Current Search: An, Linan (x)
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Title
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Polyelectrolyte and hydrogel stabilized liquid crystal droplets for the detection of bile acids.
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Creator
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Deng, Jinan, Fang, Jiyu, An, Linan, Chen, Quanfang, Cho, Hyoung Jin, Wu, Shintson, University of Central Florida
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Abstract / Description
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Liquid crystal (LC) droplets show great potential as an optical probe for sensor applications due to their large surface areas and stimuli-response director configurations. Bile acids with amphipathic properties, which are formed in liver and secreted into the small intestine, play an important role in the digestion of fats and fat-soluble vitamins. After the digestion process, most of bile acids are recycled back to the liver and ready for the next digestion. Only a few of them are excreted...
Show moreLiquid crystal (LC) droplets show great potential as an optical probe for sensor applications due to their large surface areas and stimuli-response director configurations. Bile acids with amphipathic properties, which are formed in liver and secreted into the small intestine, play an important role in the digestion of fats and fat-soluble vitamins. After the digestion process, most of bile acids are recycled back to the liver and ready for the next digestion. Only a few of them are excreted into body fluids. However, there is significant increases in the concentration level of bile acids in body fluids for patients with liver and intestinal diseases, which makes bile acids a biomarker for the early diagnosis of liver and intestinal diseases. Chromatography-mass spectrometry and electrochemical sensors are common methods for the detection of bile acids. However, these detection methods are time consuming, require relatively large sample volumes, and expensive instruments. To date, there is still a demand in the development of simple, low-cost and user-friendly sensing platforms for the rapid detection of bile acids in clinical settings.In this dissertation, two simple and low-cost LC droplet-based sensing platforms were developed for the rapid and real-time detection of bile acids with a small sample volume. First, a miniaturized LC droplet-based sensor platform was designed and fabricated by the integration of polyelectrolytes/surfactant/sulfate ?-cyclodextrin (?-CD) complex-stabilized LC droplets into a microfluidic channel for the selective detection of bile acids in a small amount of solution, in which the ?-CD immobilized at the surface of the LC droplets acts as a selective barricade and the director configuration of the LC droplets serves as an optical probe. Second, a flexible LC droplet-based sensor platform was formed by the integration of surfactant-stabilized LC droplets in biopolymer hydrogel films. The LC droplet-based hydrogel film was cut into small sheets for the real-time detection of bile acids in a small amount of solution, in which the configuration transition of LC droplets induced by the interaction of bile acids with the surfactants absorbing on the surface of LC droplets serves as an optical probe.Cholic acid (CA) and deoxycholic acid (DCA), which are the most related to the liver and intestinal diseases, were detected in phosphate buffered saline (PBS) solution in the presence of the interference species of uric acid (UA) and ascorbic acid (AA) in this dissertation. These miniaturized LC droplet-based sensor platforms can be used to selectively detect CA and DCA in the presence of UA and AA. The detection limit of these sensor platforms for CA and DCA can be tuned by the number of LC droplets and the nature of surfactants. Furthermore, we find that these sensor platforms are more sensitive for DCA with the shorter response time and lower detection limit over CA due to their difference in hydrophobicity. These miniaturized 5CB droplet-based sensor platforms are easily handled, allowing the rapid and real-time detection of bile acids in a small sample volume in the presence of interference species, which are highly desirable for the "point-of-care" analysis of bile acids.
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Date Issued
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2017
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Identifier
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CFE0006939, ucf:51664
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0006939
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Title
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Electrical properties of polymer-derived silicoaluminum carboxide ceramics and their applications in micro-sensors.
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Creator
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Cao, Yejie, An, Linan, Fang, Jiyu, Zhai, Lei, Chen, Quanfang, Orlovskaya, Nina, University of Central Florida
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Abstract / Description
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Polymer-derived ceramic (PDC) is a new kind of material which is directly synthesized by the thermal decomposition of polymer precursors. Due to their unique structure, which consists of the amorphous matrix phase and free-carbon phase, PDCs exhibit many distinguished properties even at high-temperature environment such as oxidation and creep resistance, amorphous semiconducting behavior as well as piezoresistive behavior. These outstanding properties make PDCs become promising candidates for...
Show morePolymer-derived ceramic (PDC) is a new kind of material which is directly synthesized by the thermal decomposition of polymer precursors. Due to their unique structure, which consists of the amorphous matrix phase and free-carbon phase, PDCs exhibit many distinguished properties even at high-temperature environment such as oxidation and creep resistance, amorphous semiconducting behavior as well as piezoresistive behavior. These outstanding properties make PDCs become promising candidates for various applications especially for high-temperature microsensors. However, most common used PDCs in the market now are SiC, SiCN and Si(M)CN ceramics, the high price and toxicity of their raw materials as well as strict operating requirements limit their applications. SiCO ceramics are appealing increasing attentions because they can cover these shortcomings of non-oxide ceramics, but their oxidation and corrosion resistance is so weak. In this dissertation, SiAlCO ceramics are chosen as main material. The addition of Al can improve the oxidation and corrosion resistance of SiCO ceramics. In this dissertation, the SiAlCO ceramics are synthesized by using silicone resin and aluminum tri-sec-butoxide (ATSB), then ceramic samples are obtained by pyrolyzing disk green bodies at 1000, 1100, 1200, 1300, 1400?C. Firstly, the composition, microstructure and structure evolution of SiAlCO ceramics are characterized via X-Ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and Impedance spectroscopy (IS). The results indicate all ceramic samples pyrolyzed below 1400?C are amorphous and a sudden structure change point around 1100?C is observed due to the increase of degree of ordering. Si-C, Si-O, C-C/H, and C=C bonds are observed within the materials.Secondly, the room-temperature and temperature-dependent conductivity of the SiAlCO ceramics are studied. The optical absorption spectra are also measured. The conductivity increases by ~6 orders of magnitude when pyrolysis temperature increases from 1000 to 1400?C. A very high activation energy of 7.15eV is observed, and the redistribution of oxygen within the material is found to be responsible for it. Amorphous semiconductor behavior which follows the band-tail hopping (BTH) process is observed within this material. And the BTH process is resulted from unique electronic structures of the materials.Thirdly, SiAlCO ceramic exhibits extraordinary piezoresistive behavior with an extremely high gauge factor in range of 7000 ~16000, which is higher than that of any previously reported high-temperature materials. The coupling effect of pressure and temperature on the piezoresistive behavior is also studied. The piezoresistive stress coefficient increases with increasing temperature, which is contradictive to other reported materials. Such change of the piezoresistive stress coefficient is due to the change in the characteristic temperature, which is reversely related to the density of state within the band-tail level.In addition, SiAlCO also shows anomalous piezo-dielectricity with the positive pressure coefficient of the dielectric constant as high as 0.10-0.25 MPa-1, which is much higher than that of other high-temperature materials. The polarizability of the material also increases with increasing pressure. There behaviors are attributed to the unique cell-like structure of the materials.In the end, a pressure sensor is successfully developed. A supportive circuit is designed and the relationships among pressure, resistance and output voltage of the system are tested. The sensitivity of the sensor is calculated to be ?1 V=?15.125 Pa, indicating the SiAlCO ceramics are promising candidates for pressure sensor materials.
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Date Issued
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2016
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Identifier
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CFE0006275, ucf:51052
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0006275
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Title
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Interdiffusion, Crystallography and Mechanical Properties of Nickel Manganese Gallium Alloys.
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Creator
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Zhou, Le, Sohn, Yongho, Heinrich, Helge, Coffey, Kevin, An, Linan, Orlovskaya, Nina, University of Central Florida
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Abstract / Description
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NiMnGa Heusler alloys, functioning as either ferromagnetic shape memory alloys or mangetocaloric materials, have both practical applications and fundamental research value. The functional properties of NiMnGa alloys are closely related to the martensitic transformation from high temperature austenitic phase to low temperature martensitic phase. Alloys can be used for room temperature or high temperature applications, depending on the martensitic transformation temperature, which is...
Show moreNiMnGa Heusler alloys, functioning as either ferromagnetic shape memory alloys or mangetocaloric materials, have both practical applications and fundamental research value. The functional properties of NiMnGa alloys are closely related to the martensitic transformation from high temperature austenitic phase to low temperature martensitic phase. Alloys can be used for room temperature or high temperature applications, depending on the martensitic transformation temperature, which is compositional sensitive. The microstructure and crystallography of the martensites can be very complex but are crucial to the optimization of the material performance. In this study, for the first time, a combinatorial study by combining solid-to-solid diffusion couples and various characterization techniques was carried out to fundamentally investigate the NiMnGa ternary alloys. Phase equilibria, interdiffusion behavior, microstructural and crystallographic development, and mechanical properties in NiMnGa alloys were systematically examined. Selected diffusion couples between pure Ni, Ni25Mn75 and four ternary off-stoichiometric NiMnGa alloys (i.e., Ni52Mn18Ga30, Ni46Mn30Ga24, Ni52Mn30Ga18, Ni58Mn18Ga24 in atomic percent) were assembled and annealed at 800, 850 and 900 (&)deg;C for 480, 240 and 120 hours, respectively. The microstructure and concentration profiles of the interdiffusion zone were examined by scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS). Concentration profiles across the interdiffusion zone were further quantified by electron probe micro analysis (EPMA). Detailed microstructure and crystallography of the austenite and martensite were investigated using transmission electron microscopy (TEM). TEM thin foils were prepared by using focused ion beam (FIB) in situ lift out (INLO) technique, which is able to select desired composition from diffusion couples. The mechanical properties, namely reduced elastic modulus and hardness, as a function of composition were assessed via nanoindentation. Solubility values obtained for various phases were mostly consistent with the existing isothermal phase diagrams, but the phase boundary of the ?(Mn) + ? two-phase region was slightly modified. In addition, equilibrium compositions for the ?(Ni) and ?' phases at 900 (&)deg;C were also determined for the respective two-phase regions. Both austenitic and martensitic phases were found at room temperature in each diffusion couple with a clear interphase boundary. The compositions at the interfaces corresponded close to valence electron concentration (e/a) of 7.6, but decreased to lower values when Mn concentration increased to more than 35 at. %. Average effective interdiffusion coefficients for the ? phase over various compositional ranges were determined and reported in the light of temperature-dependence. Ternary interdiffusion coefficients were also determined and examined to assess the ternary diffusional interactions among Ni, Mn and Ga. Ni was observed to interdiffuse the fastest, followed by Mn then Ga. Interdiffusion flux of Ni also has strong influences on the interdiffusion of Mn and Ga with large and negative cross interdiffusion coefficients. The main ternary interdiffusion coefficients exhibited minimum values near 52 at. % Ni concentration. Extensive TEM analyses have been performed for the study of microstructure and crystallography of austenite and martensite from all diffusion couples. Crystallographic variations in martensitic phase, including non-modulated (NM) martensite, modulated (5M or 7M) martensite, were found in the diffusion couples. The 5M and 7M martensites were only found near the interface between austenite and martensite, corresponding to compositions with lower e/a ratio. The NM martensites were found mostly away from the interface region, with high e/a ratios. The tetragonality ratio (c/a) for NM martensite generally increases with e/a ratio, but also depended on the composition. All martensitic microstructure consists of twinned variants with different orientations that were documented using electron diffraction. The twinning relationship along with the c/a ratio was correlated to martensitic transformation temperature. In addition, pre-martensitic state has been clearly observed in the cubic austenitic phase region, with distinctive tweed microstructure originating from the local lattice distortions. Mechanical properties including reduced elastic modulus (Er) and hardness (H) as a function of composition were measured and analyzed by nanoindentation. A decrease of Er and H was observed with Mn or Ni substituting Ga, and Ni substituting Mn for the austenitic phase. However, an opposite trend was found for the martensitic phase. The softening of the elastic constants near the vicinity of martensitic transformation contributed to the sharp decrease in Er and H near the interface region. The measured Er and H had larger scatter for the martensitic phase than those for the austenitic phase. The scatters observed were attributed to the martensitic variants with different orientations. Contribution from the variation in grain orientation or shape memory effect was determined to be small in this investigation.
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Date Issued
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2016
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Identifier
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CFE0006204, ucf:51108
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0006204
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Title
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Scandia and ceria stabilized zirconia based electrolytes and anodes for intermediate temperature solid oxide fuel cells: Manufacturing and properties.
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Creator
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Chen, Yan, Orlovskaya, Nina, An, Linan, Chen, Quanfang, Sohn, Yongho, Raghavan, Seetha, Huang, Xinyu, University of Central Florida
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Abstract / Description
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Scandia and ceria stabilized zirconia (10 mol% Sc2O3 (-) 1 mol% CeO2 (-) ZrO2, SCSZ) has superior ionic conductivity in the intermediate temperature range for the operation of solid oxide fuel cells, but it does not exhibit good phase stability in comparison with yttria stabilized zirconia (8 mol% Y2O3 (-) ZrO2, YSZ). To maintain high ionic conductivity and improve the stability of the electrolyte, layered structures with YSZ outer layers and SCSZ inner layers were designed, along with the...
Show moreScandia and ceria stabilized zirconia (10 mol% Sc2O3 (-) 1 mol% CeO2 (-) ZrO2, SCSZ) has superior ionic conductivity in the intermediate temperature range for the operation of solid oxide fuel cells, but it does not exhibit good phase stability in comparison with yttria stabilized zirconia (8 mol% Y2O3 (-) ZrO2, YSZ). To maintain high ionic conductivity and improve the stability of the electrolyte, layered structures with YSZ outer layers and SCSZ inner layers were designed, along with the referential electrolytes containing pure SCSZ or YSZ. The electrolytes were manufactured by tape casting, laminating, and pressureless sintering techniques. After sintering, while the thickness of YSZ outer layers remained constant at ~30 ?m, the thickness of inner layers of SCSZ for the 3-, 4- and 6-layer designs varied at ~30, ~60 and ~120 ?m, respectively. Selected characterizations were employed to study the structure, morphology, impurity content and the density of the electrolytes. Furthermore, in situ X-ray diffraction, neutron diffraction and Raman scattering were carried out to study the phase transition and lattice distortion during long-term annealing at 350 (&)deg;C and 275 (&)deg;C for SCSZ and YSZ, respectively, where the dynamic damping occurred when Young's modulus was measured.In YSZ/SCSZ electrolytes, thermal residual stresses and strains were generated due to the mismatch of coefficients of thermal expansion from each layer of different compositions. They could be adjusted by varying the thickness ratios of each layer in different designs of laminates. The theoretical residual stresses have been calculated for different thickness ratios. The effect of thermal residual stress on the biaxial flexural strength was studied in layered electrolytes. The biaxial flexure tests of electrolytes with various layered designs were performed using a ring-on-ring method at both room temperature and 800 (&)deg;C. The maximum principal stress during fracture indicated an increase of flexural strength in the electrolytes with layered structure at both temperatures in comparison with the electrolytes without compositional gradient. Such an increase of strength is the result of the existence of residual compressive stresses in the outer YSZ layer. In addition, Weibull statistics of the strength values were built for the layered electrolytes tested at room temperature, and the effect of thermal residual stresses on Weibull distribution was established. The calculation of residual stress present at the outer layers was verified. The high ionic conductivity was maintained with layered electrolyte designs in the intermediate temperature range. It was also established that the ionic conductivity of layered electrolytes exhibited 7% (-) 11% improvement at 800 (&)deg;C due to the stress/strain effects, and the largest improvements in a certain electrolyte was found to nearly coincide with the largest residual compressive strain in the outer YSZ layer.In addition to the study of layered electrolytes, mechanical properties of porous Ni/SCSZ cermet were studied. The anode materials were reduced by 65 wt% NiO (-) 35 wt% SCSZ (N65) and 50 wt% NiO (-) 50 wt% SCSZ (N50) porous ceramics in the forming gas. Young's modulus as well as strength and fracture toughness of non-reduced and reduced anodes has been measured, both at room and high temperatures. High temperature experiments were performed in the reducing environment of forming gas. It was shown that while at 700 (&)deg;C and 800 (&)deg;C the anode specimens exhibited purely brittle deformation, a brittle-to-ductile transition occurred at 800 (-) 900 (&)deg;C, and the anode deformed plastically at 900 (&)deg;C. Fractography of the anode specimens were studied to identify the fracture modes of the anodes tested at different temperatures.
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Date Issued
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2013
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Identifier
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CFE0005090, ucf:50750
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005090
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Title
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Non-Oxide Porous Ceramics from Polymer Precursor.
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Creator
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Yang, Xueping, An, Linan, Fang, Jiyu, Zhai, Lei, Huo, Qun, Wu, Shintson, University of Central Florida
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Abstract / Description
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Non-oxide porous ceramics exhibit many unique and superior properties, such as better high-temperature stability, improved chemical inertness/corrosive resistance, as well as wide band-gap semiconducting behavior, which lead to numerous potential applications in catalysis, high temperature electronic and photonic devices, and micro-electromechanical systems. Currently, most mesoporous non-oxide ceramics (e.g. SiC) are formed by two-step templating methods, which are hard to adjust the pore...
Show moreNon-oxide porous ceramics exhibit many unique and superior properties, such as better high-temperature stability, improved chemical inertness/corrosive resistance, as well as wide band-gap semiconducting behavior, which lead to numerous potential applications in catalysis, high temperature electronic and photonic devices, and micro-electromechanical systems. Currently, most mesoporous non-oxide ceramics (e.g. SiC) are formed by two-step templating methods, which are hard to adjust the pore sizes, and require a harmful etching step or a high temperature treatment to remove the templates.In this dissertation, we report a novel technique for synthesizing hierarchically mesoporous non-oxide SiC ceramic from a block copolymer precursor. The copolymer precursors with vairing block length were synthesized by reversible addition fragmentation chain transfer polymerization. The block copolymers self-assemble into nano-scaled micelles with a core-shell structure in toluene. With different operation processes, hollow SiC nanospheres and bulk mesoporous SiC ceramics were synthesized after the subsequent pyrolysis of precorsur micelles. The resultant SiC ceramics have potential applications in catalysis, solar cells, separation, and puri?cation processes.The polymer synthesis and pyrolysis process will investigated by NMR, FTIR, GPC, TEM, and TGA/DSC. The morphology and structure of synthesised SiC hollow spheres and mesoporous ceramics were analyzed by SEM, TGA/DSC and BET/BJH analysis.Besides forming core shell micelles in selective solvent Toluene, we found that PVSZ-b-PS could also exhibit this property in the air water interface. By inducing the Langmuir-Blodgett deposition, a precursor monolayer with homogeously distributed povinylsilazane particles deposited on silicon wafer synthesized by spreading the diblock copolymer PVSZ-b-PS in the air water interface. After the pyrolysis process, orderly arranging SiC nano particles formed from the polymer precursor monolayer doped on the surface of silicon wafer, which shows great potential as an optoelectronic material. The deposition process and the relationship between compress pressure and monolayer morphology were studies, and the structure of monolayer and SiC dots were investigated by AFM, SEM.
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Date Issued
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2014
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Identifier
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CFE0005564, ucf:50274
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005564
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Title
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Integrated Microwave Resonator/Antenna Structures for Sensor and Filter Applications.
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Creator
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Cheng, Haitao, Gong, Xun, Wahid, Parveen, Wu, Thomas, Kapoor, Vikram, An, Linan, University of Central Florida
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Abstract / Description
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This dissertation presents design challenges and promising solutions for temperature and pressure sensors which are highly desirable for harsh-environment applications, such as turbine engines. To survive the harsh environment consisting of high temperatures above 1000oC, high pressures around 300 psi, and corrosive gases, the sensors are required to be robust both electrically and mechanically. In addition, wire connection of the sensors is a challenging packaging problem, which remains...
Show moreThis dissertation presents design challenges and promising solutions for temperature and pressure sensors which are highly desirable for harsh-environment applications, such as turbine engines. To survive the harsh environment consisting of high temperatures above 1000oC, high pressures around 300 psi, and corrosive gases, the sensors are required to be robust both electrically and mechanically. In addition, wire connection of the sensors is a challenging packaging problem, which remains unresolved as of today. In this dissertation, robust ceramic sensors are demonstrated for both high temperature and pressure measurements. Also, the wireless sensors are achieved based on microwave resonators.Two types of temperature sensors are realized using integrated resonator/antennas and reflective patches, respectively. Both types of the sensors utilize alumina substrate which has a temperature-dependent dielectric constant. The temperature in the harsh environment is wirelessly detected by measuring the resonant frequency of the microwave resonator, which is dependent on the substrate permittivity. The integrated resonator/antenna structure minimizes the sensor dimension by adopting a seamless design between the resonator sensor and antenna. This integration technique can be also used to achieve an antenna array integrated with cavity filters. Alternatively, the aforementioned reflective patch sensor works simultaneously as a resonator sensor and a radiation element. Due to its planar structure, the reflective patch sensor is easy for design and fabrication. Both temperature sensors are measured above 1000oC.A pressure sensor is also demonstrated for high-temperature applications. Pressure is detected via the change in resonant frequency of an evanescent-mode resonator which corresponds to cavity deformation under gas pressure. A compact sensor size is achieved with a post loading the cavity resonator and a low-profile antenna connecting to the sensor. Polymer-Derived-Ceramic (PDC) is developed and used for the sensor fabrication. The pressure sensor is characterized under various pressures at high temperatures up to 800oC. In addition, to facilitate sensor characterizations, a robust antenna is developed in order to wirelessly interrogate the sensors. This specially-developed antenna is able to survive a record-setting temperature of 1300oC.
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Date Issued
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2014
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Identifier
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CFE0005473, ucf:50335
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005473
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Title
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Modeling and Contour Control of Multi-Axis Linear Driven Machine Tools.
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Creator
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Zhao, Ran, Lin, Kuo-Chi, Xu, Chengying, Bai, Yuanli, Das, Tuhin, An, Linan, University of Central Florida
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Abstract / Description
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In modern manufacturing industries, many applications require precision motion control of multi-agent systems, like multi-joint robot arms and multi-axis machine tools. Cutter (end effector) should stay as close as possible to the reference trajectory to ensure the quality of the final products. In conventional computer numerical control (CNC), the control unit of each axis is independently designed to achieve the best individual tracking performance. However, this becomes less effective when...
Show moreIn modern manufacturing industries, many applications require precision motion control of multi-agent systems, like multi-joint robot arms and multi-axis machine tools. Cutter (end effector) should stay as close as possible to the reference trajectory to ensure the quality of the final products. In conventional computer numerical control (CNC), the control unit of each axis is independently designed to achieve the best individual tracking performance. However, this becomes less effective when dealing with multi-axis contour following tasks because of the lack of coordination among axes. This dissertation studies the control of multi-axis machine tools with focus on reducing the contour error. The proposed research explicitly addresses the minimization of contour error and treats the multi-axis machine tool as a multi-input-multi-output (MIMO) system instead of several decoupled single-input-single-output (SISO) systems. New control schemes are developed to achieve superior contour following performance even in the presence of disturbances. This study also extends the applications of the proposed control system from plane contours to regular contours in R3. The effectiveness of the developed control systems is experimentally verified on a micro milling machine.
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Date Issued
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2014
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Identifier
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CFE0005287, ucf:50552
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005287
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Title
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bio-inspired attitude control of micro air vehicles using rich information from airflow sensors.
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Creator
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Shen, He, Xu, Yunjun, Lin, Kuo-Chi, Kauffman, Jeffrey, An, Linan, University of Central Florida
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Abstract / Description
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Biological phenomena found in nature can be learned and customized to obtain innovative engineering solutions. In recent years, biologists found that birds and bats use their mechanoreceptors to sense the airflow information and use this information directly to achieve their agile flight performance. Inspired by this phenomenon, an attitude control system for micro air vehicles using rich amount of airflow sensor information is proposed, designed and tested. The dissertation discusses our...
Show moreBiological phenomena found in nature can be learned and customized to obtain innovative engineering solutions. In recent years, biologists found that birds and bats use their mechanoreceptors to sense the airflow information and use this information directly to achieve their agile flight performance. Inspired by this phenomenon, an attitude control system for micro air vehicles using rich amount of airflow sensor information is proposed, designed and tested. The dissertation discusses our research findings on this topic. First, we quantified the errors between the calculated and measured lift and moment profiles using a limited number of micro pressure sensors over a straight wing. Then, we designed a robust pitching controller using 20 micro pressure sensors and tested the closed-loop performance in a simulated environment. Additionally, a straight wing was designed for the pressure sensor based pitching control with twelve pressure sensors, which was then tested in our low-speed wind tunnel. The closed-loop pitching control system can track the commanded angle of attack with a rising time around two seconds and an overshoot around 10%. Third, we extended the idea to the three-axis attitude control scenarios, where both of the pressure and shear stress information are considered in the simulation. Finally, a fault tolerant controller with a guaranteed asymptotically stability is proposed to deal with sensor failures and calculation errors. The results show that the proposed fault tolerant controller is robust, adaptive, and can guarantee an asymptotically stable performance even in case that 50% of the airflow sensors fail in flight.
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Date Issued
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2014
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Identifier
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CFE0005711, ucf:50150
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005711
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Title
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Synthesis and Properties of Self-Assembled C/SiCN Nanocomposite Derived from Polymer Precursors.
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Creator
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Li, Cheng, An, Linan, Fang, Jiyu, Coffey, Kevin, Liao, Yi, Xu, Chengying, Zhai, Lei, University of Central Florida
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Abstract / Description
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The properties of C/SiCN nanocomposites synthesized by thermal decomposition of polymer precursors were studied in this work. The novel polymer-to-ceramic process enables us to tailor the ceramic structure in atomic level by designing the starting chemicals and pyrolysis procedures. It is of both fundamental and practical significance to investigate the properties and structures relationship of the nanocomposites. In this work, we explored their application potential in using as anode of...
Show moreThe properties of C/SiCN nanocomposites synthesized by thermal decomposition of polymer precursors were studied in this work. The novel polymer-to-ceramic process enables us to tailor the ceramic structure in atomic level by designing the starting chemicals and pyrolysis procedures. It is of both fundamental and practical significance to investigate the properties and structures relationship of the nanocomposites. In this work, we explored their application potential in using as anode of lithium-ion secondary batteries. The structure and structural evolution of C/SiCN nanocomposite were investigated by using XRD, FTIR, SEM, TEM, Solid state NMR and Raman spectroscopy. The results revealed the nanocomposites consisted of amorphous SiCxNx-4 matrix and carbon nanoclusters distributed within it. The size of the carbon was measured by Raman spectroscopy, varied with starting chemicals and pyrolysis temperature. The electronic properties of the C/SiCN nanocomposite were studied by measuring the I-V curves and a.c. impedance. The d.c. conductivity increased with carbon content and pyrolysis temperatures. The impedance spectra and fitted equivalent circuit results confirmed the existence of two phases in the nanocomposite. The possibility of using C/SiCN as anode in lithium-ion secondary batteries was investigated by electrochemical measurements, namely cyclic voltammetry, galvanostatic cyclic test and electrochemical impedance spectroscopy. The galvanostatic measurements showed that the nanocomposite with 26% of carbon nanoclusters exhibited a specific capacity of 480 mAh/g, which is 30% higher than that of commercial graphite anode. The high capacity of the nanocomposites is attributed to the formation of a novel structure around C/SiCN interface. The excellent electrochemical properties, together with the simple, low-cost processing, make the nanocomposites very promising for Li-ion battery applications.
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Date Issued
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2012
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Identifier
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CFE0004194, ucf:49028
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004194
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Title
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Structure and Properties of Polymer-Derived SiBCN Ceramics.
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Creator
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Chen, Yaohan, An, Linan, Fang, Jiyu, Xu, Chengying, Zhai, Lei, Huo, Qun, Gong, Xun, University of Central Florida
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Abstract / Description
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Polymer-derived ceramics (PDCs) are a unique class of multifunctional materials synthesized by thermal decomposition of polymeric precursors. Due to their unique and excellent properties and flexible manufacturing capability, PDC is a promising technology to prepare ceramic fibers, coatings, composites and micro-sensors for high-temperature applications. However, the structure-property relationships of PDCs have not been well understood. The lack of such understandings drastically limited the...
Show morePolymer-derived ceramics (PDCs) are a unique class of multifunctional materials synthesized by thermal decomposition of polymeric precursors. Due to their unique and excellent properties and flexible manufacturing capability, PDC is a promising technology to prepare ceramic fibers, coatings, composites and micro-sensors for high-temperature applications. However, the structure-property relationships of PDCs have not been well understood. The lack of such understandings drastically limited the further developments and applications of the materials.In this dissertation, the structure and properties of amorphous polymer-derived silicon carbonitride (SiCN) and silicoboron carbonitride (SiBCN) have been studied. The SiCN was obtained using commercially available polysilazane as pre-ceramic precursor, and the SiBCN ceramics with varied Si-to-B ratio were obtained from polyborosilazanes, which were synthesized by the hydroboration and dehydrocoupling reaction of borane and polysilazane. The structural evolution of polymer-derived SiCN and SiBCN ceramics from polymer to ceramics was investigated by NMR, FTIR, Raman, EPR, TG/DTA, and XRD. The results show a phase-separation of amorphous matrix and a graphitization of (")free(") carbon phase, and suggest that the boron doping has a great influence on the structural evolution. The electric and dielectric properties of the SiCN and SiBCNs were studied by I-V curves, LCR Meter, and network analyzer. A new electronic conduction mechanism and structure model has been proposed to account for the relationships between the observed properties and microstructure of the materials. Furthermore, the SiBCN ceramics showed the improved dielectric properties at characterization temperature up to 1300 (&)#186;C, which allows the fabrication of ultrahigh-temperature wireless microsensors for extreme environments.
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Date Issued
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2012
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Identifier
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CFE0004195, ucf:49014
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004195
Pages