Current Search: electrospray (x)
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- Title
- Enhanced Structure and Crystallinity of Semiconducting Polymer Films Through Electrospray Deposition.
- Creator
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Rodriguez, Johan, Deng, Weiwei, Challapalli, Suryanarayana, Orlovskaya, Nina, University of Central Florida
- Abstract / Description
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Electrospray atomization is a method that uses electrical stresses as the means of generatingcharged droplets. The fundamental working principles of electrospray have previously been extensivelystudied and demonstrated to have monodisperse droplet size distribution, good stabilityand scalability. Electrospray is a bottom-up deposition method which opens up the possibility of aroll-to-roll compatible process and is functional at regular atmospheric conditions. Due to this setof positive...
Show moreElectrospray atomization is a method that uses electrical stresses as the means of generatingcharged droplets. The fundamental working principles of electrospray have previously been extensivelystudied and demonstrated to have monodisperse droplet size distribution, good stabilityand scalability. Electrospray is a bottom-up deposition method which opens up the possibility of aroll-to-roll compatible process and is functional at regular atmospheric conditions. Due to this setof positive qualities, this atomization method holds promise as a means of solution based materialprocessing that is cost effective and scalable. Conjugated polymers are among the solution processablematerials of most interest, poly(3-hexylthiophene)(P3HT) standing out as one of the mostextensively studied. Applications of P3HT as a p-type semiconductor have been demonstrated indevices like organic solar cells, light emitting diodes and transistors. Improvements in the performanceof the mentioned devices have been correlated with a higher degree of crystallinity as wellas the film structure in the case of organic solar cells.The effects of different electrospray process parameters are investigated and various P3HT filmstructures are presented in this study. Electric repulsion present within the droplets in electrosprayand evaporation of the solvent were used to obtain high aspect ratio features on the P3HT films. Aclever design for the electrospray nozzle devised to improve the process stability is presented. Also,the crystallinity of the films was characterized using grazing incidence x-ray diffraction (GIXRD)and ultraviolet visible spectroscopy. All results in this study are presented as a comparison tospin coated control process. The GIXRD results suggest that the electrospray process producescrystallites that have an orientation opposite of the orientation observed in the spin coated process.Analysis of the ultraviolet visible spectroscopy absorption spectrum shows a red-shift, signalingan increase in the crystallinity. Lastly, good contact between the deposited P3HT and the substratewas confirmed using conductive atomic force microscopy (CAFM).iii
Show less - Date Issued
- 2015
- Identifier
- CFE0005879, ucf:50881
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005879
- Title
- SCALABLE NANO PARTICLE PRODUCTION OF LOW BIOAVAILABILITY PHARMACEUTICALS FOR AUGMENTED AQUEOUS SOLUBILITY.
- Creator
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Madden, Aaron, Deng, Wei Wei, University of Central Florida
- Abstract / Description
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The billion dollar pharmaceutical research and development pipeline suffers greatly from high attrition rates of novel therapeutic compounds within pre-clinical and clinical trials. Poor bioavailability in many new drugs, originating in the various methodologies of high throughput screening, may explain part of these growing failure rates. One interpretation of this phenomenon relies on bioavailability's correlation with aqueous solubility; much modern processing allows chemicals to fully...
Show moreThe billion dollar pharmaceutical research and development pipeline suffers greatly from high attrition rates of novel therapeutic compounds within pre-clinical and clinical trials. Poor bioavailability in many new drugs, originating in the various methodologies of high throughput screening, may explain part of these growing failure rates. One interpretation of this phenomenon relies on bioavailability's correlation with aqueous solubility; much modern processing allows chemicals to fully develop without touching water, yielding upwards of 90% of new chemical entities practically insoluble in aqueous media. Thus, one approach to alleviating bioavailability and potentially clinical attrition rates necessitates augmented aqueous solubility. The amorphous nanoparticle presents the largest boost in aqueous solubility of a chemical through processing alone. In this contribution, we propose electrospray as a novel, competitive candidate to produce pharmaceutical amorphous nanoparticles with the intent of augmenting solubility. Electrospray represents an idyllic nominee for three reasons: repeatability, flexibility, and scalability. Electrospray offers low batch to batch variation with less than 30% relative standard deviation between various droplets. This triumphs over the several orders of magnitude in variation in pneumatic sprays. Electrospray's flexibility draws from its ability to attain diameters over several orders of magnitude, ranging from hundreds of microns to several nanometers; in this contribution droplets are produced between 500 nm and 1 [micro]m. Finally, electrospray displays scalability to any industrial requirement; though a single nozzle operates at mere microliters per hour, a single multiplexed array of emitters may increase this throughput by several orders of magnitude. This exploration, utilizing Indomethacin as a model low solubility chemical, verifies electrospray as a compatible processing tool for the pharmaceutical industry. Scanning electron microscopy coupled with the image analysis software ImageJ gleans the size and shape of emitted (and dried) particles. Amorphicity verification of particles employs grazing angle x-ray diffraction. Finally, ultraviolet and visual spectrum spectroscopy evaluates the solubility advantage of particles.
Show less - Date Issued
- 2014
- Identifier
- CFH0004546, ucf:45179
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004546
- Title
- Electroplated micro- and nanoscale structures for emitters and sensors.
- Creator
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Wang, Xiaochen, Cho, Hyoung, Fang, Jiyu, Chen, Quanfang, Lee, Woo Hyoung, University of Central Florida
- Abstract / Description
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In the electroplating process, dissolved metal cations are reduced by electrical current to a form a coherent metal coating on an electrode. Therefore, electroplating is primarily applied to modify the surface properties of an object (e.g. abrasion and wear resistance, corrosion protection, lubricity, aesthetic qualities, etc.), but also be applied to build up high aspect ratio structures on undersized parts or to form devices by electroforming.Compared with other common MEMS ...
Show moreIn the electroplating process, dissolved metal cations are reduced by electrical current to a form a coherent metal coating on an electrode. Therefore, electroplating is primarily applied to modify the surface properties of an object (e.g. abrasion and wear resistance, corrosion protection, lubricity, aesthetic qualities, etc.), but also be applied to build up high aspect ratio structures on undersized parts or to form devices by electroforming.Compared with other common MEMS (microelectromechanical systems) metal device fabrication techniques, such as vapor depositions, electroplating has several outstanding advantages. First, the fabrication process is cost-efficient because electroplating process can be set up easily without complex and expensive facilities. Second, the fabrication condition of electroplating is less demanding and does not require high temperature or low pressure. Furthermore, the process is applicable to making various features consisting of nanometer to millimeter scale particles, wires, and films. Thus, in this thesis, based on the design requirements of electrospray emitters and environmental sensors, the electroplating method was chosen to fabricate micro- and nanoscale structures for such applications.Electrospray is an atomization technique by which an electrically conductive liquid through a small capillary is charged with high voltage (kV) and ejected to a ground electrode. To minimize the electric field edge effect of the emitter nozzles to get even electro-hydrodynamic pulling force on the liquid among the nozzles and minimize variation from one emitter to another, the device needs to have the viscous pressure drop across each nozzle dominant over the electro-hydrodynamic pulling force. Therefore, embedded structures that can create high flow impedance are desirable to achieve uniform feeding of low flow rate of liquid to each emitter.We designed and fabricated in-plane metallic electrospray devices with an embedded array of micropillars within a microchannel by photolithography and electroplating. The novelty of the proposed research lies in its embedded flow restriction structure, scalability, and ease of fabrication. The formation of jets as well as the flexing capability of the emitter was achieved. The other application of electroplating was demonstrated in the fabrication of environmental sensors. Utilizing a pulsed electroplating method, Co-Cu metal alloy films were prepared and Cu was selectively etched to fabricate nanoporous electrodes which could be used to measure both absolute levels and changes of phosphate concentration in aqueous environments. The formation of cobalt phosphate compound could be used for the detection. The increased surface area and relatively simple fabrication protocols make the proposed method attractive and promising for many environmental sensing applications.
Show less - Date Issued
- 2014
- Identifier
- CFE0005274, ucf:50548
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005274
- Title
- Electrospray and Superlens Effect of Microdroplets for Laser-Assisted Nanomanufacturing.
- Creator
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Castillo Orozco, Eduardo, Kumar, Ranganathan, Mansy, Hansen, Peles, Yoav, University of Central Florida
- Abstract / Description
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Nanoparticles of various materials are known to exhibit excellent mechanical, chemical, electrical, and optical properties. However, it is difficult to deposit and transform nanoparticles into large two-dimensional and three-dimensional structures, such as thin films and discrete arrays. Electrospray technology and laser heating enable the deposition of these nanoparticles through the dual role of microdroplets as nanoparticle carriers and superlenses. The main goals of this dissertation are...
Show moreNanoparticles of various materials are known to exhibit excellent mechanical, chemical, electrical, and optical properties. However, it is difficult to deposit and transform nanoparticles into large two-dimensional and three-dimensional structures, such as thin films and discrete arrays. Electrospray technology and laser heating enable the deposition of these nanoparticles through the dual role of microdroplets as nanoparticle carriers and superlenses. The main goals of this dissertation are to delineate the electrospray modes, to achieve subwavelength focusing, and to enable a process for the deposition of nanoparticles into microlayers and discrete nanodots (a nanodot is a cluster of nanoparticles) on rigid and flexible substrates. This additive manufacturing process is based on the electrospray generation of water microdroplets that carry nanoparticles onto a substrate and the laser sintering of these nanoparticles. The process involves injecting nanoparticles (contained inside electric field-driven water microdroplets) into a hollow laser beam. The laser beam heats the droplets, causing the water to evaporate and the nanoparticles to sinter and form deposit of material on the substrate.The electrohydrodynamic inkjet printing of nanoparticle suspensions has been accomplished by the operation of an electrospray in microdripping mode and it allows the deposition of monodisperse microdroplets containing nanoparticles into discrete nanodot arrays, narrow lines, and thin films. For flow rates with low Reynolds number, the mode changes from dripping to microdripping mode, and then to a planar oscillating microdripping mode as the electric capillary number, Cae increases. The microdripping mode which is important for depositing discrete array of nanodots is found to occur in a narrow range, 2 ? Cae ? 2.5. The effect of the physical properties on the droplet size and frequency of droplet formation is more precisely described by the relative influence of the electric, gravity, viscous, and capillary forces. A scaling analysis is derived from a fundamental force balance and has yielded a parameter based on the electric capillary number, capillary number, and Bond number. Results for different nanoparticle suspensions with a wide range of physical properties show that the normalized radius of droplet, can be correlated using this parameter in both dripping and microdripping modes. The same parameter also correlates the normalized frequency of droplet formation, Nd* as an increasing function in the microdripping mode. Viscosity affects the shape of the cone by resisting its deformation and thus promoting a stable microdripping mode. Reduction in surface tension decreases the droplet size in the electrospray modes. However, the capillary size and electrical conductivity have minimal effect on the size of the ejected droplets. Electrical conductivity affects the transition between microdripping and oscillating microdripping modes. Based on this analysis, it is possible to design the electrospray to produce uniform monodisperse droplets by manipulating the voltage at the electrode, for any desired nanoparticle concentration of a suspension to be sintered on a substrate. For the fabrication of nanodots, a laser beam of wavelength ? = 1064 nm was focused to a diameter smaller than its wavelength. When the microdroplets did not carry nanoparticles, the subwavelength focusing of the laser yielded nanoholes smaller than its wavelength. Results show that tiny features with high resolution can be created by loading microdroplets with nanoparticles and squeezing the laser beam to subwavelength regions. Nanodots of silicon and germanium with diameters between 100 - 500 nm have been deposited on a silicon substrate. This study demonstrates an interdisciplinary mechanism to achieve subwavelength focusing in a laser process. In this process, the microdroplets serve as both a nanoparticle carrier and a superlens that focuses a laser beam to subwavelength diameters up to ? /10, thus overcoming the diffraction limit. The microdroplets are generated from a suspension of nanoparticles using an electrospray technique and the superlens characteristic of these microdroplets is attributed to three optical phenomena such as Maxwell's fish eye lens or L(&)#252;neberg lens, evanescent waves by laser scattering, and evanescent waves by the total internal reflection principle. A microfluidic cooling effect can also contribute to creating subwavelength features. In summary, this work describes a new laser-assisted additive manufacturing process for the fabrication of nanodots and microlayers using nanoparticles of different materials. In this process, microdroplets from an electrospray are used as nanoparticle carriers and superlenses to focus the laser to a diameter smaller than its wavelength. While this process is demonstrated to produce subwavelength holes and nanodots, the process is scalable to produce narrow lines and thin films of semiconductor materials by an additive manufacturing technique. This process extends the application of infrared lasers to the production of nanostructures and nanofeatures, and, therefore, provides a novel technology for nanomanufacturing.
Show less - Date Issued
- 2018
- Identifier
- CFE0007563, ucf:52579
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007563
- Title
- Response of Electrified Micro-Jets to Electrohydrodynamic Perturbations.
- Creator
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Yang, Weiwei, Deng, Weiwei, Chen, Ruey-Hung, Ilie, Marcel, University of Central Florida
- Abstract / Description
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The breakup of liquid jets is ubiquitous with rich underpinning physics and widespread applications. The natural breakup of liquid jets originates from small ambient perturbations, which can grow exponentially until the amplitude as large as the jet radius is reached. For unelectrified inviscid jets, surface energy analysis shows that only the axisymmetric perturbation is possibly unstable, and this mode is referred as varicose instability. For electrified jets, the presence of surface charge...
Show moreThe breakup of liquid jets is ubiquitous with rich underpinning physics and widespread applications. The natural breakup of liquid jets originates from small ambient perturbations, which can grow exponentially until the amplitude as large as the jet radius is reached. For unelectrified inviscid jets, surface energy analysis shows that only the axisymmetric perturbation is possibly unstable, and this mode is referred as varicose instability. For electrified jets, the presence of surface charge enables additional unstable modes, among which the most common one is the whipping (or kink) instability that bends and stretches the charged jet that is responsible for the phenomena of electrospinning. A closer examination of the two instabilities suggests that due to mass conservation, the uneven jet stretching from whipping may translate into radial perturbations and trigger varicose instabilities. Although the varicose and whipping instabilities of electrified micro-jets have both been extensively studied separately, there is little attention paid to the combined effect of these two, which may lead to new jet breakup phenomena. This dissertation investigates the dynamic response of electrified jets under transverse electrohydrodynamic (EHD) perturbations which were introduced by exciters driven by alternating voltage of sweeping frequency. Three different jetting mechanisms are used to generate jets with various ranges of jet diameters: ~150 micrometer inertial jets from liquid pressurized through a small orifice, ~50 micrometer flow focused jets, and ~20 micrometer electrified Taylor-cone jets. The transverse perturbations enable systematic triggering of varicose and whipping instabilities, and consequently a wide range of remarkable phenomena emerge. For inertial jets with zero or low charge levels, only varicose instability is observable due to suppressed whipping instability. At modest charge levels, inertia jets can respond to the fundamental perturbation frequency as well as the second harmonic of the perturbation frequency. Highly charged jets such as fine jets generated from Taylor cones exhibit distinct behavior for different perturbation wavenumber x. Typical behavior include: whipping jets with superimposed varicose instability at small x, jet bifurcation from crossover of whipping and varicose instabilities at x~0.5, Coulombic fission owing to the surge of surface charge density as the slender liquid segments recover spherical shapes at x~0.7, and simple varicose mode near wave numbers of unity. The phenomena observed in this work may be explained by a linear model and rationalized by the phase diagram in the space of wave number and dimensionless charge levels. The experimental apparatus used in this dissertation is simple, non-intrusive, and scalable to a linear array of jets. The rich phenomena combined with the versatile apparatus may spawn new research directions such as regulated electrospinning, generating strictly monodisperse micro/nano droplets, and manufacturing of non-spherical particles from drying droplets that undergo controlled Coulombic fissions.
Show less - Date Issued
- 2014
- Identifier
- CFE0005744, ucf:50086
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005744
- Title
- EFFECTS OF BINARY SOLVENT SYSTEM ON MORPHOLOGY OF PARTICLES.
- Creator
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Besana, Patrick, Deng, Weiwei, University of Central Florida
- Abstract / Description
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Recent advancements in cancer research has led to the synthesis of a new drug known as docetaxel. Meant to replace paclitaxel, its more natural counterpart whose ingredients are difficult to obtain, the drug is known to effectively treat a wide array of cancers, including breast cancer, ovarian cancer, and prostate cancer. The establishment of a synthetic alternative to paclitaxel has increased its bioavailability, thereby lowering the cost needed to utilize the drug. Still, the limiting...
Show moreRecent advancements in cancer research has led to the synthesis of a new drug known as docetaxel. Meant to replace paclitaxel, its more natural counterpart whose ingredients are difficult to obtain, the drug is known to effectively treat a wide array of cancers, including breast cancer, ovarian cancer, and prostate cancer. The establishment of a synthetic alternative to paclitaxel has increased its bioavailability, thereby lowering the cost needed to utilize the drug. Still, the limiting factor in minimizing costs is the method in which the drug is processed. Current methods in drug processing have their limitations, which include the introduction of impurities and a low effective yield due to poor powder geometry. Thus, the goal of this study looks to explore a new way to process the drug in a more efficient manner. In this study, a new method for processing docetaxel is explored on in great detail. A more direct method of using electrospray deposition is utilized for the creation of monodisperse nanoparticles, with the main intention of increasing the efficiency at which the drug is processed and prepared for drug delivery to the patient by means of injection. A key feature in electrospray deposition is its ability to produce droplets that are sized homogenously. These droplets eventually evaporate at homogenous rates. These two concepts have been exploited to consistently produce nanoparticles of the cancer drug, which is made possible by the fact that the minimal variation in droplet sizes has easily translated to minimal variation in dry particle sizes. Compared to other methods of drug processing, one other benefit that electrospray deposition conveys is that through evaporation, virtually all impurities and unwanted foreign material are eliminated. Moreover, a binary solvent system is investigated in more detail in this study, so as to determine its effects on both the evaporation of the solvent and the diffusion of the drug into nanoparticles. From there, material and geometric properties of the electrospray nozzle were explored upon in great detail, with the main goal of being able to produce a cone jet that consistently dissociates into monodisperse droplets. At the same time, controllable properties of the electrospray atomizer were investigated and continuously modified. Modifications in both the components of the solution and the operating temperature were also considered to enhance both the electrospray deposition process and the geometry of the particles. Scanning electron microscopy (SEM) characterization is continuously utilized to determine suitability of results obtained in experiments. Ultimately, the goal of this study is to determine the ideal conditions (solvent ratios, flow rate, operating temperature, electrospray atomizer nozzle configurations, etc.) in which spherical docetaxel particles sized at 100-200 nm can be produced.
Show less - Date Issued
- 2015
- Identifier
- CFH0004872, ucf:45412
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004872
- Title
- BLACK WRITING INK ANALYSIS BY DIRECT INFUSION ELECTROSPRAY MASS SPECTROSCOPY.
- Creator
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Moody, Christopher, Sigman, Michael, University of Central Florida
- Abstract / Description
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An optimized method of extraction, an instrumental analysis method and data analysis was proposed for black writing inks based on direct infusion electrospray-mass spectrometry (ESI-MS). The sampling and analysis method is both minimally destructive and able to assess differences in inks from a reference collection of thirty ballpoint, gel, and rollerball inks. The methanol extracts of ink on paper samples were analyzed with three direct infusion (ESI-MS) methods. Each method varied scan...
Show moreAn optimized method of extraction, an instrumental analysis method and data analysis was proposed for black writing inks based on direct infusion electrospray-mass spectrometry (ESI-MS). The sampling and analysis method is both minimally destructive and able to assess differences in inks from a reference collection of thirty ballpoint, gel, and rollerball inks. The methanol extracts of ink on paper samples were analyzed with three direct infusion (ESI-MS) methods. Each method varied scan voltage negative and positive, ESI fragmentor applied voltage (+120V, +0V, and -120V), and mobile phase additive. Direct infusion ESI-MS analysis, followed by pair-wise comparisons of the observed ion data in binary form allowed inks to be distinguished from each other. The photobleaching of the dye Basic Violet 3 (BV3) in ink-on-paper samples was examined to determine the use of degradation products as a marker of the age of the writing sample. The extent of photobleaching of BV3 was determined using several illumination sources. Pair-wise comparison of observed ion data was able to distinguish 29 of 30 ink samples using the combined three instrumental methods. Out of 435 pair-wise comparisons 429 pairs could be discriminated from each other using the combined three methods. This is a 98.6% discrimination with the combined analysis scheme.
Show less - Date Issued
- 2010
- Identifier
- CFE0003563, ucf:48929
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003563
- Title
- Towards Scalable Nanomanufacturing: Modeling the Interaction of Charged Droplets from Electrospray using GPU.
- Creator
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Yang, Weiwei, Deng, Weiwei, Chen, Ruey-Hung, Ilie, Marcel, University of Central Florida
- Abstract / Description
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Electrospray is an atomization method subject to intense study recently due to its monodispersity and the wide size range of droplets it can produce, from nanometers to hundreds of micrometers. This thesis focuses on the numerical and theoretical modeling of the interaction of charged droplets from the single and multiplexed electrospray. We studied two typical scenarios: large area film depositions using multiplexed electrospray and fine pattern printings assisted by linear electrostatic...
Show moreElectrospray is an atomization method subject to intense study recently due to its monodispersity and the wide size range of droplets it can produce, from nanometers to hundreds of micrometers. This thesis focuses on the numerical and theoretical modeling of the interaction of charged droplets from the single and multiplexed electrospray. We studied two typical scenarios: large area film depositions using multiplexed electrospray and fine pattern printings assisted by linear electrostatic quadrupole focusing. Due to the high computation power requirement in the unsteady n-body problem, graphical processing unit (GPU) which delivers 10 Tera flops in computation power is used to dramatically speed up the numerical simulation both efficiently and with low cost. For large area film deposition, both the spray profile and deposition number density are studied for different arrangements of electrospray and electrodes. Multiplexed electrospray with hexagonal nozzle configuration can not give us uniform deposition though it has the highest packing density. Uniform film deposition with variation (<) 5% in thickness was observed with the linear nozzle configuration combined with relative motion between ES source and deposition substrate. For fine pattern printing, linear quadrupole is used to focus the droplets in the radial direction while maintaining a constant driving field at the axial direction. Simulation shows that the linear quadrupole can focus the droplets to a resolution of a few nanometers quickly when the inter-droplet separation is larger than a certain value. Resolution began to deteriorate drastically when the inter-droplet separation is smaller than that value. This study will shed light on using electrospray as a scalable nanomanufacturing approach.
Show less - Date Issued
- 2012
- Identifier
- CFE0004463, ucf:49333
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004463
- Title
- MICROSCOPIC SURFACE TEXTURES CREATED BY INTERFACIAL FLOW INSTABILITIES.
- Creator
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Gu, Jing, Weiwei Deng, Dr., University of Central Florida
- Abstract / Description
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In nature, microscopic surface textures impact useful function, such as the drag reduction of shark skin (Dean & Bhushan, 2010) and superhydrophobicity of the lotus leaf(Pan, Kota, Mabry, & Tuteja, 2013). In this study, we explore these phenomena by re-creating microscopic surface textures via the method of interfacial flow instability in drying polyvinylidene fluoride (PVDF) acetone solutions. In general, PVDF films can be made using either spin coating or electrospray deposition with...
Show moreIn nature, microscopic surface textures impact useful function, such as the drag reduction of shark skin (Dean & Bhushan, 2010) and superhydrophobicity of the lotus leaf(Pan, Kota, Mabry, & Tuteja, 2013). In this study, we explore these phenomena by re-creating microscopic surface textures via the method of interfacial flow instability in drying polyvinylidene fluoride (PVDF) acetone solutions. In general, PVDF films can be made using either spin coating or electrospray deposition with various weight concentrations in acetone. In order to study the morphology of the porous structure of PVDF films, wet deposition samples were fabricated by spin coating or near-field electrospray. Possible theories are discussed and examined to explain the formation of these porous structures resulting in development of a well-controlled method to create porous PVDF films with various pore sizes and pore densities. All samples are characterized and found to exhibit superhydrophobicity and drag reduction. To connect porous PVDF film morphology to the established field of dry particle fabrication, PVDF particle synthesis by far-field electrospray is also reviewed and discussed. An established method to generate polymer particles of different morphologies in other polymers (Almeria-Diez, 2012) by electrospray drying is confirmed using PVDF as well. Due to the ability of scalable and re-configurable electrospray, the microscopic surface textures can be applied to areas of any size to reduce drag or impart water-repelling properties.
Show less - Date Issued
- 2013
- Identifier
- CFH0004479, ucf:45066
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004479
- Title
- A Linear Multiplexed Electrospray Thin Film Deposition System.
- Creator
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Lojewski, Brandon, Deng, Weiwei, Chen, Ruey-Hung, Chen, Quanfang, University of Central Florida
- Abstract / Description
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Liquid spray is essential to industries requiring processes such as spray coating, spray drying, spray pyrolysis, or spray cooling. This thesis reports the design, fabrication, and characterization of a thin film deposition system which utilizes a linear multiplexed electrospray (LINES) atomizer. First, a thorough review of the advantages and limitations of prior multiplexed electrospray systems leads to discussion of the design rationale for this work. Next, the line of charge model was...
Show moreLiquid spray is essential to industries requiring processes such as spray coating, spray drying, spray pyrolysis, or spray cooling. This thesis reports the design, fabrication, and characterization of a thin film deposition system which utilizes a linear multiplexed electrospray (LINES) atomizer. First, a thorough review of the advantages and limitations of prior multiplexed electrospray systems leads to discussion of the design rationale for this work. Next, the line of charge model was extended to prescribe the operating conditions for the experiments and to estimate the spray profile. The spray profile was then simulated using a Lagrangian model and solved using a desktop supercomputer based on Graphics Processing Units (GPUs). The simulation was extended to estimate the droplet number density flux during deposition. Pure ethanol was electrosprayed in the cone-jet mode from a 51-nozzle aluminum LINES atomizer with less than 3% relative standard deviation in the D10 average droplet diameter as characterized using Phase Doppler Interferometry (PDI). Finally a 25-nozzle LINES was integrated into a thin film deposition system with a heated, motion controlled stage, to deposit TiO2 thin films onto silicon wafers from an ethanol based nanoparticle suspension. The resulting deposition pattern was analyzed using SEM, optical profilometry, and macro photography and compared with the numerical simulation results. The LINES tool developed here is a step forward to enabling the power of electrospray for industrial manufacturing applications in clean energy, health care, and electronics.
Show less - Date Issued
- 2013
- Identifier
- CFE0005106, ucf:50745
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005106
- Title
- STATISTICAL ANALYSIS OF VISIBLE ABSORPTION SPECTRA AND MASS SPECTRA OBTAINED FROM DYED TEXTILE FIBERS.
- Creator
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White, Katie, Sigman, Michael, University of Central Florida
- Abstract / Description
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The National Academy of Sciences recently published a report which calls for improvements to the field of forensic science. Their report criticized many forensic disciplines for failure to establish rigorously-tested methods of comparison, and encouraged more research in these areas to establish limitations and assess error rates. This study applies chemometric and statistical methods to current and developing analytical techniques in fiber analysis. In addition to analysis of commercially...
Show moreThe National Academy of Sciences recently published a report which calls for improvements to the field of forensic science. Their report criticized many forensic disciplines for failure to establish rigorously-tested methods of comparison, and encouraged more research in these areas to establish limitations and assess error rates. This study applies chemometric and statistical methods to current and developing analytical techniques in fiber analysis. In addition to analysis of commercially available dyed textile fibers, two pairs of dyes are selected for custom fabric dyeing based on the similarities of their absorbance spectra and dye molecular structures. Visible absorption spectra for all fiber samples are collected using microspectrophotometry (MSP) and mass spectra are collected using electrospray ionization (ESI) mass spectrometry. Statistical calculations are performed using commercial software packages and software written in-house. Levels of Type I and Type II error are examined for fiber discrimination based on hypothesis testing of visible absorbance spectra profiles using a nonparametric permutation method. This work also explores evaluation of known and questioned fiber populations based on an assessment of statistical p-value distributions from questioned-known fiber comparisons with those of known fiber self-comparisons. Results from the hypothesis testing are compared with principal components analysis (PCA) and discriminant analysis (DA) of visible absorption spectra, as well as PCA and DA of ESI mass spectra. The sensitivity of a statistical approach will also be discussed in terms of how instrumental parameters and sampling methods may influence error rates.
Show less - Date Issued
- 2010
- Identifier
- CFE0003454, ucf:48396
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003454