View All Items

Title: THREE-DIMENSIONAL MICRON-SCALE METAL PHOTONIC CRYSTALS VIA MULTI-PHOTON DIRECT LASER WRITING AND ELECTROLESS METAL DEPOSITION.
Creator: Tal, Amir, Kuebler, Stephen, University of Central Florida
Abstract / Description: Three-dimensional (3D) metal photonic crystals (MPCs) can exhibit interesting electromagnetic properties such as ultra-wide photonic or "plasmonic" band gaps, selectively tailored thermal emission, extrinsically modified absorption, and negative refractive index. Yet, optical-wavelength 3D MPCs remain relatively unexplored due to the challenges posed by their fabrication. This work explores the use of multi-photon direct laser writing (DLW) coupled with electroless metallization as a means...
Show moreThree-dimensional (3D) metal photonic crystals (MPCs) can exhibit interesting electromagnetic properties such as ultra-wide photonic or "plasmonic" band gaps, selectively tailored thermal emission, extrinsically modified absorption, and negative refractive index. Yet, optical-wavelength 3D MPCs remain relatively unexplored due to the challenges posed by their fabrication. This work explores the use of multi-photon direct laser writing (DLW) coupled with electroless metallization as a means for preparing MPCs. Multi-photon DLW was used to prepare polymeric photonic crystal (PC) templates having a targeted micron-scale structure and form. MPCs were then created by metallizing the polymeric PCs via wet-chemical electroless deposition. The electromagnetic properties of the polymeric PCs and the metallized structures were characterized using Fourier transform infrared spectroscopy. It is shown that metallization transforms the optical properties of the structures from those of conventional 3D dielectric PCs to those consistent with 3D MPCs that exhibit ultra-wide photonic band gaps. These data demonstrate that multi-photon DLW followed by electroless deposition provides a viable and highly flexible route to MPCs, opening a new path to metal photonic materials and devices.
Show less
Date Issued: 2007
Identifier: CFE0001787, ucf:47261
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001787

Title: GOLD NANOPARTICLE GENERATION USING IN SITU REDUCTION ON A PHOTORESIST POLYMER SUBSTRATE.
Creator: Clukay, Christopher, Kuebler, Stephen, University of Central Florida
Abstract / Description: This report presents evidence that in-situ reduction of metal ions bound to a cross-linked polymer surface does not always result in nanoparticle formation solely at the interface, as is commonly assumed, but also as much as 40 nm deep within the polymer matrix. Tetrachloroaurate ions were bound using a variety of multi-functional amines to cured films of SU-8 -- a cross-linkable epoxide frequently used for micro- and nanofabrication -- and then treated using one of several reducing agents....
Show moreThis report presents evidence that in-situ reduction of metal ions bound to a cross-linked polymer surface does not always result in nanoparticle formation solely at the interface, as is commonly assumed, but also as much as 40 nm deep within the polymer matrix. Tetrachloroaurate ions were bound using a variety of multi-functional amines to cured films of SU-8 -- a cross-linkable epoxide frequently used for micro- and nanofabrication -- and then treated using one of several reducing agents. The resulting gold-nanoparticle decorated films were examined by X-ray photoelectron spectroscopy and by plan-view and cross-sectional transmission electron microscopy. Reduction using sodium borohydride or sodium citrate generates bands of interspersed particles as much as 40 nm deep within the polymer, suggesting both the Au(III) complex and the reducing agent are capable of penetrating the surface and affecting reduction and formation of nanoparticles within the polymer matrix. It is shown that nanoparticle formation can be confined nearer to the polymer interface by using hydroquinone, a sterically bulkier and less flexible reducing agent, or by reacting the surface in aqueous media with high molecular-weight multifunctional amines, that presumably confine Au(III) nearer to the true interface. These finding have important implications for technologies that apply surface bound nanoparticles, including electroless metallization, catalysis, nano-structure synthesis, and surface enhanced spectroscopy.
Show less
Date Issued: 2011
Identifier: CFH0004091, ucf:44794
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH0004091

Title: DESIGN, ANALYSIS, AND OPTIMIZATION OF DIFFRACTIVE OPTICAL ELEMENTS UNDER HIGH NUMERICAL APERTURE FOCUSING.
Creator: Jabbour, Toufic, Kuebler, Stephen, University of Central Florida
Abstract / Description: The demand for high optical resolution has brought researchers to explore the use of beam shaping diffractive optical elements (DOEs) for improving performance of high numerical aperture (NA) optical systems. DOEs can be designed to modulate the amplitude, phase and/or polarization of a laser beam such that it focuses into a targeted irradiance distribution, or point spread function (PSF). The focused PSF can be reshaped in both the transverse focal plane and along the optical axis. Optical...
Show moreThe demand for high optical resolution has brought researchers to explore the use of beam shaping diffractive optical elements (DOEs) for improving performance of high numerical aperture (NA) optical systems. DOEs can be designed to modulate the amplitude, phase and/or polarization of a laser beam such that it focuses into a targeted irradiance distribution, or point spread function (PSF). The focused PSF can be reshaped in both the transverse focal plane and along the optical axis. Optical lithography, microscopy and direct laser writing are but a few of the many applications in which a properly designed DOE can significantly improve optical performance of the system. Designing DOEs for use in high-NA applications is complicated by electric field depolarization that occurs with tight focusing. The linear polarization of off-axis rays is tilted upon refraction towards the focal point, generating additional transverse and longitudinal polarization components. These additional field components contribute significantly to the shape of the PSF under tight focusing and cannot be neglected as in scalar diffraction theory. The PSF can be modeled more rigorously using the electromagnetic diffraction integrals derived by Wolf, which account for the full vector character of the field. In this work, optimization algorithms based on vector diffraction theory were developed for designing DOEs that reshape the PSF of a 1.4-NA objective lens. The optimization techniques include simple exhaustive search, iterative optimization (Method of Generalized Projections), and evolutionary computation (Particle Swarm Optimization). DOE designs were obtained that can reshape either the transverse PSF or the irradiance distribution along the optical axis. In one example of transverse beam shaping, all polarization components were simultaneously reshaped so their vector addition generates a focused flat-top square irradiance pattern. Other designs were obtained that can be used to narrow the axial irradiance distribution, giving a focused beam that is superresolved relative to the diffraction limit. In addition to theory, experimental studies were undertaken that include (1) fabricating an axially superresolving DOE, (2) incorporating the DOE into the optical setup, (3) imaging the focused PSF, and (4) measuring aberrations in the objective lens to study how these affect performance of the DOE.
Show less
Date Issued: 2009
Identifier: CFE0002844, ucf:48063
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002844

Title: Quasi-Gorenstein Modules.
Creator: York, Alexander, Brennan, Joseph, Martin, Heath, Ismail, Mourad, Kuebler, Stephen, University of Central Florida
Abstract / Description: This thesis will study the various roles that quasi-Gorenstein modules and their properties play in the study of homological dimensions and linkage of modules. To that effect we begin by studying these modules in their own right. An $R$-module $M$ of grade $g$ will be quasi-Gorenstein if $\Ext_R^i(M,R)=0$ for $i\neq g$ and there is an isomorphism $M\cong\Ext_R^g(M,R)$. Such modules have many nice properties which we will explore throughout this thesis. We will show they help extend a...
Show moreThis thesis will study the various roles that quasi-Gorenstein modules and their properties play in the study of homological dimensions and linkage of modules. To that effect we begin by studying these modules in their own right. An $R$-module $M$ of grade $g$ will be quasi-Gorenstein if $\Ext_R^i(M,R)=0$ for $i\neq g$ and there is an isomorphism $M\cong\Ext_R^g(M,R)$. Such modules have many nice properties which we will explore throughout this thesis. We will show they help extend a characterization of diagonalizable matrices over principal ideal domains to more general rings. We will use their properties to help lay a foundation for a study of homological dimensions, helping to generalize the concept of Gorenstein dimension to modules of larger grade and present a connection to these new dimensions with certain generalized Serre conditions.We then give a categorical construction to the concept of linkage. The main motivation of such a construction is to generalize ideal and module linkage into one unified theory. By using the defintion of linkage presented by Nagel \cite{NagelLiaison}, we can use categorical language to define linkage between categories. One of the focuses of this thesis is to show that the history of linkage has been wrought with a misunderstanding of which classes of objects to study. We give very compelling evidence to suggest that linkage is a tool to gain information about the even linkage classes of objects. Further, scattered among the literature is a wide array of results pertaining to module linkage, homological dimensions, duality, and adjoint functor pairs and for which we show that these fall under the umbrella of this unified theory. This leads to an intimate relationship between associated homological dimensions and the linkage of objects in a category. We will give many applications of the theory to modules allowing one to cover vast grounds from Gorenstein dimensions to Auslander and Bass classes to local cohomology and local homology. Each of these gives useful insight into certain classes of modules by applying this categorical approach to linkage.
Show less
Date Issued: 2018
Identifier: CFE0007268, ucf:52202
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007268

Title: Development of S-nitroso-N-acetylpenicillamine (SNAP) Impregnated Medical Grade Polyvinyl Chloride for Antimicrobial Medical Device Interfaces.
Creator: Feit, Corbin, Brisbois, Elizabeth, Vaidyanathan, Raj, Kuebler, Stephen, University of Central Florida
Abstract / Description: In the clinical setting, polyvinyl chloride (PVC) accounts for 25% of all polymers used in medical device applications. However, medical devices fabricated with PVC, such as endotracheal tubes, extracorporeal circuits (ECCs), or intravenous catheters suffer from thrombosis and infection. Mortality associated with hospital associated infections (HAIs) exceed 100,000 deaths each year. One method to overcome these challenges is to develop bioactive polymers with nitric oxide (NO) release. Nitric...
Show moreIn the clinical setting, polyvinyl chloride (PVC) accounts for 25% of all polymers used in medical device applications. However, medical devices fabricated with PVC, such as endotracheal tubes, extracorporeal circuits (ECCs), or intravenous catheters suffer from thrombosis and infection. Mortality associated with hospital associated infections (HAIs) exceed 100,000 deaths each year. One method to overcome these challenges is to develop bioactive polymers with nitric oxide (NO) release. Nitric oxide exhibits many physiological roles including, antibacterial, antithrombic, anti-inflammatory activity. In this study, Tygon(&)#174; PVC tubing was impregnated with a NO donor molecule, S-nitroso-N-acetylpenicillamine (SNAP), via a simple solvent-swelling-impregnation method, where polymer samples were submerged in a SNAP impregnation-solvent (methanol, acetone, plasticizer). An additional topcoat of a biocompatible CarboSil 2080A (CB) was applied to reduce SNAP leaching. The SNAP-PVC-CB were characterized for NO release using chemiluminescence, leaching with UV-Vis spectroscopy, surface characterization with scanning electron microscopy, tensile strength analysis, stability during storage and sterilization, and antimicrobial properties in vitro. The SNAP-PVC-CB exhibited NO flux of 4.29 (&)#177; 0.80 x 10-10 mol cm-2 min-1 over the initial 24 h under physiological conditions and continued to release physiological levels of NO for up 14 d (incubated in PBS at 37 (&)deg;C). The addition of CB-topcoat reduced the total SNAP leaching by 86% during incubation. Mechanical properties and surface topography remained similar to original PVC after SNAP-impregnation and application of CB-topcoat. After ethylene oxide sterilization and 1-month storage, SNAP-PVC-CB demonstrated excellent SNAP stability (ca. 90% SNAP remaining). In a 24 h antibacterial assay, SNAP-PVC reduce viable bacteria colonization (ca. 1 log reduction) of S. aureus and E. coli compared to PVC controls. This novel method for SNAP-impregnation of medical grade plasticized PVC holds great potential for improving the biocompatibility of post-fabricated PVC medical devices.
Show less
Date Issued: 2019
Identifier: CFE0007887, ucf:52782
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007887

Title: Nanoscale Control of Gap-plasmon Enhanced Optical Processes.
Creator: Lumdee, Chatdanai, Kik, Pieter, Dogariu, Aristide, Kuebler, Stephen, Huo, Qun, University of Central Florida
Abstract / Description: Surface plasmon resonances of metal nanostructures have been studied intensely in recent years. The strong plasmon-mediated electric field enhancement and field confinement well beyond the diffraction limit has been demonstrated to improve the performance of optical devices including ultrasensitive sensors, light emitters, and optical absorbers. A plasmon resonance mode of particular recent interest is the gap plasmon resonance that occurs on closely spaced metallic structures. In contrast to...
Show moreSurface plasmon resonances of metal nanostructures have been studied intensely in recent years. The strong plasmon-mediated electric field enhancement and field confinement well beyond the diffraction limit has been demonstrated to improve the performance of optical devices including ultrasensitive sensors, light emitters, and optical absorbers. A plasmon resonance mode of particular recent interest is the gap plasmon resonance that occurs on closely spaced metallic structures. In contrast to plasmon resonances supported by isolated metal nanostructures, coupled nanostructures provide additional spectral and spatial control over the plasmon resonance response. For example, the resonance frequencies of metal nanoparticle dimers depend strongly on the gap size between the nanoparticles. Gap plasmons can produce local electric field enhancement factors that are several orders of magnitude stronger and more confined than surface plasmon resonances of isolated plasmonic nanospheres. The reliance of gap plasmons on few-nanometer separation between nanostructures makes it difficult to prepare gap-plasmon supporting structures with predictable resonance frequency and field enhancement. A structure that avoids this challenge is the film-coupled nanoparticle (NP). Similar to nanoparticle dimers, a nanoparticle on a supporting metallic film (or NP-on-a-mirror) can offer a strong coupling between the particle and its local environment, in this case the supporting film instead of adjacent nanoparticles, enabling strongly confined gap-plasmon modes. The NP-on-a-mirror geometry has been shown to produce reproducible gap plasmon resonances in a chemically and thermally robust, easy to fabricate structure. In this Thesis, we first present a scheme for controlling the gap plasmon resonance frequency of single gold nanoparticles using aluminum oxide coated metal films. We demonstrate experimentally and numerically that the gap-plasmon resonance of single gold nanoparticles can be tuned throughout the visible range by controlling the aluminum oxide thickness via anodization. In a separate study of Au NP on Al2O3 coated gold films it is shown that the oxide coating improves the stability of the structure under intense laser irradiation. An combined experimental and numerical analysis of the spectral response of Au NP on rough Au films shows that a film roughness of a few nanometer can affect the gap plasmon resonance in the absence of an oxide spacer layer. A photoluminescence study of single gold nanoparticles on an Al2O3 coated gold film shows that the gap-plasmon resonance of this type of plasmonic structure can increase gold photoluminescence by more than four orders of magnitude. Related numerical simulations reveal that the local photoluminescence enhancement of a gold nanoparticle on an Al2O3 coated gold film can be as high as one million near the particle-film junction. Finally, a new plasmonic sensing element was proposed based on our findings in the previous chapters. This proposed hole-in-one structure offers several attractive features including an easily optically accessible gap plasmon mode, while maintaining a relatively simple fabrication method. Taken together, the research presented in this Thesis demonstrates how the resonance frequency, field enhancement, mode polarization, structural stability, and structure reliability can be controlled at the nanoscale. The knowledge gained in the course of this work could lead to further development of nanophotonic devices that utilize extremely confined optical fields and precisely controlled resonance frequencies.
Show less
Date Issued: 2015
Identifier: CFE0005972, ucf:50772
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005972

Title: Liquid Crystal-Based Biosensors for the Detection of Bile Acids.
Creator: He, Sihui, Wu, Shintson, Kuebler, Stephen, Kik, Pieter, Fang, Jiyu, University of Central Florida
Abstract / Description: Bile acids are physiologically important metabolites, which are synthesized in liver as the end products of cholesterol metabolism and then secreted into intestine. They are amphiphilic molecules which play a critical role in the digestion and absorption of fats and fat-soluble vitamins through emulsification. The concentration of bile acids is an indicator for liver function. Individual suffering from liver diseases has a sharp increase in bile acid concentrations. Hence, the concentration...
Show moreBile acids are physiologically important metabolites, which are synthesized in liver as the end products of cholesterol metabolism and then secreted into intestine. They are amphiphilic molecules which play a critical role in the digestion and absorption of fats and fat-soluble vitamins through emulsification. The concentration of bile acids is an indicator for liver function. Individual suffering from liver diseases has a sharp increase in bile acid concentrations. Hence, the concentration level of bile acids has long been used as a biomarker for the early diagnosis of intestinal and liver diseases.Conventional methods of bile acid detection such as chromatography-mass spectrometry and enzymatic reactions are complex and expensive. It is highly desired to have a simple, fast, and low-cost detection of bile acids that is available for self-testing or point-of-care testing. To achieve this goal, we develop a liquid crystal-based biosensor for the detection of bile acids. The sensor platform is based on the anchoring transition of liquid crystals (LCs) at the sodium dodecyl sulfate (SDS)-laden LC/aqueous interface for the detection of bile acids in aqueous solution. The first part of this dissertation focuses on the detection mechanism of bile acids. Our studies show that the displacement of SDS from the LC/aqueous interface by the competitive adsorption of bile acids induces a homeotropic-to-planar anchoring transition of the LC at the interface, providing an optical signature for the simple and rapid detection of bile acids. The adsorption of bile acids on the interface was found to follow Langmuir-Freundlich isotherm. The adsorption kinetics of different bile acids is compared. We find that both the number and position of hydroxyl groups of bile acids affect their adsorption kinetics. The different optical patterns of LC films formed by the adsorption of bile acids are also discussed. The second part of this dissertation studies the effect of solution conditions, surfactants, and liquid crystals on the detection limit of the LC-based biosensor for bile acids. Low pH and high ionic strength in the aqueous solution can reduce the electrostatic interaction between SDS and bile acids, which leads to a decreased detection limit. Surfactants with smaller headgroup and lower packing density also help to reduce the detection limit. To further reduce the detection limit, we investigate the effect of LC structures and find that LCs with a shorter chain length give lower detection limits. Also, by substituting a phenyl ring with a cyclohexane ring, we find that the detection limit is further reduced due to the decrease of the interaction between the phenyl rings of LCs. By mixing different LCs together, the detection limit can be linearly tuned from 160 (&)#181;M to 1.5 (&)#181;M, which is comparable to the traditional methods. But the LC-based biosensors have much simpler design and manufacture process.The third part of this dissertation is to apply this LC-based biosensor to the detection of urinary bile acids. We test the influence of several potential interfering species such as urea, creatinine, uric acid and ascorbic acid by conducting experiments in synthetic urine. By adjusting the concentration of SDS, we are able to eliminate the impact of those interfering species, and demonstrate that the LC-based biosensors can selectively detect urinary bile acids in human urine, suggesting its potential for screening liver dysfunctions. The final part of this dissertation is to investigate the application of LC-based biosensors in detecting the lipolysis process by porcine pancreatic lipase (PPL). It has been a long-standing argument over the role of bile salts on the activity of PPL. Thus, we study the time course of the hydrolysis of phospholipid L-dipalmitoylphosphatidylcholine (L-DPPC) by PPL at LC/aqueous interface. The hydrolysis of L-DPPC leads to a homeotropic-to-tilted anchoring transition of the LC at the interface, which allows the hydrolysis process to be monitored by a polarizing optical microscope. The microscopy image analysis reveals a lag-burst kinetics where a lag phase is followed by a burst phase. The effect of bile acids on these two phases is studied. We find that the activity of PPL both in the presence and absence of colipase can be improved by increasing the concentration of bile acids. The improvement becomes more distinct in the presence of colipase.
Show less
Date Issued: 2015
Identifier: CFE0005804, ucf:50028
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005804

Title: Customizable Antenna Array Using Reconfigurable Antenna Elements.
Creator: Shirazi, Mahmoud, Gong, Xun, Wahid, Parveen, Jones, W Linwood, Abdolvand, Reza, Kuebler, Stephen, University of Central Florida
Abstract / Description: A shared-aperture reconfigurable slot-ring antenna array switching between different frequency bands and polarizations is presented for phased array applications. PIN diode switches are incorporated into the slots of the antenna to change the state of the reconfigurable slot-ring antenna array. Each frequency band has its own feeding lines which allows for the use of high-performance narrow-band transmit/receive (T/R) modules instead of ultra wideband (UWB) T/R modules. Furthermore, the...
Show moreA shared-aperture reconfigurable slot-ring antenna array switching between different frequency bands and polarizations is presented for phased array applications. PIN diode switches are incorporated into the slots of the antenna to change the state of the reconfigurable slot-ring antenna array. Each frequency band has its own feeding lines which allows for the use of high-performance narrow-band transmit/receive (T/R) modules instead of ultra wideband (UWB) T/R modules. Furthermore, the spacing between the elements in each frequency band is less than half free-space wavelength (?0) over the frequency band of operation which enables grating-lobe-free beam scanning. This is the first shared-aperture reconfigurable dual-polarized antenna with separate feeding for each band which is scalable to a larger array with element spacing of less than 0.5?0 in all frequency bands of operation.First, a switchable-band reconfigurable antenna array switching between L and C bands is presented. This antenna operates at 1.76/5.71 GHz with a fractional bandwidth (FBW) of 8.6%/11.5%, realized gain of 0.1/4.2 dBi and radiation efficiency of 66.6%/80.7% in the L-/C- band operating states, respectively. Second, a wideband version of the reconfigurable antenna element using fractal geometries is presented. This dual-polarized antenna element is switching between S and C bands with wide bandwidth in each operating state. In the S-/C-band operating state, this antenna shows 69.1%/58.3% FBW with a maximum realized gain of 2.4/3.1 dBi. Third, the wideband antenna element is extended to an antenna array. The reconfigurable dual-polarized antenna array with vertical coaxial feeding switches between S- and C-band states with full-band coverage. A 2(&)#215;2 S-band antenna array can be reconfigured to a 4(&)#215;4 C-band antenna array by activating/deactivating PIN diode switches. This antenna array shows 64.3%/66.7% FBW with 8.4/14.3 dBi maximum realized gain in the S-/C-band operating states, respectively. Finally, a reconfigurable antenna element covering three adjacent frequency bands is presented. The FBW of this tri-band antenna element is 75%/63%/26% in the S/C/X band state.
Show less
Date Issued: 2018
Identifier: CFE0007373, ucf:52092
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007373

Title: Nanoscale Characterization and Mechanism of Electroless Deposition of Silver Metal.
Creator: Grabill, Christopher, Kuebler, Stephen, Beazley, Melanie, Zou, Shengli, Frazer, Andrew, Bhattacharya, Aniket, University of Central Florida
Abstract / Description: This dissertation is an investigation of the nanoscale characteristics and mechanism of electrolessly deposited silver metal seeded by gold nanoparticles. The process of growing seed-nanoparticles on a polymer surface was studied. Several bifunctional amines and organic reducing agents were used to explore how these chemical factors affect the size and distribution of gold nanoparticles formed at the interface. The nanoparticles were characterized by transmission electron microscopy (TEM) and...
Show moreThis dissertation is an investigation of the nanoscale characteristics and mechanism of electrolessly deposited silver metal seeded by gold nanoparticles. The process of growing seed-nanoparticles on a polymer surface was studied. Several bifunctional amines and organic reducing agents were used to explore how these chemical factors affect the size and distribution of gold nanoparticles formed at the interface. The nanoparticles were characterized by transmission electron microscopy (TEM) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). An electroless deposition (ED) bath developed by Danscher was selected to study electroless deposition of silver in detail. The chemical species in the bath were varied to determine how concentration, nature of the carboxylate buffering species, and the presence and absence of gum arabic affect the morphology of silver metal formed by ED and the overall rate of deposition at the surface. The kinetics of deposition using the Danscher bath was studied in detail to elucidate the mechanism of ED. Knowledge generated from this investigation can be used to expand applications of silver ED where strict control over the nanoscale morphology of the deposited metal is required to obtain specific chemical and physical properties.
Show less
Date Issued: 2018
Identifier: CFE0007009, ucf:52051
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007009

Title: Design, Synthesis, Stability, and Photocatalytic Studies of Sustainable Metal-Organic Frameworks.
Creator: Logan, Matthew, Uribe Romo, Fernando, Zhai, Lei, Yuan, Yu, Kuebler, Stephen, Rahman, Talat, University of Central Florida
Abstract / Description: The presented dissertation focuses on the design, synthesis, and characterization of metal-organic frameworks (MOFs) composed of earth-abundant elements the exhibit photoredox activity and studied their application as heterogeneous photocatalysts in organic synthesis and in solar-to-chemical energy conversion. In particular, the structure-property relationships of titanium-based MOFs relating the structure of the organic building unit and the photophysical and photochemical activity of the...
Show moreThe presented dissertation focuses on the design, synthesis, and characterization of metal-organic frameworks (MOFs) composed of earth-abundant elements the exhibit photoredox activity and studied their application as heterogeneous photocatalysts in organic synthesis and in solar-to-chemical energy conversion. In particular, the structure-property relationships of titanium-based MOFs relating the structure of the organic building unit and the photophysical and photochemical activity of the solid material is studied. The first novel family of seven MOFs isoreticular to MIL-125-NH2, includes functionalized with N-alkyl groups with increasing chain length (methyl to heptyl) and with varying connectivity (primary or secondary). The functionalized materials displayed reduced optical bandgaps correlated with the increased inductive donor ability of the alkyl substituents, enhanced excited-state lifetimes, mechanistic information towards visible light CO2 reduction, and improved water stability. The second family of titanium MOFs was prepared with a new secondary building unit and organic links of varying lengths, for which Their crystal structure was solved utilizing powder X-ray diffraction crystallography. This work provides guidelines for the next generation of photocatalyst for the conversion of solar-to-chemical energy and other organic transformations.
Show less
Date Issued: 2018
Identifier: CFE0007219, ucf:52217
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007219

Title: Improved system for fabrication and characterization of nanophotonic devices by multi-photon lithography.
Creator: Sharma, Rashi, Kuebler, Stephen, Zou, Shengli, Huo, Qun, Beazley, Melanie, Phanstiel, Otto, University of Central Florida
Abstract / Description: A new system for multi-photon lithography (MPL) was developed and used to fabricate three-dimensional (3D) structures with higher aspect ratio, better resolution, improved fidelity, and reduced structural distortion relative to a conventional implementation of MPL.A set of curved waveguides (Rbend = 19 (&)#181;m, and 38 (&)#181;m) and straight waveguides (length = 50 (&)#181;m, Rbend = ?) were fabricated in an epoxide photopolymer and optically characterized using light having a wavelength in...
Show moreA new system for multi-photon lithography (MPL) was developed and used to fabricate three-dimensional (3D) structures with higher aspect ratio, better resolution, improved fidelity, and reduced structural distortion relative to a conventional implementation of MPL.A set of curved waveguides (Rbend = 19 (&)#181;m, and 38 (&)#181;m) and straight waveguides (length = 50 (&)#181;m, Rbend = ?) were fabricated in an epoxide photopolymer and optically characterized using light having a wavelength in vacuum of ?0 = 2.94 (&)#181;m. The optical performance of the waveguides was compared to novel spatially-variant photonic crystals (SVPCs) previously studied in the group. The waveguides were found to guide light with 90% lower efficiency, due to mode leakage. The study provides further evidence that SVPCs operate not through total internal reflection, but rather through self-collimation, as designed.3D uniform-lattice photonic crystals (ULPCs) were fabricated by MPL using a commercial acrylate photopolymer. The ULPCs were optically characterized at ?0 = 1.55 (&)#181;m. A laser beam with adjustable bandwidth was used to measure the self-collimation in the ULPCs. For the low bandwidth beam, vertically polarized light was self-collimated, whereas horizontally polarized light diverged. The transmission efficiency of the ULPCs was also measured as a function of fill factor. The ULPC having a fill factor of 48% exhibited 80% transmission.An etching process was also developed for non-destructively removing Au/Pd coatings that must be deposited onto structures to image them by scanning electron microscopy. The structural and optical integrity of the samples was found to be maintained despite etching. The sputter-coated sample sustained no structural damage when exposed to the ?0 = 1.55 (&)#181;m. However, the metal coating resulted in diminished transmission efficiency due to the high reflection of the 1.55 (&)#181;m beam by the metal coating.
Show less
Date Issued: 2018
Identifier: CFE0007767, ucf:52380
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007767

Title: Engineering Noble-metal Nanostructures for Biosensing Applications.
Creator: Ye, Haihang, Xia, Xiaohu, Kuebler, Stephen, Chen, Gang, Beazley, Melanie, Feng, Xiaofeng, University of Central Florida
Abstract / Description: The ability to engineer noble-metal nanostructures (NMNSs) in a controllable manner and to understand the structure-dependent properties greatly boost our knowledge in rational design of biosensing technologies. In particular, as a type of highly efficient peroxidase mimics, NMNSs hold promising potential to break through the bottleneck of conventional enzyme-based in vitro diagnostics.During the time of my Ph.D. study, I have successfully: 1) directed a two-step method involving seed...
Show moreThe ability to engineer noble-metal nanostructures (NMNSs) in a controllable manner and to understand the structure-dependent properties greatly boost our knowledge in rational design of biosensing technologies. In particular, as a type of highly efficient peroxidase mimics, NMNSs hold promising potential to break through the bottleneck of conventional enzyme-based in vitro diagnostics.During the time of my Ph.D. study, I have successfully: 1) directed a two-step method involving seed-mediated growth and chemical etching for the synthesis of Ru nanoframes (RuNFs) with face-centered cubic crystal phase and enhanced catalytic activities; 2) demonstrated, for the first time, the inherent peroxidase-like activity of RuNFs as a type of efficient peroxidase mimics, opening up possibilities for their bioapplications; 3) developed an enzyme-free signal amplification technique for ultrasensitive colorimetric assay of disease biomarkers by using Pd-Ir nanooctahedra encapsulated gold vesicles as labels; 4) prepared polyvinylpyrrolidone (PVP)-capped Pt nanocubes with superior peroxidase-like catalytic activity and record-high specific catalytic activity; 5) developed a facile colorimetric method for the detection of Ag(I) ions with picomolar sensitivity by using the PVP-capped Pt nanocubes as the probes; 6) developed a non-enzyme cascade amplification strategy for colorimetric assay of disease biomarkers by taking advantage of the interaction between the Ag(I) ions and PVP-capped Pt nanocubes; and 7) established a highly sensitive colorimetric lateral flow assay platform by using Au@Pt core-shell nanoparticles as the labels that possess both plasmonic and catalytic properties.
Show less
Date Issued: 2019
Identifier: CFE0007559, ucf:52626
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007559

Title: Reconfigurable Reflectarray Antennas with Bandwidth Enhancement for High Gain, Beam-Steering Applications.
Creator: Trampler, Michael, Gong, Xun, Wahid, Parveen, Jones, W Linwood, Chen, Kenle, Kuebler, Stephen, University of Central Florida
Abstract / Description: Reconfigurable reflectarrays are a class of antennas that combine the advantages of traditional parabolic antennas and phased array antennas. Chapter 1 discusses the basic operational theory of reflectarrays and their design. A review of previous research and the current status is also presented. Furthermore the inherent advantages and disadvantages of the reflectarray topography are presented. In chapter 2, a BST-integrated reflectarray operating at Ka band is presented. Due to the...
Show moreReconfigurable reflectarrays are a class of antennas that combine the advantages of traditional parabolic antennas and phased array antennas. Chapter 1 discusses the basic operational theory of reflectarrays and their design. A review of previous research and the current status is also presented. Furthermore the inherent advantages and disadvantages of the reflectarray topography are presented. In chapter 2, a BST-integrated reflectarray operating at Ka band is presented. Due to the monolithic integration of the tuning element, this design is then extended to V band where a novel interdigital gap configuration is utilized. Finally to overcome loss and phase limitations of the single resonant design, a BST-integrated, dual-resonance unit cell operating at Ka band is designed. While the losses are still high, a 360(&)deg; phase range is demonstrated.In chapter 3, the operational theory of dual-resonant array elements is introduced utilizing Q theory. An equivalent circuit is developed and used to demonstrate design tradeoffs. Using this theory the design procedure of a varactor tuned dual-resonant unit cell operating at X-band is presented. Detailed analysis of the design is performed by full-wave simulations and verified via measurements. In chapter 4, the array performance of the dual-resonance unit cell is analyzed. The effects of varying angles of incidence on the array element are studied using Floquet simulations. The beam scanning, cross-polarization and bandwidth performance of a 7(&)#215;7 element reflectarray is analyzed using full-wave simulations and verified via measurements.In chapter 5 a loss analysis of the dual-resonant reflectarray element is performed. Major sources of loss are identified utilizing full-wave simulations before an equivalent circuit is utilized to optimize the loss performance while maintaining a full phase range and improved bandwidth performance. Finally the dual-resonance unit cell is modified to support two linear polarizations. Overall, the operational and design theory of dual resonant reflectarray unit cells using Q theory is developed. A valuable equivalent circuit is developed and used to aid in array element design as well as optimize the loss and bandwidth performance. The proposed theoretical models provide valuable physical insight through the use of Q theory to greatly aid in reflectarray design
Show less
Date Issued: 2019
Identifier: CFE0007735, ucf:52457
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007735

Title: Frequency-Reconfigurable Microstrip Patch and Cavity-Backed Slot ESPARs.
Creator: Ouyang, Wei, Gong, Xun, Vosoughi, Azadeh, Wahid, Parveen, Abdolvand, Reza, Kuebler, Stephen, University of Central Florida
Abstract / Description: Wireless communication systems have rapidly evolved over the past decade which has led to an explosion of mobile data traffic. Since more and more wireless devices and sensors are being connected, the transition from the current 4G/LTE mobile network to 5G is expected to happen within the next decade. In order to improve signal-to-noise ratio (SNR), system capacity, and link budget, beam steerable antenna arrays are desirable due to their advantage in spatial selectivity and high directivity....
Show moreWireless communication systems have rapidly evolved over the past decade which has led to an explosion of mobile data traffic. Since more and more wireless devices and sensors are being connected, the transition from the current 4G/LTE mobile network to 5G is expected to happen within the next decade. In order to improve signal-to-noise ratio (SNR), system capacity, and link budget, beam steerable antenna arrays are desirable due to their advantage in spatial selectivity and high directivity. Electronically steerable parasitic array radiator (ESPAR) that can achieve low-cost continuously beamsteering using varactor diodes have attracted a lot of attention. This dissertation explores bandwidth enhancement of the ESPAR using frequency-reconfigurable microstrip patch and cavity-backed slot (CBS) antennas. In chapter 2, an ESPAR of three closely-coupled rectangular patch elements that do not use phase shifters is presented; the beamsteering is realized by tunable reactive loads which are used to control the mutual coupling between the elements. Additional loading varactors are strategically placed on the radiating edge of all the antenna elements to achieve a 15% continuous frequency tuning range while simultaneously preserving the beamsteering capability at each operating frequency. Therefore, this frequency-reconfigurable ESPAR is able to provide spectrum diversity in addition to the spatial diversity inherent in a frequency-fixed ESPAR. A prototype of the patch ESPAR is fabricated and demonstrated to operate from 0.87 to 1.02 GHz with an instantaneous fractional bandwidth (FBW) of ~1%. At each operating frequency, this ESPAR is able to scan from -20 to +20 degrees in the H plane. However, the beamsteering of the patch ESPAR is limited in the H-plane and its instantaneous S11 fractional bandwidth (FBW) is very narrow. This dissertation also explores how to achieve 2-D beamsteering with enhanced FBW using CBS antennas. A 20-element cavity-backed slot antenna array is designed and fabricated based on a CBS ESPAR cross subarray in chapter 5. This ESPAR array is able to steer the main beam from +45 degrees to -45 degrees in the E plane and from +40 degrees to -40 degrees in the H plane, respectively, without grating lobes in either plane. The impedance matching is maintained below -10 dB from 6.0 to 6.4 GHz (6.4% fractional bandwidth) at all scan angles. In addition, the CBS ESPAR exhibits minimum beam squint at all scan angles within the impedance matching bandwidth. This array successfully demonstrates the cost savings and associated reduction in the required number of phase shifters in the RF front end by employing ESPAR technology.
Show less
Date Issued: 2019
Identifier: CFE0007699, ucf:52426
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007699

Title: Fabrication and Characterization of Nonlinear Optical Ceramics for Random Quasi-Phase-Matching.
Creator: Chen, Xuan, Gaume, Romain, Richardson, Kathleen, Challapalli, Suryanarayana, Sohn, Yongho, Kuebler, Stephen, University of Central Florida
Abstract / Description: A number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline...
Show moreA number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline aggregates, in a so-called random quasi-phase-matching (rQPM) process. In this dissertation, we examine appropriate fabrication pathways for (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-PT) and ZnSe transparent ceramics for applications in the mid-IR. The main challenge associated with the fabrication of high transparency PMN-PT ceramics is to avoid the parasitic pyrochlore phase. The most effective method to suppress the formation of this undesired phase is to use magnesium niobate (MgNb2O6) as the starting material. We have found that, contrary to commercially available lead oxide powders, nanopowders synthesized in our lab by the combustion method help improve the densification of ceramics and their overall optical quality. The effects of dopants on the microstructure evolution and phase-purity control in PMN-PT ceramics are also investigated and show that La3+ helps control grain-growth and get a pure perovskite phase, thereby improving the samples transparency. With large second order susceptibility coefficients and wide transmission window from 0.45 to 21 (&)#181;m, polycrystalline zinc selenide is also an ideal candidate material for accessing the MWIR spectrum through rQPM nonlinear interaction. We have investigated non-stoichiometric heat-treatment conditions necessary to develop adequate microstructure for rQPM from commercial CVD-grown ZnSe ceramics. We have been able to demonstrate the world's first optical parametric oscillation (OPO) based on rQPM in ZnSe transparent ceramic, enabling broadband frequency combs spanning 3-7.5 (&)#181;m.
Show less
Date Issued: 2018
Identifier: CFE0007748, ucf:52403
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007748

Title: Fabrication and Characterization of Spatially-Variant Self-Collimating Photonic Crystals.
Creator: Digaum, Jennefir, Kuebler, Stephen, Kik, Pieter, Schoenfeld, Winston, Likamwa, Patrick, Gesquiere, Andre, University of Central Florida
Abstract / Description: Spatially-variant photonic crystals (SVPCs) created using materials having a low refractive index are shown to be capable of abruptly controlling light beams with high polarization selectivity. SVPCs are photonic crystals for which the orientation of the unit cell is controllably varied throughout the lattice to control the flow of light. Multi-photon lithography in a photo polymer was used to fabricate three-dimensional SVPCs that direct the flow of light around a 90 degree bend. The optical...
Show moreSpatially-variant photonic crystals (SVPCs) created using materials having a low refractive index are shown to be capable of abruptly controlling light beams with high polarization selectivity. SVPCs are photonic crystals for which the orientation of the unit cell is controllably varied throughout the lattice to control the flow of light. Multi-photon lithography in a photo polymer was used to fabricate three-dimensional SVPCs that direct the flow of light around a 90 degree bend. The optical performance of the SVPCs was characterized using a scanning optical-fiber system that introduced light onto the input face of a structure and measured the intensity of light emanating from the output faces.As a proof-of-concept, SVPCs that can bend a beam at a wavelength of ?0 = 2.94 ?m were fabricated in the photo-polymer SU-8. The SVPCs were shown to direct infrared light of one polarization through a sharp bend, while the other polarization propagated straight through the SVPC, when the volumetric fill-factor is near 50%. The peak-to-peak ratio of intensities of the bent- and straight-through beams was 8:1, and a power efficiency of 8% was achieved. The low efficiency is attributed to optical absorption in SU-8 at ?0 = 2.94 ?m.SVPCs that can bend a beam at telecommunications wavelengths near ?0 = 1.55 ?m were fabricated by multi-photon lithography in the photo-polymer IP-Dip. IP-Dip was chosen over SU 8 to enable fabrication of finer features, as are needed for an SVPC scaled in size to operate at shorter wavelengths. Experimental characterization shows that these particular SVPCs provide effective control of the vertically polarized beam at ?0 = 1.55 ?m, when the volumetric fill-factor is around 46%. The beam bending peak efficiency was found to be 52.5% with a peak-to-peak ratio between the bent- and straight-through beams of 78.7. Additionally, these SVPCs can bend a light beam with a broad bandwidth of 153 nm that encompasses both the C- and S-bands of the telecommunications window. Furthermore, the SVPCs have high tolerance to misalignment, in which an offset of the input beam by as much as 6 ?m causes the beam-bending efficiency to drop no more than 50%. Finally, it is shown that these particular SVPCs can bend beams without significantly distorting the mode profile. This work introduces a new scheme for controlling light that should be useful for integrated photonics.The penultimate chapter discusses nonlinear phenomena that were observed during the optical characterization of the SVPCs using a high peak-power amplified femtosecond laser system. The first of these effects is referred to as "super-collimation", in which the beam bending peak efficiency of certain SVPCs increases with input intensity, reaching as high as 68%. The second effect pertains to nonlinear imaging of light at ?0 = 1.55 ?m scattered from an SVPC and detected using a silicon-CCD camera. This effect enables beam bending within the device to be imaged in real time. The dissertation concludes with an outlook for SVPCs, discussing potential applications and challenges that must be addressed to advance their use in photonics.
Show less
Date Issued: 2016
Identifier: CFE0006527, ucf:51371
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006527

Title: Design of surface chemical reactivity and optical properties in glasses.
Creator: Lepicard, Antoine, Richardson, Kathleen, Seal, Sudipta, Gaume, Romain, Dussauze, Marc, Kuebler, Stephen, University of Central Florida
Abstract / Description: Thermal poling is a technique which involves the application of a strong DC electric field to a glass substrate heated below its glass transition temperature (Tg). Following the treatment, a static electric field is frozen inside the glass matrix, effectively breaking its centrosymmetry. Historically, this treatment has been used as a way to gain access to second order non-linear optical properties in glasses. However, recent efforts have shown that the treatment was responsible for...
Show moreThermal poling is a technique which involves the application of a strong DC electric field to a glass substrate heated below its glass transition temperature (Tg). Following the treatment, a static electric field is frozen inside the glass matrix, effectively breaking its centrosymmetry. Historically, this treatment has been used as a way to gain access to second order non-linear optical properties in glasses. However, recent efforts have shown that the treatment was responsible for structural changes as well as surface property modifications. Our study was focused on using this technique to tailor surface properties in oxide (borosilicate and niobium borophosphate) and chalcogenide glasses. A strong emphasis was put on trying to control all changes at the micrometric scale. After poling, property changes were assessed using a set of characterization tools: the Maker fringes technique (a Second Harmonic Generation ellipsometry technique), micro-Second Harmonic Generation ((&)#181;-SHG), vibrational spectroscopy and Secondary Ion Mass Spectroscopy (SIMS). Surface reactivity in borosilicate glasses was effectively changed while in niobium borophosphate and chalcogenide glasses, the optical properties were controlled linearly and nonlinearly. Finally, property changes were effectively controlled at the micrometric scale. This opens up new applications of thermal poling as a mean to design glass substrate for integrated photonics and lab-on-a-chip devices.
Show less
Date Issued: 2016
Identifier: CFE0006471, ucf:51435
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006471

Title: Enhancement of Antenna Array Performance Using Reconfigurable Slot-Ring Antennas and Integrated Filter/Antennas.
Creator: Li, Tianjiao, Gong, Xun, Wahid, Parveen, Yuan, Jiann-Shiun, Abdolvand, Reza, Kuebler, Stephen, University of Central Florida
Abstract / Description: As modern communication system technology develops, the demand for devices with smaller size, higher efficiency, and more functionality has increased dramatically. In addition, highly integrated RF-front-end modules with a reduced footprint and less transition loss between cascaded devices are desirable in most advanced wireless communication systems. Antenna arrays are widely used in wireless communication systems due to their high directivity and beam steering capability. Moreover, antenna...
Show moreAs modern communication system technology develops, the demand for devices with smaller size, higher efficiency, and more functionality has increased dramatically. In addition, highly integrated RF-front-end modules with a reduced footprint and less transition loss between cascaded devices are desirable in most advanced wireless communication systems. Antenna arrays are widely used in wireless communication systems due to their high directivity and beam steering capability. Moreover, antenna arrays are preferred in mobile communication systems for diversity reception to reduce signal fading effects. In order to meet the various requirements of rapidly developing wireless communication systems, low cost, compact, multifunctional integrated antenna arrays are in high demand.Reconfigurable antennas that can flexibly adapt to different applications by dynamically changing their frequency and radiation properties have attracted a lot of attention. Frequency, radiation pattern, polarization, or a combination of two or more of these parameters in the reconfiguration of antennas was studied and presented in recent years. A single reconfigurable antenna is able to replace multiple traditional antennas and accomplish different tasks. Thus, the complexity of wireless communication systems can be greatly reduced with a smaller device size. On the other hand, the integration of antennas with other devices in wireless communication systems that can improve the efficiency and shrink the device size is a growing trend in antenna technology. Compact and highly efficient integrated filters and antennas were studied previously; the studies show that by seamlessly co-designing filters with patch antennas, the fractional bandwidth (FBW) of the antennas can be enhanced as compared to stand-alone antennas.However, the advantages of both the reconfigurable antenna and integrated filter/antenna technology have not been fully applied to antenna array applications. Therefore, this dissertation explores how to maximize the antenna array performance using reconfigurable antennas and integrated filter/antennas. A continuously frequency reconfigurable slot-ring antenna/array with switches and varactors is presented first. By changing the state of the loaded switches, the reconfigurable slot-ring antenna/array is able to operate as an L-band slot-ring antenna or a 2(&)#215;2 S-band slot-ring antenna array. In each frequency band, the operation frequency of the antenna/array can be continuously tuned with the loaded varactors. To further enhance the functionality of the reconfigurable slot-ring antenna array, a dual-polarized fractal-shaped reconfigurable slot-ring antenna/array is developed with a reduced number of switches and an increased FBW. Additionally, ground plane solutions are explored to achieve single-sided radiation. The benefits of filter/antenna integration are also investigated in both linearly polarized patch phased arrays and circularly polarized patch antenna arrays. Finally, a preliminary study of a tunable integrated evanescent mode filter/antenna is conducted to validate the concept of combining reconfigurable antennas and integrated filter/antennas.
Show less
Date Issued: 2017
Identifier: CFE0006950, ucf:51661
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006950

Title: Development of a nano-sensing approach and a portable prototype for real-time detection and quantification of free mercury in stream-flow: combining science and engineering in pro of the environment.
Creator: Chemnasiri, Warinya, Hernandez, Florencio, Kuebler, Stephen, Zou, Shengli, Uribe Romo, Fernando, Huo, Qun, University of Central Florida
Abstract / Description: Mercury (Hg) is a well-known hazardous environmental contaminant existing in several forms, but all are toxic to human in one way or the others. Since Hg usually settles into water polluting the environment and accumulating in living organisms, it is crucial to monitor Hg levels in the aquatic ecosystem. Although there are many well established techniques currently used to detect Hg, most of them require elaborate and time-consuming sample preparation and pre-concentration procedures, as well...
Show moreMercury (Hg) is a well-known hazardous environmental contaminant existing in several forms, but all are toxic to human in one way or the others. Since Hg usually settles into water polluting the environment and accumulating in living organisms, it is crucial to monitor Hg levels in the aquatic ecosystem. Although there are many well established techniques currently used to detect Hg, most of them require elaborate and time-consuming sample preparation and pre-concentration procedures, as well as costly and bulky equipment that limit their practical application in the field. In order to overcome the existent limitations in Hg determination methods, Hernandez and co-workers proposed the first surface Plasmon resonance (SPR) (-) based Hg sensor using gold nanorods (AuNRs) that offers high sensitivity and selectivity, attributed to the strong affinity between Au and Hg. In this dissertation, I first present my contribution to the understanding of the effect of size and aspect ratio of AuNRs on the limit of detection (LOD) and the dynamic range (DR) of the SPR-based Hg sensor using the qualitative model. In this part I demonstrate how both sensitivity and DR can be improved simultaneously via a modified wet chemistry procedure. Then, I show our approach towards the immobilization of AuNRs silane coated glass slides to expand the application of the SPR-based Hg sensor to stream-flow. Finally, I present the design and fabrication of the first real prototype of the SPR-based Hg sensor, and its application in stream-flow detection and speciation of mercury in the environment. The outcomes of my research have resulted in an innovative real-time portable Hg sensor apparatus with the desired high sensitivity, selectivity and DR to be used in stream-flow applications in Oak Ridge National Labs sites.
Show less
Date Issued: 2015
Identifier: CFE0006283, ucf:51589
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006283

Title: An Adhesive Vinyl-Acrylic Electrolyte and Electrode Binder for Lithium Batteries.
Creator: Tran, Binh, Zhai, Lei, Zou, Shengli, Kuebler, Stephen, Hernandez, Florencio, Gesquiere, Andre, University of Central Florida
Abstract / Description: This dissertation describes a new vinyl-acrylic copolymer that displays great potential for applications in lithium ion batteries by enabling novel, faster, safer and cost-effective processes. Understanding the chemistry of materials and processes related to battery manufacturing allows the design of techniques and methods that can ultimately improve the performance of existing batteries while reducing the cost. The first and second parts of this dissertation focuses on the free radical...
Show moreThis dissertation describes a new vinyl-acrylic copolymer that displays great potential for applications in lithium ion batteries by enabling novel, faster, safer and cost-effective processes. Understanding the chemistry of materials and processes related to battery manufacturing allows the design of techniques and methods that can ultimately improve the performance of existing batteries while reducing the cost. The first and second parts of this dissertation focuses on the free radical polymerization of poly(ethylene glycol) methyl ether methacrylate (PEGMA), methyl methacrylate (MMA), and isobutyl vinyl ether (IBVE) monomers to afford a vinyl-acrylic poly(PEGMA-co-MME-co-IBVE) random copolymer and the investigation of its properties as a soluble, amorphous, and adhesive electrolyte that is able to permanently hold 800 times its own weight. Such material properties envision a printable battery manufacturing procedure, since existing electrolytes lack adhesion at a single macromolecular level. Electrolytes can also be used as an electrode binder so long as it has structural integrity and allows ion transfer to and from the active electrode material during insertion/extraction processes. In the third section, the use of this electrolyte as a water-soluble binder for the aqueous fabrication of LiCoO2 cathodes is presented. Results of this study demonstrated the first aqueous process fabrication of thick, flexible, and fully compressed lithium ion battery electrodes by using commercial nickel foam as a supporting current collector. This feat is rather impressive because these properties are far superior to other aqueous binders in terms of material loading per electrode, specific area capacity, durability, and cell resistance. Finally, the fourth section expands on this concept by using the poly(PEGMA-co-MMA-co-IBVE) copolymer for the aqueous fabrication of a low voltage Li4Ti5O12 anode type electrode. Altogether, results demonstrate as a proof of concept that switching the current toxic manufacturing of lithium-ion batteries to an aqueous process is highly feasible. Furthermore, new electrode manufacturing techniques are also deemed possible.
Show less
Date Issued: 2013
Identifier: CFE0004761, ucf:49780
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004761

SU-8 (3)	+ -
Beam steering (2)	+ -
Nanoparticles (2)	+ -
nanophotonics (2)	+ -
photonic crystals (2)	+ -

?^(2) interaction (1)	+ -
Adjoint Functors (1)	+ -
Antenna (1)	+ -
Antimicrobial (1)	+ -
Array (1)	+ -
Atomic Number Contrast (1)	+ -
Auslander and Bass Classes (1)	+ -
Auslander-Bridger formula (1)	+ -
Auslander-Buchsbaum formula (1)	+ -
Beam Shaping (1)	+ -
Biocompatibilty (1)	+ -
Cascaded Field Enhancement (1)	+ -
Categories with Linkage (1)	+ -
Category Theory (1)	+ -
Cohen-Macaulay rings (1)	+ -
Commutative Algebra (1)	+ -
Depth (1)	+ -
Diffractive Optical Element (1)	+ -
Electroless deposition (1)	+ -
Electronic Circular Dichroism (1)	+ -
FIB (1)	+ -
FeMo-co Biosynthesis (1)	+ -
Filter (1)	+ -
Filtrations (1)	+ -
Gold (1)	+ -

ETD Collection (26)	+ -
Honors Collection (1)	+ -

Kuebler, Stephen (27)	+ -
University of Central Florida (27)	+ -
Gong, Xun (4)	+ -
Hernandez, Florencio (4)	+ -
Kik, Pieter (4)	+ -

Wahid, Parveen (4)	+ -
Zou, Shengli (4)	+ -
Abdolvand, Reza (3)	+ -
Beazley, Melanie (3)	+ -
Huo, Qun (3)	+ -
Uribe Romo, Fernando (3)	+ -
Zhai, Lei (3)	+ -
Belfield, Kevin (2)	+ -
Del Barco, Enrique (2)	+ -
Gaume, Romain (2)	+ -
Gesquiere, Andre (2)	+ -
Heinrich, Helge (2)	+ -
Jones, W Linwood (2)	+ -
Richardson, Kathleen (2)	+ -
Bhattacharya, Aniket (1)	+ -
Blair, Richard (1)	+ -
Brennan, Joseph (1)	+ -
Brisbois, Elizabeth (1)	+ -
Campiglia, Andres (1)	+ -
Challapalli, Suryanarayana (1)	+ -
Chemnasiri, Warinya (1)	+ -
Chen, Bo (1)	+ -
Chen, Gang (1)	+ -
Chen, Kenle (1)	+ -
Chen, Xuan (1)	+ -

Search In

Pages

Pages

Sort Results By:

Narrow results by:

Topical Subject

Collection

Type of Resource

Language

Creator

Format

Owner