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"BACK" TO THE FUTURE: AN EVALUATION OF MORPHOLOGICAL INTEGRATION IN KYPHOSIS
Title
"BACK" TO THE FUTURE: AN EVALUATION OF MORPHOLOGICAL INTEGRATION IN KYPHOSIS.
Creator
Ceuninck, Kristyna L, Starbuck, John, University of Central Florida
Abstract / Description
Morphological integration refers to the interdependence of two or more phenotypic structures. The morphological integration concept is based on the fact that parts of complex organisms do not vary randomly and instead display degrees of non-independence that are thought to occur from shared genetic or developmental origins, and/or functional demands. Integrated traits may develop, evolve, and be inherited together. One instance of morphological integration can be found between the vertebral...
Show moreMorphological integration refers to the interdependence of two or more phenotypic structures. The morphological integration concept is based on the fact that parts of complex organisms do not vary randomly and instead display degrees of non-independence that are thought to occur from shared genetic or developmental origins, and/or functional demands. Integrated traits may develop, evolve, and be inherited together. One instance of morphological integration can be found between the vertebral column and the skull. Due to the position of the skull resting atop of the vertebral column, posture may influence skull development and overall craniofacial morphology. Morphological integration within or between structures is typically statistically assessed by exploring correlation and covariation patterns among biological structures of interest. In this study, an analysis of morphological integration was carried out by studying covariation of morphometric measures from the vertebral column and craniofacial complex. Age- and sex-matched, de-identified computed tomography images of individuals with kyphosis spinal malformation (n = 15) and controls (n = 19) were acquired from Florida Hospital. It is hypothesized that the sample of individuals with kyphosis will exhibit statistically significant covariance differences relative to the control group for T6 vertebral and midfacial linear distance measurements. Anatomical landmarks were identified on the T6 thoracic vertebrae (n = 6) and the midfacial skeleton (n = 6), and XYZ coordinates were recorded for analysis. A subset of 10 individuals (5 kyphosis, 5 controls) individuals were measured on two occasions to assess reliability and measurement error. An Euclidean Distance Matrix Analysis (EDMA) of morphological integration was carried out on the entire sample by calculating correlation values for paired linear distance measurements (one vertebral and one midfacial) separately for the kyphosis and control samples (n = 225 for each sample). Next, EDMA calculated correlation differences and statistically assessed significance using a non-parametric bootstrap (1,000 resamples) and confidence interval testing (? ? 0.10). Only 35 of the 225 (15.56%) correlation differences were statistically significant. Patterns of variation among these significant correlation differences were explored by examining sample directionality of differences, sign patterns, and strengths. The relevance of these results to clinical and anthropological pursuits are discussed. Several recommendations for future investigations are made.
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Date Issued
2018
Identifier
CFH2000286, ucf:45812
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFH2000286
Study of the Effect of Surface Morphology on Mass Transfer and Fouling Behavior of Reverse Osmosis and Nanofiltration Membrane Processes
Title
Study of the Effect of Surface Morphology on Mass Transfer and Fouling Behavior of Reverse Osmosis and Nanofiltration Membrane Processes.
Creator
Fang, Yuming, Duranceau, Steven, Randall, Andrew, Wang, Dingbao, Yestrebsky, Cherie, University of Central Florida
Abstract / Description
Reverse osmosis (RO) and nanofiltration (NF) membranes are pressure driven, diffusion controlled process. The influence of surface characteristics on membrane process performance is considered significant and is not well understood. Current mass transport models generally assume constant mass transfer coefficients (MTCs) based on a homogeneous surface. This work evaluated mass transfer processes by incorporating surface morphology into a diffusion-based model assuming MTCs are dependent on...
Show moreReverse osmosis (RO) and nanofiltration (NF) membranes are pressure driven, diffusion controlled process. The influence of surface characteristics on membrane process performance is considered significant and is not well understood. Current mass transport models generally assume constant mass transfer coefficients (MTCs) based on a homogeneous surface. This work evaluated mass transfer processes by incorporating surface morphology into a diffusion-based model assuming MTCs are dependent on the thickness variation of the membrane's active layer. To mathematically create such a surface layer, Gaussian random vectors embedded in a software system (MATLAB) were used to generate a three-dimensional ridge and valley active layer morphologies. A (")SMOOTH(") script was incorporated to reduce the influence of outlying data and make the hypothetical surfaces visually comparable to the AFM images. A non-homogeneous solution diffusion model (NHDM) was then developed to account for surface variations in the active layer. Concentration polarization (CP) is also affected by this non-homogeneous surface property; therefore, the NHDM was modified by incorporating the CP factor. In addition, recent studies have shown that the membrane surface morphology influences colloidal fouling behavior of RO and NF membranes. With consideration of the spatial variation of the cake thickness along the membranes, a fouling model was established by assuming cake growth is proportional to the localized permeate flow. Flux decline was assumed to be controlled by the resistance of cake growth and accumulated particle back diffusion at the membrane surface.A series of simulations were performed using operating parameters and water qualities data collected from a full-scale brackish water reverse osmosis membrane water treatment plant. The membrane channel was divided into a thousand uniform slices and the water qualities were determined locally through a finite difference approach. Prediction of the total dissolved solid (TDS) permeate concentration using the model was found to be accurate within 5% to 15% as an average percentage of difference (APD) using the NHDM developed in this research work. A comparison of the NHDM and the modified NHDM for concentration polarization (CP) with the commonly accepted homogeneous solution diffusion model (HSDM) using pilot-scale brackish water RO operating data indicated that the NHDM is more accurate when the solute concentration in the feed stream is low, while the NHDMCP appears to be more predictive of permeate concentration when considering high solute feed concentration. Simulation results indicated that surface morphology affects the water qualities in the permeate stream. Higher salt passage was expected to occur at the valley areas when diffusion mass transfer would be greater than at the peaks where the thin-film membrane is thicker. A rough surface tends to increase the TDS accumulation on the valley areas, causing an enhanced osmotic pressure at the valleys of membrane.To evaluate the impact of surface morphology on RO and NF performance, fouling experiments were conducted using flat-sheet membrane and three different nanoparticles, which included SiO2, TiO2 and CeO2. In this study, the rate and extent of fouling was markedly influenced by membrane surface morphology. The atomic force microscopy (AFM) analysis revealed that the higher fouling rate of RO membranes compared to that of NF membranes is due to the inherent ridge-and-valley morphology of the RO membranes. This unique morphology increases the surface roughness, leading to particle accumulation in the valleys, causing a higher flux decline than in smoother membranes. Extended fouling experiments were conducted using one of the RO membranes to compare the effect of different particles on actual water. It was determined that membrane flux decline was not affected by particle type when the feed water was laboratory grade water. On the other hand, membrane flux decline was affected by particle type when diluted seawater served as the feed water. It was found that CeO2 addition resulted in the least observable flux decline and fouling rate, followed by SiO2 and TiO2. Fouling simulation was conducted by fitting the monitored flux data into a cake growth rate model. The model was discretized by a finite difference method to incorporate the surface thickness variation. The ratio of cake growth term (k_1) and particle back diffusion term (k_2) was compared in between different RO and NF membranes. Results indicate that k_2 was less significant for surfaces that exhibited a higher roughness. It was concluded that the valley areas of thin-film membrane surfaces have the ability to capture particles, limiting particle back diffusion.
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Date Issued
2013
Identifier
CFE0004837, ucf:49707
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004837
MICROSCOPIC ANALYSIS OF SYMPATHETIC AND PARASYMPATHETIC DISTRIBUTION, TERMINAL MORPHOLOGY, AND INTERACTION IN WHOLE-MOUNT ATRIA OF C57BL/6 MICE
Title
MICROSCOPIC ANALYSIS OF SYMPATHETIC AND PARASYMPATHETIC DISTRIBUTION, TERMINAL MORPHOLOGY, AND INTERACTION IN WHOLE-MOUNT ATRIA OF C57BL/6 MICE.
Creator
Harden, Scott, Cheng, Zixi (Jack), University of Central Florida
Abstract / Description
The sympathetic (SNS) and parasympathetic (PSNS) branches of the autonomic nervous system (ANS) innervate the heart, exerting excitatory and inhibitory influences (respectively) over cardiac functions (heart rate, AV conduction velocity, and contractility). However, the distribution and structure of SNS and PSNS innervation has not yet been well studied. Detailed characterization of the distributional organization and structural morphology of the SNS and PSNS in normal states is essential to...
Show moreThe sympathetic (SNS) and parasympathetic (PSNS) branches of the autonomic nervous system (ANS) innervate the heart, exerting excitatory and inhibitory influences (respectively) over cardiac functions (heart rate, AV conduction velocity, and contractility). However, the distribution and structure of SNS and PSNS innervation has not yet been well studied. Detailed characterization of the distributional organization and structural morphology of the SNS and PSNS in normal states is essential to the study of pathological autonomic remodeling. The present study utilized double immunohistochemical labeling techniques to examine tyrosine hydroxylase (TH) immunoreactive (IR) SNS and vesicular acetylcholine transporter (VAChT) IR PSNS axons and terminal structures in whole-mount atria of C57BL/6 mice. We found that: (1) The atria contain a dense network of ANS axons. TH-IR, VAChT-IR, and dual cholinergic/dopaminergic TH+VAChT-IR axons travel together in bundles on the epicardium before branching into differentiated terminal structures. (2) Parallel TH-IR and VAChT-IR axons often diverge from epicardial bundles and travel in parallel (less than 1μm apart) before forming terminal structures in the epicardium and myocardium. Such parallel SNS/PSNS axons interdigitize and have large alternating varicosities along their length adjacent to one other, suggesting possible antagonistic communication between both branches of the ANS at the prejunctional level. (3) Intrinsic cardiac ganglia (ICG) are targets for extrinsic sympathetic nerves which travel through ICG without forming large synaptic varicosities around cardiac principal neurons (PNs). (4) Small intensely fluorescent (SIF) cells (presumably chemoreceptors and/or interneurons) exist near SNS bundles, inside ICG, and in the epicardium unaccompanied by ganglia and nerve bundles. (5) The subpopulation of TH+VAChT-IR PNs within ICG form loose terminals in the atria and do not project to other PNs. (6) Both TH-IR and VAChT-IR axons innervate atrial vasculature. (7) TH-IR axons innervate fat pads adjacent to the heart. (8) SNS/PSNS parallelism is not exclusive to the atria. Similar structures exist in the esophagus, right ventricle, and small intestine. This study provides a novel and overall view of the innervation and interaction of the SNS and PSNS in the atria. This will underlie a foundation for future physiological, pharmacological, and anatomical studies of SNS/PSNS innervation, interaction, and remodeling in pathological states (such as aging, intermittent hypoxia and diabetes).
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Date Issued
2009
Identifier
CFE0002561, ucf:47647
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002561
THE EFFECT OF NEIGHBORHOOD SIZE AND MORPHOLOGY IN THE CHINESE LANGUAGE
Title
THE EFFECT OF NEIGHBORHOOD SIZE AND MORPHOLOGY IN THE CHINESE LANGUAGE.
Creator
Nguyen, Long, Sims, Valerie, University of Central Florida
Abstract / Description
The Neighborhood Size Effect (NSE), characterized as the effect in word determination based on changing one orthographic aspect of that word. The amount of words that can be created through such manipulation is called a neighborhood size (NS). Number of other factors such as frequency, how often a word appears and morphology, the combination of meaningful word units, have been suggested to have an overriding effect on NSE. In addition, there is a lack of research on NSE with non-alphabetical...
Show moreThe Neighborhood Size Effect (NSE), characterized as the effect in word determination based on changing one orthographic aspect of that word. The amount of words that can be created through such manipulation is called a neighborhood size (NS). Number of other factors such as frequency, how often a word appears and morphology, the combination of meaningful word units, have been suggested to have an overriding effect on NSE. In addition, there is a lack of research on NSE with non-alphabetical languages such as Chinese, which uses characters comprising of a multitude of semantic or phonetic markers. In this experiment, participants coming from mainland China were presented with 60 individual characters and 59 characters with Chinese morphology made up of two characters which form single words. Both conditions, were manipulated with NS by adjusting the semantic or phonetical radical within a character and with frequency by using a website that measures how frequent a character appeared within the language. Both character conditions were found to have a significant effect with frequency and neighborhood size (NS) with characters with higher frequency and lower NS found to have higher accuracy and lower reaction times. With low frequency single characters, it was that those with higher neighborhood size had greater delay in reaction time and lower accuracy. With low frequency morphologically constructed characters, it was found that lower neighborhood size had higher accuracy, but no significant result with regards to reaction time. Due to differing accuracy results with NS and character condition, it is suggested that further factors such as morphological processing in single characters and bigram frequency in morphologically constructed characters might have an effect on word determination in conjunction with neighborhood size. Thus, it is a possibility that Chinese morphological may depend more on other factors than neighborhood size.
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Date Issued
2016
Identifier
CFH2000098, ucf:45556
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFH2000098
ADAPTIVE RESPONSES OF BRANCHIAL MORPHOLOGY TO HYPOXIA IN THE NEOTROPICAL ELECTRIC FISH GENUS BRACHYHYPOPOMUS
Title
ADAPTIVE RESPONSES OF BRANCHIAL MORPHOLOGY TO HYPOXIA IN THE NEOTROPICAL ELECTRIC FISH GENUS BRACHYHYPOPOMUS.
Creator
Pathak, Leilani, Crampton, William, University of Central Florida
Abstract / Description
Many tropical aquatic environments worldwide are characterized by intermittent or prolonged hypoxia (low dissolved oxygen). Nevertheless, many tropical freshwater fishes are able to inhabit these challenging environments via a range of morphological, physiological and behavioral adaptations. Brachyhypopomus is a diverse genus of weakly electric fishes represented by 28 known species distributed from Panama to Argentina. 17 species are restricted to permanently normoxic habitats (blackwater...
Show moreMany tropical aquatic environments worldwide are characterized by intermittent or prolonged hypoxia (low dissolved oxygen). Nevertheless, many tropical freshwater fishes are able to inhabit these challenging environments via a range of morphological, physiological and behavioral adaptations. Brachyhypopomus is a diverse genus of weakly electric fishes represented by 28 known species distributed from Panama to Argentina. 17 species are restricted to permanently normoxic habitats (blackwater rivers and terra firme streams), eight species are restricted to seasonally or perennially hypoxic habitats (whitewater floodplains of large tropical rivers or permanent swampy habitats), and three species are eurytopic (occur in both seasonally hypoxic and normoxic habitats). These habitat distributions offer the opportunity to explore both species- and population-level variation in adaptive responses to hypoxia. Across 25 of the 28 known species in the genus (for which specimens were available), one- and two-way ANOVA was used to correlate total gill filament length (a metric of gill surface area) with lifestyle -divided into four categories: 1) stenotopic species (i.e. species occurring in a narrow range of habitats) restricted to hypoxic habitats; 2) stenotopic species restricted to normoxic habitats; 3) populations of eurytopic species from hypoxic habitats, and; 4) populations of eurytopic species from normoxic habitats. One-way ANOVA revealed that populations of eurytopic species from hypoxic habitats had significantly larger total gill filament lengths than stenotopic species from the same habitat (P = 0.0169). Likewise, populations of eurytopic from normoxic habitats had significantly larger total gill filament lengths than stenotopic species from normoxic habitats (P < 0.005). Two-way ANOVA showed that eurytopic species had significantly larger total gill filament lengths than stenotopic species, independent of the disparity in total gill filament length associated with either hypoxic or normoxic habitats. Results indicate a strong correlation between gill surface area and oxygen-habitat among species and populations, which supports the hypothesis that an enlarged gill surface area increases oxygen uptake and serves as an adaptive response to seasonal hypoxia.
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Date Issued
2011
Identifier
CFE0003651, ucf:48822
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0003651
IMAGING AND SPECTROSCOPY OF CONDUCTING POLYMER-FULLERENE COMPOSITE MATERIALS
Title
IMAGING AND SPECTROSCOPY OF CONDUCTING POLYMER-FULLERENE COMPOSITE MATERIALS.
Creator
Tenery, Daeri, Gesquiere, Andre, University of Central Florida
Abstract / Description
Since the development and optical study of conjugated (conducting) polymers it has become apparent that chain conformation and aggregation at the molecular scale result in complex heterogeneous nanostructured bulk materials for which a detailed insight into morphological, spectroscopic as well as optoelectronic properties and mechanisms is overwhelmingly difficult to obtain. Nanoparticles composed of the conjugated polymer poly (MEH-PPV) and nanocomposite nanoparticles consisting of MEH-PPV...
Show moreSince the development and optical study of conjugated (conducting) polymers it has become apparent that chain conformation and aggregation at the molecular scale result in complex heterogeneous nanostructured bulk materials for which a detailed insight into morphological, spectroscopic as well as optoelectronic properties and mechanisms is overwhelmingly difficult to obtain. Nanoparticles composed of the conjugated polymer poly (MEH-PPV) and nanocomposite nanoparticles consisting of MEH-PPV doped with 1-(3-methoxycarbonylpropyl)-1-phenyl-C61 (PCBM) were prepared as model systems to study these materials at the length scale of one to a few domains. The MEH-PPV and PCBM doped nanoparticles were analyzed by single imaging/particle spectroscopy (SPS) and revealed molecular scale information on the structure-property relationships of these composite materials. The data obtained from SPS were investigated in terms of spectral difference between doped and undoped nanoparticles. The doped nanoparticles are blue shifted by approximately 5-10 nm, have an additional blue shoulder, and show different vibronic structure than the undoped nanoparticles. Specifically, relative intensity of the 0-1 transition is lower than for the undoped nanoparticles. These data are indicative of differences in molecular order between both nanoparticle systems, detected at the molecular scale. In addition, the effect of electrical fields present in devices on the interfacial charge transfer properties was evaluated. Furthermore, these nanoparticles were incorporated into the lipid nanotubes to study the diffusion process of the single MEH-PPV nanoparticles inside the lipid nanotubes. Our data shows a clear proof of concept that diffusion of nanoparticles inside the hollow lipid nanotubes can be studied on a single particle basis, which will allow us to study diffusion processes quantitatively and mechanistically within the framework of developing a biocompatible drug and gene delivery platform.
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Date Issued
2009
Identifier
CFE0002708, ucf:48155
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002708
Developing Methods for the Estimation of Stature and their Use as a Proxy for Health among the Ancient Chachapoya of Peru
Title
Developing Methods for the Estimation of Stature and their Use as a Proxy for Health among the Ancient Chachapoya of Peru.
Creator
Anzellini, Armando, Toyne, J. Marla, Schultz, John, Starbuck, John, University of Central Florida
Abstract / Description
Population mean stature and patterns of health are often linked in anthropological studies, yet few studies control for the multifactorial nature of achieving adult standing height. This thesis explores the intersection of health and stature by analyzing the skeletal remains of 161 adult individuals from the archaeological site of Kuelap, in the eastern slopes of the northern Peruvian Andes, and also tests current biometric methods for estimating stature from skeletal remains. This Chachapoya...
Show morePopulation mean stature and patterns of health are often linked in anthropological studies, yet few studies control for the multifactorial nature of achieving adult standing height. This thesis explores the intersection of health and stature by analyzing the skeletal remains of 161 adult individuals from the archaeological site of Kuelap, in the eastern slopes of the northern Peruvian Andes, and also tests current biometric methods for estimating stature from skeletal remains. This Chachapoya site dates to the Late Intermediate Period (AD 900 (-) 1470) and Late Horizon (AD 1470 (-) 1536) and resides in the high altitude sub-tropical forests of the Andes. An anatomical method of stature estimation was applied to a subsample of 36 individuals and linear regression formulae were created, proving especially effective for the tibia and calcaneus in this sample. These new formulae produced more accurate results, regardless of sex, when compared to traditional estimates and suggest that sexually specific formulae are not necessary in studies of stature. However, sexual dimorphism in skeletal elements did produce an effective method of sex determination from individual appendicular elements and was tested successfully on commingled remains. This investigation produced valuable formulae for estimating both sex and stature from isolated remains in the Chachapoyas region. The results established that interregional variance in stature is consistent, but mean stature is strongly affected by environmental pressures. This study highlights the ineffectiveness of using stature to assess the relative health of geographically distinct populations, but demonstrates the possibility of culturally specific health interpretations. The formulae for sex and stature estimation created in this study have provided a glimpse of the intersection between culture, environment, and health in human biological diversity.
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Date Issued
2016
Identifier
CFE0006069, ucf:50958
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006069
Tidal hydrodynamic response to sea level rise and coastal geomorphology in the Northern Gulf of Mexico
Title
Tidal hydrodynamic response to sea level rise and coastal geomorphology in the Northern Gulf of Mexico.
Creator
Passeri, Davina, Hagen, Scott, Medeiros, Stephen, Wang, Dingbao, Weishampel, John, University of Central Florida
Abstract / Description
Sea level rise (SLR) has the potential to affect coastal environments in a multitude of ways, including submergence, increased flooding, and increased shoreline erosion. Low-lying coastal environments such as the Northern Gulf of Mexico (NGOM) are particularly vulnerable to the effects of SLR, which may have serious consequences for coastal communities as well as ecologically and economically significant estuaries. Evaluating potential changes in tidal hydrodynamics under SLR is essential for...
Show moreSea level rise (SLR) has the potential to affect coastal environments in a multitude of ways, including submergence, increased flooding, and increased shoreline erosion. Low-lying coastal environments such as the Northern Gulf of Mexico (NGOM) are particularly vulnerable to the effects of SLR, which may have serious consequences for coastal communities as well as ecologically and economically significant estuaries. Evaluating potential changes in tidal hydrodynamics under SLR is essential for understanding impacts to navigation, ecological habitats, infrastructure and the morphologic evolution of the coastline. The intent of this research is to evaluate the dynamic effects of SLR and coastal geomorphology on tidal hydrodynamics along the NGOM and within three National Estuarine Research Reserves (NERRs), namely Grand Bay, MS, Weeks Bay, AL, and Apalachicola, FL. An extensive literature review examined the integrated dynamic effects of SLR on low gradient coastal landscapes, primarily in the context of hydrodynamics, coastal morphology, and marsh ecology. Despite knowledge of the dynamic nature of coastal systems, many studies have neglected to consider the nonlinear effects of SLR and employed a simplistic (")bathtub(") approach in SLR assessments. More recent efforts have begun to consider the dynamic effects of SLR (e.g., the nonlinear response of hydrodynamics under SLR); however, little research has considered the integrated feedback mechanisms and co-evolution of multiple interdependent systems (e.g., the nonlinear responses and interactions of hydrodynamics and coastal morphology under SLR). Synergetic approaches that integrate the dynamic interactions between physical and ecological environments will allow for more comprehensive evaluations of the impacts of SLR on coastal systems.Projecting future morphology is a challenging task; various conceptual models and statistical methods have been employed to project future shoreline positions. Projected shoreline change rates from a conceptual model were compared with historic shoreline change rates from two databases along sandy shorelines of the. South Atlantic Bight and NGOM coasts. The intent was not to regard one method as superior to another, but rather to explore similarities and differences between the methods and offer suggestions for projecting shoreline changes in SLR assessments.The influence of incorporating future shoreline changes into hydrodynamic modeling assessments of SLR was evaluated for the NGOM coast. Astronomic tides and hurricane storm surge were simulated under present conditions, the projected 2050 sea level with present-day shorelines, and the projected 2050 sea level with projected 2050 shorelines. Results demonstrated that incorporating shoreline changes had variable impacts on the hydrodynamics; storm surge was more sensitive to the shoreline changes than astronomic tides. It was concluded that estimates of shoreline change should be included in hydrodynamic assessments of SLR along the NGOM. Evaluating how hydrodynamics have been altered historically under a changing landscape in conjunction with SLR can provide insight to future changes. The Grand Bay estuary has undergone significant landscape changes historically. Tidal hydrodynamics were simulated for present and historic conditions (dating back to 1848) using a hydrodynamic model modified with unique sea levels, bathymetry, topography, and shorelines representative of each time period. Changes in tidal amplitudes varied across the domain. Harmonic constituent phases sped up from historic conditions. Tidal velocities in the estuary were stronger historically, and reversed from being flood dominant in 1848 to ebb dominant in 2005. To project how tidal hydrodynamics may be altered under future scenarios along the NGOM and within the three NERRs, a hydrodynamic model was used to simulate present (circa 2005) and future (circa 2050 and 2100) astronomic tides. The model was modified with projections of future sea levels as well as shoreline positions and dune elevations obtained from a Bayesian network (BN) model. Tidal amplitudes within some of the embayments increased under the higher SLR scenarios; there was a high correlation between the change in the inlet cross-sectional area under SLR and the change in the tidal amplitude within each bay. Changes in harmonic constituent phases indicated faster tidal propagation in the future scenarios within most of the bays. Tidal velocities increased in all of the NERRs which altered flood and ebb current strengths.The work presented herein improves the understanding of the response of tidal hydrodynamics to morphology and SLR. This is beneficial not only to the scientific community, but also to the management and policy community. These findings will have synergistic effects with a variety of coastal studies including storm surge and biological assessments of SLR. In addition, findings can benefit monitoring and restoration activities in the NERRs. Ultimately, outcomes will allow coastal managers and policy makers to make more informed decisions that address specific needs and vulnerabilities of each particular estuary, the NGOM coastal system, and estuaries elsewhere with similar conditions.
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Date Issued
2015
Identifier
CFE0006049, ucf:50962
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006049
LATINATE WORD PARTS AND VOCABULARY:CONTRASTS AMONG THREE GROUPS COMPRISINGTHE COMMUNITY COLLEGE PREPARATORY READING CLASS
Title
LATINATE WORD PARTS AND VOCABULARY:CONTRASTS AMONG THREE GROUPS COMPRISINGTHE COMMUNITY COLLEGE PREPARATORY READING CLASS.
Creator
Bellomo, Tom, Taylor, Rosemarye, University of Central Florida
Abstract / Description
Students enrolled in a college preparatory reading class at one particular community college were categorized based on language origin. Native English speaking students comprised one group and foreign students formed two additional groups--students whose language origin was Latin-based (i.e. Romance languages) and students whose language origin was not Latin-based (i.e. Japanese). A pretest assessment measure was used to quantify the extent that pre-existing knowledge of Latinate word parts...
Show moreStudents enrolled in a college preparatory reading class at one particular community college were categorized based on language origin. Native English speaking students comprised one group and foreign students formed two additional groups--students whose language origin was Latin-based (i.e. Romance languages) and students whose language origin was not Latin-based (i.e. Japanese). A pretest assessment measure was used to quantify the extent that pre-existing knowledge of Latinate word parts and morphologically complex vocabulary differed among groups based on language origin. The identical instrument served as a posttest to measure the extent that direct instruction in morphological analysis resulted in change among the same groups after one semester of instruction. Two sections on both the pretest and posttest yielded a total of four distinct mean scores that formed the primary basis for comparison. Categorizing students within the college preparatory reading class based on language origin revealed distinctive strengths and weaknesses relative to group identity when learning Latin-based word parts and vocabulary. Results of a one-way fixed-factor analysis of variance, in conjunction with multiple comparison procedures, indicated that the Latin-based group performed the strongest. This group had the greatest mean score on all four measurements; however, only for the word part section of the pretest was the difference statistically significant. The non Latin-based group performed the poorest as evidenced by scoring the lowest on three of the four measures, with a statistically significant difference for the vocabulary pretest. Additionally, a disproportionately large number of students within the native English-speaking group had difficulty mastering word parts. Though the lower group mean was statistically significant for the word part section of the posttest, practical significance was not observable from the descriptive data. A follow-up frequency tabulation revealed a dichotomization within the native English speaking group between those who proceeded to master word parts and those who did not. Furthermore, results from a pretest/posttest comparison for each respective group indicated that all three groups made significant gains on both sections of the test instrument as a result of direct instruction in Latinate word parts and vocabulary. However, there was an incongruity between word part and vocabulary mastery as all three group means were markedly better on the word part section of the instrument. The results of this study suggest that college preparatory students, regardless of their language origin, enter higher education with limited knowledge of Latinate word parts and vocabulary. The results further suggest that students comprising the heterogeneously populated college preparatory reading class can profit from direct instruction in morphological analysis--regardless of language origin. Prior research has demonstrated that college-level content words tend to be morphologically complex, singular in meaning, and likely to be Latinate in origin. Reading is the salient skill utilized across the curriculum and often the primary means of content dissemination. Reading, in turn, is principally linked to the extent of one's vocabulary. Consequently, teaching morphologically complex vocabulary at the college preparatory level along with providing a working knowledge of morphemes can assist students toward college readiness.
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Date Issued
2005
Identifier
CFE0000444, ucf:46384
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0000444
EFFECTS OF BINARY SOLVENT SYSTEM ON MORPHOLOGY OF PARTICLES
Title
EFFECTS OF BINARY SOLVENT SYSTEM ON MORPHOLOGY OF PARTICLES.
Creator
Besana, Patrick, Deng, Weiwei, University of Central Florida
Abstract / Description
Recent advancements in cancer research has led to the synthesis of a new drug known as docetaxel. Meant to replace paclitaxel, its more natural counterpart whose ingredients are difficult to obtain, the drug is known to effectively treat a wide array of cancers, including breast cancer, ovarian cancer, and prostate cancer. The establishment of a synthetic alternative to paclitaxel has increased its bioavailability, thereby lowering the cost needed to utilize the drug. Still, the limiting...
Show moreRecent advancements in cancer research has led to the synthesis of a new drug known as docetaxel. Meant to replace paclitaxel, its more natural counterpart whose ingredients are difficult to obtain, the drug is known to effectively treat a wide array of cancers, including breast cancer, ovarian cancer, and prostate cancer. The establishment of a synthetic alternative to paclitaxel has increased its bioavailability, thereby lowering the cost needed to utilize the drug. Still, the limiting factor in minimizing costs is the method in which the drug is processed. Current methods in drug processing have their limitations, which include the introduction of impurities and a low effective yield due to poor powder geometry. Thus, the goal of this study looks to explore a new way to process the drug in a more efficient manner. In this study, a new method for processing docetaxel is explored on in great detail. A more direct method of using electrospray deposition is utilized for the creation of monodisperse nanoparticles, with the main intention of increasing the efficiency at which the drug is processed and prepared for drug delivery to the patient by means of injection. A key feature in electrospray deposition is its ability to produce droplets that are sized homogenously. These droplets eventually evaporate at homogenous rates. These two concepts have been exploited to consistently produce nanoparticles of the cancer drug, which is made possible by the fact that the minimal variation in droplet sizes has easily translated to minimal variation in dry particle sizes. Compared to other methods of drug processing, one other benefit that electrospray deposition conveys is that through evaporation, virtually all impurities and unwanted foreign material are eliminated. Moreover, a binary solvent system is investigated in more detail in this study, so as to determine its effects on both the evaporation of the solvent and the diffusion of the drug into nanoparticles. From there, material and geometric properties of the electrospray nozzle were explored upon in great detail, with the main goal of being able to produce a cone jet that consistently dissociates into monodisperse droplets. At the same time, controllable properties of the electrospray atomizer were investigated and continuously modified. Modifications in both the components of the solution and the operating temperature were also considered to enhance both the electrospray deposition process and the geometry of the particles. Scanning electron microscopy (SEM) characterization is continuously utilized to determine suitability of results obtained in experiments. Ultimately, the goal of this study is to determine the ideal conditions (solvent ratios, flow rate, operating temperature, electrospray atomizer nozzle configurations, etc.) in which spherical docetaxel particles sized at 100-200 nm can be produced.
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Date Issued
2015
Identifier
CFH0004872, ucf:45412
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFH0004872
An Investigation of the Biomechanical Implications of Lower Limb Fractures and Leg Length Disparity
Title
An Investigation of the Biomechanical Implications of Lower Limb Fractures and Leg Length Disparity.
Creator
Mills, Elizabeth, Dupras, Tosha, Williams, Lana, Starbuck, John, University of Central Florida
Abstract / Description
One of the primary goals of biological anthropology is to develop an accurate understanding of human anatomy, health, disease, and injury in both modern and archaeological populations. Paleopathological analyses are a fruitful means of identifying disease and injury in skeletal assemblages, but the individual long-term biomechanical effects associated with pathological conditions have not yet been adequately explored in the literature. Leg fractures are a common pathological condition in both...
Show moreOne of the primary goals of biological anthropology is to develop an accurate understanding of human anatomy, health, disease, and injury in both modern and archaeological populations. Paleopathological analyses are a fruitful means of identifying disease and injury in skeletal assemblages, but the individual long-term biomechanical effects associated with pathological conditions have not yet been adequately explored in the literature. Leg fractures are a common pathological condition in both modern and archaeological populations, the effects of which may alter the biomechanics of gait. A growing body of clinical literature demonstrates that abnormal ambulatory function may have far-reaching effects in the rest of the body.To assess the long-term consequences of pathological conditions of the lower extremities, the relationship between lower limb long bone fracture occurrence, incidence of leg length disparity (LLD), and temporomandibular dysfunction (TMD) was analyzed. A total of 56 adult individuals (29 fractured, 27 unfractured) from the Hamann-Todd Osteological Collection (HTOC) at the Cleveland Museum of Natural History (curated between 1912 and 1938) were examined in this study. In total, the sample consisted of 37 males and 19 females (ages 25-76) of either black or white ancestry. LLD was assessed by taking standardized measurements of the lower limb long bones. TMD was analyzed by scoring the presence and severity of osteoarthritis of the temporomandibular joint (TMJ OA), dental attrition, and antemortem tooth loss. Kendall's Tau correlation statistics were used to assess morphological integration between all unique pairwise combinations of lower limb and jaw measurements among unfractured and fractured groups. Results indicate that several measures of LLD and jaw dysfunction are correlated differently in the unfractured and fractured groups. Comparisons of the All Unfractured and All Fractured groups most often showed higher absolute correlation values in unfractured individuals. Samples were also subdivided and compared based on known sex. Significant differences in patterns of morphological integration were observed between male and female sub-samples. Significant correlation values were almost always higher in the unfractured sample than in the fractured sample. Females, however, demonstrated both significant increases and significant decreases in absolute correlation values when comparing fractured and unfractured samples. Thus, patterns of significant differences in morphological integration between the lower limbs and jaw differ for males and females, with fairly consistent decreases in integration strength in the former and a mixed pattern of integration strength increases and decreases in the latter, when a leg fracture is involved. It is argued that these differences are explained by fundamental sexually dimorphic morphological and kinematic differences between males and females, such that fractures resulting in LLD affect the two sexes differently. Gendered lifetime social experiences and activity patterns may also explain the different male and female patterns identified in the analysis. These insights are applied to larger anthropological questions of social identity and the long-term injury experience.
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Date Issued
2016
Identifier
CFE0006694, ucf:51917
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006694
INNERVATION, DISTRIBUTION AND MORPHOLOGY OF CALCITONIN GENE RELATED PEPTIDE AND SUBSTANCE P IMMUNOREACTIVE AXONS IN THE WHOLE-MOUNT ATRIA OF FVB MICE
Title
INNERVATION, DISTRIBUTION AND MORPHOLOGY OF CALCITONIN GENE RELATED PEPTIDE AND SUBSTANCE P IMMUNOREACTIVE AXONS IN THE WHOLE-MOUNT ATRIA OF FVB MICE.
Creator
Li, Liang, Cheng, Zixi, University of Central Florida
Abstract / Description
Degeneration of nociceptive afferent axons and terminals in the heart is associated with painless sudden cardiac death. However, innervation, distribution and morphological structures of sympathetic cardiac nociceptive afferent axons and terminals have not yet been fully characterized. The aim of the present study is to characterize the density, arrangement, and structural features of differentiated sympathetic afferent axons and terminals in whole-mount FVB mouse atria. FVB mice (3-6 months...
Show moreDegeneration of nociceptive afferent axons and terminals in the heart is associated with painless sudden cardiac death. However, innervation, distribution and morphological structures of sympathetic cardiac nociceptive afferent axons and terminals have not yet been fully characterized. The aim of the present study is to characterize the density, arrangement, and structural features of differentiated sympathetic afferent axons and terminals in whole-mount FVB mouse atria. FVB mice (3-6 months old) were perfused and the tissues were fixed. The right and left atria were processed with immunohistochemistry. Calcitonin gene-related peptide (CGRP) and substance P (SP) are two neuropeptides which have been widely used to label sympathetic nociceptive afferent axons in many tissues. CGRP (rabbit anti-CGRP) and SP (Goat anti-SP) primary antibodies were applied, followed by Alexa Fluor 594 and 660 conjugated secondary antibodies. Whole-mount preparations of right and left atria were examined using a laser scanning confocal microscope. We found that 1) CGRP immunoreactive (IR) axon bundles innervated the right and left atria including the auricle and entrance area of the superior vena cava, the inferior vena cava, left precaval vein and pulmonary veins. Large axon bundles entered the area from the major veins and bifurcated into smaller axon bundles and single axon fibers to form terminal end-nets and free endings in the epicardium at each region with a similar pattern. In the atrial muscle layer, varicose CGRP-IR axons had close contacts with muscle fibers. In addition, CGRP-IR axons terminated in the intrinsic cardiac ganglia (ICGs) with varicosities surrounding individual ganglionic principle neurons (PNs). In the aortic arch, the CGRP-IR fibers exhibited similar terminal structures to those seen in the atria. 2) SP-IR axons also projected to the right and left atria and aorta. Similar to CGRP-IR axons, these SP-IR axons also formed end-nets and free endings in these areas. In cardiac ganglia, SP-IR axons formed varicose endings around many individual PNs. However, a salient difference was found: There appeared to be fewer SP-IR axons and terminals than CGRP-IR axons and terminals in the atria. 3) None of the cardiac PNs in ICG were CGRP-IR or SP-IR. 4) Many SP-IR axon terminals around PNs within ICGs and atrial muscles were found to have colocalized expression of CGRP-IR. Collectively, our data for the first time documented the distribution patterns and morphology of sympathetic afferent axons and terminals in each region of the atria in the mouse model. This will provide a foundation for future analysis of the pathological changes of sympathetic afferent nerves in the atria in different disease models (e.g., diabetes, sleep apnea, and aging). This study was supported by NIH R01 HL-79636.
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Date Issued
2010
Identifier
CFE0003536, ucf:48965
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0003536
Endocrine and Contralateral Muscle Responses to Short-term Unilateral Resistance Training
Title
Endocrine and Contralateral Muscle Responses to Short-term Unilateral Resistance Training.
Creator
Boone, Carleigh, Fragala, Maren, Hoffman, Jay, Stout, Jeffrey, Fukuda, David, University of Central Florida
Abstract / Description
PURPOSE: The purpose of this study was to examine the effects of short-term lower body unilateral resistance training on hormonal, muscle morphological, and performance measures in young men. METHODS: Seventeen healthy, untrained young men (Age: 22.8 (&)#177; 3.7 y; BMI: 26.5 (&)#177; 4.9 kg/m2) were randomly assigned to one of two groups (UT: 22.9 (&)#177; 4.6 y, 25.3 (&)#177; 4.2 kg/m2; CON: 24.0 (&)#177; 4.6 y, 27.7 (&)#177; 5.1 kg/m2). Resistance training consisted of 4 weeks of...
Show morePURPOSE: The purpose of this study was to examine the effects of short-term lower body unilateral resistance training on hormonal, muscle morphological, and performance measures in young men. METHODS: Seventeen healthy, untrained young men (Age: 22.8 (&)#177; 3.7 y; BMI: 26.5 (&)#177; 4.9 kg/m2) were randomly assigned to one of two groups (UT: 22.9 (&)#177; 4.6 y, 25.3 (&)#177; 4.2 kg/m2; CON: 24.0 (&)#177; 4.6 y, 27.7 (&)#177; 5.1 kg/m2). Resistance training consisted of 4 weeks of unilateral lower body and bilateral upper body exercises on 3 days per week. Each training session entailed unilateral countermovement jumps (3 (&)#215; 8), unilateral leg press (LP), bilateral chest press (CP), unilateral leg extension (LE), and bilateral low row (LR). Strength exercises were performed for 3 sets of 8-10 repetitions; lower body exercises were performed with the dominant leg only. Muscle thickness (MT), pennation angle (PA), cross-sectional area (CSA), and echo-intensity (EI) of the vastus lateralis (VL) and rectus femoris (RF) muscles of both legs was assessed via ultrasound. Fascicle length (FL) was calculated as [MT / sin(PA)]. Maximal dynamic unilateral LP and LE strength was assessed during one-repetition maximum (1RM) testing; CP and LR 1RM strength was estimated as [repetition weight/(1.0278-0.0278)(reps)]. Maximal isometric knee extensor strength was isolaterally assessed via maximal voluntary contraction (MVC) testing. Mean and peak power output (Watts) was quantified during unilateral countermovement jumps via accelerometry. Fasting concentrations of total testosterone and growth hormone were obtained at baseline (PRE), immediately post (IP), 30-minutes post (30P), and 60-minutes post (60P) during both testing exercise sessions (Pre and Post). Following the 4-week intervention, all participants' maximal dynamic and isometric strength, mean and peak power output, muscle morphology, and hormonal responses were reassessed. Performance, ultrasound, and area under the curve data were analyzed using ANCOVA to observe between-group comparisons while controlling for baseline (PRE) values. Endocrine data were analyzed using a two-way, mixed-factorial repeated-measures ANOVA. RESULTS: Participants in the UT group experienced significant strength improvements of the trained (28 to 150%) and untrained legs (12 to 160%). Training did not elicit significant improvements in maximal isometric strength or power output of the trained or untrained leg. The trained RF experienced significant increases in CSA and MT. The trained VL experienced a significant increase in CSA. Muscle size of the untrained leg was not significantly augmented. Training did not elicit changes in the acute hormonal response to exercise. CONCLUSIONS: Four weeks of unilateral lower body resistance training using the dominant leg appears sufficient to evoke strength gains of both the ipsilateral and contralateral legs. However, meaningful morphological changes were observed in the trained leg only. Differences in acute hormonal responses to resistance exercise did not appear to explain the observed differences. In addition, unilateral lower body resistance training did not appear to augment the acute endocrine response to an acute bout of resistance exercise. Current findings suggest that the cross-educational strength transfer during the early stage of training is attributable to factors other than changes in muscle morphology and circulating hormones.
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Date Issued
2014
Identifier
CFE0005307, ucf:50538
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0005307
PROBING AND TUNING THE SIZE, MORPHOLOGY, CHEMISTRY AND STRUCTURE OF NANOSCALE CERIUM OXIDE
Title
PROBING AND TUNING THE SIZE, MORPHOLOGY, CHEMISTRY AND STRUCTURE OF NANOSCALE CERIUM OXIDE.
Creator
Kuchibhatla, Satyanarayana, Seal, Sudipta, University of Central Florida
Abstract / Description
Cerium oxide (ceria)-based materials in the nanoscale regime are of significant fundamental and technological interest. Nanoceria in pure and doped forms has current and potential use in solid oxide fuel cells, catalysis, UV- screening, chemical mechanical planarization, oxygen sensors, and bio-medical applications. The characteristic feature of Ce to switch between the +3 and + 4 oxidation states renders oxygen buffering capability to ceria. The ease of this transformation was expected to be...
Show moreCerium oxide (ceria)-based materials in the nanoscale regime are of significant fundamental and technological interest. Nanoceria in pure and doped forms has current and potential use in solid oxide fuel cells, catalysis, UV- screening, chemical mechanical planarization, oxygen sensors, and bio-medical applications. The characteristic feature of Ce to switch between the +3 and + 4 oxidation states renders oxygen buffering capability to ceria. The ease of this transformation was expected to be enhanced in the nanoceria. In most the practical scenarios, it is necessary to have a stable suspension of ceria nanoparticles (CNPs) over longer periods of time. However, the existing literature is confined to short term studies pertaining to synthesis and property evaluation. Having understood the need for a comprehensive understanding of the CNP suspensions, this dissertation is primarily aimed at understanding the behavior of CNPs in various chemical and physical environments. We have synthesized CNPs in the absence of any surfactants at room temperature and studied the aging characteristics. After gaining some understanding about the behavior of this functional oxide, the synthesis environment and aging temperature were varied, and their affects were carefully analyzed using various materials analysis techniques such as high resolution transmission electron microscopy (HRTEM), UV-Visible spectroscopy (UV-Vis), and X-ray photoelectron spectroscopy (XPS). When the CNPs were aged at room temperature in as-synthesized condition, they were observed to spontaneously assemble and evolve as fractal superoctahedral structures. The reasons for this unique polycrystalline morphology were attributed to the symmetry driven assembly of the individual truncated octahedral and octahedral seed of the ceria. HRTEM and Fast Fourier Transform (FFT) analyses were used to explain the agglomeration behavior and evolution of the octahedral morphology. Some of the observations were supported by molecular dynamic simulations. Poly (ethylene glycol) (PEG) and ethylene glycol (EG) were used to control the kinetics of this morphology evolution. The ability to control the agglomeration of CNPs in these media stems from the lower dielectric constant and an increased viscosity of the EG and PEG based solvents. CNPs when synthesized and aged in frozen conditions, i.e. in ice, were found to form one dimensional, high aspect ratio structures. A careful analysis has provided some evidence that the CNPs use the porous channels in ice as a template and undergo oriented attachment to form nanorods. When the aging treatment was done near freezing temperature in solution, the nanorods were not observed, confirming the role of channels in ice. When synthesized in aqueous media such as DI water, PEG and EG; CNPs were observed to exhibit a reversible oxidation state switching between +3 and +4. Band gap values were computed from the optical absorption data. The changes in the band gap values observed were attributed to the changes in the oxidation state of CNPs as opposed to the quantum confinement effects, as expected in other nanoparticle systems. The work presented in this dissertation demonstrates, with evidence, that in order to obtain a comprehensive understanding of the properties of nanoscale materials it is of paramount importance to monitor their behavior over relatively longer periods of time under various ambient environments. While the solution based techniques offer a versatility and low cost route to study the fundamental properties of nanomaterials, they suffer some inherent problems such as precursor contamination and uncontrolled chemical reactions. Especially when analyzing the behavior of ceria-based materials for applications like solid oxide fuel cells, a great control in the density and crystalline quality are desired. In order to achieve this, as a first step pure ceria thin films were synthesized using oxygen plasma assisted molecular beam epitaxy (OPA-MBE). The ceria films were analyzed using various in situ and ex situ techniques to study the crystal structure, growth mode and epitaxial quality of the films. It was observed that the epitaxial orientation of the ceria films could be tuned by varying the deposition rate. When the films were grown at low deposition rate (< 8 Å/min) ceria films with epitaxial (200) orientation were observed where as the films grown at high deposition rates (up to 30 Å/min) showed (111) orientation. Theoretical simulations were used to confirm some of the experimental facts observed in both nanoparticles and thin films.
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Date Issued
2008
Identifier
CFE0002163, ucf:47499
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002163
Effects of Rest Position on Ultrasound-Derived Morphological Characteristics of the Vastus Lateralis and Lower-Body Force Production
Title
Effects of Rest Position on Ultrasound-Derived Morphological Characteristics of the Vastus Lateralis and Lower-Body Force Production.
Creator
Varanoske, Alyssa, Wells, Adam, Fukuda, David, Stout, Jeffrey, Mangine, Gerald, University of Central Florida
Abstract / Description
INTRODUCTION: Ultrasound assessment of the lower body typically encompasses 10-15 minutes of supine rest prior to examination because of the potential influence of gravitational fluid shifts on tissue size and composition. However, examination of the vastus lateralis (VL) muscle requires individuals to lay in the lateral recumbent position, and this change in position may influence muscle morphological characteristics and their ability to predict muscle function.PURPOSE: The purpose of this...
Show moreINTRODUCTION: Ultrasound assessment of the lower body typically encompasses 10-15 minutes of supine rest prior to examination because of the potential influence of gravitational fluid shifts on tissue size and composition. However, examination of the vastus lateralis (VL) muscle requires individuals to lay in the lateral recumbent position, and this change in position may influence muscle morphological characteristics and their ability to predict muscle function.PURPOSE: The purpose of this investigation was to examine the effect of rest position on ultrasound-derived morphological characteristics of the VL and to determine whether or not rest position affects the relationships between muscle morphological characteristics of the VL and lower-body force and power production. METHODS: Thirty-one resistance-trained males (age: 23.0 (&)#177; 2.1 years; height: 1.79 (&)#177; 0.08 m; body mass: 87.4 (&)#177; 11.7 kg) participated in this investigation. Muscle morphological characteristics, including cross-sectional area (CSA), muscle thickness (MT), pennation angle (PA), echo intensity (UnCorEI), subcutaneous adipose tissue thickness (SFT), and EI corrected for SFT (CorEI) of the VL were assessed in the dominant limb after 15 minutes of rest in 3 recumbent positions: supine (SUP), dominant lateral recumbent (DLR), non-dominant lateral recumbent (NDLR), as well as after 15 minutes of standing (ST) and immediately after laying down (IP). Following ultrasound assessments, participants completed unilateral performance assessments, including vertical jumps (UVJ), isometric/isokinetic testing, and a 1-repetition maximum (1-RM) leg press. RESULTS: A repeated-measures analysis of variance revealed significantly different (p (<) 0.05) CSA, MT, PA, UnCorEI, and SFT in ST compared to recumbent positions after 15 minutes of rest (NDLR, DLR, and SUP). Additionally, significant differences were observed between recumbent positions for CSA, CorEI, and UnCorEI; however, no differences were observed for MT, PA, and SFT. Different magnitudes of relationships were observed between muscle morphological characteristics measured after rest in different positions and performance variables. However, muscle morphology after IP generally appears to be the best predictor of performance for most variables, although utilizing the NDLR and DLR positions may provide comparable, or potentially stronger results for variables such as IsokPF. The relationship between muscle morphology and various performance variables in ST were weaker compared to the recumbent positions examined, specifically for IsokPF, 1-RM leg press, and for all UVJ variables, except total work.CONCLUSIONS: Muscle morphology differs depending on the rest position utilized prior to ultrasound analysis. These rest positions also affect the ability for muscle morphology to predict lower-body force production. Future research should consider evaluation of muscle morphology of the VL after IP in the prediction of muscle function; however, NDLR and DLR may also be used. SUP and ST provide significantly weaker relationships for some performance variables compared to the other recumbent positions.
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Date Issued
2019
Identifier
CFE0007550, ucf:52610
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0007550
Characterization of composite broadband absorbing conjugated polymer nanoparticles by steady-state, time-resolved and single particle spectroscopy
Title
Characterization of composite broadband absorbing conjugated polymer nanoparticles by steady-state, time-resolved and single particle spectroscopy.
Creator
Bonner, Maxwell, Gesquiere, Andre, Campiglia, Andres, Santra, Swadeshmukul, Hernandez, Florencio, Perez Figueroa, Jesus, Ye, Jingdong, Fernandez-Valle, Cristina, University of...
Show moreBonner, Maxwell, Gesquiere, Andre, Campiglia, Andres, Santra, Swadeshmukul, Hernandez, Florencio, Perez Figueroa, Jesus, Ye, Jingdong, Fernandez-Valle, Cristina, University of Central Florida
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Abstract / Description
As the global economy searches for reliable, inexpensive and environmentally friendly renewable energy resources, energy conservation by means of photovoltaics has seen near exponential growth in the last decade. Compared to state-of-the-art inorganic solar cells, organic photovoltaics (OPVs) composed of conjugated polymers are particularly interesting because of their processability, flexibility and the potential for large area devices at a reduced fabrication cost. It has been extensively...
Show moreAs the global economy searches for reliable, inexpensive and environmentally friendly renewable energy resources, energy conservation by means of photovoltaics has seen near exponential growth in the last decade. Compared to state-of-the-art inorganic solar cells, organic photovoltaics (OPVs) composed of conjugated polymers are particularly interesting because of their processability, flexibility and the potential for large area devices at a reduced fabrication cost. It has been extensively documented that the interchain and intrachain interactions of conjugated polymers complicate the fundamental understanding of the optical and electronic properties in the solid-state (i.e. thin film active layer). These interactions are highly dependent on the nanoscale morphology of the solid-state material, leading to a heterogeneous morphology where individual conjugated polymer molecules obtain a variety of different optoelectronic properties. Therefore, it is of the utmost importance to fundamentally study conjugated polymer systems at the single molecule or nanoparticle level instead of the complex macroscopic bulk level.This dissertation research aims to develop simplified nanoparticle models that are representation of the nanodomains found in the solid-state material, while fundamentally addressing light harvesting, energy transfer and interfacial charge transfer mechanisms and their relationship to the electronic structure, material composition and morphology of the nanoparticle system. In preceding work, monofunctional doped nanoparticles (polymer-polymer) were fabricated with enhanced light harvesting and F?rster energy transfer properties by blending Poly[(o-phenylenevinylene)-alt-(2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene)] (BPPV) and Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) at various MEH-PPV doping ratios. While single particle spectroscopy (SPS) reveals a broad distribution of optoelectronic and photophysical properties, time-correlated single photon counting (TC-SPC) spectroscopy displays multiple fluorescence lifetime components for each nanoparticle composition, resulting from changing polymer chain morphologies and polymer-polymer aggregation. In addition, difunctional doped nanoparticles were fabricated by doping the monofunctional doped nanoparticles with PC60BM ([6,6]-phenyl-C61-butyric acid methyl ester) to investigate competition between intermolecular energy transfer and interfacial charge transfer. Specifically, the difunctional SPS data illustrated enhanced and reduced energy transfer mechanisms that are dependent on the material composition of MEH-PPV and PC60BM. These data are indicative of changes in inter- and intrachain interactions of BPPV and MEH-PPV and their respective nanoscale morphologies. Together, these fundamental studies provide a thorough understanding of monofunctional and difunctional doped nanoparticle photophysics, necessary for understanding the morphological, optoelectronic and photophysical processes that can limit the efficiency of OPVs and provide insight for strategies aimed at improving device efficiencies.
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Date Issued
2011
Identifier
CFE0004089, ucf:49143
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004089
X-ray Scattering Investigations of Metallic Thin Films
Title
X-ray Scattering Investigations of Metallic Thin Films.
Creator
Warren, Andrew, Coffey, Kevin, Sohn, Yongho, Suryanarayana, Challapalli, Heinrich, Helge, Barmak, Katayun, Toney, Michael, University of Central Florida
Abstract / Description
Nanometric thin films are used widely throughout various industries and for various applications. Metallic thin films, specifically, are relied upon extensively in the microelectronics industry, among others. For example, alloy thin films are being investigated for CMOS applications, tungsten films find uses as contacts and diffusion barriers, and copper is used often as interconnect material. Appropriate metrology methods must therefore be used to characterize the physical properties of...
Show moreNanometric thin films are used widely throughout various industries and for various applications. Metallic thin films, specifically, are relied upon extensively in the microelectronics industry, among others. For example, alloy thin films are being investigated for CMOS applications, tungsten films find uses as contacts and diffusion barriers, and copper is used often as interconnect material. Appropriate metrology methods must therefore be used to characterize the physical properties of these films. X-ray scattering experiments are well suited for the investigation of nano-scaled systems, and are the focus of this doctoral dissertation. Emphasis is placed on (1) phase identification of polycrystalline thin films, (2) the evaluation of the grain size and microstrain of metallic thin films by line profile analysis, and (3) the study of morphological evolution in solid/solid interfaces.To illustrate the continued relevance of x-ray diffraction for phase identification of simple binary alloy systems, Pt-Ru thin films, spanning the compositional range from pure Pt to pure Ru were investigated. In these experiments, a meta-stable extension of the HCP phase is observed in which the steepest change in the electronic work function coincides with a rapid change in the c/a ratio of the HCP phase.For grain size and microstrain analysis, established line profile methods are discussed in terms of Cu and W thin film analysis. Grain sizes obtained by x-ray diffraction are compared to transmission electron microscopy based analyses. Significant discrepancies between x-ray and electron microscopy are attributed to sub-grain misorientations arising from dislocation core spreading at the film/substrate interface. A novel "residual" full width half max parameter is introduced for examining the contribution of strain to x-ray peak broadening. The residual width is subsequently used to propose an empirical method of line profile analysis for thin films on substrates.X-ray reflectivity was used to study the evolution of interface roughness with annealing for a series of Cu thin films that were encapsulated in both SiO2 and Ta/SiO2. While all samples follow similar growth dynamics, notable differences in the roughness evolution with high temperature ex-situ annealing were observed. The annealing resulted in a smoothing of only one interface for the SiO2 encapsulated films, while neither interface of the Ta/SiO2 encapsulated films evolved significantly. The fact that only the upper Cu/SiO2 interface evolves is attributed to mechanical pinning of the lower interface to the rigid substrate. The lack of evolution of the Cu/Ta/SiO2 interface is consistent with the lower diffusivity expected of Cu in a Cu/Ta interface as compared to that in a Cu/SiO2 interface. The smoothing of the upper Cu/SiO2 interface qualitatively follows that expected for capillarity driven surface diffusion but with notable quantitative deviation.
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Date Issued
2013
Identifier
CFE0004770, ucf:49784
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004770
Evolution and distribution of phenotypic diversity in the venom of Mojave Rattlesnakes (Crotalus scutulatus)
Title
Evolution and distribution of phenotypic diversity in the venom of Mojave Rattlesnakes (Crotalus scutulatus).
Creator
Strickland, Jason, Savage, Anna, Parkinson, Christopher, Hoffman, Eric, Rokyta, Darin, University of Central Florida
Abstract / Description
Intraspecific phenotype diversity allows for local adaption and the ability for species to respond to changing environmental conditions, enhancing survivability. Phenotypic variation could be stochastic, genetically based, and/or the result of different environmental conditions. Mojave Rattlesnakes, Crotalus scutulatus, are known to have high intraspecific venom variation, but the geographic extent of the variation and factors influencing venom evolution are poorly understood. Three primary...
Show moreIntraspecific phenotype diversity allows for local adaption and the ability for species to respond to changing environmental conditions, enhancing survivability. Phenotypic variation could be stochastic, genetically based, and/or the result of different environmental conditions. Mojave Rattlesnakes, Crotalus scutulatus, are known to have high intraspecific venom variation, but the geographic extent of the variation and factors influencing venom evolution are poorly understood. Three primary venom types have been described in this species based on the presence (Type A) or absence (Type B) of a neurotoxic phospholipase A2 called Mojave toxin and an inverse relationship with the presence of snake venom metalloproteinases (SVMPs). Individuals that contain both Mojave toxin and SVMPs, although rare, are the third, and designated Type A + B. I sought to describe the proteomic and transcriptomic venom diversity of C. scutulatus across its range and test whether diversity was correlated with genetic or environmental differences. This study includes the highest geographic sampling of Mojave Rattlesnakes and includes the most venom-gland transcriptomes known for one species. Of the four mitochondrial lineages known, only one was monophyletic for venom type. Environmental variables poorly correlated with the phenotypes. Variability in toxin and toxin family composition of venom transcriptomes was largely due to differences in transcript expression. Four of 19 toxin families identified in C. scutulatus account for the majority of differences in toxin number and expression variation. I was able to determine that the toxins primarily responsible for venom types are inherited in a Mendelian fashion and that toxin expression is additive when comparing heterozygotes and homozygotes. Using the genetics to define venom type is more informative and the Type A + B phenotype is not unique, but rather heterozygous for the PLA2 and/or SVMP alleles. Intraspecific venom variation in C. scutulatus highlights the need for fine scale ecological and natural history information to understand how phenotypic diversity is generated and maintained geographically through time.
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Date Issued
2018
Identifier
CFE0007252, ucf:52198
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0007252