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THE ACUTE TOXICITY OF GROUND RECYCLED AUTOMOBILE TIRES ON AQUATIC LIFE WITH MODEL SPECIES P. PROMELAS
Title
THE ACUTE TOXICITY OF GROUND RECYCLED AUTOMOBILE TIRES ON AQUATIC LIFE WITH MODEL SPECIES P. PROMELAS.
Creator
Baldassari, Trillian, Cooper, David, University of Central Florida
Abstract / Description
Used tires have the potential for becoming popular in pollution control media used in stormwater applications including pervious pavement sub bases, green roof growth media, and upflow filters. Using tire crumb to decrease nutrients can minimize impacts on ecology while reducing the human footprint left by used tires. However, if tire crumb is not examined for toxicity, the ecological balance could unknowingly be disrupted. This research tested the acute toxicity of tire crumb in aquatic...
Show moreUsed tires have the potential for becoming popular in pollution control media used in stormwater applications including pervious pavement sub bases, green roof growth media, and upflow filters. Using tire crumb to decrease nutrients can minimize impacts on ecology while reducing the human footprint left by used tires. However, if tire crumb is not examined for toxicity, the ecological balance could unknowingly be disrupted. This research tested the acute toxicity of tire crumb in aquatic systems by finding the Lethal Concentration for 50% kill (LC50). Using an extreme tire crumb load, P. promelas (fathead minnow) were exposed to leachates created with tire crumb and several different types of water including distilled water, tap water, and detention pond water. For distilled and tap water, the addition of tire crumb increased the survival of P. promelas. For detention pond water, the addition of tire crumb decreased the survival of P. promelas, though only enough to find an LC50 for detention pond water influenced immediately by stormwater runoff. An LC50 was found when 100 percent tire crumb filtrate is prepared with 25 grams of tire crumb per liter of detention pond water collected directly after a storm. The LC50 found is resultant of a tire crumb load significantly higher than what can be expected in the environment. Based on this research, tire crumb is considered non-threatening to aquatic fish and safe to use with detention pond water.
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Date Issued
2008
Identifier
CFE0002282, ucf:47850
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002282
FATE OF NITROGEN AND PHOSPHORUS SPECIES FROM A BLACK AND GOLDTM NUGGET MIX IN A LABORATOY COLUMN SIMULATED SEPTIC TANK DRAINFIELD
Title
FATE OF NITROGEN AND PHOSPHORUS SPECIES FROM A BLACK AND GOLDTM NUGGET MIX IN A LABORATOY COLUMN SIMULATED SEPTIC TANK DRAINFIELD.
Creator
Shah, Timir, Wanielista, Martin, University of Central Florida
Abstract / Description
The presence of nitrates and phosphorus in ground water is a worldwide problem. A septic tank with drainfield that is conventionally designed does not typically remove nitrogen in the form of nitrates. The main risks are in "Blue baby" syndrome and suspected carcinogenic effect of nitrates on humans and the nutrient enrichment of receiving waters. In some areas nitrate and phosphorus removal are essentially required. Thus the information in this report concentrates on using media in the...
Show moreThe presence of nitrates and phosphorus in ground water is a worldwide problem. A septic tank with drainfield that is conventionally designed does not typically remove nitrogen in the form of nitrates. The main risks are in "Blue baby" syndrome and suspected carcinogenic effect of nitrates on humans and the nutrient enrichment of receiving waters. In some areas nitrate and phosphorus removal are essentially required. Thus the information in this report concentrates on using media in the drainfield for the removal of nitrogen and phosphorus. Extensive work has been conducted in the past few decades in order to find suitable media for denitrification with high selectivity towards nitrogen. Column experiments were conducted at the University of Central Florida to simulate the actual septic tank drainfield using mixes of fine sand. In one of the columns Sawdust and Tire Crumb were added to the Sand (STS) and in the other column Paper and Tire Crumb were added to the Sand (STP). Tire crumb was added as a carbon source required for better denitrification and for sorption. The columns were dosed daily using regular septic tank effluent and it was a continuous batch system. Samples were taken after a hydraulic retention time (HRT) of 24 hours and comparisons were made of the effluent with the influent to show percentage removal of nitrogen (nitrates, ammonia and total nitrogen), phosphorus (ortho-phosphorus and total phosphorus) and BOD. STS and STP columns showed more than 90% removal for all parameters (nitrates, ammonia, total nitrogen, ortho-phosphorus, total phosphorus, BOD). The results indicate that the investigated media blend (Black and GoldTM Nugget Mix) has the potential for successful application in full scale operations. It is recommended that Black and GoldTM Nugget Mix be used to achieve the required removal of the nutrients.
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Date Issued
2007
Identifier
CFE0001824, ucf:47335
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001824
A KINETICS STUDY OF SELECTED FILTRATION MEDIA FOR NUTRIENT REMOVAL AT VARIOUS TEMPERATURES
Title
A KINETICS STUDY OF SELECTED FILTRATION MEDIA FOR NUTRIENT REMOVAL AT VARIOUS TEMPERATURES.
Creator
Henderson, Elizabeth, Chang, Ni-Bin, University of Central Florida
Abstract / Description
In recent years the nutrient levels of the Upper Floridan aquifer have been increasing (USGS, 2008). An example of this is found in Ocala, Florida where Silver Springs nitrate concentrations have risen from 0.5 mg/L in the 1960's to approximately 1.0 mg/L in 2003 (Phelps, 2004). Because stormwater is a contributor to surficial and groundwater aquifer recharge, there is an increasing need for methods that decrease nitrogen and phosphorus levels. A laboratory column study was conducted to...
Show moreIn recent years the nutrient levels of the Upper Floridan aquifer have been increasing (USGS, 2008). An example of this is found in Ocala, Florida where Silver Springs nitrate concentrations have risen from 0.5 mg/L in the 1960's to approximately 1.0 mg/L in 2003 (Phelps, 2004). Because stormwater is a contributor to surficial and groundwater aquifer recharge, there is an increasing need for methods that decrease nitrogen and phosphorus levels. A laboratory column study was conducted to simulate a retention pond with saturated soil conditions. The objectives of the column studies reported in this thesis were to investigate the capabilities of a natural soil and soil augmentations to remove nitrogen and phosphorus for a range of concentrations at three different temperatures. An analytical attempt to model the columns through low order reaction kinetics and derive the corresponding temperature conversion constant to relate the rate constants is also presented. The Media Mixes were selected through a process of research, preliminary batch testing and then implemented in column studies. Three columns measuring three feet in length and 6 inches outer diameter were packed with a control and two media mixes. Media Mix 1 consisted of 50% fine sand, 30% tire crumb, 20% sawdust by weight and Media Mix 2 consisted of 50% fine sand, 25% sawdust, 15% tire crumb, 10% limestone by weight. The control column was packed with natural soil from Hunter's Trace retention pond located in Ocala, Florida. The reaction rates for nitrate are best modeled as first order for Media Mix 1, and zero order for the Control and Media Mix 2. The reaction rates for orthophosphate are best modeled as zero order, second order and first order for the Control, Media Mix 1, and Media Mix 2 respectively. The best overall media for both nitrate and orthophosphate removal from this study would be Media Mix 1. Media Mix 2 does have the highest average orthophosphate removal of all the mixes for all of the temperatures; however Media Mix 1 outperforms Mix 2 for the other two temperatures. The best column for Nitrate removal is the Media Mix 1 column. The temperature conversion factors for nitrate were found to be 1.11, 1.1, and 1.01 for Media Mix 1, the Control and Media Mix 2 respectively. The temperature conversion factors for orthophosphate were found to be 1.02, 0.99, and 0.95. As well as temperature conversion factors, the activation energies and frequency factors for the Arrhenius Equation were investigated. Average values corresponding to each column, species, and temperature would be inaccurate due to the large variation in calculated values.
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Date Issued
2008
Identifier
CFE0002458, ucf:47727
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0002458
THE EFFECTS OF BAM AS AN ADSORPTIVE MEDIA ON PHOSPHORUS REMOVAL IN STORMWATER
Title
THE EFFECTS OF BAM AS AN ADSORPTIVE MEDIA ON PHOSPHORUS REMOVAL IN STORMWATER.
Creator
Salamah, Sultan, Randall, Andrew, Duranceau, Steven, Chopra, Manoj, University of Central Florida
Abstract / Description
To maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of...
Show moreTo maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of this project is to find the BAM values for coefficients such as maximum adsorption capacity (QM: 4.35E-05) for the media through SRP isotherm equilibrium experiments using the Langmuir and Freundlich models. In addition, an upflow column experiment was also performed to study BAM nutrient removal from stormwater runoff. Finally, the information from the isotherm and the column experiments are used to estimate the life expectancy or quantity required of the media, and to define the effectiveness of BAM in phosphorus removal. The result of this study shows that BAM is a feasible stormwater treatment that can remove 60% SRP and (>)40% TP at temperature between 21-23 (&)deg;C. The media is adequately modeled by both the Langmuir and the Freundlich models over the concentration range of interest in stormwater.
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Date Issued
2014
Identifier
CFE0005244, ucf:50589
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0005244
Comparison of a modified and traditional rapid infiltration basin for treatment and control of nutrients in wastewater effluent
Title
Comparison of a modified and traditional rapid infiltration basin for treatment and control of nutrients in wastewater effluent.
Creator
Cormier, Jessica, Duranceau, Steven, Wang, Dingbao, Sadmani, A H M Anwar, University of Central Florida
Abstract / Description
Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water...
Show moreRapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, and sand (CTS) was selected to serve as the BAM material (Bold and Gold(TM) CTS media). Each RIB was constructed with two feet of either sand or BAM, covering more than 43,600 square feet of surface area. The BAM-modified RIB had an initial 90 pounds per cubic-foot in-place density, and the density of the control RIB approximated about 94 pounds per cubic-foot. Over an eight-month period, loadings to the BAM RIB and control RIB approximated 5.4 million gallons (MG) per acre each. Water samples, collected from lysimeters installed below the 2-foot of sand or BAM materials, were gathered monthly during 2017 (except for September and October due to the impacts of hurricane Irma); these samples were analyzed for water quality to determine nitrate removal. Soil moisture and weather data were also collected over the study period. This study demonstrated the nitrate removal effectiveness of a field-scale BAM-modified RIB as compared to a traditional field-scale sand-based RIB. Results suggest that BAM removed 30 percent more nitrates than the Control (78% and 47%, respectively) under the conditions of the study. Furthermore, BAM removed higher percentages of TN (31%) and TP (62%) than the Control (12% and 28%, respectively).
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Date Issued
2018
Identifier
CFE0007566, ucf:52583
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0007566
ANALYSIS OF THE FLORIDAÂÂ'S SHOWCASE GREEN ENVIROHOME WATER/WASTEWATER SYSTEMS AND DEVELOPMENT OF A COST-BENEFIT GREEN ROOF OPTIMIZATION MODEL
Title
ANALYSIS OF THE FLORIDAÂÂ'S SHOWCASE GREEN ENVIROHOME WATER/WASTEWATER SYSTEMS AND DEVELOPMENT OF A COST-BENEFIT GREEN ROOF OPTIMIZATION MODEL.
Creator
Rivera, Brian, Chang, Ni-Bin, University of Central Florida
Abstract / Description
The Florida Showcase Green Envirohome (FSGE) incorporates many green technologies. FSGE is built to meet or exceed 12 green building guidelines and obtain 8 green building certificates. The two-story 3292 ft2 home is a ÂÂ"Near Zero-Loss Home™ÂÂ", ÂÂ"Near Zero-Energy Home™ÂÂ", "Near Zero-Runoff Home™", and ÂÂ"Near Zero...
Show moreThe Florida Showcase Green Envirohome (FSGE) incorporates many green technologies. FSGE is built to meet or exceed 12 green building guidelines and obtain 8 green building certificates. The two-story 3292 ft2 home is a ÂÂ"Near Zero-Loss Home™ÂÂ", ÂÂ"Near Zero-Energy Home™ÂÂ", "Near Zero-Runoff Home™", and ÂÂ"Near Zero-Maintenance Home™ÂÂ". It is spawned from the consumer-driven necessity to build a home resistant to hurricanes, tornadoes, floods, fire, mold, termites, impacts, and even earthquakes given up to 500% increase in insurance premiums in natural disaster zones, the dwindling flexibility and coverage of insurance policies, and rising energy, water and maintenance costs (FSGE 2008). The FSGE captures its stormwater runoff from the green roof, metal roof and wood decking area and routes it to the sustainable water cistern. Graywater from the home (after being disinfected using ozone) is also routed to the sustainable water cistern. This water stored in the sustainable water cistern is used for irrigation of the green roof, ground level landscape, and for toilet flushing water. This study was done in two phases. During phase one, only stormwater runoff from the green roof, metal roof and wood decking area is routed to the sustainable water cistern. Then, during phase two, the water from the graywater system is added to the sustainable water cistern. The sustainable water cistern quality is analyzed during both phases to determine if the water is acceptable for irrigation and also if it is suitable for use as toilet flushing water. The water quality of the sustainable cistern is acceptable for irrigation. The intent of the home is to not pollute the environment, so as much nutrients as possible should be removed from the wastewater before it is discharged into the groundwater. Thus, the FSGE design is to evaluate a new on-site sewage treatment and disposal (OSTD) system which consists of a sorption media labeled as Bold and GoldTM filtration media. The Bold and GoldTM filtration media is a mixture of tire crumb and other materials. This new OSTD system has sampling ports through the system to monitor the wastewater quality as it passes through. Also, the effluent wastewater quality is compared to that of a conventional system on the campus of the University of Central Florida. The cost-benefit optimization model focused on designing a residential home which incorporated a green roof, cistern and graywater systems. This model had two forms, the base model and the grey linear model. The base model used current average cost of construction of materials and installation. The grey model used an interval for the cost of construction materials and green roof energy savings. Both models included a probabilistic term to describe the rainfall amount. The cost and energy operation of a typical Florida home was used as a case study for these models. Also, some of the parameters of the model were varied to determine their effect on the results. The modeling showed that the FSGE 4500 gallon cistern design was cost effective in providing irrigation water. Also, the green roof area could have been smaller to be cost effective, because the green roof cost is relatively much higher than the cost of a regular roof.
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Date Issued
2010
Identifier
CFE0003297, ucf:48499
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0003297
An Assessment of Biosorption Activated Media for the Removal of Pollutants in Up-Flow Stormwater Treatment Systems
Title
An Assessment of Biosorption Activated Media for the Removal of Pollutants in Up-Flow Stormwater Treatment Systems.
Creator
Hood, Andrew, Randall, Andrew, Wanielista, Martin, Chopra, Manoj, O'Reilly, Andrew, Moore, Sean, University of Central Florida
Abstract / Description
Nitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical...
Show moreNitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical in ultra-urban environments where above ground space is limited. Upflow filters utilizing biosorption activated media (BAM) that can be placed underground offer a small footprint alternative. Additionally, BAM upflow filters can be installed at the discharge point of traditional stormwater ponds to provide further treatment. This research simulated stormwater that had already been treated for solids removal; thus, most of the nutrients and solids in the influent were assumed to be as non-settable suspended solids or dissolved solids. Three different BAM mixtures in an upflow filter configuration were compared for the parameters of nitrogen, phosphorus, total coliform, E. coli, and heterotrophic plate count (HPC). Additionally, genetic testing was conducted using Polymerase Chain Reaction (PCR), in conjunction with a nitrogen mass balance, to determine if Anammox was a significant player in the nitrogen removal. The columns were run at both 22-minute and 220-minute Empty Bed Contact Times (EBCTs). All the BAM mixtures analyzed were shown to be capable at the removal of nitrogen, phosphorus, and total coliform during both the 22-minute and 220-minute EBCTs, with BAM #1 having the highest removal performance for all three parameters during both EBCTs. All BAM mixtures experienced an increase in HPC. Additionally, PCR analysis confirmed the presence of Anammox in the biofilm and via mass balance it was determined that the biological nitrogen removal was due to Anammox and endogenous denitrification with Anammox being a significant mechanism.
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Date Issued
2019
Identifier
CFE0007817, ucf:52875
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0007817