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Phase transformation and growth kinetics in reaction zone between uranium alloy and zirconium diffusion barrier
Title
Phase transformation and growth kinetics in reaction zone between uranium alloy and zirconium diffusion barrier.
Creator
Park, Young Joo, Sohn, Yongho, Coffey, Kevin, Fang, Jiyu, University of Central Florida
Abstract / Description
U-10wt.%Mo (U10Mo) alloy as a part of monolithic fuel system is being developed under Material Management and Minimization Reactor Conversion (MMMRC) program, tasked with replacing high-enriched uranium (HEU) fuel with low-enriched uranium (LEU) fuel in civilian research and test reactors. Use of U10Mo fuel alloy entails a Zr diffusion barrier to avoid the undesirable interdiffusion and reactions between the U10Mo and Al-alloy cladding. To better understand the interaction between these fuel...
Show moreU-10wt.%Mo (U10Mo) alloy as a part of monolithic fuel system is being developed under Material Management and Minimization Reactor Conversion (MMMRC) program, tasked with replacing high-enriched uranium (HEU) fuel with low-enriched uranium (LEU) fuel in civilian research and test reactors. Use of U10Mo fuel alloy entails a Zr diffusion barrier to avoid the undesirable interdiffusion and reactions between the U10Mo and Al-alloy cladding. To better understand the interaction between these fuel system constituents, microstructural development and diffusion kinetics in U-Mo-Zr, U-Zr and fuel plate assembly processed by co-rolling and hot isostatic pressing (HIP) were investigated using a variety of analytical techniques accompanying scanning electron microscopy and transmission electron microscopy.Phase constituents, microstructure and diffusion kinetics between U10Mo and Zr were examined using solid-to-solid diffusion couples annealed at 650 (&)deg;C for 240, 480 and 720 hours. Concentration profiles were mapped as diffusion paths on the isothermal ternary phase diagram. Within the diffusion zone, single-phase layers of (?U,?Zr) were observed along with a discontinuous layer of Mo2Zr between the ?Zr and ?U layers. In the vicinity of Mo2Zr phase, islands of ?Zr phase were also found. In addition, acicular ?Zr and U6Zr3Mo phases were observed within the ?U(Mo). Growth rate of the interdiffusion-reaction zone was determined to be 1.81 (&)#215; 10-15 m2/sec at 650 (&)deg;C, however with an assumption of a certain incubation period.Investigation for interdiffusion and reaction between U and Zr were carried out using solid-to-solid diffusion couples annealed at 580, 650, 680 and 710 (&)deg;C. The interdiffusion and reaction layer consisted of ?U containing Zr acicular precipitate, ?' (oC4-variant) and (?U,?Zr) solid solution at 650, 680 and 710 (&)deg;C. The ?-UZr2 phase, instead of (?U,?Zr) solid solution phase, was observed in the couple annealed at 580 (&)deg;C. The interdiffusion fluxes and coefficients were determined for the ?U, (?U,?Zr) and ?-UZr2 (580 ?C only) phases using both Sauer-Freise and Boltzmann-Matano analyses. For the ?'-phase with negligible concentration gradient, integrated interdiffusion coefficients were determined via Wagner method. Marker plane was found in (?U,?Zr) (cI2) solid solution from the couples annealed at 650, 680 and 710 (&)deg;C and ?-UZr2 from the couple at 580 (&)deg;C. Intrinsic diffusion coefficients at the compositions corresponding to the marker plane were determined based on Heumann analysis: U intrinsically diffused an order magnitude faster than Zr. Arrhenius temperature-dependence, Darken relation, and comparison to existing literature data demonstrated consistency in results.Monolithic fuel plate assembly was fabricated by sequential process of (1) co-rolling to laminate the Zr barrier onto the U10Mo fuel alloy and (2) HIP to encase the fuel laminated with Zr, within the Al-alloy 6061 (AA6061). In this study, HIP process was carried out as functions of temperature (520, 540, 560 and 580 (&)deg;C for 90 minutes), time (45, 60, 90, 180 and 345 minutes at 560 (&)deg;C) with ramp-cool rate (35, 70 and 280 (&)deg;C/hour). At the interface between the U10Mo and Zr, following the co-rolling, the UZr2 phase was observed to develop adjacent to Zr, and the ?U phase was found between the UZr2 and U10Mo. Mo2Zr was found as precipitates mostly within the ?U phase. Observable growth due to HIP was only observed for the (Al,Si)3Zr phase found at the Zr/AA6061 interface, however, with a large activation energy of 457 kJ/mol. Decomposition of ?U into ?U and ?' was observed in the U10Mo alloy. The volume fraction of ? and ?' increased as the HIP temperature and ramp-cool rate decreased. The UC-UO2 inclusions within the U10Mo fuel alloy were observed, but the volume percent of the UC-UO2 inclusions within the U10Mo alloy, ranging from approximately 0.5 to 1.8, did not change as functions of HIP temperature and holding time. However, the inclusions located near the surface of the U10Mo alloy, were frequently observed to interfere the uniformity of interdiffusion and reaction between the U10Mo alloy and Zr diffusion barrier. The regions of limited interaction between the U10Mo and Zr barrier associated with UC-UO2 inclusions decreased with an increase in HIP temperature, however no significant trend was observed with an increase in HIP duration at 560 (&)deg;C.
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Date Issued
2016
Identifier
CFE0006371, ucf:51499
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006371
MECHANISMS OF LIFETIME IMPROVEMENT IN THERMAL BARRIER COATINGS WITH HF AND/OR Y MODIFICATION OF CMSX-4 SUPERALLOY SUBSTRATES
Title
MECHANISMS OF LIFETIME IMPROVEMENT IN THERMAL BARRIER COATINGS WITH HF AND/OR Y MODIFICATION OF CMSX-4 SUPERALLOY SUBSTRATES.
Creator
Liu, Jing, Sohn, Yong ho, University of Central Florida
Abstract / Description
In modern turbine engines for propulsion and energy generation, thermal barrier coating (TBCs) protect hot-section blades and vanes, and play a critical role in enhancing reliability, durability and operation efficiency. In this study, thermal cyclic lifetime and microstructural degradation of electron beam physical vapor deposited (EB-PVD) Yttria Stabilized Zirconia (YSZ) with (Ni,Pt)Al bond coat and Hf- and/or Y- modified CMSX-4 superalloy substrates were examined. Thermal cyclic lifetime...
Show moreIn modern turbine engines for propulsion and energy generation, thermal barrier coating (TBCs) protect hot-section blades and vanes, and play a critical role in enhancing reliability, durability and operation efficiency. In this study, thermal cyclic lifetime and microstructural degradation of electron beam physical vapor deposited (EB-PVD) Yttria Stabilized Zirconia (YSZ) with (Ni,Pt)Al bond coat and Hf- and/or Y- modified CMSX-4 superalloy substrates were examined. Thermal cyclic lifetime of TBCs was measured using a furnace thermal cycle test that consisted of 10-minute heat-up, 50-minute dwell at 1135C, and 10-minute forced-air-quench. TBC lifetime was observed to improve from 600 cycles to over 3200 cycles with appropriated Hf- and/or Y alloying of CMSX-4 superalloys. This significant improvement in TBC lifetime is the highest reported lifetime in literature with similar testing parameters. Beneficial role of reactive element (RE) on the durability of TBCS were systematically investigated in this study. Photostimulated luminescence spectroscopy (PL) was employed to non-destructively measure the residual stress within the TGO scale as a function of thermal cycling. Extensive microstructural analysis with emphasis on the YSZ/TGO interface, TGO scale, TGO/bond coat interface was carried out by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning electron microscopy (STEM) as a funcion of thermal cycling including after the spallation failure. Focused ion beam in-situ lift-out (FIB-INLO) technique was employed to prepare site-specific TEM specimens. X-ray diffraction (XRD) and secondary ion mass spectroscopy (SIMS) were also employed for phase identification and interfacial chemical analysis. While undulation of TGO/bond coat interface (e.g., rumpling and ratcheting) was observed to be the main mechanism of degradation for the TBCs on baseline CMSX-4, the same interface remained relatively flat (e.g., suppressed rumpling and ratcheting) for durable TBCs on Hf- and/or Y-modified CMSX-4. The fracture paths changed from the YSZ/TGO interface to the TGO/bond coat interface when rumpling was suppressed. The geometrical incompatibility between the undulated TGO and EB-PVD YSZ lead to the failure at the YSZ/TGO interface for TBCs with baseline CMSX-4. The magnitude of copressive residual stress within the TGO scale measured by PL gradually decreased as a function of thermal cycling for TBCs with baseline CMSX-4 superalloy substrates. This gradual decrease corrsponds well to the undulation of the TGO scale that may lead to relaxation of the compressive residual stress within the TGO scale. For TBCs with Hf- and/or Y-modified CMSX-4 superalloy substrates, the magnitude of compressive residual stress within the TGO scale remained relatively constant throughout the thermal cycling, although PL corresponding to the stress-relief caused by localized cracks at the TGO/bond coat interface and within the TGO scale was observed frequently starting 50% of lifetime. A slightly smaller parabolic growth constant and grain size of the TGO scale was observed for TBCs with Hf- and/or Y- modified CMSX-4. Small monoclinic HfO2 precipitates were observed to decorate grain boundaries and the triple pointes within the alpha-Al2O3 scale for TBCs with Hf- and/or Y-modified CMSX-4 substrates. Segregation of Hf/Hf4+ at the TGO/bond coat interfaces was also observed for TBCs with Hf- and/or Y-modified CMSX-4 superalloys substrates. Adherent and pore-free YSZ/TGO interface was observed for TBCs with Hf- and/or Y-modified CMSX-4, while a significant amount of decohesion at the YSZ/TGO interface was observed for TBCs with baseline CMSX-4. The beta-NiAl(B2) phase in the (Ni,Pt)Al bond coat was observed to partially transform into gama prime-Ni3Al (L12) phase due to depletion of Al in the bond coat during oxidation. More importantly, the remaining beta-NiAl phase transformed into L10 martensitic phase upon cooling even though there was no significant difference in these phase transformations for all TBCs. Results from these microstructural observations are documented to elucidate mechanisms that suppress the rumpling of the TGO/bond coat interface, which is responsible for superior performance of EB-PVD TBCs with (Ni,Pt)Al bond coat and Hf- and/or Y-modified CMXS-4 superalloy.
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Date Issued
2007
Identifier
CFE0001872, ucf:47382
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001872
PHASE-SHIFTING HAAR WAVELETS FOR IMAGE-BASED RENDERING APPLICATIONS
Title
PHASE-SHIFTING HAAR WAVELETS FOR IMAGE-BASED RENDERING APPLICATIONS.
Creator
Alnasser, Mais, Foroosh, Hassan, University of Central Florida
Abstract / Description
In this thesis, we establish the underlying research background necessary for tackling the problem of phase-shifting in the wavelet transform domain. Solving this problem is the key to reducing the redundancy and huge storage requirement in Image-Based Rendering (IBR) applications, which utilize wavelets. Image-based methods for rendering of dynamic glossy objects do not truly scale to all possible frequencies and high sampling rates without trading storage, glossiness, or computational time,...
Show moreIn this thesis, we establish the underlying research background necessary for tackling the problem of phase-shifting in the wavelet transform domain. Solving this problem is the key to reducing the redundancy and huge storage requirement in Image-Based Rendering (IBR) applications, which utilize wavelets. Image-based methods for rendering of dynamic glossy objects do not truly scale to all possible frequencies and high sampling rates without trading storage, glossiness, or computational time, while varying both lighting and viewpoint. This is due to the fact that current approaches are limited to precomputed radiance transfer (PRT), which is prohibitively expensive in terms of memory requirements when both lighting and viewpoint variation are required together with high sampling rates for high frequency lighting of glossy material. At the root of the above problem is the lack of a closed-form run-time solution to the nontrivial problem of rotating wavelets, which we solve in this thesis. We specifically target Haar wavelets, which provide the most efficient solution to solving the tripleproduct integral, which in turn is fundamental to solving the environment lighting problem. The problem is divided into three main steps, each of which provides several key theoretical contributions. First, we derive closed-form expressions for linear phase-shifting in the Haar domain for one-dimensional signals, which can be generalized to N-dimensional signals due to separability. Second, we derive closed-form expressions for linear phase-shifting for two-dimensional signals that are projected using the non-separable Haar transform. For both cases, we show that the coefficients of the shifted data can be computed solely by using the coefficients of the original data. We also derive closed-form expressions for non-integer shifts, which has not been reported before. As an application example of these results, we apply the new formulae to image shifting, rotation and interpolation, and demonstrate the superiority of the proposed solutions to existing methods. In the third step, we establish a solution for non-linear phase-shifting of two-dimensional non-separable Haar-transformed signals, which is directly applicable to the original problem of image-based rendering. Our solution is the first attempt to provide an analytic solution to the difficult problem of rotating wavelets in the transform domain.
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Date Issued
2008
Identifier
CFE0002214, ucf:47882
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002214
Phase Transformations and Microstructural Evolution in the U-10 wt.% Mo Alloy with Various Zr Additions at 900C and 650C
Title
Phase Transformations and Microstructural Evolution in the U-10 wt.% Mo Alloy with Various Zr Additions at 900C and 650C.
Creator
Eriksson, Nicholas, Sohn, Yongho, Challapalli, Suryanarayana, Coffey, Kevin, University of Central Florida
Abstract / Description
The Reduced Enrichment for Research and Test Reactor (RERTR) now known as the Material Minimization and Management Reactor Control program (MMMRC) seeks to replace the use of highly enriched uranium (HEU) fuels used in research and test nuclear reactors around the world. The low enriched uranium (LEU) fuels must have fissionable uranium densities comparable to the HEU fuels. After extensive investigation by various researchers around the world, the U-Mo alloys were selected as a promising...
Show moreThe Reduced Enrichment for Research and Test Reactor (RERTR) now known as the Material Minimization and Management Reactor Control program (MMMRC) seeks to replace the use of highly enriched uranium (HEU) fuels used in research and test nuclear reactors around the world. The low enriched uranium (LEU) fuels must have fissionable uranium densities comparable to the HEU fuels. After extensive investigation by various researchers around the world, the U-Mo alloys were selected as a promising candidate. The Mo alloyed with U allows for the stabilization of the face-centered cubic ?-U phase, which demonstrated favorable irradiation behavior. However, deleterious diffusional interaction between the fuel and the cladding, typically Al-base alloy, remain a challenge to overcome for application of U-Mo alloys as the LEU fuel. Zr has been identified as a potential diffusion barrier between monolithic U-10 wt.% Mo (U10Mo) metallic fuel and AA6061 cladding alloys for the development of a LEU fuel system. However, interdiffusion and reaction between the Zr barrier and U10Mo fuel can produce phases such as Mo2Zr, and promote the destabilization of ?-U phase into ?'-U (U2Mo) and ?-U. In order to better understand this phenomenon, this study examined the phases that are present in the U10Mo alloys with varying Zr concentration, 0, 0.5, 1.0, 2.0, 5.0, 10.0, 20.0 wt.% at room temperature after heat treatment at 900(&)deg;C for 168 hours and 650(&)deg;C for 3 hours. These two temperatures are relevant to fuel plate fabrication process of homogenization and hot-rolling, respectively. Scanning electron microscopy and X-ray diffraction were employed to identify and quantitatively document the constituent phases and microstructure to elucidate the nature of phase transformations. For U10Mo alloys containing less than 1.0 wt.% Zr, there was no significant formation of Mo2Zr after 900?C homogenization and subsequent heat treatment at 650?C for 3 hours. The ?-U phase also remained stable correspondingly for these alloys containing less than 1.0 wt.% Zr. For U10Mo alloys containing 2 wt.% or more Zr, a significant amount of Mo2Zr formation was observed after 900?C homogenization and subsequent heat treatment at 650?C for 3 hours. For these alloys, destabilization of ?-U into ?'-U (U2Mo), UZr2 and ?-U was observed. The alloy containing 20 wt.% Zr, however, did not demonstrate ?-U decomposition even though Mo2Zr was observed after heat treatments. The formation of Mo2Zr effectively reduced the stability of the metastable ?-U phase by depleting the ?-stabilizing Mo. The destabilization of ?-U phase into the ?-U phase is not favorable due to anisotropic and poor irradiation behavior of ?-U phase. Therefore the formation of Mo2Zr at the interface between U10Mo fuel and Zr diffusion barrier must be carefully controlled during the fabrication of monolithic LEU fuel system for successful implementation.
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Date Issued
2015
Identifier
CFE0005943, ucf:50812
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0005943
INVESTIGATION OF THERMAL, ELASTIC AND LOAD-BIASED TRANSFORMATION STRAINS IN NITI SHAPE MEMORY ALLOYS
Title
INVESTIGATION OF THERMAL, ELASTIC AND LOAD-BIASED TRANSFORMATION STRAINS IN NITI SHAPE MEMORY ALLOYS.
Creator
Qiu, Shipeng, Vaidyanathan, Raj, University of Central Florida
Abstract / Description
Polycrystalline NiTi shape memory alloys have the ability to recover their original, pre-deformed shape in the presence of external loads when heated through a solid-solid phase transformation from a lower-symmetry B19' martensite phase to a higher-symmetry B2 austenite phase. The strain associated with a shape memory alloy in an actuator application typically has thermal, elastic and inelastic contributions. The objective of this work was to investigate the aforementioned strains by...
Show morePolycrystalline NiTi shape memory alloys have the ability to recover their original, pre-deformed shape in the presence of external loads when heated through a solid-solid phase transformation from a lower-symmetry B19' martensite phase to a higher-symmetry B2 austenite phase. The strain associated with a shape memory alloy in an actuator application typically has thermal, elastic and inelastic contributions. The objective of this work was to investigate the aforementioned strains by recourse to in situ neutron diffraction experiments during selected combinations of heating, cooling and/or mechanical loading. The primary studies were conducted on polycrystalline Ni49.9Ti50.1 specimens on the Spectrometer for MAterials Research at Temperature and Stress (SMARTS) at Los Alamos National Laboratory. Quantitative information on the phase-specific strain, texture and phase fraction evolution was obtained from the neutron data using Rietveld refinement and single-peak analyses, and compared with macroscopic data from extensometry. First, the lattice strain evolution during heating and cooling in an unloaded sample (i.e., free-recovery experiment) was studied. The lattice strain evolution remained linear with temperature and was not influenced by intergranular stresses, enabling the determination of a thermal expansion tensor that quantified the associated anisotropy due to the symmetry of B19' NiTi. The tensor thus determined was subsequently used to obtain an average coefficient of thermal expansion that was consistent with macroscopic dilatometric measurements and a 30,000 grain polycrystalline self-consistent model. The accommodative nature of B19' NiTi was found to account for macroscopic shape changes lagging (with temperature) the start and finish of the transformation. Second, the elastic response of B19' martensitic NiTi variants during monotonic loading was studied. Emphasis was placed on capturing and quantifying the strain anisotropy which arises from the symmetry of monoclinic martensite and internal stresses resulting from intergranular constraints between individual variants and load re-distribution among variants as the texture evolved during variant reorientation and detwinning. The methodology adopted took into account both tensile and compressive loading given the asymmetric response in the texture evolution. Plane specific elastic moduli were determined from neutron measurements and compared with those determined using a self-consistent polycrystalline deformation model and from recently reported elastic stiffness constants determined via ab initio calculations. The comparison among the three approaches further helped understand the influence of elastic anisotropy, intergranular constraint, and texture evolution on the deformation behavior of polycrystalline B19' NiTi. Connections were additionally made between the assessed elastic properties of martensitic NiTi single crystals (i.e., the single crystal stiffness tensor) and the overall macroscopic response in bulk polycrystalline form. Lastly, the role of upper-cycle temperature, i.e., the maximum temperature reached during thermal cycling, was investigated during load-biased thermal cycling of NiTi shape memory alloys at selected combinations of stress and temperature. Results showed that the upper-cycle temperature, under isobaric conditions, significantly affected the amount of transformation strain and thus the work output available for actuation. With the objective of investigating the underlying microstructural and micromechanical changes due to the influence of the upper-cycle temperature, the texture evolution was systematically analyzed. While the changes in transformation strain were closely related to the evolution in texture of the room temperature martensite, retained martensite in the austenite state could additionally affect the transformation strain. Additionally, multiple thermal cycles were performed under load-biased conditions in both NiTi and NiTiPd alloys, to further assess and understand the role of retained martensite. Dimensional and thermal stabilities of these alloys were correlated with the volume fraction and texture of retained martensite, and the internal strain evolution in these alloys. The role of symmetry, i.e., B19' monoclinic martensite vs. B19 orthorhombic martensite in these alloys was also assessed. This work not only established a methodology to study the thermal and elastic properties of the low symmetry B19' monoclinic martensite, but also provided valuable insight into quantitative micromechanical and microstructural changes responsible for the thermomechanical response of NiTi shape memory alloys. It has immediate implications for optimizing shape memory behavior in the alloys investigated, with extension to high temperature shape memory alloys with ternary and quaternary elemental additions, such as Pd, Pt and Hf. This work was supported by funding from NASAÂÂ's Fundamental Aeronautics Program, Supersonics Project (NNX08AB51A) and NSF (CAREER DMR-0239512). It benefited additionally from the use of the Lujan Neutron Scattering Center at Los Alamos National Laboratory, which is funded by the Office of Basic Energy Sciences (Department of Energy) and is operated by Los Alamos National Security LLC under DOE Contract DE-AC52-06NA25396.
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Date Issued
2010
Identifier
CFE0003362, ucf:48440
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0003362