You are here

UCF Digital Collections ยป ETD Collection

Highly-Sensitive Stoichiometric Analysis of YAG Ceramics Using Laser-Induced Breakdown Spectroscopy (LIBS)

Download pdf | Full Screen View

Date Issued:
2014
Abstract/Description:
Transparent ceramics are an important class of optical materials with applications in high-strength windows, radiation detectors and high-power lasers. Despite the many successful developments of the past decades, their challenging fabrication still needs to be perfected to achieve a better consistency in optical quality. In particular, ternary phase materials such as Yttrium Aluminum Garnet (YAG, Y3Al5O12), a long standing high-power laser host, require a precise control of stoichiometry, often beyond the precision of current analytical techniques, in order to reduce scattering losses and the presence of deleterious point defects. This work explores the potential of Laser-Induced Breakdown Spectroscopy (LIBS) for the quantitative analysis of ceramic compositions near stoichiometry. We have designed a compact and automated LIBS system to determine the plasma composition of sintered mixtures of Y2O3-Al2O3 near the garnet composition. The performance of our setup is evaluated and compared to conventional techniques. Optimized conditions for the acquisition of plasma emission spectra are discussed and the intensity ratios of Y+ and Al in the 300 to 400nm spectral range are analyzed using simple plasma models. The results show that, for the selected parameters of our experiments, the fluctuations in plasma temperature are minimal, and the stability of the plasma is improved. Current results show that ceramic compositions can be resolved within 1 at% in oxide and several suggestions are proposed to further increase the accuracy and precision of the method.
Title: Highly-Sensitive Stoichiometric Analysis of YAG Ceramics Using Laser-Induced Breakdown Spectroscopy (LIBS).
36 views
16 downloads
Name(s): Kazemi Jahromi, Ali, Author
Gaume, Romain, Committee Chair
Richardson, Martin, Committee Member
Seal, Sudipta, Committee Member
, Committee Member
University of Central Florida, Degree Grantor
Type of Resource: text
Date Issued: 2014
Publisher: University of Central Florida
Language(s): English
Abstract/Description: Transparent ceramics are an important class of optical materials with applications in high-strength windows, radiation detectors and high-power lasers. Despite the many successful developments of the past decades, their challenging fabrication still needs to be perfected to achieve a better consistency in optical quality. In particular, ternary phase materials such as Yttrium Aluminum Garnet (YAG, Y3Al5O12), a long standing high-power laser host, require a precise control of stoichiometry, often beyond the precision of current analytical techniques, in order to reduce scattering losses and the presence of deleterious point defects. This work explores the potential of Laser-Induced Breakdown Spectroscopy (LIBS) for the quantitative analysis of ceramic compositions near stoichiometry. We have designed a compact and automated LIBS system to determine the plasma composition of sintered mixtures of Y2O3-Al2O3 near the garnet composition. The performance of our setup is evaluated and compared to conventional techniques. Optimized conditions for the acquisition of plasma emission spectra are discussed and the intensity ratios of Y+ and Al in the 300 to 400nm spectral range are analyzed using simple plasma models. The results show that, for the selected parameters of our experiments, the fluctuations in plasma temperature are minimal, and the stability of the plasma is improved. Current results show that ceramic compositions can be resolved within 1 at% in oxide and several suggestions are proposed to further increase the accuracy and precision of the method.
Identifier: CFE0005191 (IID), ucf:50624 (fedora)
Note(s): 2014-05-01
M.S.
Optics and Photonics, Optics and Photonics
Masters
This record was generated from author submitted information.
Subject(s): 11/26/2013
Persistent Link to This Record: http://purl.flvc.org/ucf/fd/CFE0005191
Restrictions on Access: public 2014-05-15
Host Institution: UCF

In Collections