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Title: Planar Organic Photovoltaic Devices.
Creator: Alzubi, Feras, Khondaker, Saiful, Chow, Lee, Schelling, Patrick, Gesquiere, Andre, University of Central Florida
Abstract / Description: Organic Photovoltaic devices (OPV) are considered to be attractive candidates for clean and renewable energy source because of their potential for low cost of fabrication, easy processing, and their mechanical flexibility. The device efficiency of OPV cells are limited by several factors. Among them are: (i) donor-acceptor interface, (ii) morphology of the materials, (iii) electrode-organic semiconductor (OSC) interface and (iv) device architecture such as active material thickness and...
Show moreOrganic Photovoltaic devices (OPV) are considered to be attractive candidates for clean and renewable energy source because of their potential for low cost of fabrication, easy processing, and their mechanical flexibility. The device efficiency of OPV cells are limited by several factors. Among them are: (i) donor-acceptor interface, (ii) morphology of the materials, (iii) electrode-organic semiconductor (OSC) interface and (iv) device architecture such as active material thickness and electrode separation. Although, the donor-acceptor interface has been studied in detail, the commonly prevalent vertical OPV device structure does not allow a good understanding of the other key issues as the vertical structure limits one of the electrode to be a transparent electrode as well as introducing inseparable relation between the electrodes separation and the active material thickness. In addition, it is also well known that the charge transport in OSC is anisotropic and the charge mobility is better in lateral direction rather than vertical direction. In order to address some of these issues, we fabricated OPV devices in a planar device structure where cathode and anode of dissimilar metals are in-plane with each other and their photovoltaic behaviors were studied. We used poly(3-hexylthiophene) and [6,6]-pheny1 C61-butyric acid methy1 ester (P3HT:PCBM) blend as an active material. In particular, we present a detailed study about the effects of the structural parameters such as the channel length, the active layer thickness, and the work function of the electrodes on the open circuit voltage (Voc), short circuit current (Isc), fill factor (FF) and the power conversion efficiency (PCE).In order to determine the suitable anode and cathode for the planar organic photovoltaic (P-OPV) structure, we first fabricated and measured organic field effect transistor (OFET) devices with different contacts and studied the effect of barrier height at the P3HT:PCBM/electrode interface on the device output and transport properties. The study showed a clear effect of varying the contact material on the charge injection mechanism and on the carriers mobilities. The results have also shown that Au with high hole mobility and on current in the p-channel can be used as an anode (holes extractor) in the P-OPV device while In, Cr, and Ti that showed a reasonable value of electron mobility can be good candidates for cathode (electron extractor). We also found that, Ag, Al, and Mg showed large barrier which resulted in large threshold voltage in the I-V curve making them undesired cathode materials in the P-OPV device. We then fabricated P-OPV devices with Au as an anode material and varied the cathode material to study the effect of the interface between the P3HT:PCBM layer and the cathode material. When Al, Mg, or Ag used as a cathode material no PV behavior was observed, while PV behavior was observed for In, Cr, and Ti cathode materials. The PV behavior and the characteristic parameters including Voc, Isc, FF and PCE were affected by varying the cathode material. The results have shown that the P-OPV device performance can be affected by the cathode material depending on the properties and the work function of the metal.We have also studied the effect of varying the P3HT:PCBM layer thickness at a fixed channel length for Cr and Ti cathode materials and Au as anode. While Voc and FF values do not change, Isc and PCE increase with increasing the layer thickness due to the increase of the light absorption and charges generation. Moreover, we studied the effect of varying the channel length at a fixed film thickness; and showed that the values of Isc and PCE increase with decreasing channel length while Voc and FF maintain the same value. In this thesis we will also present the results on experimentally defining and testing the illuminated area in the P-OPV device by using different measurement set-ups and different electrodes patterns. The results prove that the illuminated area in the P-OPV device is the area enclosed between the two electrodes. Lastly, we will present the effect of the P3HT:PCBM ratio on the P-OPV device performance. We show that 1:2 ratio is the optimized ratio for the P-OPV device. The detailed results in this thesis show a potential opportunity to help improving and understanding the design of OPV device by understanding the effects of the device structural parameters.
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Date Issued: 2013
Identifier: CFE0004804, ucf:49754
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004804

Title: Advanced Metrology and Diagnostic Loss Analytics for Crystalline Silicon Photovoltaics.
Creator: Schneller, Eric, Schoenfeld, Winston, Thomas, Jayan, Fenton, James, Coffey, Kevin, Sundaram, Kalpathy, University of Central Florida
Abstract / Description: Characterization plays a key role in developing a comprehensive understanding of the structure and performance of photovoltaic devices. High quality characterization methods enable researchers to assess material choices and processing steps, ultimately giving way to improved device performance and reduced manufacturing costs. In this work, several aspects of advanced metrology for crystalline silicon photovoltaic are investigated including in-line applications for manufacturing, off-line...
Show moreCharacterization plays a key role in developing a comprehensive understanding of the structure and performance of photovoltaic devices. High quality characterization methods enable researchers to assess material choices and processing steps, ultimately giving way to improved device performance and reduced manufacturing costs. In this work, several aspects of advanced metrology for crystalline silicon photovoltaic are investigated including in-line applications for manufacturing, off-line applications for research and development, and module/system level applications to evaluate long-term reliability. A frame work was developed to assess the cost and potential value of metrology within a manufacturing line. This framework has been published to an on-line calculator in an effort to provide the solar industry with an intuitive and transparent method of evaluating the economics of in-line metrology. One important use of metrology is in evaluating spatial non-uniformities, as localized defects in large area solar cells often reduce overall device performance. Techniques that probe spatial uniformity were explored and analysis algorithms were developed that provide insights regarding process non-uniformity and its impact on device performance. Finally, a comprehensive suite of module level characterization was developed to accurately evaluate performance and identify degradation mechanisms in field deployed photovoltaic modules. For each of these applications, case-studies were used to demonstrate the value of these techniques and to highlight potential use cases.
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Date Issued: 2016
Identifier: CFE0006499, ucf:51386
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006499

Title: ANALYSIS AND SIMULATION TOOLS FOR SOLAR ARRAY POWER SYSTEMS.
Creator: Pongratananukul, Nattorn, Kasparis, Takis, University of Central Florida
Abstract / Description: This dissertation presents simulation tools developed specifically for the design of solar array power systems. Contributions are made in several aspects of the system design phases, including solar source modeling, system simulation, and controller verification. A tool to automate the study of solar array configurations using general purpose circuit simulators has been developed based on the modeling of individual solar cells. Hierarchical structure of solar cell elements, including...
Show moreThis dissertation presents simulation tools developed specifically for the design of solar array power systems. Contributions are made in several aspects of the system design phases, including solar source modeling, system simulation, and controller verification. A tool to automate the study of solar array configurations using general purpose circuit simulators has been developed based on the modeling of individual solar cells. Hierarchical structure of solar cell elements, including semiconductor properties, allows simulation of electrical properties as well as the evaluation of the impact of environmental conditions. A second developed tool provides a co-simulation platform with the capability to verify the performance of an actual digital controller implemented in programmable hardware such as a DSP processor, while the entire solar array including the DC-DC power converter is modeled in software algorithms running on a computer. This "virtual plant" allows developing and debugging code for the digital controller, and also to improve the control algorithm. One important task in solar arrays is to track the maximum power point on the array in order to maximize the power that can be delivered. Digital controllers implemented with programmable processors are particularly attractive for this task because sophisticated tracking algorithms can be implemented and revised when needed to optimize their performance. The proposed co-simulation tools are thus very valuable in developing and optimizing the control algorithm, before the system is built. Examples that demonstrate the effectiveness of the proposed methodologies are presented. The proposed simulation tools are also valuable in the design of multi-channel arrays. In the specific system that we have designed and tested, the control algorithm is implemented on a single digital signal processor. In each of the channels the maximum power point is tracked individually. In the prototype we built, off-the-shelf commercial DC-DC converters were utilized. At the end, the overall performance of the entire system was evaluated using solar array simulators capable of simulating various I-V characteristics, and also by using an electronic load. Experimental results are presented.
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Date Issued: 2005
Identifier: CFE0000331, ucf:46290
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000331

Title: PROCESSING AND STUDY OF CARBON NANOTUBE / POLYMER NANOCOMPOSITES AND POLYMER ELECTROLYTE MATERIALS.
Creator: Harish, Muthuraman, Huo, Qun, University of Central Florida
Abstract / Description: The first part of the study deals with the preparation of carbon nanotube/polymer nanocomposite materials. The dispersion of multi-walled carbon nanotubes (MWNTs) using trifluoroacetic acid (TFA) as a co-solvent and its subsequent use in polymer nanocomposite fabrication is reported. The use of carbon nanotube/ polymer nanocomposite system for the fabrication of organic solar cells is also studied. TFA is a strong but volatile acid which is miscible with many commonly used organic solvents....
Show moreThe first part of the study deals with the preparation of carbon nanotube/polymer nanocomposite materials. The dispersion of multi-walled carbon nanotubes (MWNTs) using trifluoroacetic acid (TFA) as a co-solvent and its subsequent use in polymer nanocomposite fabrication is reported. The use of carbon nanotube/ polymer nanocomposite system for the fabrication of organic solar cells is also studied. TFA is a strong but volatile acid which is miscible with many commonly used organic solvents. Our study demonstrates that MWNTs can be effectively purified and readily dispersed in a range of organic solvents including dimethyl formamide (DMF), tetrahydrofuran (THF), and dichloromethane when mixed with 10 vol% trifluoroacetic acid (TFA). X-ray photoelectron spectroscopic analysis revealed that the chemical structure of the TFA-treated MWNTs remained intact without oxidation. The dispersed carbon nanotubes in TFA/THF solution were mixed with poly(methyl methacrylate) (PMMA) to fabricate polymer nanocomposites. A good dispersion of nanotubes in solution and in polymer matrices was observed and confirmed by SEM and optical microscopy study. Low percolation thresholds of electrical conductivity were observed from the fabricated MWNT/PMMA composite films. A carbon nanotube/ polymer nanocomposites system was also used for the fabrication of organic solar cells. A blend of single-wall carbon nanotubes (SWNTs) and poly3-hexylthiophene (P3HT) was used as the active layer in the device. The device characteristics showed that the fabrication of the solar cells was successful without any shorts in the circuit. The second part of the study deals with the preparation and characterization of electrode and electrolyte materials for lithium ion batteries. A system of lithium trifluoroacetate/ PMMA was used for its study as the electrolyte in lithium battery. A variety of different processing conditions were used to prepare the polymer electrolyte system. The conductivity of the electrolyte plays a critical role in the high power output of a battery. A high power output requires fast transport of lithium ions for which the conductivity of the electrolyte must be at least 3 x 10^-4 S/cm. Electrochemical Impedance Spectroscopy (EIS) was used to determine the conductivity of the polymer electrolyte films. Among the different processing conditions used to prepare the polymer electrolyte material, wet films of PMMA/salt system prepared by using 10vol% of TFA in THF showed the best results. At about 70wt% loading of the salt in the polymer, the conductivity obtained was about 1.1 x 10^-2 S/cm. Recently, the use of vanadium oxide material as intercalation host for lithium has gained widespread attention. Sol-gel derived vanadium oxide films were prepared and its use as a cathode material for lithium ion battery was studied. The application of carbon nanotubes in lithium ion battery was explored. A carbon nanotube /block copolymer (P3HT-b-PS) composite was prepared and its potential as an anode material was evaluated.
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Date Issued: 2007
Identifier: CFE0001941, ucf:47436
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001941

Title: HIGH VOLTAGE BIAS TESTING AND DEGRADATION ANALYSIS OF PHOTOVOLTAIC MODULES.
Creator: Hadagali, Vinaykumar, Dhere, Neelkanth, University of Central Florida
Abstract / Description: This thesis mainly focuses on two important aspects of the photovoltaic modules. The first aspect addressed the high voltage bias testing and data and degradation analysis of high voltage biased thin film photovoltaic modules. The second aspect addressed the issues of reliability and durability of crystalline silicon module. Grid-connected photovoltaic systems must withstand high voltage bias in addition to harsh environmental conditions such as intermittent solar irradiance, high humidity,...
Show moreThis thesis mainly focuses on two important aspects of the photovoltaic modules. The first aspect addressed the high voltage bias testing and data and degradation analysis of high voltage biased thin film photovoltaic modules. The second aspect addressed the issues of reliability and durability of crystalline silicon module. Grid-connected photovoltaic systems must withstand high voltage bias in addition to harsh environmental conditions such as intermittent solar irradiance, high humidity, heat and wind. a-Si:H thin-film photovoltaic modules with earlier generation SnO2:F transparent conducting oxide (TCO) on the front glass installed on the FSEC High Voltage Test Bed were monitored since December 2001. The data was collected on a daily basis and analyzed. The leakage currents for some chosen time period were calculated and compared with the measured values. Current-voltage characteristic measurements were carried out to check any reduction in the power. Samples were cored and extracted for analysis from one of the -600 V biased modules. Leakage currents in high-voltage-biased laminates specially prepared with improved SnO2:F TCO are being monitored in the hot and humid climate in Florida. Negatively-biased modules showed clear signs of delamination. The leakage currents in high-voltage biased photovoltaic modules are functions of both temperature and relative humidity. Photovoltaic module leakage conductance was found to be thermally stimulated with a characteristic activation energy that depends on relative humidity. The adhesional strength was lost completely in the damaged area. Leakage current values from support to ground in new, unframed laminates fabricated with improved SnO2:F TCO layer were ~100 times lower under the high voltage bias in hot and humid environment. Information on the failure of field deployed modules must be complemented with why and how the modules fail while considering the issues of reliability and durability of crystalline silicon module. At present, all the failure modes have not been identified and failure mechanisms have not been understood. Experience has shown that as the materials and processes are changed, reliability issues that apparently had been resolved resurface. A multicrystalline silicon photovoltaic module that was manufactured by a non-US company and that had shown >50% performance loss in field-deployment of <2 years in hot and dry climate were studied for degradation analysis in comparison with a mc-Si module that was manufactured by the same company and that performed well after 10 years of field-deployment in hot and humid climate.. I-V measurements were carried out to analyze the reduction in photovoltaic parameters. Solder bond strength in mc-Si photovoltaic modules were measured to understand early degradation of performance. Samples were cored and extracted for further analysis. Adhesional strength between the busline metallization and the silicon cell in a newer generation mc-Si photovoltaic module was found to be considerably lower than that in the earlier vintage module. These results can be useful for early detection and diagnosis of field reliability issues and could assist in establishing correlation between long-term field data and observations and accelerated environmental stress testing. It is suggested that more detailed study should be undertaken using unencapsulated strings of crystalline silicon modules so as to avoid complication due to encapsulant creeping beneath the ribbons.
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Date Issued: 2005
Identifier: CFE0000798, ucf:46563
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000798

Title: FPGA-BASED DESIGN OF A MAXIMUM-POWER-POINT TRACKING SYSTEM FOR SPACE APPLICATIONS.
Creator: Persen, Todd, Ejnioui, Abdel, University of Central Florida
Abstract / Description: Satellites need a source of power throughout their missions to help them remain operational for several years. The power supplies of these satellites, provided primarily by solar arrays, must have high efficiencies and low weights in order to meet stringent design constraints. Power conversion from these arrays is required to provide robust and reliable conversion which performs optimally in varying conditions of peak power, solar flux, and occlusion conditions. Since the role of these arrays...
Show moreSatellites need a source of power throughout their missions to help them remain operational for several years. The power supplies of these satellites, provided primarily by solar arrays, must have high efficiencies and low weights in order to meet stringent design constraints. Power conversion from these arrays is required to provide robust and reliable conversion which performs optimally in varying conditions of peak power, solar flux, and occlusion conditions. Since the role of these arrays is to deliver power, one of the principle factors in achieving maximum power output from an array is tracking and holding its maximum-power point. This point, which varies with temperature, insolation, and loading conditions, must be continuously monitored in order to react to rapid changes. Until recently, the control of maximum power point tracking (MPPT) has been implemented in microcontrollers and digital signal processors (DSPs). While DSPs can provide a reasonable performance, they do not provide the advantages that field-programmable gate arrays (FPGA) chips can potentially offer to the implementation of MPPT control. In comparison to DSP implementations, FPGAs offer lower cost implementations since the functions of various components can be integrated onto the same FPGA chip as opposed to DSPs which can perform only DSP-related computations. In addition, FPGAs can provide equivalent or higher performance with the customization potential of an ASIC. Because FPGAs can be reprogrammed at any time, repairs can be performed in-situ while the system is running thus providing a high degree of robustness. Beside robustness, this reprogrammability can provide a high level of (i) flexibility that can make upgrading an MPPT control system easy by merely updating or modifying the MPPT algorithm running on the FPGA chip, and (ii) expandability that makes expanding an FPGA-based MPPT control system to handle multi-channel control. In addition, this reprogrammability provides a level of testability that DSPs cannot match by allowing the emulation of the entire MPPT control system onto the FPGA chip. This thesis proposes an FPGA-based implementation of an MPPT control system suitable for space applications. At the core of this system, the Perturb-and-observe algorithm is used to track the maximum power point. The algorithm runs on an Alera FLEX 10K FPGA chip. Additional functional blocks, such as the ADC interface, FIR filter, dither generator, and DAC interface, needed to support the MPPT control system are integrated within the same FPGA device thus streamlining the part composition of the physical prototype used to build this control system.
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Date Issued: 2004
Identifier: CFE0000287, ucf:46232
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000287

Title: THREE-PORT MICRO-INVERTER WITH POWER DECOUPLING CAPABILITY FOR PHOTOVOLTAIC (PV) SYSTEMS APPLICATIONS.
Creator: Harb, Souhib, Batarseh, Issa, University of Central Florida
Abstract / Description: The Photovoltaic (PV) systems have been realized using different architectures, starting with the string and centralized PV system to the modular PV system. Presently, decentralized inverters are being developed at the PV panel power level (known as AC Ã‚Â– PV Modules). Such new PV systems are becoming more attractive and many expect this will be the trend of the future. The AC-Module PV system consists of an inverter attached to one PV panel. This integration requires...
Show moreThe Photovoltaic (PV) systems have been realized using different architectures, starting with the string and centralized PV system to the modular PV system. Presently, decentralized inverters are being developed at the PV panel power level (known as AC Ã‚Â– PV Modules). Such new PV systems are becoming more attractive and many expect this will be the trend of the future. The AC-Module PV system consists of an inverter attached to one PV panel. This integration requires that both devices have the same life-span. Although, the available commercial inverters have a relatively short life-span (10 years) compared to the 25 Ã‚Â–year PV. It has been stated in literature that the energy storage capacitor (electrolytic type) in the single-phase inverter is the most vulnerable electronic component. Hence, many techniques such as (power decoupling techniques) have been proposed to solve this problem by replacing the large electrolytic capacitor with a small film capacitor. This thesis will present a quick review of these power decoupling techniques, and proposes a new three-port micro-inverter with power decoupling capability for AC-Module PV system applications.
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Date Issued: 2010
Identifier: CFE0003357, ucf:48474
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003357

Title: IMAGING AND SPECTROSCOPY OF CONDUCTING POLYMER-FULLERENE COMPOSITE MATERIALS.
Creator: Tenery, Daeri, Gesquiere, Andre, University of Central Florida
Abstract / Description: Since the development and optical study of conjugated (conducting) polymers it has become apparent that chain conformation and aggregation at the molecular scale result in complex heterogeneous nanostructured bulk materials for which a detailed insight into morphological, spectroscopic as well as optoelectronic properties and mechanisms is overwhelmingly difficult to obtain. Nanoparticles composed of the conjugated polymer poly (MEH-PPV) and nanocomposite nanoparticles consisting of MEH-PPV...
Show moreSince the development and optical study of conjugated (conducting) polymers it has become apparent that chain conformation and aggregation at the molecular scale result in complex heterogeneous nanostructured bulk materials for which a detailed insight into morphological, spectroscopic as well as optoelectronic properties and mechanisms is overwhelmingly difficult to obtain. Nanoparticles composed of the conjugated polymer poly (MEH-PPV) and nanocomposite nanoparticles consisting of MEH-PPV doped with 1-(3-methoxycarbonylpropyl)-1-phenyl-C61 (PCBM) were prepared as model systems to study these materials at the length scale of one to a few domains. The MEH-PPV and PCBM doped nanoparticles were analyzed by single imaging/particle spectroscopy (SPS) and revealed molecular scale information on the structure-property relationships of these composite materials. The data obtained from SPS were investigated in terms of spectral difference between doped and undoped nanoparticles. The doped nanoparticles are blue shifted by approximately 5-10 nm, have an additional blue shoulder, and show different vibronic structure than the undoped nanoparticles. Specifically, relative intensity of the 0-1 transition is lower than for the undoped nanoparticles. These data are indicative of differences in molecular order between both nanoparticle systems, detected at the molecular scale. In addition, the effect of electrical fields present in devices on the interfacial charge transfer properties was evaluated. Furthermore, these nanoparticles were incorporated into the lipid nanotubes to study the diffusion process of the single MEH-PPV nanoparticles inside the lipid nanotubes. Our data shows a clear proof of concept that diffusion of nanoparticles inside the hollow lipid nanotubes can be studied on a single particle basis, which will allow us to study diffusion processes quantitatively and mechanistically within the framework of developing a biocompatible drug and gene delivery platform.
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Date Issued: 2009
Identifier: CFE0002708, ucf:48155
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002708

Title: Predictive modeling for assessing the reliability of bypass diodes in Photovoltaic modules.
Creator: Shiradkar, Narendra, Sundaram, Kalpathy, Schoenfeld, Winston, Atia, George, Abdolvand, Reza, Xanthopoulos, Petros, University of Central Florida
Abstract / Description: Solar Photovoltaics (PV) is one of the most promising renewable energy technologies for mitigating the effect of climate change. Reliability of PV modules directly impacts the Levelized Cost of Energy (LCOE), which is a metric for cost competitiveness of any energy technology. Further reduction in LCOE of PV through assured long term reliability is necessary in order to facilitate widespread use of solar energy without the need for subsidies. This dissertation is focused on frameworks for...
Show moreSolar Photovoltaics (PV) is one of the most promising renewable energy technologies for mitigating the effect of climate change. Reliability of PV modules directly impacts the Levelized Cost of Energy (LCOE), which is a metric for cost competitiveness of any energy technology. Further reduction in LCOE of PV through assured long term reliability is necessary in order to facilitate widespread use of solar energy without the need for subsidies. This dissertation is focused on frameworks for assessing reliability of bypass diodes in PV modules. Bypass diodes are critical components in PV modules that provide protection against shading. Failure of bypass diode in short circuit results in reducing the PV module power by one third, while diode failure in open circuit leaves the module susceptible for extreme hotspot heating and potentially fire hazard. PV modules, along with the bypass diodes are expected to last at least 25 years in field. The various failure mechanisms in bypass diodes such as thermal runaway, high temperature forward bias operation and thermal cycling are discussed. Operation of bypass diode under shading is modeled and method for calculating the module I-V curve under any shading scenario is presented. Frameworks for estimating the diode temperature in field deployed modules based on Typical Meteorological Year (TMY) data are developed. Model for predicting the susceptibility of bypass diodes for thermal runaway is presented. Diode wear out due to High Temperature Forward Bias (HTFB) operation and Thermal Cycling (TC) is studied under custom designed accelerated tests. Overall, this dissertation is an effort towards estimating the lifetime of bypass diodes in field deployed modules, and therefore, reducing the uncertainty in long term reliability of PV modules.
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Date Issued: 2015
Identifier: CFE0006001, ucf:51023
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006001

Title: Optimization and design of photovoltaic micro-inverter.
Creator: Zhang, Qian, Batarseh, Issa, Shen, Zheng, Wu, Xinzhang, Lotfifard, Saeed, Kutkut, Nasser, University of Central Florida
Abstract / Description: To relieve energy shortage and environmental pollution issues, renewable energy, especially PV energy has developed rapidly in the last decade. The micro-inverter systems, with advantages in dedicated PV power harvest, flexible system size, simple installation, and enhanced safety characteristics are the future development trend of the PV power generation systems. The double-stage structure which can realize high efficiency with nice regulated sinusoidal waveforms is the mainstream for the...
Show moreTo relieve energy shortage and environmental pollution issues, renewable energy, especially PV energy has developed rapidly in the last decade. The micro-inverter systems, with advantages in dedicated PV power harvest, flexible system size, simple installation, and enhanced safety characteristics are the future development trend of the PV power generation systems. The double-stage structure which can realize high efficiency with nice regulated sinusoidal waveforms is the mainstream for the micro-inverter.This thesis studied a double stage micro-inverter system. Considering the intermittent nature of PV power, a PFC was analyzed to provide additional electrical power to the system. When the solar power is less than the load required, PFC can drag power from the utility grid.In the double stage micro-inverter, the DC/DC stage was realized by a LLC converter, which could realize soft switching automatically under frequency modulation. However it has a complicated relationship between voltage gain and load. Thus conventional variable step P(&)O MPPT techniques for PWM converter were no longer suitable for the LLC converter. To solve this problem, a novel MPPT was proposed to track MPP efficiently. Simulation and experimental results verified the effectiveness of the proposed MPPT.The DC/AC stage of the micro-inverter was realized by a BCM inverter. With duty cycle and frequency modulation, ZVS was achieved through controlling the inductor current bi-directional in every switching cycle. This technique required no additional resonant components and could be employed for low power applications on conventional full-bridge and half-bridge inverter topologies. Three different current mode control schemes were derived from the basic theory of the proposed technique. They were referred to as Boundary Current Mode (BCM), Variable Hysteresis Current Mode (VHCM), and Constant Hysteresis Current Mode (CHCM) individually in this paper with their advantages and disadvantages analyzed in detail. Simulation and experimental results demonstrated the feasibilities of the proposed soft-switching technique with the digital control schemes.The PFC converter was applied by a single stage biflyback topology, which combined the advantages of single stage PFC and flyback topology together, with further advantages in low intermediate bus voltage and current stresses. A digital controller without current sampling requirement was proposed based on the specific topology. To reduce the voltage spike caused by the leakage inductor, a novel snubber cell combining soft switching technique with snubber technique together was proposed. Simulation and experimental waveforms illustrated the same as characteristics as the theoretical analysis.In summary, the dissertation analyzed each power stage of photovoltaic micro-inverter system from efficiency and effectiveness optimization perspectives. Moreover their advantages were compared carefully with existed topologies and control techniques. Simulation and experiment results were provided to support the theoretical analysis.
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Date Issued: 2013
Identifier: CFE0005286, ucf:50540
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005286

Title: Polymer Optical Fibers for Luminescent Solar Concentration.
Creator: Banaei, Seyed Esmaeil, Fathpour, Sasan, Gong, Xun, Sundaram, Kalpathy, Malocha, Donald, Abouraddy, Ayman, University of Central Florida
Abstract / Description: Luminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber....
Show moreLuminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber. A hybrid fiber structure is proposed for an efficient two-stage concentration of incident light, first into a small doped core using a cylindrical micro-lens that extends along the fiber, and second to the fiber ends by guiding the fluoresced light from the active dopants. Flexible sheets are assembled with fibers that can be bundled and attached to small-area PV cells. Small dimensions and directional guiding of the fibers allow for approximately one order of magnitude geometrical gain improvement over that of existing flat LSC's. In addition, the undesired limit of LSC size is eliminated in one direction.Modeling and optimization of an FLSC design is presented using polarization-ray tracing under realistic conditions with solar spectrum radiation and broad-band absorption and emission spectra of fluorescence materials with their inevitable self-absorption effect.Methods and results of fabrication and accurate optical characterization of such FLSC using two off-the-shelf organic dyes and a commercially available polymer, COP, are discussed in detail. Fiber preforms, fabricated under optimized conditions for low light transport loss, are thermally drawn into sub-millimeter-size fibers. Characterization of several samples with various concentrations of the two dyes shows an optical-to-optical conversion efficiency of 9.1% for a tandem combination of two 2.5-cm-long fibers with the efficiency gradually decreasing to 4.9% with increase in fiber length to 10 cm.
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Date Issued: 2013
Identifier: CFE0005083, ucf:50733
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005083

Title: EFFECT OF COMPOSITION, MORPHOLOGY AND SEMICONDUCTING PROPERTIES ON THE EFFICIENCY OF CUIN1-XGAXSE2-YSY THIN-FILM SOLAR CELLS PREPARED BY RAPID THERMAL PROCESSING.
Creator: Kulkarni, Sachin, Dhere, Neelkanth, University of Central Florida
Abstract / Description: A rapid thermal processing (RTP) reactor for the preparation of graded CuIn1-xGaxSe2-ySy (CIGSeS) thin-film solar cells has been designed, assembled and is being used at the Photovoltaic Materials Laboratory of the Florida Solar Energy Center. CIGSeS films having the optimum composition, morphology, and semiconducting properties were prepared using RTP. Initially films having various Cu/(In+Ga) ratios were prepared. In the next step selenium incorporation in these films was optimized,...
Show moreA rapid thermal processing (RTP) reactor for the preparation of graded CuIn1-xGaxSe2-ySy (CIGSeS) thin-film solar cells has been designed, assembled and is being used at the Photovoltaic Materials Laboratory of the Florida Solar Energy Center. CIGSeS films having the optimum composition, morphology, and semiconducting properties were prepared using RTP. Initially films having various Cu/(In+Ga) ratios were prepared. In the next step selenium incorporation in these films was optimized, followed by sulfur incorporation in the surface to increase the bandgap at the surface. The compositional gradient of sulfur was fine-tuned so as to increase the conversion efficiency. Materials properties of these films were characterized by optical microscopy, SEM, AFM, EDS, XRD, GIXRD, AES, and EPMA. The completed cells were extensively studied by electrical characterization. Current-voltage (I-V), external and internal quantum efficiency (EQE and IQE), capacitance-voltage (C-V), and light beam induced current (LBIC) analysis were carried out. Current Density (J)-Voltage (V) curves were obtained at different temperatures. The temperature dependence of the open circuit voltage and fill factor has been estimated. The bandgap value calculated from the intercept of the linear extrapolation was ~1.1-1.2 eV. Capacitance-voltage analysis gave a carrier density of ~4.0 x 1015 cm-3. Semiconductor properties analysis of CuIn1-xGaxSe2-ySy (CIGSeS) thin-film solar cells has been carried out. The values of various PV parameters determined using this analysis were as follows: shunt resistance (Rp) of ~510 Ohms-cm2 under illumination and ~1300 Ohms-cm2 in dark, series resistance (Rs) of ~0.8 Ohms-cm2 under illumination and ~1.7 Ohms-cm2 in dark, diode quality factor (A) of 1.87, and reverse saturation current density (Jo) of 1.5 x 10-7A cm-2. The efficiency of 12.78% obtained during this research is the highest efficiency obtained by any University or National Lab for copper chalcopyrite solar cells prepared by RTP. CIGS2 cells have a better match to the solar spectrum due to their comparatively higher band-gap as compared to CIGS cells. However, they are presently limited to efficiencies below 13% which is considerably lower than that of CIGS cells of 19.9%. One of the reasons for this lower efficiency is the conduction band offset between the CIGS2 absorber layer and the CdS heterojunction partner layer. The band offset value between CIGS2 and CdS was estimated by a combination of ultraviolet photoelectron spectroscopy (UPS) and Inverse Photoemission Spectroscopy (IPES) to be -0.45 eV, i.e. a cliff is present between these two layers, enhancing the recombination at the junction, this limits the efficiency of CIGS2 wide-gap chalcopyrite solar cells.
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Date Issued: 2008
Identifier: CFE0002467, ucf:47728
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002467

Title: DEVELOPMENT OF TRANSPARENT AND CONDUCTING BACK CONTACTS ON CDS/CDTE SOLAR CELLS FOR PHOTOELECTROCHEMICAL APPLICATION.
Creator: Avachat, Upendra, Dhere, Neelkanth, University of Central Florida
Abstract / Description: The development of devices with high efficiencies can only be attained by tandem structures which are important to the advancement of thin-film photoelectrochemical (PEC) and photovoltaic (PV) technologies. FSEC PV Materials Lab has developed a PEC cell using multiple bandgap tandem of thin film PV cells and a photocatalyst for hydrogen production by water splitting. CdS/CdTe solar cell, a promising candidate for low-cost, thin-film PV cell is used as one of the thin film solar cells in a PEC...
Show moreThe development of devices with high efficiencies can only be attained by tandem structures which are important to the advancement of thin-film photoelectrochemical (PEC) and photovoltaic (PV) technologies. FSEC PV Materials Lab has developed a PEC cell using multiple bandgap tandem of thin film PV cells and a photocatalyst for hydrogen production by water splitting. CdS/CdTe solar cell, a promising candidate for low-cost, thin-film PV cell is used as one of the thin film solar cells in a PEC cell. This research work focuses on developing various back contacts with good transparency in the infrared region (~750 - 1150 nm) for a CdS/CdTe solar cell. CdS/CdTe solar cells were prepared with three different configurations, Glass/SnO2:F/CdS/CdTe/ZnTe:Cu/ITO/Ni-Al (series 1), Glass/SnO2:F/CdS/CdTe/Cu2Te/ITO/Ni-Al (series 2), Glass/SnO2:F/CdS/CdTe/Br-Me etching/Cu/ITO/Ni-Al (series 3). The back contact preparation process for a CdS/CdTe solar cell involves the deposition of a primary p-type back contact interface layer followed by the deposition of transparent and conducting ITO and a Ni-Al outer metallization layer. Back contact interface layers were initially optimized on glass substrates. A ZnTe:Cu layer for a series 1 cell was deposited using hot wall vacuum evaporation (HWVE). Cu2Te and Cu thin films for series 2 and series 3 cells were deposited by vacuum evaporation. HWVE technique produced highly stoichiometric ZnTe:Cu thin films with cubic phase having {111} texture orientation. All the back contact interface layers demonstrated better transparency in the infrared region on glass substrate. Formation of crystalline phase and texture orientation were studied using X-ray diffraction (XRD). The composition was analyzed by electron probe microanalysis (EPMA). Transparency measurements were carried out by optical transmission spectroscopy. Thickness measurements were carried out using a DEKTAK surface profile measuring system. Finally, completed solar cells for all the series were characterized for current-voltage (I-V) measurements using the I-V measurement setup developed at the FSEC PV Materials Lab. The PV parameters for the best series 1 cell measured at an irradiance of 1000 W/m2 were: open circuit voltage, Voc = 630 mV, short circuit current, Isc = 7.68 mA/ cm2, fill factor, FF = 37.91 %, efficiency, ç = 3.06 %. The PV parameters for the best series 2 cell measured were: Voc = 690 mV, Isc = 8.7 mA/ cm2, FF = 45.19 %, ç = 4.8 %. The PV parameters for the best series 3 cell measured were: Voc = 550 mV, Isc = 9.70 mA/ cm2, FF = 42.25 %, ç = 5.63 %. The loss in efficiency was attributed to the possible formation of a non-ohmic contact at the interface of CdTe and back contact interface layer. Decrease in the fill factor was attributed to high series resistance in the device.
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Date Issued: 2005
Identifier: CFE0000682, ucf:46483
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000682

Title: PREPARATION AND CHARACTERIZATION OF CIGSS SOLAR CELLS AND PV MODULE DATA ANALYSIS.
Creator: Shirolikar, Jyoti, Dhere, Neelkanth, University of Central Florida
Abstract / Description: In this thesis, multiple activities have been carried out in order to improve the process of CIGSS solar cell fabrication on a 4" x 4" substrate. The process of CIGSS solar cell fabrication at FSEC's PV Materials Lab involves a series of steps that were all carried out manually in the past. A LABVIEW program has been written to carry out automated sputter deposition of Mo back contact, CuGa, In metallic precursors on a soda lime glass substrate using a stepper motor control for better...
Show moreIn this thesis, multiple activities have been carried out in order to improve the process of CIGSS solar cell fabrication on a 4" x 4" substrate. The process of CIGSS solar cell fabrication at FSEC's PV Materials Lab involves a series of steps that were all carried out manually in the past. A LABVIEW program has been written to carry out automated sputter deposition of Mo back contact, CuGa, In metallic precursors on a soda lime glass substrate using a stepper motor control for better uniformity. Further, selenization/ sulfurization of these precursors was carried out using rapid thermal processing (RTP). CIGS films were sulfurized using chemical bath deposition (CBD). ZnO:Al was deposited on the CIGSS films using RF sputtering. A separate LABVIEW program was written to automate the process of ZnO:Al deposition. Ni/Al contact fingers were deposited on the ZnO:Al layer using the e-beam evaporation technique. Further, in order to test these solar cells in-house, a simple current-voltage (IV) tracer was fabricated using LABVIEW. A quantum efficiency (QE) measurement setup was built with guidance from the National Renewable Energy Laboratory (NREL). Lastly, analysis of data from photovoltaic (PV) modules installed on the FSEC test site has been carried out using a LABVIEW program in order to find out their rate of degradation as time progresses. A 'C' program has also been written as an aid for keeping a daily log of errors in data and for troubleshooting of the same.
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Date Issued: 2005
Identifier: CFE0000859, ucf:46645
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000859

Title: CHARACTERIZATION OF ALUMINUM DOPED ZINC OXIDE THIN FILMS FOR PHOTOVOLTAIC APPLICATIONS.
Creator: Shantheyanda, Bojanna, Kalpathy, Sundaram, University of Central Florida
Abstract / Description: Growing demand for clean source of energy in the recent years has increased the manufacture of solar cells for converting sun energy directly into electricity. Research has been carried out around the world to make a cheaper and more efficient solar cell technology by employing new architectural designs and developing new materials to serve as light absorbers and charge carriers. Aluminum doped Zinc Oxide thin film, a Transparent conductive Oxides (TCO) is used as a window material in the...
Show moreGrowing demand for clean source of energy in the recent years has increased the manufacture of solar cells for converting sun energy directly into electricity. Research has been carried out around the world to make a cheaper and more efficient solar cell technology by employing new architectural designs and developing new materials to serve as light absorbers and charge carriers. Aluminum doped Zinc Oxide thin film, a Transparent conductive Oxides (TCO) is used as a window material in the solar cell these days. Its increased stability in the reduced ambient, less expensive and more abundance make it popular among the other TCOÃ‚Â's. It is the aim of this work to obtain a significantly low resistive ZnO:Al thin film with good transparency. Detailed electrical and materials studies is carried out on the film in order to expand knowledge and understanding. RF magnetron sputtering has been carried out at various substrate temperatures using argon, oxygen and hydrogen gases with various ratios to deposit this polycrystalline films on thermally grown SiO2 and glass wafer. The composition of the films has been determined by X-ray Photoelectron Spectroscopy and the identification of phases present have been made using X-ray diffraction experiment. Surface imaging of the film and roughness calculations are carried out using Scanning Electron Microscopy and Atomic Force Microscopy respectively. Determination of resistivity using 4-Probe technique and transparency using UV spectrophotometer were carried out as a part of electrical and optical characterization on the obtained thin film.The deposited thin films were later annealed in vacuum at various high temperatures and the change in material and electrical properties were analyzed.
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Date Issued: 2010
Identifier: CFE0003142, ucf:48623
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003142

Title: Light Trapping in Thin Film Crystalline Silicon Solar Cells.
Creator: Boroumand Azad, Javaneh, Chanda, Debashis, Peale, Robert, Del Barco, Enrique, Flitsiyan, Elena, Schoenfeld, Winston, University of Central Florida
Abstract / Description: This dissertation presents numerical and experimental studies of a unified light trapping approach that is extremely important for all practical solar cells. A 2D hexagonal Bravais lattice diffractive pattern is studied in conjunction with the verification of the reflection mechanisms of single and double layer anti-reflective coatings in the broad range of wavelength 400 nm - 1100 nm. By varying thickness and conformity, we obtained the optimal parameters which minimize the broadband...
Show moreThis dissertation presents numerical and experimental studies of a unified light trapping approach that is extremely important for all practical solar cells. A 2D hexagonal Bravais lattice diffractive pattern is studied in conjunction with the verification of the reflection mechanisms of single and double layer anti-reflective coatings in the broad range of wavelength 400 nm - 1100 nm. By varying thickness and conformity, we obtained the optimal parameters which minimize the broadband reflection from the nanostructured crystalline silicon surface over a wide range of angle 0(&)deg;-65(&)deg;. While the analytical design of broadband, angle independent anti-reflection coatings on nanostructured surfaces remains a scientific challenge, numerical optimization proves a viable alternative, paving the path towards practical implementation of the light trapping solar cells. A 3 (&)#181;m thick light trapping solar cell is modeled in order to predict and maximize combined electron-photon harvesting in ultrathin crystalline silicon solar cells. It is shown that the higher charge carrier generation and collection in this design compensates the absorption and recombination losses and ultimately results in an increase in energy conversion efficiency. Further, 20 (&)#181;m and 100 (&)#181;m thick functional solar cells with the light trapping scheme are studied. The efficiency improvement is observed numerically and experimentally due to photon absorption enhancement in the light trapping cells with respect to a bare cell of same thickness.
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Date Issued: 2017
Identifier: CFE0006936, ucf:51654
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006936

Title: Atmospheric Pressure Chemical Vapor Deposition of Functional Oxide Materials for Crystalline Silicon Solar Cells.
Creator: Davis, Kristopher, Schoenfeld, Winston, Likamwa, Patrick, Moharam, Jim, Habermann, Dirk, University of Central Florida
Abstract / Description: Functional oxides are versatile materials that can simultaneously enable efficiency gains and cost reductions in crystalline silicon (c-Si) solar cells. In this work, the deposition of functional oxide materials using atmospheric pressure chemical vapor deposition (APCVD) and the integration of these materials into c-Si solar cells are explored. Specifically, thin oxide films and multi-layer film stacks are utilized for the following purposes: (1) to minimize front surface reflectance without...
Show moreFunctional oxides are versatile materials that can simultaneously enable efficiency gains and cost reductions in crystalline silicon (c-Si) solar cells. In this work, the deposition of functional oxide materials using atmospheric pressure chemical vapor deposition (APCVD) and the integration of these materials into c-Si solar cells are explored. Specifically, thin oxide films and multi-layer film stacks are utilized for the following purposes: (1) to minimize front surface reflectance without increasing parasitic absorption within the anti-reflection coating(s); (2) to maximize internal back reflectance of rear passivated cells, thereby increasing optical absorption of weakly absorbed long wavelength photons (? (>) 900 nm); (3) to minimize recombination losses by providing excellent surface passivation; and (4) to improve doping processes during cell manufacturing (e.g., emitter and surface field formation) by functioning as highly controllable dopant sources compatible with in-line diffusion processes. The oxide materials deposited by APCVD include amorphous and polycrystalline titanium oxide, aluminum oxide, boron-doped aluminum oxide, silicon oxide, phosphosilicate glass, and borosilicate glass. The microstructure, optical properties, and electronic properties of these films are characterized for different deposition conditions. Additionally, the impact of these materials on the performance of different types of c-Si solar cells is presented using both simulated and experimental current-voltage curves.
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Date Issued: 2015
Identifier: CFE0005599, ucf:50267
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005599

Title: Modeling and fault detection in DC side of Photovoltaic Arrays.
Creator: Akram, Mohd, Lotfifard, Saeed, Mikhael, Wasfy, Wu, Thomas, University of Central Florida
Abstract / Description: Fault detection in PV systems is a key factor in maintaining the integrity of any PV system. Faults in photovoltaic systems can cause irrevocable damages to the stability of the PV system and substantially decrease the power output generated from the array of PV modules. Among'st the various AC and DC faults in a PV system, the clearance of the AC side faults is achieved by conventional AC protection schemes,the DC side, however , there still exists certain faults which are difficult to...
Show moreFault detection in PV systems is a key factor in maintaining the integrity of any PV system. Faults in photovoltaic systems can cause irrevocable damages to the stability of the PV system and substantially decrease the power output generated from the array of PV modules. Among'st the various AC and DC faults in a PV system, the clearance of the AC side faults is achieved by conventional AC protection schemes,the DC side, however , there still exists certain faults which are difficult to detect and clear. This paper deals with the modeling, detection and classification of these types of DC faults. It is essential to be able to simulate the PV characteristics and faults through software. In this thesis a comprehensive literature survey of fault detection methods for DC side of a PV system is presented. The disparities in the techniques employed for fault detection are studied . A new method for modeling the PV systems information only from manufacturers datasheet using both the Normal Operating Cell temperature conditions (NOCT) and Standard Operating Test Conditions (STC) conditions is then proposed.The input parameters for modeling the system are Isc,Voc,Impp,Vmpp and the temperature coefficients of Isc and Voc for both STC and NOCT conditions. The model is able to analyze the variations of PV parameters such as ideality factor, Series resistance, thermal voltage and Band gap energy of the PV module with temperature. Finally a novel intelligent method based on Probabilistic Neural Network for fault detection and classification for PV farm with string inverter technology is proposed.
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Date Issued: 2014
Identifier: CFE0005293, ucf:50571
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005293

Title: A Holistic Analysis of the Long-Term Challenges (&) Potential Benefits of the Green Roof, Solar PV Roofing, and GRIPV Roofing Markets in Orlando, Florida.
Creator: Kelly, Carolina, Tatari, Omer, Oloufa, Amr, Mayo, Talea, Zheng, Qipeng, University of Central Florida
Abstract / Description: Green roofs and roof-mounted solar PV arrays have a wide range of environmental and economic benefits, including significantly longer roof lifetimes, reductions in urban runoff, mitigation of the urban heat island (UHI) effect, reduced electricity demand and energy dependence, and/or reduced emissions of greenhouse gases (GHGs) and other harmful pollutants from the electricity generation sector. Consequently, green roofs and solar panels have both become increasingly popular worldwide, and...
Show moreGreen roofs and roof-mounted solar PV arrays have a wide range of environmental and economic benefits, including significantly longer roof lifetimes, reductions in urban runoff, mitigation of the urban heat island (UHI) effect, reduced electricity demand and energy dependence, and/or reduced emissions of greenhouse gases (GHGs) and other harmful pollutants from the electricity generation sector. Consequently, green roofs and solar panels have both become increasingly popular worldwide, and promising new research has emerged for their potential combination in Green Roof Integrated Photovoltaic (GRIPV) roofing applications. However, due to policy resistance, these alternatives still have marginal market shares in the U.S., while GRIPV research and development is still severely limited today. As a result, these options are not yet sufficiently widespread in the United States as to realize their full potential, particularly due to a variety of policy resistance effects with respect to each specific alternative. The steps in the System Dynamics (SD) methodology to be used in this study are summarized as follows. First, based on a comprehensive review of relevant literature, a causal loop diagram (CLD) will be drawn to provide a conceptual illustration of the modeled system. Second, based on the feedback relationships observed in this CLD, a stock-flow diagram (SFD) will be developed to form a quantitative model. Third, the modeled SFD will be tested thoroughly to ensure its structural and behavioral validity with respect to the modeled system in reality using whatever real world data is available. Fourth, different policy scenarios will be simulated within the model to evaluate their long-term effectiveness. Fifth, uncertainty analyses will be performed to evaluate the inherent uncertainties associated with the analyses in this study. Finally, the results observed for the analyses in this study and possible future research steps will be discussed and compared as appropriate.
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Date Issued: 2018
Identifier: CFE0007406, ucf:52741
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007406

Title: ELECTRON INJECTION-INDUCED EFFECTS IN III-NITRIDES: PHYSICS AND APPLICATIONS.
Creator: Burdett, William Charles, Chernyak, Leonid, University of Central Florida
Abstract / Description: This research investigated the effect of electron injection in III-Nitrides. The combination of electron beam induced current and cathodoluminescence measurements was used to understand the impact of electron injection on the minority carrier transport and optical properties. In addition, the application of the electron injection effect in optoelectronic devices was investigated.The impact of electron injection on the minority carrier diffusion length was studied at various temperatures in Mg...
Show moreThis research investigated the effect of electron injection in III-Nitrides. The combination of electron beam induced current and cathodoluminescence measurements was used to understand the impact of electron injection on the minority carrier transport and optical properties. In addition, the application of the electron injection effect in optoelectronic devices was investigated.The impact of electron injection on the minority carrier diffusion length was studied at various temperatures in Mg-doped p-GaN, p-AlxGa1-xN, and p-AlxGa1-x N/GaN superlattices. It was found that the minority carrier diffusion length experienced a multi-fold linear increase and that the rate of change of the diffusion length decreased exponentially with increasing temperature. The effect was attributed to a temperature-activated release of the electrons, which were trapped by the Mg levels.The activation energies for the electron injection effect in the Mg-doped (Al)GaN samples were found to range from 178 to 267 meV, which is close to the thermal ionization energy of the Mg acceptor. The activation energy observed for Al0.15Ga0.85N and Al0.2Ga0.8N was consistent with the deepening of the Mg acceptor level due to the incorporation of Al into the GaN lattice. The activation energy in the homogeneously doped Al0.2Ga0.8N/GaN superlattice indicates that the main contribution to the electron injection effect comes from the capture of injected electrons by the wells (GaN). The electron injection effect was successfully applied to GaN doped with an impurity (Mn) other than Mg. Electron injection into Mn-doped GaN resulted in a multi-fold increase of the minority carrier diffusion length and a pronounced decrease in the band-to-band cathodoluminescence intensity. The activation energy due to the electron injection effect was estimated from temperature-dependent cathodoluminescence measurements to be 360 meV. The decrease in the band-to-band cathodoluminescence is consistent with an increase in the diffusion length and these results are attributed to an increase in the minority carrier lifetime due to the trapping of injected electrons by the Mn levels.A forward bias was applied to inject electrons into commercially built p-i-n and Schottky barrier photodetectors. Up to an order of magnitude increase in the peak (360 nm) responsivity was observed. The enhanced photoresponse lasted for over four weeks and was attributed to an electron injection-induced increase of the minority carrier diffsuion length and the lifetime.
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Date Issued: 2004
Identifier: CFE0000080, ucf:46109
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000080

photovoltaics (6)	+ -
photovoltaic (4)	+ -
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renewable energy (2)	+ -
solar cell (2)	+ -
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Black silicon (1)	+ -
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Carbon nanotubes (1)	+ -
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