime approximation models to ensure reliability and durability.In this study, we first examined the microstructural degradation of air plasma sprayed ZrO2-8wt.%Y2O3 TBCs with a low-pressure plasma sprayed CoNiCrAlY bond coat on an IN 738LC superalloy substrate. The durability of TBCs were assessed through furnace thermal cyclic tests carried out in air at 1100(&)deg;C with a 1-, 10-, and 50-hour dwell period, preceded by a 10-minute heat-up and followed by a 10-minute forced-air-quench. Failure mechanisms of the TBCs were thoroughly investigated through materials characterization techniques including: X-Ray Diffraction, Scanning Electron Microscopy, and Energy Dispersive X-Ray Spectroscopy.Quantitative microstructural analyses were then carried out to document the growth of the thermally grown oxide (TGO) scale, the depletion of the Al-rich ?-NiAl phase in the bond coat, and the population and growth of micro-cracks near the YSZ/bond coat interface. Trends in the TGO growth and the ?-phase depletion in the bond coat followed those of diffusion-controlled processes(-)parabolic growth of the TGO and exponential depletion of the ?-phase. Formation and propagation of cracks within the YSZ resulted in complete spallation of the YSZ topcoat from the bond-coated superalloy substrate.Evolution in these microstructural features was correlated to the lifetime of TBCs, which showed cracking within the YSZ to be the cause of failure; thus a lifetime approximation model was developed, via modification of Paris Law, based on the experimental data. The model predicted the TBC lifetime within 10% of the experimental lifetime.
Show less
Date Issued
2011
Identifier
CFE0004087, ucf:49145
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004087
Energy Efficient and Secure Wireless Sensor Networks Design
Title
Energy Efficient and Secure Wireless Sensor Networks Design.
Creator
Attiah, Afraa, Zou, Changchun, Chatterjee, Mainak, Wang, Jun, Yuksel, Murat, Wang, Chung-Ching, University of Central Florida
Abstract / Description
ABSTRACTWireless Sensor Networks (WSNs) are emerging technologies that have the ability to sense,process, communicate, and transmit information to a destination, and they are expected to have significantimpact on the efficiency of many applications in various fields. The resource constraintsuch as limited battery power, is the greatest challenge in WSNs design as it affects the lifetimeand performance of the network. An energy efficient, secure, and trustworthy system is vital whena WSN...
Show moreABSTRACTWireless Sensor Networks (WSNs) are emerging technologies that have the ability to sense,process, communicate, and transmit information to a destination, and they are expected to have significantimpact on the efficiency of many applications in various fields. The resource constraintsuch as limited battery power, is the greatest challenge in WSNs design as it affects the lifetimeand performance of the network. An energy efficient, secure, and trustworthy system is vital whena WSN involves highly sensitive information. Thus, it is critical to design mechanisms that are energyefficient and secure while at the same time maintaining the desired level of quality of service.Inspired by these challenges, this dissertation is dedicated to exploiting optimization and gametheoretic approaches/solutions to handle several important issues in WSN communication, includingenergy efficiency, latency, congestion, dynamic traffic load, and security. We present severalnovel mechanisms to improve the security and energy efficiency of WSNs. Two new schemes areproposed for the network layer stack to achieve the following: (a) to enhance energy efficiencythrough optimized sleep intervals, that also considers the underlying dynamic traffic load and (b)to develop the routing protocol in order to handle wasted energy, congestion, and clustering. Wealso propose efficient routing and energy-efficient clustering algorithms based on optimization andgame theory. Furthermore, we propose a dynamic game theoretic framework (i.e., hyper defense)to analyze the interactions between attacker and defender as a non-cooperative security game thatconsiders the resource limitation. All the proposed schemes are validated by extensive experimentalanalyses, obtained by running simulations depicting various situations in WSNs in orderto represent real-world scenarios as realistically as possible. The results show that the proposedschemes achieve high performance in different terms, such as network lifetime, compared with thestate-of-the-art schemes.
Show less
Date Issued
2018
Identifier
CFE0006971, ucf:51672
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006971
Thermally induced motion, collision and mixing of levitated droplets
Title
Thermally induced motion, collision and mixing of levitated droplets.
Creator
Davanlou, Ashkan, Kumar, Ranganathan, Cho, Hyoung Jin, Deng, Weiwei, Mansy, Hansen, Shivamoggi, Bhimsen, University of Central Florida
Abstract / Description
This dissertation investigates the motion of a levitated droplet experimentally and analytically against the Marangoni flow in an immiscible outer fluid at higher speeds than is possible currently. Based on our earlier experiments, when a droplet is released from a height of 1.5 (-) 4 times its diameter from the liquid surface, it can overcome the impact and stay levitated at the liquid-air interface due to the existence of an air gap between the droplet and the liquid film. In order to...
Show moreThis dissertation investigates the motion of a levitated droplet experimentally and analytically against the Marangoni flow in an immiscible outer fluid at higher speeds than is possible currently. Based on our earlier experiments, when a droplet is released from a height of 1.5 (-) 4 times its diameter from the liquid surface, it can overcome the impact and stay levitated at the liquid-air interface due to the existence of an air gap between the droplet and the liquid film. In order to explain this behavior of droplet traveling against the counter-current motion, we propose a simple approach: first, the Marangoni convection inside the thin film is considered without the droplet floating on the surface. By using a level-set method and solving the Navier-Stokes equation, the free surface velocity and deformation are calculated. Then, these quantities are used to solve for droplet velocity and drag coefficient simultaneously using a force balance. In order to compare the simulation results, experiments with levitated water droplets on an immiscible carrier liquid, FC-43, were conducted for various temperature gradients, and droplet velocities were measured at different locations using high-speed imaging. The experimental results are in good agreement with the developed theoretical model. For a Reynolds number range of 2-32, it is shown that the drag coefficients are up to 66% higher than those for the fully immersed sphere at the same Reynolds numbers. A correlation is proposed to calculate the drag coefficient of levitated droplets for various temperature drops across the channel.For the first time, it is shown that it is possible to realize the natural coalescence of droplets through Marangoni effect without any external stimulation, and deliver the coalesced droplet to a certain destination through the use of surface tension gradients. The effects of the various shapes and sizes upon collision are studied. Regions of coalescence and stretching separation of colliding droplets are delineated based on Weber number and impact number. The existence of the transition line between coalescence and stretching separation in this passive mode of transport is similar to what was observed in the literature for forced coalescence at significantly higher Weber numbers. It is also found that a thermocapillary environment improves the mixing process. In order to illustrate and quantify the mixing phenomenon, the dispensed droplets were made of potassium hydroxide and phenolphthalein which is used as a pH indicator. The experiments show the possibility to reach mixing rates as high as 74% within 120 ms. This study offers new insight to thermo-coalescence and demonstrates how natural coalescence could be used to transport, mix and collect biochemical assays more efficiently. The results of this research can be engineered to enhance the performance of self-cleaning surfaces and micro-total analysis systems ((&)#181;TAS), where sample transport, filtration, chemical reactions, separation and detection are of great interest.
Show less
Date Issued
2015
Identifier
CFE0006213, ucf:51106
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006213
Fluorescence Lifetime Imaging and Spectroscopy Aided Tracking of ZnO and CdS:Mn/ZnS/ N-acetyl cysteine (NAC) Quantum Dots in Citrus Plants
Title
Fluorescence Lifetime Imaging and Spectroscopy Aided Tracking of ZnO and CdS:Mn/ZnS/ N-acetyl cysteine (NAC) Quantum Dots in Citrus Plants.
Creator
Washington, Torus, Gesquiere, Andre, Rajaraman, Swaminathan, Zhai, Lei, University of Central Florida
Abstract / Description
In this thesis, we present an efficacious way of tracking nanoparticle movement in plant tissue through the use of fluorescence lifetime imaging (FLIM) and spectroscopy as well as a review of nanoparticle uptake in plants and the proposed mechanisms governing them. Given the increasing number of nanomaterials in agriculture and society as a whole, proper imaging tools and proactive measures must be taken to track nanoparticle movement in plant tissues and create infrastructure and products to...
Show moreIn this thesis, we present an efficacious way of tracking nanoparticle movement in plant tissue through the use of fluorescence lifetime imaging (FLIM) and spectroscopy as well as a review of nanoparticle uptake in plants and the proposed mechanisms governing them. Given the increasing number of nanomaterials in agriculture and society as a whole, proper imaging tools and proactive measures must be taken to track nanoparticle movement in plant tissues and create infrastructure and products to keep things sustainable and safe. Herein we report a ZnO comparable nanoparticle(-) a CdS:Mn/ZnS/ N-acetyl cysteine (NAC) quantum dot(-) which boasts longer lifetimes and suitable fluorescent properties above ZnO to properly delineate from plant tissue fluorescence of chlorophyll and cinnamic acids. In addition to FLIM mapping, quantum dot localization in plant vascular tissue was clearly seen and confirmed via characteristic emission spectra and time correlated single photon counting decay curves (TCSPC). Most quantum dots were seen to reside in the xylem. Plant age and structure was seen to affect uptake. QD size likely restricted extensive translocation. Inhibitive effects of QDs were likely water and mechanical stress. We surmise that travel of the cadmium quantum dots up the leaf and branch plant tissues is likely most governed by diffusion as the quantum dots bound to the cell structures create a diffusion gradient which aids travel up the leaf.
Show less
Date Issued
2017
Identifier
CFE0006820, ucf:51772
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006820
OPTICAL AND PHYSICAL PROPERTIES OF CERAMIC CRYSTAL LASER MATERIALS
Title
OPTICAL AND PHYSICAL PROPERTIES OF CERAMIC CRYSTAL LASER MATERIALS.
Creator
Simmons, Jed, Bass, Michael, University of Central Florida
Abstract / Description
Historically ceramic crystal laser material has had disadvantages compared to single crystal laser material. However, progress has been made in the last decade and a half to overcome the disadvantages associated with ceramic crystal. Today, because of the promise of ceramic crystal as a high power laser material, investigation into its properties, both physical and optical, is warranted and important. Thermal expansion was measured in this thesis for Nd:YAG (yttrium aluminum garnet) ceramic...
Show moreHistorically ceramic crystal laser material has had disadvantages compared to single crystal laser material. However, progress has been made in the last decade and a half to overcome the disadvantages associated with ceramic crystal. Today, because of the promise of ceramic crystal as a high power laser material, investigation into its properties, both physical and optical, is warranted and important. Thermal expansion was measured in this thesis for Nd:YAG (yttrium aluminum garnet) ceramic crystal using an interferometric method. The interferometer employed a spatially filtered HeNe at 633 nm wavelength. Thermal expansion coefficients measured for the ceramic crystal samples were near the reported values for single crystal Nd:YAG. With a similar experimental setup as that for the thermal expansion measurements, dn/dT for ceramic crystal Nd:YAG was measured and found to be slightly higher than the reported value for single crystal. Depolarization loss due to thermal gradient induced stresses can limit laser performance. As a result this phenomenon was modeled for ceramic crystal materials and compared to single crystals for slab and rod shaped gain media. This was accomplished using COMSOL Multiphysics, and MATLAB. Results indicate a dependence of the depolarization loss on the grain size where the loss decreases with decreased grain size even to the point where lower loss may be expected in ceramic crystals than in single crystal samples when the grain sizes in the ceramic crystal are sufficiently small. Deformation-induced thermal lensing was modeled for a single crystal slab and its relevance to ceramic crystal is discussed. Data indicates the most notable cause of deformation-induced thermal lensing is a consequence of the deformation of the top and bottom surfaces. Also, the strength of the lensing along the thickness is greater than the width and greater than that due to other causes of lensing along the thickness of the slab. Emission spectra, absorption spectra, and fluorescence lifetime were measured for Nd:YAG ceramic crystal and Yb:Lu2O3 ceramic crystal. No apparent inhomogeneous broadening appears to exist in the Nd:YAG ceramic at low concentrations. Concentration and temperature dependence effects on emission spectra were measured and are presented. Laser action in a thin disk of Yb:Y2O3 ceramic crystal was achieved. Pumping was accomplished with a fiber coupled diode laser stack at 938 nm. A slope efficiency of 34% was achieved with maximum output energy of 28.8 mJ/pulse.
Show less
Date Issued
2007
Identifier
CFE0001764, ucf:47273
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001764
DEVELOPMENT OF LUMINESCENT RUTHENIUM COMPLEXES FOR IN-VITRO FLUORESCENCE IMAGING OF ANGIOGENESIS WITH THE RGD PEPTIDE.
Title
DEVELOPMENT OF LUMINESCENT RUTHENIUM COMPLEXES FOR IN-VITRO FLUORESCENCE IMAGING OF ANGIOGENESIS WITH THE RGD PEPTIDE.
Creator
Victoria, Rosmery, Hinkle, Charles R., University of Central Florida
Abstract / Description
Herein we report the synthesis of an RGD-ruthenium bipyridine 2+ complex aimed at the detection of angiogenesis. Angiogenesis plays a critical role in many pathophysiological processes, such as tumor growth. The alpha v-integrins (alpha v beta 3, alpha v beta 5) are currently used as molecular targeting sites for anti-angiogenic therapies. The 2+ complex is an organometallic luminescent probe, which enables noninvasive, in vitro imaging of alpha v beta 3 expression. Peptides containing the...
Show moreHerein we report the synthesis of an RGD-ruthenium bipyridine 2+ complex aimed at the detection of angiogenesis. Angiogenesis plays a critical role in many pathophysiological processes, such as tumor growth. The alpha v-integrins (alpha v beta 3, alpha v beta 5) are currently used as molecular targeting sites for anti-angiogenic therapies. The 2+ complex is an organometallic luminescent probe, which enables noninvasive, in vitro imaging of alpha v beta 3 expression. Peptides containing the arginine-glycine-aspartic acid (RGD) sequence have been shown to bind strongly to the alpha v beta 3 integrin. The RuBpy probes are soluble in water, display long lifetimes, and are photochemically stable. These properties enable the Ru(tris-bpy) complexes to be useful in numerous applications in biophysical and cell biology. The 2+ complex was synthesized by combining the succinimidyl ester on the RuBpy complex with the lysine of the c(RGDfK) peptide. The results of the one-photon fluorescence bioimaging showed selective binding of the cyclic RGD to alpha v beta 3 integrin, which supports previous literature. The high luminescence intensity, long lifetimes, and low cell toxicity levels of dye 2+, illustrates the potential usage of this probe for future biological applications.
Show less
Date Issued
2012
Identifier
CFH0004234, ucf:44898
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFH0004234