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Title: Stormwater Management for Urban Areas.
Creator: Chancellor, Gerald L., Wanielista, Martin P., Engineering
Abstract / Description: Florida Technological University College of Engineering Thesis; Stormwater management in urban areas is a major concern today. The problem of disposing of this stormwater runoff in a satisfactory manner is very difficult indeed. Both the quantity and quality aspects of the runoff must be dealt with to obtain a solution of this problem. The water quality of the runoff can vary depending upon the different land uses of the drainage basin. The quantity of the stormwater runoff also depends upon...
Show moreFlorida Technological University College of Engineering Thesis; Stormwater management in urban areas is a major concern today. The problem of disposing of this stormwater runoff in a satisfactory manner is very difficult indeed. Both the quantity and quality aspects of the runoff must be dealt with to obtain a solution of this problem. The water quality of the runoff can vary depending upon the different land uses of the drainage basin. The quantity of the stormwater runoff also depends upon the land uses, the rainfall intensity and duration of the storm. The traditional methods available for determining the quantity of the stormwater runoff are numerous. These traditional methods and recently developed mathematical simulation models are discussed in this paper. Prediction of the water quality of stormwater runoff is in its infancy. Several of the mathematical models have the capabilities of quality simulation, however, the simulation results are usually inconsistent with actual quality data. Of the simulation models currently in use, the EPA Storm Water Management Model is one of the most comprehensive models. Application and verification of these newly developed models is limited. The EPA Model was chosen to simulate the quantity and quality of a small urban drainage area. The study area chosen was an urban commercial section of the Lake Eola drainage basin. Physical data of the study area, such as ground slopes, storm swere sizes and locations and slopes were determined. This data was then utilized for simulations of actual rainfall events. Verification of the quantity and quality simulation results was performed with actual quantity and quality data obtained for these rainfall events. Quantity simulation was considered successful with good correlation between the simulated and actual runoff. Quality simulation was successful to a lesser degree, the conclusion being that further quality calibration of the Model was required. Correlation between actual and simulated stormwater quality was achieved to some extent. The lack of correlation was felt to be due to calibration of the Model.
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Date Issued: 1975
Identifier: CFR0008137, ucf:52951
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFR0008137

Title: Mixing effects on shallow water bodies.
Creator: Powell, Kim Robin, Yousef, Yousef A., Engineering
Abstract / Description: Florida Technological University College of Engineering Thesis; This report is intended to examine the ecological changes due to mixing in shallow water bodies. Physical, chemical, and biological changes are reported in literature. A literature search revealed the range of mixing nodes or processes. Assessment of ecological changes due to mixing by boating activities had been evaluated in a research project supported by the environmental Protection Agency and conducted at Florida...
Show moreFlorida Technological University College of Engineering Thesis; This report is intended to examine the ecological changes due to mixing in shallow water bodies. Physical, chemical, and biological changes are reported in literature. A literature search revealed the range of mixing nodes or processes. Assessment of ecological changes due to mixing by boating activities had been evaluated in a research project supported by the environmental Protection Agency and conducted at Florida Technological University. The examination of changes due to mechanical mixing on lake ecology simulated in fifty-five gallon drums indicated the sensitivity of such parameters as total Kjeldahl nitrogen, conductivity, pH, temperature, and dissolved oxygen. Problems of reproducibility and simulation are inherent in transporting sediments and water samples from a natural environment to an isolated barrel test. Even though care was taken to insure similar initial conditions for all water quality parameters in all of the drums, differences were recognized. The useful information from a pilot study of this nature comes from the relative comparison of each drum before and after mechanical stirring.
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Date Issued: 1975
Identifier: CFR0003462, ucf:53036
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFR0003462

Title: Ichetucknee Springs: Measuring the Effects of Visitors on Water Quality Parameters through Continuous Monitoring.
Creator: Faraji, Sarah, Singh, Arvind, Wang, Dingbao, Mayo, Talea, University of Central Florida
Abstract / Description: Ichetucknee Springs System is in north central Florida, under the jurisdiction of the Suwannee River Water Management District (SRWMD). The Ichetucknee River is one of the most pristine spring-fed rivers in Florida and became a state park in 1970. Over 400,000 people visited the Ichetucknee Springs State Park in 2016. From that total, over 130,000 people came during the tubing season alone (Memorial Day to Labor Day). During the tubing season, only 750 visitors per day are allowed to launch...
Show moreIchetucknee Springs System is in north central Florida, under the jurisdiction of the Suwannee River Water Management District (SRWMD). The Ichetucknee River is one of the most pristine spring-fed rivers in Florida and became a state park in 1970. Over 400,000 people visited the Ichetucknee Springs State Park in 2016. From that total, over 130,000 people came during the tubing season alone (Memorial Day to Labor Day). During the tubing season, only 750 visitors per day are allowed to launch from the North Launch, near the Ichetucknee Head Spring. The park enforces visitor usage of the river during these time frames to protect the integrity of the aquatic vegetation and aquatic organisms in the northern portion of the River. The objective of this study is to evaluate the response of water quality from the Head Spring to the seasonal changes in visitor numbers to the Park. Water quality parameters were continuously monitored and recorded by a SRWMD station using a YSI EXO2 and SUNA nitrate sensor: temperature, turbidity, pH, specific conductivity, dissolved oxygen content, and nitrates (NO2+NO3). Water quality data from April 2015 to September 2017 was reviewed and processed into max daily values that were compared to daily visitor counts. Results from the statistical analysis indicate there is a significant difference in turbidity from the Head Spring during the tubing season and outside the tubing season (Kruskal-Wallis, p(<)0.001), which results from higher visitor counts during the weekends of the tubing season. However, due to inconsistency of water quality readings and equipment damage, some data were lost or outside the range of monitoring capabilities; which may have resulted in decreased correlation between water quality and daily visitor counts. Continued evaluation of water quality by continuous monitoring is warranted as it can assist the SRWMD and Ichetucknee Springs State Park Staff better monitor and evaluate the health of the Ichetucknee Springs System.
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Date Issued: 2017
Identifier: CFE0006873, ucf:51748
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006873

Title: Molecular Size Distributions of Heavy Metals in Lake Washington.
Creator: Andrews, William B., Taylor, James S., Engineering
Abstract / Description: University of Central Florida College of Engineering Thesis; Four untreated and one magnesium treated water samples from Lake Washington, the potable water source for the city of Melbourne, Florida, were collected and analyzed for As, Cd, Cr, Cu, Fe, Pb, Ni, Zn, Mb, Ca, and color on the basis of molecular weight distribution. Molecular weight distributions of the samples were obtained using a Millipore ultrafiltration system and filters in the following sizes: 106, 105, 2.5 x 104, 104, and...
Show moreUniversity of Central Florida College of Engineering Thesis; Four untreated and one magnesium treated water samples from Lake Washington, the potable water source for the city of Melbourne, Florida, were collected and analyzed for As, Cd, Cr, Cu, Fe, Pb, Ni, Zn, Mb, Ca, and color on the basis of molecular weight distribution. Molecular weight distributions of the samples were obtained using a Millipore ultrafiltration system and filters in the following sizes: 106, 105, 2.5 x 104, 104, and 103 nominal molecular weight limits (nmwl). color causing materials in the untreated samples were found to be located in the molecular weight fraction greater than 2.5 x 104 nmwl. The majoity of the metals concentrations (approximately greater than 80%) were also found to be located in the molecular weight fraction greater than 2.5 x 104 nmwl. Analysis of the magnesium treated (for maximum color removal) sample showed higher concentrations of metals passing the respective filter sizes as opposed to the untreated samples indicating less complexation or smaller molecular complexes of the metals. Thus, a fairly strong correlation betwee heavy metals concentrations and colorin the Lake Washington samples was indicated.
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Date Issued: 1979
Identifier: CFR0008138, ucf:52945
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFR0008138

Title: Dishwashing Water Recycling System and Related Water Quality Standards for Military Use.
Creator: Church, Jared, Lee, Woo Hyoung, Randall, Andrew, Duranceau, Steven, University of Central Florida
Abstract / Description: As the demand for reliable and safe water supplies increases, both water quality and available quantity are being challenged by population growth and climate change. Greywater reuse is becoming a common practice worldwide; however, in remote locations of limited water supply, such as those encountered in military installations, it is desirable to expand its classification to include dishwashing water to maximize the conservation of fresh water. Given that no standards for dishwashing...
Show moreAs the demand for reliable and safe water supplies increases, both water quality and available quantity are being challenged by population growth and climate change. Greywater reuse is becoming a common practice worldwide; however, in remote locations of limited water supply, such as those encountered in military installations, it is desirable to expand its classification to include dishwashing water to maximize the conservation of fresh water. Given that no standards for dishwashing greywater reuse by the military are currently available, the current study determined a specific set of water quality standards for dishwater recycling systems for U.S military field operations. A tentative water reuse standard for dishwashing water was developed based on federal and state regulations and guidelines for non-potable water, and the developed standard was cross-evaluated by monitoring water quality data from a full-scale dishwashing water recycling system using an innovative electrocoagulation and ultrafiltration process. A quantitative microbial risk assessment (QMRA) was also performed based on exposure scenarios derived from literature data. As a result, a specific set of dishwashing water reuse standards for field analysis (simple, but accurate) was finalized as follows: turbidity ((<)1 NTU), E. coli ((<)50 cfu mL-1), and pH (6(-)9). UV254 was recommended as a surrogate for organic contaminants (e.g., BOD5), but requires further calibration steps for validation. The developed specific water standard is the first for dishwashing water reuse and will be expected to ensure that water quality is safe for field operations, but not so stringent that design complexity, cost, and operational and maintenance requirements will not be feasible for field use. In addition the parameters can be monitored using simple equipment in a field setting with only modest training requirements and real-time or rapid sample turn-around. This standard may prove useful in future development of civilian guidelines.
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Date Issued: 2015
Identifier: CFE0005773, ucf:50061
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005773

Title: THE EFFECTS OF BAM AS AN ADSORPTIVE MEDIA ON PHOSPHORUS REMOVAL IN STORMWATER.
Creator: Salamah, Sultan, Randall, Andrew, Duranceau, Steven, Chopra, Manoj, University of Central Florida
Abstract / Description: To maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of...
Show moreTo maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of this project is to find the BAM values for coefficients such as maximum adsorption capacity (QM: 4.35E-05) for the media through SRP isotherm equilibrium experiments using the Langmuir and Freundlich models. In addition, an upflow column experiment was also performed to study BAM nutrient removal from stormwater runoff. Finally, the information from the isotherm and the column experiments are used to estimate the life expectancy or quantity required of the media, and to define the effectiveness of BAM in phosphorus removal. The result of this study shows that BAM is a feasible stormwater treatment that can remove 60% SRP and (>)40% TP at temperature between 21-23 (&)deg;C. The media is adequately modeled by both the Langmuir and the Freundlich models over the concentration range of interest in stormwater.
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Date Issued: 2014
Identifier: CFE0005244, ucf:50589
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005244

Title: IMPACT OF CORROSION INHIBITOR BLENDED ORTHOPHOSPHATE ON WATER QUALITY IN WATER DISTRIBUTION SYSTEMS.
Creator: Alshehri, Abdulrahman, Taylor, James, University of Central Florida
Abstract / Description: The impact of blended orthophosphate (BOP) inhibitor addition on the corrosion of iron, copper, and lead in drinking water distribution systems was studied under changing water quality environment. Release of iron, copper, and lead were monitored at varying inhibitor doses and changing blends of source waters (groundwater, surface water, and desalinated water). Solid corrosion products on pipe surfaces under BOP treatment were evaluated with surface characterization techniques. Performance of...
Show moreThe impact of blended orthophosphate (BOP) inhibitor addition on the corrosion of iron, copper, and lead in drinking water distribution systems was studied under changing water quality environment. Release of iron, copper, and lead were monitored at varying inhibitor doses and changing blends of source waters (groundwater, surface water, and desalinated water). Solid corrosion products on pipe surfaces under BOP treatment were evaluated with surface characterization techniques. Performance of the BOP inhibitor was compared to other corrosion control strategies. Iron scales for iron and galvanized steel coupons incubated in different blended waters in the presence of BOP inhibitor were analyzed by X-ray Photoelectron Spectroscopy (XPS) for surface composition. Identified iron corrosion products were ferric oxide (Fe2O3), magnetite (Fe3O4), and hydrated ferric oxide (FeOOH), in addition to ferric phosphate (FePO4) on coupons exposed to BOP inhibitor. Variations of water quality did not significantly affect the distribution of solid iron forms on surface films. Thermodynamic modeling indicated siderite (FeCO3) was the controlling solid phase of iron release. XPS indicated addition of BOP inhibitor produced a solid phosphate film in the iron scale which could inhibit iron release. Impact of BOP, orthophosphate, and pH adjustment on iron release in a distribution system was examined. Iron release was sensitive to water quality variations (alkalinity and chloride) associated with source and blends of finished water. Finished waters with high alkalinity content (between 149 and 164 mg/L as CaCO3) consistently mitigated iron release regardless of inhibitor use. Dissolved iron constituted about 10% of total iron release. Empirical models were developed that related water quality, inhibitor type and dose to iron release. The BOP inhibitor minimized total iron release followed closely by increasing pH (between 7.9 and 8.1), while orthophosphate dose did not affect iron release. Temperature (ranged from 21.2 to 25.3) had limited influence on iron release with BOP treatment. Monitoring copper release showed that dissolved copper was the dominant form in the effluent, at about 88%. BOP inhibitor doses of 0.5 to 2.0 mg/L proved beneficial in controlling copper concentrations to an average of below 0.5 mg/L. Control of copper release improved with increasing BOP dose, despite changes in alkalinity. Elevation of pH by 0.3 unit beyond pHs (between 7.9 and 8.1) resulted in noticeable decrease in copper concentrations of about 30%, but was more sensitive to higher alkalinity (146 to 151 mg/L as CaCO3) than BOP treatment. Developed empirical models confirmed the importance of BOP inhibitor dose, pH increase, and alkalinity content on copper release. Statistical comparison of the corrosion control strategies proved the advantage of BOP inhibitor, at all doses, over pH elevation in controlling copper release. The BOP inhibitor mitigated lead release below action level, and consistently outperformed pH elevation, in all water quality conditions. XPS analysis identified lead dioxide (PbO2), lead oxide (PbO), cerussite (PbCO3), and hydrocerussite (Pb3(CO3)2(OH)2) as the corrosion products in the scale of lead/tin coupons exposed to BOP inhibitor. XPS and Scanning Electron Microscopy (SEM) analysis suggested cerussite or hydrocerussite is the controlling solid phase of lead release. Thermodynamic models for cerussite and hydrocerussite grossly over predicted actual concentrations. Solubility and equilibrium relationships suggested the possibility of a lead orthophosphate solid that would describe the effectiveness of BOP inhibitor, although no lead-phosphate solid was detected by surface analysis. BOP inhibitor appeared to have mitigated lead release by forming a surface film between lead scale and the bulk water.
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Date Issued: 2008
Identifier: CFE0002229, ucf:47922
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002229

Title: LAND USE EFFECTS ON LAKE WATER QUALITY IN CENTRAL FLORIDA.
Creator: Seiler, Jonathan, Weishampel, John F., University of Central Florida
Abstract / Description: ABSTRACT Land use affects the water quality of lakes. Different land use types yield different effects due to varying amounts and constituents of runoff. In this study, the effects of surrounding land use on the water quality of 50 lakes in Seminole County, Florida was assessed. Using GIS, I placed buffers of 100 and 500 m around each lake. The percentages of land use type were calculated within these buffers for 1990 and 1995. An ordination of lakes was done using Canonical Correspondence...
Show moreABSTRACT Land use affects the water quality of lakes. Different land use types yield different effects due to varying amounts and constituents of runoff. In this study, the effects of surrounding land use on the water quality of 50 lakes in Seminole County, Florida was assessed. Using GIS, I placed buffers of 100 and 500 m around each lake. The percentages of land use type were calculated within these buffers for 1990 and 1995. An ordination of lakes was done using Canonical Correspondence Analysis (CCA) to determine if the surrounding land use patterns were adequate to describe the trophic status of the lakes. Correlations between land use and water quality were found to be significant for the 1990 100 and 500 m buffers. Inter-set correlations showed that among land use types: residential, urban, agriculture, hardwoods, and wetlands were the most influential in determining water quality in that they had the most positive or negative correlation with the WA scores depending on the year and buffer zone. Excessively drained and very poorly drained soils were the most influential of the soil types. A Discriminant Function Analysis (DFA) was also performed to determine which land use and soil variables were effective in discriminating between oligotrophic, mesotrophic, and eutrophic lakes. Wetlands and very poorly drained soil were the most effective in discriminating between the groups of lakes. A multiple regression analysis was performed that determined correlations for 1990 and change in land use 100 m buffers contributed to our understanding of the relationship between land use and water quality. Effects of land use on water quality need to be considered when attempting to restore a lake or subjecting it to future land development.
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Date Issued: 2004
Identifier: CFE0000138, ucf:46174
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000138

Title: Transforming the Aquatic Urban Landscape: Nutrient Status and Management of Stormwater Basins.
Creator: Skovira, Lindsay, Bohlen, Patrick, Fauth, John, Wang, Dingbao, University of Central Florida
Abstract / Description: Urbanization is a largely irreversible anthropogenic change that degrades environmental quality, including aquatic ecosystems. Stormwater ponds are a popular best management practice (BMP) to mitigate the effects of urban land use on downstream water bodies and contribute significantly to the total area of aquatic ecosystems in some urban watersheds. My research investigated the distribution of stormwater ponds and examined how different urban land uses influenced biophysicochemical...
Show moreUrbanization is a largely irreversible anthropogenic change that degrades environmental quality, including aquatic ecosystems. Stormwater ponds are a popular best management practice (BMP) to mitigate the effects of urban land use on downstream water bodies and contribute significantly to the total area of aquatic ecosystems in some urban watersheds. My research investigated the distribution of stormwater ponds and examined how different urban land uses influenced biophysicochemical conditions and management of those ponds in a rapidly developing suburban watershed in the Econlockhatchee River basin in Florida, USA. I evaluated limnological and ecological parameters in randomly-selected ponds distributed among three urban land-use classes: high-density residential, institutional, and roadways. Ecological measures included characterizing percentage cover and composition of littoral zone plant community and the extent of any algal mats. Limnological measures included physical parameters (pH, conductivity, dissolved oxygen, and clarity), and nutrient concentrations (nitrate, ammonium, total nitrogen, dissolved reactive phosphorus, total phosphorus, and chlorophyll a). I used a subjective management intensity index to compare pond management among land-use classes. Stormwater ponds represented 40.2% of the total area of non-forested freshwater systems in the watershed, and were dominated by residential land uses (43.7%), followed by roadways (14.7%), industrial (2.7%) and institutional (2.3%). Principal Component Analysis (PCA) revealed that ponds with higher total nitrogen (TN) and chlorophyll a (chla) concentrations had lower water clarity, and that both. TN and TP were positively correlated with chla. PCA scores for school ponds, which had the highest water clarity, differed significantly from those of expressway and residential ponds, along the first PCA axis. Repeated-measures analysis of variance showed that TN concentrations differed significantly between expressway and school ponds, with expressway ponds having TN concentrations 51.7% higher than schools. Both TP and TN varied differently through time in the different lands uses. Management intensity for removal of aquatic vegetation and algae was lower in school ponds than in expressway and residential ponds, and school ponds contained the highest abundance and diversity of vegetation. Different urban land uses had varying impacts on water quality, and more intense chemical use to control vegetation and algae was related to greater nutrient and chla concentrations and lower water clarity.
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Date Issued: 2016
Identifier: CFE0006845, ucf:51781
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006845

Title: Assessing Interactions between Estuary Water Quality and Terrestrial Land Cover in Hurricane Events with Multi-sensor Remote Sensing.
Creator: Mostafiz, Chandan, Chang, Ni-bin, Wanielista, Martin, Kibler, Kelly, University of Central Florida
Abstract / Description: Estuaries are environmentally, ecologically and environmentally important places as they act as a meeting place for land, freshwater and marine ecosystems. They are also called nurseries of the sea as they often provide nesting and feeding habitats for many aquatic plants and animals. These estuaries also withstand the worst of some natural disasters, especially hurricanes. The estuaries as well as the harbored ecosystems undergo significant changes in terms of water quality, vegetation cover...
Show moreEstuaries are environmentally, ecologically and environmentally important places as they act as a meeting place for land, freshwater and marine ecosystems. They are also called nurseries of the sea as they often provide nesting and feeding habitats for many aquatic plants and animals. These estuaries also withstand the worst of some natural disasters, especially hurricanes. The estuaries as well as the harbored ecosystems undergo significant changes in terms of water quality, vegetation cover etc. and these components are interrelated. When hurricane makes landfall it is necessary to assess the damages as quickly as possible as restoration and recovery processes are time-sensitive. However, assessment of physical damages through inspection and survey and assessment of chemical and nutrient component changes by laboratory testing are time-consuming processes. This is where remote sensing comes into play. With the help of remote sensing images and regression analysis, it is possible to reconstruct water quality maps of the estuary affected. The damage sustained by the vegetation cover of the adjacent coastal watershed can be assessed using Normalized Difference Vegetation Index (NDVI) The water quality maps together with NDVI maps help observe a dynamic sea-land interaction due to hurricane landfall. The observation of hurricane impacts on a coastal watershed can be further enhanced by use of tasseled cap transformation (TCT). TCT plots provide information on a host of land cover conditions with respect to soil moisture, canopy and vegetation cover. The before and after TCT plots help assess the damage sustained in a hurricane event and also see the progress of recovery. Finally, the use of synthetic images obtained by use of data fusion will help close the gap of low temporal resolution of Landsat satellite and this will create a more robust monitoring system.
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Date Issued: 2017
Identifier: CFE0006900, ucf:51729
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006900

Title: VERIFICATION OF PILOT-SCALE IRON RELEASE MODELS.
Creator: Glatthorn, Stephen, Taylor, James, University of Central Florida
Abstract / Description: A model for the prediction of color release from a pilot distribution system was created in 2003 by Imran. This model allows prediction of the release of color from aged cast iron and galvanized steel pipes as a function of water quality and hydraulic residence time. Color was used as a surrogate measurement for iron, which exhibited a strong linear correlation. An anomaly of this model was an absence of a term to account for pH, due to the influent water being well stabilized. A new study...
Show moreA model for the prediction of color release from a pilot distribution system was created in 2003 by Imran. This model allows prediction of the release of color from aged cast iron and galvanized steel pipes as a function of water quality and hydraulic residence time. Color was used as a surrogate measurement for iron, which exhibited a strong linear correlation. An anomaly of this model was an absence of a term to account for pH, due to the influent water being well stabilized. A new study was completed to evaluate the effectiveness of corrosion inhibitors against traditional adjustment. Two control lines were supplied with nearly same water qualities, one at pH close to pHs and one at pH well above pHs. The resulting data showed that effluent iron values were typically greater in the line with lower pH. The non-linear color model by Imran shows good agreement when the LSI was largely positive, but underpredicted the color release from the lower LSI line. A modification to the Larson Ratio proposed by Imran was able to give a reasonable agreement to the data at lower LSI values. LSI showed no definite relation to iron release, although a visual trend of higher LSI mitigating iron release can be seen. An iron flux model was also developed on the same pilot system by Mutoti. This model was based on a steady state mass balance of iron in a pipe. The constants for the model were empirically derived from experiments at different hydraulic conditions with a constant water quality. Experiments were assumed to reach steady state at 3 pipe volumes due to the near constant effluent turbidity achieved at this point. The model proposes that the iron flux under laminar flow conditions is constant, while the iron flux is linearly related to the Reynolds Number under turbulent conditions. This model incorporates the color release models developed by Imran to calculate flux values from different water qualities. A limited number of experiments were performed in the current study using desalinated and ground water sources at Reynolds Numbers ranging from 50 to 200. The results of these limited experiments showed that the iron flux for cast iron pipe was approximately one-half of the predicted values from Mutoti. This discrepancy may be caused by the more extensive flushing of the pipes performed on the current experiments which allowed attainment of a true steady state. Model changes were proposed to distinguish between near stagnant flow and the upper laminar region, with the upper laminar region showing a slight linear increase. Predictions using the galvanized flux model were not accurate due to an inferior color release model that was developed for galvanized pipes. The model exhibits a high dependence on sulfate concentrations, but concentrations of sulfates in the current experiments were low. This led to low predicted flux values when the actual data showed otherwise. A new galvanized model was developed from a combination of data from the original and current experiments. The predicted flux values using the new model showed great improvement over the old model, but the new model database was limited and the resulting model was not able to be independently tested.
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Date Issued: 2007
Identifier: CFE0001704, ucf:47332
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001704

Title: Development of Treatment Train Techniques for the Evaluation of Low Impact Development in Urban Regions.
Creator: Hardin, Mike, Wanielista, Martin, Cooper, David, Randall, Andrew, University of Central Florida
Abstract / Description: Stormwater runoff from urban areas is a major source of pollution to surface water bodies. The discharge of nutrients such as nitrogen and phosphorus is particularly damaging as it results in harmful algal blooms which can limit the beneficial use of a water body. Stormwater best management practices (BMPs) have been developed over the years to help address this issue. While BMPs have been investigated for years, their use has been somewhat limited due to the fact that much of the data...
Show moreStormwater runoff from urban areas is a major source of pollution to surface water bodies. The discharge of nutrients such as nitrogen and phosphorus is particularly damaging as it results in harmful algal blooms which can limit the beneficial use of a water body. Stormwater best management practices (BMPs) have been developed over the years to help address this issue. While BMPs have been investigated for years, their use has been somewhat limited due to the fact that much of the data collected is for specific applications, in specific regions, and it is unknown how these systems will perform in other regions and for other applications. Additionally, the research was spread across the literature and performance data was not easily accessible or organized in a convenient way. Recently, local governments and the USEPA have begun to collect this data in BMP manuals to help designers implement this technology. That being said, many times a single BMP is insufficient to meet water quality and flood control needs in urban areas. A treatment train approach is required in these regions. In this dissertation, the development of methodologies to evaluate the performance of two BMPs, namely green roofs and pervious pavements is presented. Additionally, based on an extensive review of the literature, a model was developed to assist in the evaluation of site stormwater plans using a treatment train approach for the removal of nutrients due to the use of BMPs. This model is called the Best Management Practices Treatment for Removal on an Annual basis Involving Nutrients in Stormwater (BMPTRAINS) model.The first part of this research examined a previously developed method for designing green roofs for hydrologic efficiency. The model had not been tested for different designs and assumed that evapotranspiration was readily available for all regions. This work tested this methodology against different designs, both lab scale and full scale. Additionally, the use of the Blaney-Criddle equation was examined as a simple way to determine the ET for regions where data was not readily available. It was shown that the methods developed for determination of green roof efficiency had good agreement with collected data. Additionally, the use of the Blaney-Criddle equation for estimation of ET had good agreement with collected and measured data.The next part of this research examined a method to design pervious pavements. The water storage potential is essential to the successful design of these BMPs. This work examined the total and effective porosities under clean, sediment clogged, and rejuvenated conditions. Additionally, a new type of porosity was defined called operating porosity. This new porosity was defined as the average of the clean effective porosity and the sediment clogged effective porosity. This porosity term was created due to the fact that these systems exist in the exposed environment and subject to sediment loading due to site erosion, vehicle tracking, and spills. Due to this, using the clean effective porosity for design purposes would result in system failure for design type storm events towards the end of its service life. While rejuvenation techniques were found to be somewhat effective, it was also observed that often sediment would travel deep into the pavement system past the effective reach of vacuum sweeping. This was highly dependent on the pore structure of the pavement surface layer. Based on this examination, suggested values for operating porosity were presented which could be used to calculate the storage potential of these systems and subsequent curve number for design purposes.The final part of this work was the development of a site evaluation model using treatment train techniques. The BMPTRAINS model relied on an extensive literature review to gather data on performance of 15 different BMPs, including the two examined as part of this work. This model has 29 different land uses programmed into it and a user defined option, allowing for wide applicability. Additionally, this model allows a watershed to be split into up to four different catchments, each able to have their own distinct pre- and post-development conditions. Based on the pre- and post-development conditions specified by the user, event mean concentrations (EMCs) are assigned. These EMCs can also be overridden by the user. Each catchment can also contain up to three BMPs in series. If BMPs are to be in parallel, they must be in a separate catchment. The catchments can be configured in up to 15 different configurations, including series, parallel, and mixed. Again, this allows for wide applicability of site designs. The evaluation of cost is also available in this model, either in terms of capital cost or net present worth. The model allows for up to 25 different scenarios to be run comparing cost, presenting results in overall capital cost, overall net present worth, or cost per kg of nitrogen and phosphorus. The wide array of BMPs provided and the flexibility provided to the user makes this model a powerful tool for designers and regulators to help protect surface waters.
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Date Issued: 2014
Identifier: CFE0005503, ucf:50338
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005503

Title: REVERSION OF POLY-PHOSPHATES TO ORTHO-PHOSPHATES IN WATER DISTRIBUTION SYSTEMS.
Creator: shekhar, avinash, taylor, james, University of Central Florida
Abstract / Description: Orthophosphates and polyphosphates are rarely present at significant levels in raw water source but are purposefully added to the water in various forms to inhibit corrosion, iron oxidation (red water), or calcium carbonate precipitation (scale formation). Orthophosphates serve as building blocks for polyphosphates, which includes structures in linear chain, branched chains (metaphosphate) and "glassy" polyphosphate polymers. The advantage of polyphosphates over ortho phosphates lies in the...
Show moreOrthophosphates and polyphosphates are rarely present at significant levels in raw water source but are purposefully added to the water in various forms to inhibit corrosion, iron oxidation (red water), or calcium carbonate precipitation (scale formation). Orthophosphates serve as building blocks for polyphosphates, which includes structures in linear chain, branched chains (metaphosphate) and "glassy" polyphosphate polymers. The advantage of polyphosphates over ortho phosphates lies in the fact that they slowly revert to orthophosphates and thus provide corrosion inhibition action over longer period of time in distribution systems. A study was completed for Tampa Bay Water on water distribution systems in a changing water quality environment. Blended orthophosphates was used as one of the corrosion inhibitors to study its effects on metal release and thus justify its application in comparison to other corrosion inhibitors like orthophosphates, zinc orthophosphates and silicates. This work focuses on the study of reversion of polyphosphates to ortho phosphates. A first-order model was developed that quantifies reversion as a function of the hydraulic residence time and initial poly phosphate concentration. The same model was used in two different forms – one for the hybrid lines and the other for single material lines. The results from single material lines (estimated by a non linear least square regression using ANOVA) showed that the reversion rate was highest for galvanized pipe followed by unlined cast iron, lined cast iron and the lowest rate in PVC. The first-order reversion rate constant in PVC was almost two log orders less than galvanized line. A high first-order rate constant for the galvanized pipe could be attributed to a rougher surface, large surface area, reaction with the wall surface, pipe material or a combination of these effects. The results from the hybrid PDSs (estimated by an algebraic manipulation of the first-order reaction) substantially agree with the results obtained from the single material lines, with the exception of the PVC material. The data from the hybrid lines confirms that the reversion rate constant is greatest for exposure to galvanized pipe materials, but the hybrid data indicate that the rate constant associated with PVC is somewhat larger than the constants determined for either LCI or UCI. Once an overall first-order rate expression was established, efforts were made to find a relation between polyphosphate reversions with bulk water quality. None of the major water quality parameters were found to significantly affect the reversion. This observation may be attributable to a similar water quality over the study duration. A positive correlation was found between first-order reversion rate constant and temperature. An empirical equation (modified Arrhenius equation) that relates the first-order reversion rate constant with temperature was developed that showed a strong sensitivity to temperature. The results from this study could be used to predict the stability of polyphosphates in distribution systems with varying pipe materials and temperature.
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Date Issued: 2007
Identifier: CFE0001832, ucf:47350
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001832

Title: IMPACT OF ZINC ORTHOPHOSPHATE INHIBITOR ONDISTRIBUTION SYSTEM WATER QUALITY.
Creator: Guan, Xiaotao, Taylor, James, University of Central Florida
Abstract / Description: This dissertation consists of four papers concerning impacts of zinc orthophosphate (ZOP) inhibitor on iron, copper and lead release in a changing water quality environment. The mechanism of zinc orthophosphate corrosion inhibition in drinking water municipal and home distribution systems and the role of zinc were investigated. Fourteen pilot distribution systems (PDSs) which were identical and consisted of increments of PVC, lined cast iron, unlined cast iron and galvanized steel pipes were...
Show moreThis dissertation consists of four papers concerning impacts of zinc orthophosphate (ZOP) inhibitor on iron, copper and lead release in a changing water quality environment. The mechanism of zinc orthophosphate corrosion inhibition in drinking water municipal and home distribution systems and the role of zinc were investigated. Fourteen pilot distribution systems (PDSs) which were identical and consisted of increments of PVC, lined cast iron, unlined cast iron and galvanized steel pipes were used in this study. Changing quarterly blends of finished ground, surface and desalinated waters were fed into the pilot distribution systems over a one year period. Zinc orthophosphate inhibitor at three different doses was applied to three PDSs. Water quality and iron, copper and lead scale formation was monitored for the one year study duration. The first article describes the effects of zinc orthophosphate (ZOP) corrosion inhibitor on surface characteristics of iron corrosion products in a changing water quality environment. Surface compositions of iron surface scales for iron and galvanized steel coupons incubated in different blended waters in the presence of ZOP inhibitor were investigated using X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM) / Energy Dispersive X-ray Spectroscopy (EDS). Based on surface characterization, predictive equilibrium models were developed to describe the controlling solid phase and mechanism of ZOP inhibition and the role of zinc for iron release. The second article describes the effects of zinc orthophosphate (ZOP) corrosion inhibitor on total iron release in a changing water quality environment. Development of empirical models as a function of water quality and ZOP inhibitor dose for total iron release and mass balances analysis for total zinc and total phosphorus data provided insight into the mechanism of ZOP corrosion inhibition regarding iron release in drinking water distribution systems. The third article describes the effects of zinc orthophosphate (ZOP) corrosion inhibitor on total copper release in a changing water quality environment. Empirical model development was undertaken for prediction of total copper release as a function of water quality and inhibitor dose. Thermodynamic models for dissolved copper based on surface characterization of scale that were generated on copper coupons exposed to ZOP inhibitor were also developed. Surface composition was determined by X-ray Photoelectron Spectroscopy (XPS). The fourth article describes the effects of zinc orthophosphate (ZOP) corrosion inhibitor on total lead release in a changing water quality environment. Surface characterization of lead scale on coupons exposed to ZOP inhibitor by X-ray Photoelectron Spectroscopy (XPS) was utilized to identify scale composition. Development of thermodynamic model for lead release based on surface analysis results provided insight into the mechanism of ZOP inhibition and the role of zinc.
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Date Issued: 2007
Identifier: CFE0001931, ucf:47453
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001931

Title: THE EFFECT OF FREE CHLORINE AND CHLORAMINES ON LEAD RELEASE IN A DISTRIBUTION SYSTEM.
Creator: Vasquez, Ferdinand, Taylor, James, University of Central Florida
Abstract / Description: Total lead release in drinking water in the presence of free chlorine and chloramine residuals was investigated in field, laboratory and fundamental investigations for finished waters produced from ground (GW), surface (SW), saline (RO) and blended (B) sources. Field investigations found more total lead was released in the presence of chloramines than in the presence of free chlorine for RO and blended finished waters; however, there were no statistical differences in total lead release to...
Show moreTotal lead release in drinking water in the presence of free chlorine and chloramine residuals was investigated in field, laboratory and fundamental investigations for finished waters produced from ground (GW), surface (SW), saline (RO) and blended (B) sources. Field investigations found more total lead was released in the presence of chloramines than in the presence of free chlorine for RO and blended finished waters; however, there were no statistical differences in total lead release to finished GW and SW. Laboratory measurements of finished waters oxidation-reduction potential (ORP) were equivalent by source and were not affected by the addition of more than 100 mg/L of sulfates or chlorides, but were significantly higher in the presence of free chlorine relative to chloramines. Development of Pourbaix diagrams revealed the PbO2 was the controlling solid phase at the higher ORP in the presence of free chlorine and Pb3(CO3)2(OH)2(s) (hydrocerussite) was the controlling solid phase in the presence of chloramines at the lower ORP, which mechanistically accounted for the observed release of total lead as PbO2 is much less soluble than hydrocerussite. The lack of differences in total lead release to finished GW and SW was attributed to differences in water quality and intermittent behavior of particulate release from controlling solid films.
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Date Issued: 2005
Identifier: CFE0000533, ucf:46427
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000533

Title: AN INTEGRATED HYDROLOGY/HYDRAULIC AND WATER QUALITY MODEL FOR WATERSHED-SCALE SIMULATIONS.
Creator: Wang, Cheng, Yeh, Gour-Tsyh, University of Central Florida
Abstract / Description: This dissertation presents the design of an integrated watershed model, WASH123D version 3.0, a first principle, physics-based watershed-scale model of integrated hydrology/hydraulics and water quality transport. This numerical model is comprised of three modules: (1) a one-dimensional (1-D) simulation module that is capable of simulating separated and coupled fluid flow, sediment transport and reaction-based water quality transport in river/stream/canal networks and through control...
Show moreThis dissertation presents the design of an integrated watershed model, WASH123D version 3.0, a first principle, physics-based watershed-scale model of integrated hydrology/hydraulics and water quality transport. This numerical model is comprised of three modules: (1) a one-dimensional (1-D) simulation module that is capable of simulating separated and coupled fluid flow, sediment transport and reaction-based water quality transport in river/stream/canal networks and through control structures; (2) a two-dimensional (2-D) simulation module, capable of simulating separated and coupled fluid flow, sediment transport, and reactive biogeochemical transport and transformation in two-dimensional overland flow systems; and (3) a three-dimensional (3-D) simulation module, capable of simulating separated and coupled fluid flow and reactive geochemical transport and transformation in three-dimensional variably saturated subsurface systems. The Saint Venant equation and its simplified versions, diffusion wave and kinematic wave forms, are employed for surface fluid flow simulations and the modified Richards equation is applied for subsurface flow simulation. The reaction-based advection-dispersion equation is used as the governing equation for water quality transport. Several physically and mathematically based numerical options are provided to solve these governing equations for different application purposes. The surface-subsurface water interactions are considered in the flow module and simulated on the basis of continuity of interface. In the transport simulations, fast/equilibrium reactions are decoupled from slow/kinetic reactions by the decomposition of reaction networks; this enables robust numerical integrations of the governing equation. Kinetic variables are adopted as primary dependent variables rather than biogeochemical species to reduce the number of transport equations and simplify the reaction terms. In each time step, hydrologic/hydraulic variables are solved in the flow module; kinetic variables are then solved in the transport module. This is followed by solving the reactive chemical system node by node to yield concentrations of all species. Application examples are presented to demonstrate the design capability of the model. This model may be of interest to environmental scientists, engineers and decision makers as a comprehensive assessment tool to reliably predict the fluid flow as well as sediment and contaminant transport on watershed scales so as to evaluate the efficacy and impact of alternative watershed management and remediation techniques prior to incurring expense in the field.
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Date Issued: 2009
Identifier: CFE0002947, ucf:47955
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002947

Title: EFFECTS OF ORTHOPHOSPHATE CORROSION INHIBITOR IN BLENDED WATER QUALITY ENVIRONMENTS.
Creator: Stone, Erica, Duranceau, Steven, University of Central Florida
Abstract / Description: This study evaluated the effects of orthophosphate (OP) inhibitor addition on iron, copper, and lead corrosion on coupons exposed to different blends of groundwater, surface water, and desalinated seawater. The effectiveness of OP inhibitor addition on iron, copper, and lead release was analyzed by statistical comparison between OP treated and untreated pilot distribution systems (PDS). Four different doses of OP inhibitor, ranging from zero (control) to 2 mg/L as P, were investigated and non...
Show moreThis study evaluated the effects of orthophosphate (OP) inhibitor addition on iron, copper, and lead corrosion on coupons exposed to different blends of groundwater, surface water, and desalinated seawater. The effectiveness of OP inhibitor addition on iron, copper, and lead release was analyzed by statistical comparison between OP treated and untreated pilot distribution systems (PDS). Four different doses of OP inhibitor, ranging from zero (control) to 2 mg/L as P, were investigated and non-linear empirical models were developed to predict iron, copper, and lead release from the water quality and OP doses. Surface characterization evaluations were conducted using X-ray Photoelectron Spectroscopy (XPS) analyses for each iron, galvanized steel, copper, and lead/tin coupon tested. Also, a theoretical thermodynamic model was developed and used to validate the controlling solid phases determined by XPS. A comparison of the effects of phosphate-based corrosion inhibitor addition on iron, copper, and lead release from the PDSs exposed to the different blends was also conducted. Three phosphate-based corrosion inhibitors were employed; blended orthophosphate (BOP), orthophosphate (OP), and zinc orthophosphate (ZOP). Non-linear empirical models were developed to predict iron, copper, and lead release from each PDS treated with different doses of inhibitor ranging from zero (control) to 2 mg/L as P. The predictive models were developed using water quality parameters as well as the inhibitor dose. Using these empirical models, simulation of the water quality of different blends with varying alkalinity and pH were used to compare the inhibitors performance for remaining in compliance for iron, copper and lead release. OP inhibitor addition was found to offer limited improvement of iron release for the OP dosages evaluated for the water blends evaluated compared to pH adjustment alone. Empirical models showed increased total phosphorus, pH, and alkalinity reduced iron release while increased silica, chloride, sulfate, and temperature contributed to iron release. Thermodynamic modeling suggested that FePO4 is the controlling solid that forms on iron and galvanized steel surfaces, regardless of blend, when OP inhibitor is added for corrosion control. While FePO4 does not offer much control of the iron release from the cast iron surfaces, it does offer protection of the galvanized steel surfaces reducing zinc release. OP inhibitor addition was found to reduce copper release for the OP dosages evaluated for the water blends evaluated compared to pH adjustment alone. Empirical models showed increases in total phosphorus, silica, and pH reduced copper release while increased alkalinity and chloride contributed to copper release. Thermodynamic modeling suggested that Cu3(PO4)2•2H2O is the controlling solid that forms on copper surfaces, regardless of blend, when OP inhibitor is added for corrosion control. OP inhibitor addition was found to reduce lead release for the OP dosages evaluated for the water blends evaluated compared to pH adjustment alone. Empirical models showed increased total phosphorus and pH reduced lead release while increased alkalinity, chloride, and temperature contributed to lead release. Thermodynamic modeling suggested that hydroxypyromorphite is the controlling solid that forms on lead surfaces, regardless of blend, when OP inhibitor is added for corrosion control. The comparison of phosphate-based inhibitors found increasing pH to reduce iron, copper, and lead metal release, while increasing alkalinity was shown to reduce iron release but increase copper and lead release. The ZOP inhibitor was not predicted by the empirical models to perform as well as BOP and OP at the low dose of 0.5 mg/L as P for iron control, and the OP inhibitor was not predicted to perform as well as BOP and ZOP at the low dose of 0.5 mg/L as P for lead control. The three inhibitors evaluated performed similarly for copper control. Therefore, BOP inhibitor showed the lowest metal release at the low dose of 0.5 mg/L as P for control of iron, copper, and lead corrosion.
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Date Issued: 2008
Identifier: CFE0002382, ucf:47760
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002382

Title: Drinking Water Infrastructure Assessment with Teleconnection Signals, Satellite Data Fusion and Mining.
Creator: Imen, Sanaz, Chang, Ni-bin, Wang, Dingbao, Wanielista, Martin, Bohlen, Patrick, University of Central Florida
Abstract / Description: Adjustment of the drinking water treatment process as a simultaneous response to climate variations and water quality impact has been a grand challenge in water resource management in recent years. This desired and preferred capability depends on timely and quantitative knowledge to monitor the quality and availability of water. This issue is of great importance for the largest reservoir in the United States, Lake Mead, which is located in the proximity of a big metropolitan region - Las...
Show moreAdjustment of the drinking water treatment process as a simultaneous response to climate variations and water quality impact has been a grand challenge in water resource management in recent years. This desired and preferred capability depends on timely and quantitative knowledge to monitor the quality and availability of water. This issue is of great importance for the largest reservoir in the United States, Lake Mead, which is located in the proximity of a big metropolitan region - Las Vegas, Nevada. The water quality in Lake Mead is impaired by forest fires, soil erosion, and land use changes in nearby watersheds and wastewater effluents from the Las Vegas Wash. In addition, more than a decade of drought has caused a sharp drop by about 100 feet in the elevation of Lake Mead. These hydrological processes in the drought event led to the increased concentration of total organic carbon (TOC) and total suspended solids (TSS) in the lake. TOC in surface water is known as a precursor of disinfection byproducts in drinking water, and high TSS concentration in source water is a threat leading to possible clogging in the water treatment process. Since Lake Mead is a principal source of drinking water for over 25 million people, high concentrations of TOC and TSS may have a potential health impact. Therefore, it is crucial to develop an early warning system which is able to support rapid forecasting of water quality and availability. In this study, the creation of the nowcasting water quality model with satellite remote sensing technologies lays down the foundation for monitoring TSS and TOC, on a near real-time basis. Yet the novelty of this study lies in the development of a forecasting model to predict TOC and TSS values with the aid of remote sensing technologies on a daily basis. The forecasting process is aided by an iterative scheme via updating the daily satellite imagery in concert with retrieving the long-term memory from the past states with the aid of nonlinear autoregressive neural network with external input on a rolling basis onward. To account for the potential impact of long-term hydrological droughts, teleconnection signals were included on a seasonal basis in the Upper Colorado River basin which provides 97% of the inflow into Lake Mead. Identification of teleconnection patterns at a local scale is challenging, largely due to the coexistence of non-stationary and non-linear signals embedded within the ocean-atmosphere system. Empirical mode decomposition as well as wavelet analysis are utilized to extract the intrinsic trend and the dominant oscillation of the sea surface temperature (SST) and precipitation time series. After finding possible associations between the dominant oscillation of seasonal precipitation and global SST through lagged correlation analysis, the statistically significant index regions in the oceans are extracted. With these characterized associations, individual contribution of these SST forcing regions that are linked to the related precipitation responses are further quantified through the use of the extreme learning machine. Results indicate that the non-leading SST regions also contribute saliently to the terrestrial precipitation variability compared to some of the known leading SST regions and confirm the capability of predicting the hydrological drought events one season ahead of time. With such an integrated advancement, an early warning system can be constructed to bridge the current gap in source water monitoring for water supply.
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Date Issued: 2015
Identifier: CFE0005632, ucf:50215
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005632

Title: EFFECT OF SOURCE WATER BLENDING ON COPPER RELEASE IN PIPE DISTRIBUTION SYSTEM: THERMODYNAMIC AND EMPIRICAL MODELS.
Creator: Xiao, Weizhong, Taylor, James S., University of Central Florida
Abstract / Description: This dissertation focuses on copper release in drinking water. Qualitative and quantitative assessment of Cu and Fe corrosion by process water quality was assessed over one year in a field study using finished waters produced from seven different treatment process and eighteen pilot distribution systems (PDSs) that were made from unlined cast iron and galvanized steel pipes, and lined cement and PVC pipes taken from actual distribution systems. Totally seven different waters were studied,...
Show moreThis dissertation focuses on copper release in drinking water. Qualitative and quantitative assessment of Cu and Fe corrosion by process water quality was assessed over one year in a field study using finished waters produced from seven different treatment process and eighteen pilot distribution systems (PDSs) that were made from unlined cast iron and galvanized steel pipes, and lined cement and PVC pipes taken from actual distribution systems. Totally seven different waters were studied, which consisted of three source waters: groundwater, surface, and simulated brackish water designated as G1, S1, and RO. With certain pre-established blending ratios, these three waters were blended to form another three waters designated as G2, G3, and G4. Enhanced surface water treatment was CFS, ozonation and GAC filtration, which was designated as S1. The CFS surface water was nanofiltered, which is S2. All seven finished waters were stabilized and chloraminated before entering the PDSs. Corrosion potential was compared qualitatively and quantitatively for all seven waters by monitoring copper and iron release from the PDSs. This dissertation consists of four major parts.(1) Copper corrosion surface characterization in which the solid corrosion products formed in certain period of exposure to drinking water were tried to be identified with kinds of surface techniques. Surface characterization indicated that major corrosion products consists of cuprite (Cu2O) as major underneath corrosion layer and tenorite (CuO), cupric hydroxide (Cu(OH)2) on the top surface. In terms of dissolution/precipitation mechanism controlling the copper concentration in bulk solution, cupric hydroxide thermodynamic model was developed.(2) Theoretical thermodynamic models were developed to predict the copper release level quantitatively based on controlling solid phases identified in part (1). These models are compared to actual data and relative assessment is made of controlling solid phases. (3) Non-linear and linear regression models were developed that accommodated the release to total copper for varying water quality. These models were verified using independent data and provide proactive means of assessing and controlling copper release in a varying water quality environment. (4) Simulation of total copper release was conducted using all possible combinations of water quality produced by blending finished waters from ground, surface and saline sources, which involves the comparison of copper corrosion potentials among reverse osmosis, nanofiltration, enhanced coagulation, lime softening, and conventional drinking water treatment.
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Date Issued: 2004
Identifier: CFE0000042, ucf:46069
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000042

Title: A COMPARATIVE ANALYSIS OF GREEN ROOF DESIGNS INCLUDING DEPTH OF MEDIA, DRAINAGE LAYER MATERIALS, AND POLLUTION CONTROL MEDIA.
Creator: Kelly, Matt, Cooper, C. David, University of Central Florida
Abstract / Description: Population growth has lead to an increase in development and impervious areas in urban settings. Post-development conditions cause several problems for stormwater management such as limited space for stormwater storage systems and the conveyance of pollution picked up by runoff to near by water bodies. Green Roofs with cisterns have been shown to attenuate the peak flow of storm events and reduce the pollution load leaving a site and entering nearby water bodies. The purpose of this research...
Show morePopulation growth has lead to an increase in development and impervious areas in urban settings. Post-development conditions cause several problems for stormwater management such as limited space for stormwater storage systems and the conveyance of pollution picked up by runoff to near by water bodies. Green Roofs with cisterns have been shown to attenuate the peak flow of storm events and reduce the pollution load leaving a site and entering nearby water bodies. The purpose of this research is to expand the available research data on green roofs with cisterns by investigating the water quality and hydrology effects of different green roof designs including depth of media, an additional pollution control layer beneath the growth media, and different drainage layer materials. Furthermore, a comparison study is performed on the cistern water quality, direct filtrate water quality, and control roof filtrate water quality. Results show that phosphorus concentrations are lower when using a pollution control layer beneath the growing media, and that evapotransporation and filtrate factor values from the 4-inch media and the 8-inch media are approximately equal for one year. However, hydrograph results show that the 8-inch media design has a lower peak flow and longer attenuation when compared to the 4-inch media design for a single storm event. Furthermore, the drainage layer material has no significant effect on the water quality or hydrology of the green roof discharge. The data also emphasizes the importance and effectiveness of the incorporation of a cistern into a green roof system.
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Date Issued: 2008
Identifier: CFE0002107, ucf:47552
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002107

Water Quality (8)	+ -
water quality (7)	+ -
distribution system (3)	+ -
Corrosion (2)	+ -
Data Fusion (2)	+ -

Phosphorus (2)	+ -
Remote Sensing (2)	+ -
Stormwater management (2)	+ -
Water quality (2)	+ -
drinking water (2)	+ -
lead and copper rule (2)	+ -
ATP Bioluminescence (1)	+ -
Adsorption (1)	+ -
BAM (1)	+ -
BMP (1)	+ -
Bay/Estuary Model (1)	+ -
CCA (1)	+ -
Carrying Capacity (1)	+ -
Cast Iron (1)	+ -
Central Florida (1)	+ -
Color (1)	+ -
Corrosion Control (1)	+ -
Corrosion Inhibitor (1)	+ -
DFA (1)	+ -
Data Analysis (1)	+ -
Depth of Media (1)	+ -
Dishwashing Water (1)	+ -
Disinfectants (1)	+ -
Disinfection Byproducts Control (1)	+ -
Distribution System Monitoring (1)	+ -

University of Central Florida (22)	+ -
Duranceau, Steven (5)	+ -
Taylor, James (5)	+ -
Wang, Dingbao (4)	+ -
Engineering (3)	+ -

Randall, Andrew (3)	+ -
Wanielista, Martin (3)	+ -
Bohlen, Patrick (2)	+ -
Chang, Ni-bin (2)	+ -
Lee, Woo Hyoung (2)	+ -
Sadmani, A H M Anwar (2)	+ -
Taylor, James S. (2)	+ -
Yeh, Gour-Tsyh (2)	+ -
Alshehri, Abdulrahman (1)	+ -
Andrews, William B. (1)	+ -
Arenas Daza, Maria (1)	+ -
Chancellor, Gerald L. (1)	+ -
Chopra, Manoj (1)	+ -
Church, Jared (1)	+ -
Cooper, C. David (1)	+ -
Cooper, David (1)	+ -
Faraji, Sarah (1)	+ -
Fauth, John (1)	+ -
Glatthorn, Stephen (1)	+ -
Guan, Xiaotao (1)	+ -
Hardin, Mike (1)	+ -
Imen, Sanaz (1)	+ -
Kelly, Matt (1)	+ -
Kibler, Kelly (1)	+ -
MacNevin, David (1)	+ -

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