Current Search: Raghavan, Seetha (x)
View All Items
Pages
- Title
- HYBRID CARBON FIBER ALUMINA NANOCOMPOSITE FOR NON-CONTACT STRESS SENSING VIA PIEZOSPECTROSCOPY.
- Creator
-
Hanhan, Imad, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
Carbon fiber composites have become popular in aerospace structures and applications due to their light weight, high strength, and high performance. Recently, scientists have begun investigating hybrid composites that include fibers and particulate fillers, since they allow for advanced tailoring of mechanical properties, such as improved fatigue life. This project investigated a hybrid carbon fiber reinforced polymer (HCFRP) that includes carbon fiber and additional alumina nanoparticle...
Show moreCarbon fiber composites have become popular in aerospace structures and applications due to their light weight, high strength, and high performance. Recently, scientists have begun investigating hybrid composites that include fibers and particulate fillers, since they allow for advanced tailoring of mechanical properties, such as improved fatigue life. This project investigated a hybrid carbon fiber reinforced polymer (HCFRP) that includes carbon fiber and additional alumina nanoparticle fillers, which act as embedded nano stress-sensors. Utilizing the piezospectroscopic effect, the photo-luminescent spectral signal of the embedded nanoparticles has been monitored as it changes with stress, enabling non-contact stress detection of the material. The HCRFP's stress-sensitive properties have been investigated in-situ using a laser source and a tensile mechanical testing system. Hybrid composites with varying mass contents of alumina nanoparticles have been studied in order to determine the effect of particle content on the overall stress sensing properties of the material. Additionally, high resolution photo-luminescent maps were conducted of the surfaces of each sample in order to determine the particulate dispersion of samples with varying alumina content. The dispersion maps also served as a method of quantifying particulate sedimentation, and can aid in the improvement of the manufacturing process. The results showed that the emitted photo-luminescent spectrum can indeed be captured from the embedded alumina nanoparticles, and exhibits a systematic trend in photo-luminescent peak shift with respect to stress. The stress maps showed a linear increase in peak shift up to a certain critical stress, and matched closely with the DIC strain results. Therefore, the non-contact stress sensing results shown in this work have strong implications for the future of structural health monitoring and nondestructive evaluation (NDE) of aerospace structures.
Show less - Date Issued
- 2015
- Identifier
- CFH0004750, ucf:45384
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004750
- Title
- CHARACTERIZATION OF DISPERSION AND RESIDUAL STRESS IN NANOPARTICLE REINFORCED HYBRID CARBON FIBER COMPOSITES.
- Creator
-
Selimov, Alex, Raghavan,Seetha, University of Central Florida
- Abstract / Description
-
Hybrid carbon fiber reinforced composites are a new breed of materials that are currently being explored and characterized for next generation aerospace applications. Through the introduction of secondary reinforcements, such as alumina nanoparticles, hybrid properties including improved mechanical properties and stress sensing capabilities can be achieved. In order to maximize these properties, it is necessary to achieve a homogeneous dispersion of particulate filler. Utilizing the...
Show moreHybrid carbon fiber reinforced composites are a new breed of materials that are currently being explored and characterized for next generation aerospace applications. Through the introduction of secondary reinforcements, such as alumina nanoparticles, hybrid properties including improved mechanical properties and stress sensing capabilities can be achieved. In order to maximize these properties, it is necessary to achieve a homogeneous dispersion of particulate filler. Utilizing the photoluminescent properties of alumina, it is possible to compare local levels of particle concentration through emission intensities as a way to determine the effectiveness of the tested manufacturing parameters in increasing material homogeneity. Parameters of these photoluminescence emissions have been established to be stress dependent, which allows for in situ residual stress measurements. It is shown here that the application of silane coupling agents as particle surface treatments improves particle dispersion when compared to untreated samples. Reactive silane coupling agent (RSCA) treatments were found to provide for greater dispersion improvements when compared to non-reactive silane coupling agents (NRSCA). Higher resolution investigations into these samples found that treatment with a reactive coupling agent altered the stress state of particles concentrated around the fiber from a tensile stress state to a compressive stress state. This is proposed to result from bonding of the reactive groups on the coupling agent to the organic groups on the carbon fibers which adjusts the stress state of the particle. Future mechanical tests will verify the effects of the particle surface functionalization treatments on mechanical properties of the composites.
Show less - Date Issued
- 2016
- Identifier
- CFH0000233, ucf:44669
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0000233
- Title
- VORTEX TILTING AND THE ENHANCEMENT OF SPANWISE FLOW IN FLAPPING WING FLIGHT.
- Creator
-
Frank, Spencer, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
The leading edge vortex has been identified as the most critical flow structure for producing lift in flapping wing flight. Its stability depends on the transport of the entrained vorticity into the wake via spanwise flow. This study proposes a hypothesis for the generation and enhancement of spanwise flow based on the chordwise vorticity that results from the tilting of the leading edge vortex and trailing edge vortex. We investigate this phenomenon using dynamically scaled robotic model...
Show moreThe leading edge vortex has been identified as the most critical flow structure for producing lift in flapping wing flight. Its stability depends on the transport of the entrained vorticity into the wake via spanwise flow. This study proposes a hypothesis for the generation and enhancement of spanwise flow based on the chordwise vorticity that results from the tilting of the leading edge vortex and trailing edge vortex. We investigate this phenomenon using dynamically scaled robotic model wings. Two different wing shapes, one rectangular and one based on Drosophila melanogaster (fruit fly), are submerged in a tank of mineral oil and driven in a flapping motion. Two separate kinematics, one of constant angular velocity and one of sinusoidal angular velocity are implemented. In order to visualize the flow structure, a novel three dimensional particle image velocimetry system is utilized. From the three dimensional information obtained the chordwise vorticity resulting from the vortex tilting is shown using isosurfaces and planar slices in the wake of the wing. It is observed that the largest spanwise flow is located in the area between the chordwise vorticity of the leading edge vortex and the chordwise vorticity of the trailing edge vortex, supporting the hypothesis that the vortex tilting enhances the spanwise flow. Additionally the LEV on the rectangular wing is found to detach at about 80% span as opposed to 60% span for the elliptical wing. Also, two distinct regions of spanwise flow, one at the base and one at the tip, are observed at the beginning of the sinusoidal kinematic, and as the velocity of the wing increases these two regions unionize into one. Lastly, the general distribution of vorticity around each wing is found to be nearly the same, indicating that different wing shapes do not greatly affect the distribution of vorticity nor stability mechanisms in flapping flight. In summary the tilting mechanism helps to explain the overall flow structure and the stability of the leading edge vortex.
Show less - Date Issued
- 2011
- Identifier
- CFH0004124, ucf:44875
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004124
- Title
- EFFECTS OF THERMO-MECHANICAL LOADING FROM IN-SITU STUDIES OF EB-PVD THERMAL BARRIER COATINGS.
- Creator
-
Jansz, Melan, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
The thermo-mechanical effects on the strain evolution within an EB-PVD thermal barrier coating (TBC) is presented in this work using in-situ characterization. Synchrotron X-ray diffraction at sector 1-ID at the Argonne National Laboratory provided both qualitative and quantitative in-situ data on the strain evolution under a thermal cycle with mechanical loading. The results show that at a critical combination of temperature and load, the stress in the thermally grown oxide (TGO) layer in the...
Show moreThe thermo-mechanical effects on the strain evolution within an EB-PVD thermal barrier coating (TBC) is presented in this work using in-situ characterization. Synchrotron X-ray diffraction at sector 1-ID at the Argonne National Laboratory provided both qualitative and quantitative in-situ data on the strain evolution under a thermal cycle with mechanical loading. The results show that at a critical combination of temperature and load, the stress in the thermally grown oxide (TGO) layer in the TBC reaches a tensile region. These significant findings enhance existing literature showing purely compressive strains within the TGO where mechanical loads have been neglected. The results have important implications on the effects on the overall life of the coating. Depth resolved quantitative strain is presented as contour plots over a thermal cycle highlighting the complementary strains in the adjacent layers including the bond coat and the TBC with time and temperature. Systematic identification of the appropriate peaks within the multi-layer TBC system provides guidelines for future strain studies using high energy X-rays. Piezospectroscopic studies with applied mechanical loading are further presented as verification of the room temperature XRD data for future development of the method as an operational technique to be used outside the laboratory environment
Show less - Date Issued
- 2011
- Identifier
- CFE0004004, ucf:49173
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004004
- Title
- CALIBRATION OF ALUMINA-EPOXY NANOCOMPOSITES USING PIEZOSPECTROSCOPY FOR THE DEVELOPMENT OF STRESS-SENSING ADHESIVES.
- Creator
-
Stevenson, Amanda, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
A non-invasive method to quantify the stress distribution in polymer-based materials is presented through the piezospectroscopic calibration of alumina-epoxy nanocomposites. Three different alumina volume fraction nanocomposites were created and loaded under uniaxial compression in order to determine the relationship between applied stress and the frequency shift of the R-lines produced by alumina under excitation. Quantitative values for six piezospectroscopic coefficients were obtained...
Show moreA non-invasive method to quantify the stress distribution in polymer-based materials is presented through the piezospectroscopic calibration of alumina-epoxy nanocomposites. Three different alumina volume fraction nanocomposites were created and loaded under uniaxial compression in order to determine the relationship between applied stress and the frequency shift of the R-lines produced by alumina under excitation. Quantitative values for six piezospectroscopic coefficients were obtained which represent the stress-sensing property of the nanocomposites. The results were applied to an alumina-filled adhesive in a single lap shear configuration demonstrating the capability of the technique to monitor R-line peak positions with high spatial resolution and assess the stress distribution within the material prior to failure. Additionally, particle dispersion and volume fraction were confirmed with spectral intensities, introducing a novel experimental method for the assessment of quality in manufacturing of such nanocomposites. Results were further used to initiate studies in determining the load transfer to the nanoparticles and assessing the fundamental driving mechanisms.
Show less - Date Issued
- 2011
- Identifier
- CFE0003744, ucf:48777
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003744
- Title
- Spatial and Temporal Compressive Sensing for Vibration-based Monitoring: Fundamental Studies with Beam Vibrations.
- Creator
-
Ganesan, Vaahini, Das, Tuhin, Kauffman, Jeffrey L., Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
Vibration data from mechanical systems carry important information that is useful for characterization and diagnosis. Standard approaches rely on continually streaming data at a fixed sampling frequency. For applications involving continuous monitoring, such as Structural Health Monitoring (SHM), such approaches result in high data volume and require powering sensors for prolonged duration. Furthermore, adequate spatial resolution, typically involves instrumenting structures with a large...
Show moreVibration data from mechanical systems carry important information that is useful for characterization and diagnosis. Standard approaches rely on continually streaming data at a fixed sampling frequency. For applications involving continuous monitoring, such as Structural Health Monitoring (SHM), such approaches result in high data volume and require powering sensors for prolonged duration. Furthermore, adequate spatial resolution, typically involves instrumenting structures with a large array of sensors. This research shows that applying Compressive Sensing (CS) can significantly reduce both the volume of data and number of sensors in vibration monitoring applications. Random sampling and the inherent sparsity of vibration signals in the frequency domain enables this reduction. Additionally, by exploiting the sparsity of mode shapes, CS can also enable efficient spatial reconstruction using fewer spatially distributed sensors than a traditional approach. CS can thereby reduce the cost and power requirement of sensing as well as streamline data storage and processing in monitoring applications. In well-instrumented structures, CS can enable continuous monitoring in case of sensor or computational failures. The scope of this research was to establish CS as a viable method for SHM with application to beam vibrations. Finite element based simulations demonstrated CS-based frequency recovery from free vibration response of simply supported, fixed-fixed and cantilever beams. Specifically, CS was used to detect shift in natural frequencies of vibration due to structural change using considerably less data than required by traditional sampling. Experimental results using a cantilever beam provided further insight into this approach. In the experimental study, impulse response of the beam was used to recover natural frequencies of vibration with CS. It was shown that CS could discern changes in natural frequencies under modified beam parameters. When the basis functions were modified to accommodate the effect of damping, the performance of CS-based recovery further improved. Effect of noise in CS-based frequency recovery was also studied. In addition to incorporating damping, formulating noise-handling as a part of the CS algorithm for beam vibrations facilitated detecting shift in frequencies from even fewer samples. In the spatial domain, CS was primarily developed to focus on image processing applications, where the signals and basis functions are very different from those required for mechanical beam vibrations. Therefore, it mandated reformulation of the CS problem that would handle related challenges and enable the reconstruction of spatial beam response using very few sensor data. Specifically, this research addresses CS-based reconstruction of deflection shape of beams with fixed boundary conditions. Presence of a fixed end makes hyperbolic terms indispensable in the basis, which in turn causes numerical inconsistencies. Two approaches are discussed to mitigate this problem. The first approach is to restrict the hyperbolic terms in the basis to lower frequencies to ensure well conditioning. The second, a more systematic approach, is to generate an augmented basis function that will combine harmonic and hyperbolic terms. At higher frequencies, the combined hyperbolic terms will limit each other's magnitude, thus ensuring boundedness. This research thus lays the foundation for formulating the CS problem for the field of mechanical vibrations. It presents fundamental studies and discusses open-ended challenges while implementing CS to this field that will pave way for further research.
Show less - Date Issued
- 2017
- Identifier
- CFE0007120, ucf:51954
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007120
- Title
- NONDESTRUCTIVE TESTING METHODS AIDED VIA NUMERICAL COMPUTATION MODELS FOR VARIOUS CRITICAL AEROSPACE AND POWER GENERATION SYSTEMS.
- Creator
-
Warren, Peter, Ghosh, Ranajay, Raghavan, Seetha, Gou, Jihua, University of Central Florida
- Abstract / Description
-
A current critical necessity for all industries which utilize various equipment that operates in hightemperature and extreme environments, is the ability to collect and analyze data via non destructivetesting (NDT) methods. Operational conditions and material health must be constantly monitoredif components are to be implemented precisely to increase the overall performance and efficiencyof the process. Currently in both aerospace and power generation systems there are many methodsthat are...
Show moreA current critical necessity for all industries which utilize various equipment that operates in hightemperature and extreme environments, is the ability to collect and analyze data via non destructivetesting (NDT) methods. Operational conditions and material health must be constantly monitoredif components are to be implemented precisely to increase the overall performance and efficiencyof the process. Currently in both aerospace and power generation systems there are many methodsthat are being employed to gather several necessary properties and parameters of a given system.This work will focus primarly on two of these NDT methods, with the ultimate goal of contributingto not only the method itself, but also the role of numerical computation to increase the resolutionof a given technique. Numerical computation can attribute knowledge onto the governing mechanicsof these NDT methods, many of which are currently being utilized in industry. An increase inthe accuracy of the data gathered from NDT methods will ultimately lead to an increase in operationalefficiency of a given system.The first method to be analyzed is a non destructive emmision technique widely referred to asaccoustic ultrasonic thermography. This work will investigate the mechanism of heat generationin acoustic thermography using a combination of numerical computational analysis and physicalexperimentation. Many of the challenges typical of this type of system are addressed in this work.The principal challenges among them are crack detection threshold, signature quality and the effectof defect interactions. Experiments and finite element based numerical simulations are employed,in order to evaluate the proposed method, as well as draw conclusions on the viability for futureextension and integration with other digital technologies for health monitoring. A method to determinethe magnitude of the different sources of heat generation during an acoustic excitation isalso achieved in this work. Defects formed through industrial operation as well as defects formedthrough artificial manufacturing methods were analyzed and compared.The second method is a photoluminescence piezospectroscopic (PLPS) for composite materials.The composite studied in this work has one host material which does not illuminate or have photoluminescenceproperties, the second material provides the luminescence properties, as well asadditional overall strength to the composite material. Understanding load transfer between the reinforcementsand matrix materials that constitute these composites hold the key to elucidating theirmechanical properties and consequent behavior in operation. Finite element simulations of loadingeffects on representative embedded alumina particles in a matrix were investigated and comparedwith experimental results. The alumina particles were doped with chromium in order to achieveluminscence capability, and therefore take advantage of the piezospectrscopic measurement technique.Mechanical loading effects on alumina nanoparticle composites can be captured with Photostimulated luminescent spectroscopy, where spectral shifts from the particles are monitored withload. The resulting piezospectroscopic (PS) coefficients are then used to calculate load transferbetween the matrix and particle. The results from the simulation and experiments are shown tobe in general agreement of increase in load transferred with increasing particle volume fractiondue to contact stresses that are dominant at these higher volume fractions. Results from this workpresent a combination of analytical and experimental insight into the effect of particle volume fractionon load transfer in ceramic composites that can serve to determine properties and eventuallyoptimize various parameters such as particle shape, size and dispersion that govern the design ofthese composites prior to manufacture and testing.
Show less - Date Issued
- 2018
- Identifier
- CFE0007262, ucf:52203
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007262
- Title
- INVESTIGATION OF PS-PVD AND EB-PVD THERMAL BARRIER COATINGS OVER LIFETIME USING SYNCHROTRON X-RAY DIFFRACTION.
- Creator
-
Northam, Matthew, Raghavan, Seetha, Ghosh, Ranajay, Vaidyanathan, Raj, University of Central Florida
- Abstract / Description
-
Extreme operating temperatures within the turbine section of jet engines require sophisticated methods of cooling and material protection. Thermal barrier coatings (TBCs) achieve this through a ceramic coating applied to a substrate material (nickel-based superalloy). Electron-beam physical vapor deposition (EB-PVD) is the industry standard coating used on jet engines. By tailoring the microstructure of an emerging deposition method, Plasma-spray physical vapor deposition (PS-PVD), similar...
Show moreExtreme operating temperatures within the turbine section of jet engines require sophisticated methods of cooling and material protection. Thermal barrier coatings (TBCs) achieve this through a ceramic coating applied to a substrate material (nickel-based superalloy). Electron-beam physical vapor deposition (EB-PVD) is the industry standard coating used on jet engines. By tailoring the microstructure of an emerging deposition method, Plasma-spray physical vapor deposition (PS-PVD), similar microstructures to that of EB-PVD coatings can be fabricated, allowing the benefits of strain tolerance to be obtained while improving coating deposition times. This work investigates the strain through depth of uncycled and cycled samples using these coating techniques with synchrotron X-ray diffraction (XRD). In the TGO, room temperature XRD measurements indicated samples of both deposition methods showed similar in-plane compressive stresses after 300 and 600 thermal cycles. In-situ XRD measurements indicated similar high-temperature in-plane and out-of-plane stress in the TGO and no spallation after 600 thermal cycles for both coatings. Tensile in-plane residual stresses were found in the YSZ uncycled PS-PVD samples, similar to APS coatings. PS-PVD samples showed in most cases, higher compressive residual in-plane stress at the YSZ/TGO interface. These results provide valuable insight for optimizing the PS-PVD processing parameters to obtain strain compliance similar to that of EB-PVD. Additionally, external cooling methods used for thermal management in jet engine turbines were investigated. In this work, an additively manufactured lattice structure providing transpiration cooling holes is designed and residual strains are measured within an AM transpiration cooling sample using XRD. Strains within the lattice structure were found to have greater variation than that of the AM solid wall. These results provide valuable insight into the viability of implementing an AM lattice structure in turbine blades for the use of transpiration cooling.
Show less - Date Issued
- 2019
- Identifier
- CFE0007844, ucf:52830
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007844
- Title
- Investigation into the Feasibility of Adding Turbulators to Rocket Combustion Chamber Cooling Channels Using a Conjugate Heat Transfer Analysis.
- Creator
-
Buchanan, Tyler, Kapat, Jayanta, Raghavan, Seetha, Ghosh, Ranajay, University of Central Florida
- Abstract / Description
-
A conjugate heat transfer analysis will be carried out to simulate an 89 kN thrust chamber hydrogen cooling channel, to determine the feasibility of adding turbulators to the combustion chamber cooling channels at various parameters such as angle, pitch, and height of the turbulator. An existing regeneratively cooled chamber environment is simulated and used as a baseline case to be compared against. The new design includes using ribbed turbulators or delta wedges in the cooling channels to...
Show moreA conjugate heat transfer analysis will be carried out to simulate an 89 kN thrust chamber hydrogen cooling channel, to determine the feasibility of adding turbulators to the combustion chamber cooling channels at various parameters such as angle, pitch, and height of the turbulator. An existing regeneratively cooled chamber environment is simulated and used as a baseline case to be compared against. The new design includes using ribbed turbulators or delta wedges in the cooling channels to increase the heat transfer on the channel hot wall (wall adjacent to the hot gas wall) and on the two channel sidewalls. With a higher heat transfer coefficient, the sidewalls behave like fins for heat transfer and participate more in the overall heat transfer process in the channel. Efficient rib and wedge geometries are chosen based on previous investigations. A conjugate heat transfer analysis is performed using a straight duct with the rib and wedge geometries included, with boundary conditions similar to those found in the combustion chamber, to provide thermal hydraulic performance data at numerous turbulator configurations. The baseline channel's maximum hot wall temperature is the target maximum hot wall temperature that is desired to be reduced. The goal is to reduce the hot gas side wall temperature at a minimal cost in pressure drop.
Show less - Date Issued
- 2018
- Identifier
- CFE0007160, ucf:52320
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007160
- Title
- Analysis of residual stress and damage mechanisms of thermal barrier coatings deposited via PS-PVD and EB-PVD.
- Creator
-
Rossmann, Linda, Raghavan, Seetha, Sohn, Yongho, Vaidyanathan, Raj, Ghosh, Ranajay, University of Central Florida
- Abstract / Description
-
Thermal barrier coatings (TBCs) are critical to gas turbine engines, as they protect the components in the hot section from the extreme temperatures of operation. The current industry standard method of applying TBCs for turbine blades in jet engines is electron-beam physical vapor deposition (EB-PVD), which results in a columnar structure that is valued for its high degree of strain tolerance. An emerging deposition method is plasma-spray physical vapor deposition (PS-PVD), capable of...
Show moreThermal barrier coatings (TBCs) are critical to gas turbine engines, as they protect the components in the hot section from the extreme temperatures of operation. The current industry standard method of applying TBCs for turbine blades in jet engines is electron-beam physical vapor deposition (EB-PVD), which results in a columnar structure that is valued for its high degree of strain tolerance. An emerging deposition method is plasma-spray physical vapor deposition (PS-PVD), capable of producing a variety of customizable microstructures as well as non-line-of-sight deposition, which allows more complex geometries to be coated, or even multiple parts at once. The pseudo-columnar microstructure that can be produced with PS-PVD is a possible alternative to EB-PVD. However, before PS-PVD can be used to its full potential, its mechanical properties and behavior must be understood. This work contributes to this understanding by characterizing PS-PVD TBCs that have been thermally cycled to simulate multiple lifetimes (0, 300, and 600 thermal cycles). Residual stress in the thermally grown oxide (TGO) layer is characterized by photoluminescence piezospectroscopy as TGO residual stress is correlated with the lifetime of the coating. Residual stress in the top coat is characterized by Raman spectroscopy, because this stress drives cracking in the top coat that can lead to failure. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) are performed to observe microstructural and phase evolution to provide context and possible explanations for the stress results. In addition, EB-PVD samples of the same thermal cycling history are characterized in the same way so that PS-PVD can be benchmarked against the industry standard. The compressive residual stress in the TGO in both coatings was relieved with thermal cycling due to the TGO lengthening as well as microcracking. The PS-PVD samples had slightly lower TGO stress than the EB-PVD, which is attributed to the greater extent of cracking within the TGO, whereas cracking in the EB-PVD samples was at the TGO/topcoat interface. The PS-PVD cycled samples had significant cracking within the topcoat near the TGO due to both greater porosity than EB-PVD samples and regions of unmelted particles that provide little resistance to cracking. The greater convolution of the TGO in the PS-PVD samples results in greater out-of-plane tensile stresses that cause crack initiation, as well as diverts cracks away from the difficult-to-follow interface. The TGO stress results agree with existing literature and extend the thermal cycling beyond what has previously been reported for PS-PVD coatings, revealing a trend of stress relief and stress values similar to that of EB-PVD coatings in this study and in the literature. Residual stress in the topcoat for both coating types became increasingly compressive with thermal cycling, indicating loss of strain tolerance by sintering. The trend of the YSZ stress for both coating types to become more compressive with cycling and with depth agrees with the literature, and the thermal cycling is longer than has been previously reported for PS-PVD. The two coating types had quite different microstructures and crack modes as well as different as-deposited residual stresses, but after thermal cycling had similar stresses in both the TGO and top coat. No samples experienced spallation. These results indicate that, while PS-PVD coatings have different properties and behavior from EB-PVD coatings, they had comparable levels of damage to EB-PVD coatings of the same lifetime and are a viable alternative to EB-PVD. Further tuning of the processing parameters may result in PS-PVD coatings with even more similar behavior to EB-PVD coatings.
Show less - Date Issued
- 2019
- Identifier
- CFE0007717, ucf:52429
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007717
- Title
- Adiabatic Film Cooling Effectiveness of a Transpiration-Cooled Leading Edge Fabricated by Laser Additive Manufacturing.
- Creator
-
Calderon, Luisana, Kapat, Jayanta, Raghavan, Seetha, Mingareev, Ilya, University of Central Florida
- Abstract / Description
-
Laser additive manufacturing (LAM) is an emerging technology capable of fabricating complex geometries not possibly made by investment casting methods for gas turbine applications. LAM techniques consist of building parts in a layer-by-layer process by selectively melting metal powders. In the present study, a mock leading edge segment of a turbine blade fabricated by LAM of Inconel 718 powders is investigated. For this particular design, the traditional showerhead film cooling holes have...
Show moreLaser additive manufacturing (LAM) is an emerging technology capable of fabricating complex geometries not possibly made by investment casting methods for gas turbine applications. LAM techniques consist of building parts in a layer-by-layer process by selectively melting metal powders. In the present study, a mock leading edge segment of a turbine blade fabricated by LAM of Inconel 718 powders is investigated. For this particular design, the traditional showerhead film cooling holes have been replaced by two strips containing engineered-porous regions with the purpose of simulating the effect of transpiration cooling. Transpiration cooling has been considered a promising external convective cooling method capable of providing a more uniform film and higher adiabatic film cooling effectiveness than conventional discrete film cooling. In addition, many studies have shown that this technique can yield high firing temperatures with much less coolant consumption than discrete film cooling. In this current study, adiabatic film cooling effectiveness is investigated by means of mass transfer using pressure sensitive paint (PSP). The experiments are conducted for blowing ratios ranging between M = 0.03 and M = 0.28 for a nominal density ratio of 1.5. The density ratio is obtained by using air as the mainstream flow and CO2 as the secondary flow (or coolant source). Results indicate higher coverage and film cooling effectiveness when increasing blowing ratio at the expense of higher pressure drop. In addition, the experimental results are compared to numerical analyses performed using steady state Reynolds Average Navier Stokes (RANS) simulations.
Show less - Date Issued
- 2018
- Identifier
- CFE0007315, ucf:52117
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007315
- Title
- The Study of an Impinging Unsteady Jet - Fluid Mechanics and Heat Transfer Analysis.
- Creator
-
Osorio, Andrea, Kapat, Jayanta, Kinzel, Michael, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
The high heat transfer capabilities of impinging jets have led to their widespread use in industrial applications, such as gas turbine cooling. These impinging jets are usually manufactured on the walls of super-alloy metals and are influenced by being positioned with a confined setting. Studies have been shown to enhance the heat transfer of impinging jets by fluctuating the flow which will be analyzed in this project with two designs. The first design is a self-sustaining stationary fluidic...
Show moreThe high heat transfer capabilities of impinging jets have led to their widespread use in industrial applications, such as gas turbine cooling. These impinging jets are usually manufactured on the walls of super-alloy metals and are influenced by being positioned with a confined setting. Studies have been shown to enhance the heat transfer of impinging jets by fluctuating the flow which will be analyzed in this project with two designs. The first design is a self-sustaining stationary fluidic oscillator that causes a sweeping motion jet to impinge on the surface. This is investigated using Particle Image Velocimetry (PIV) to study the flow field as well as copper- block heated surface to study the heat transfer. The second design involves pulsating the jet through a rotating disk that opens and closes the jet hole, providing a pulsing impingement on the surface. This is examined using hot-wire anemometry for understanding the fluid mechanics and copper-block heated surface to study the heat transfer. Both configurations are tested at a constant Reynolds number of 30,000 with the oscillator tested at normalized jet-to-surface spacings of 3, 4, 6 and the pulsing mechanism tested at jet-to-surface spacing of 3. The results for the fluidic oscillator indicate: Reynolds stress profiles of the jet demonstrated elevated levels of mixing for the fluidic oscillator; heat transfer enhancement was seen in some cases; a confined jet does worse than an unconfined case; and the oscillator's heat removal performed best at lower jet-to- surface spacings. The results for the pulsing mechanism indicate: lower frequencies displayed high turbulence right at the exit of the jet as well as the jet-to-surface spacing of 3; the duty cycle parameter strongly influences the heat transfer results; and heat transfer enhancement was seen for a variation of frequencies.
Show less - Date Issued
- 2018
- Identifier
- CFE0007353, ucf:52102
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007353
- Title
- Surface Measurements and Predictions of Full-Coverage Film Cooling.
- Creator
-
Natsui, Gregory, Kapat, Jayanta, Raghavan, Seetha, Vasu Sumathi, Subith, University of Central Florida
- Abstract / Description
-
Full-coverage film cooling is investigated both experimentally and numerically. First,surface measurements local of adiabatic film cooling eeffectiveness and heat transfer augmentation for four different arrays are described. Reported next is a comparison between two very common turbulence models, Realizable k-epsilon and SST k-omega, and their ability to predict local film cooling effectiveness throughout a full-coverage array.The objective of the experimental study is the quantification of...
Show moreFull-coverage film cooling is investigated both experimentally and numerically. First,surface measurements local of adiabatic film cooling eeffectiveness and heat transfer augmentation for four different arrays are described. Reported next is a comparison between two very common turbulence models, Realizable k-epsilon and SST k-omega, and their ability to predict local film cooling effectiveness throughout a full-coverage array.The objective of the experimental study is the quantification of local heat transferaugmentation and adiabatic film cooling effectiveness for four surfaces cooled by large, both in hole count and in non-dimensional spacing, arrays of film cooling holes. The four arrays are of two different hole-to-hole spacings (P=D = X=D = 14.5; 19.8) and two different hole inclination angles (alpha = 30°; 45°), with cylindrical holes compounded relative to the flow(beta = 45°) and arranged in a staggered configuration. Arrays of up to 30 rows are tested so that the superposition effect of the coolant film can be studied. In addition, shortened arrays of up to 20 rows of coolant holes are also tested so that the decay of the coolant film following injection can be studied.Levels of laterally averaged effectiveness reach values as high as η = 0.5, and are not yet at the asymptotic limit even after 20 - 30 rows of injection for all cases studied. Levels of heat transfer augmentation asymptotically approach values of h=h0 ≈ 1.35 rather quickly, only after 10 rows. It is conjectured that the heat transfer augmentation levels off very quickly due to the boundary layer reaching an equilibrium in which the perturbation from additional film rows has reached a balance with the damping effect resulting from viscosity. The levels of laterally averaged adiabatic film cooling effectiveness far exceeding eta = 0.5 aremuch higher than expected. The heat transfer augmentation levels off quickly as opposed tothe film effectiveness which continues to rise (although asymptotically) at large row numbers. This ensures that an increased row count represents coolant well spent.The numerical predictions are carried out in order to test the ability of the two mostcommon turbulence models to properly predict full-coverage film cooling. The two models chosen, Realizable k-epsilon (RKE) and Shear Stress Transport k-omega (SSTKW), areboth two-equation models coupled with Reynolds Averaged governing equations which makeseveral gross physical assumptions and require several empirical values. Hence, the modelsare not expected to provide perfect results. However, very good average values are seen tobe obtained through these simple models. Using RKE in order to model full-coverage filmcooling will yield results with 30% less error than selecting SSTKW.
Show less - Date Issued
- 2012
- Identifier
- CFE0004580, ucf:49221
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004580
- Title
- Enhancing CNT Composites with Raman Spectroscopy.
- Creator
-
Freihofer, Gregory, Raghavan, Seetha, Gou, Jihua, Zhai, Lei, University of Central Florida
- Abstract / Description
-
Carbon Nanotubes (CNTs) have been the subject of intense research for their potential to improve a variety of material properties when developed as nano-composites. This research aims to address the challenges that limit the ability to transfer the outstanding nano-scale properties of CNTs to bulk nano-composites through Raman characterization.These studies relate the vibrational modes to microstructural characterization of CNT composites including stress, interface behavior, and defects. The...
Show moreCarbon Nanotubes (CNTs) have been the subject of intense research for their potential to improve a variety of material properties when developed as nano-composites. This research aims to address the challenges that limit the ability to transfer the outstanding nano-scale properties of CNTs to bulk nano-composites through Raman characterization.These studies relate the vibrational modes to microstructural characterization of CNT composites including stress, interface behavior, and defects. The formulation of a new fitting procedure using the pseudo-Voigt function is presented and shown to minimizethe uncertainty of characteristics within the Raman G and D doublet. Methods for optimization of manufacturing processes using the Raman characterization are presentedfor selected applications in a polymer multiwalled nanotube (MWNT) composite andlaser-sintered ceramic-MWNT composite. In the first application, the evolution of theMWNT microstructure throughout a functionalization and processing of the polymer-MWNT composite was monitored using the G peak position and D/G intensity ratio.Processing parameters for laser sintering of the ceramic-MWNT composites were optimized by obtaining maximum downshift in stress sensitive G-band peak position, whilekeeping disorder sensitive D/G integrated intensity ratio to a minimum. Advanced Raman techniques, utilizing multiple wavelengths, were used to show that higher excitationenergies are less sensitive to double resonance Raman effects. This reduces their ininfluence and allows the microstructural strain in CNT composites to be probed more accurately. The use of these techniques could be applied to optimize any processing parameters in the manufacturing of CNT composites to achieve enhanced properties.
Show less - Date Issued
- 2011
- Identifier
- CFE0004110, ucf:49098
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004110
- Title
- Design and Optimization of a Wave Energy Harvester Utilizing a Flywheel Energy Storage System.
- Creator
-
Helkin, Steven, Lin, Kuo-Chi, Gordon, Ali, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
This thesis details the design and optimization of a buoy used to collect renewable energy from ocean waves. The proposed buoy is a point absorber(-)a device that transforms the kinetic energy of the vertical motion of surface waves into electrical energy. The focus of the research is on the mechanical system used to collect the energy, and methods to improve it for eventual use in an actual wave energy harvester. A flywheel energy storage system was utilized in order to provide an improved...
Show moreThis thesis details the design and optimization of a buoy used to collect renewable energy from ocean waves. The proposed buoy is a point absorber(-)a device that transforms the kinetic energy of the vertical motion of surface waves into electrical energy. The focus of the research is on the mechanical system used to collect the energy, and methods to improve it for eventual use in an actual wave energy harvester. A flywheel energy storage system was utilized in order to provide an improved power output from the system, even with the intermittent input of force exerted by ocean waves. A series of laboratory prototypes were developed to analyze parameters that are important to the success of the point absorb mechanical system. By introducing a velocity-based load control scheme in conjunction with flywheel energy storage, it was seen that the average power output by the prototype was increased. The generator load is controlled via a relay switch that removes electrical resistance from the generator(-)this sacrifices time during which power is drawn from the system, but also allows the buoy to move with less resistance. A simulation model was developed in order to analyze the theoretical wave absorber system and optimize the velocity threshold parameters used in the load control. Results indicate that the power output by the system can be substantially improved through the use of a flywheel energy storage control scheme that engages and disengages the electrical load based on the rotational velocity of the flywheel system. The results of the optimization are given for varying-sized generator systems input into the simulation in order to observe the associated trends.
Show less - Date Issued
- 2011
- Identifier
- CFE0004118, ucf:49113
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004118
- Title
- Aerodynamic Characteristics of a Gas Turbine Exhaust Diffuser with an Accompanying Exhaust Collection System.
- Creator
-
Bernier, Bryan, Kapat, Jayanta, Deng, Weiwei, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
The effects of an industrial gas turbine's Exhaust Collector Box (ECB) geometry on static pressure recovery and total pressure loss were investigated in this study experimentally and computationally. This study aims to further understand how exit boundary conditions affect the performance of a diffuser system as well as the accuracy of industry standard computational models. A design of experiments approach was taken using a Box-Behnken design method for investigating three geometric...
Show moreThe effects of an industrial gas turbine's Exhaust Collector Box (ECB) geometry on static pressure recovery and total pressure loss were investigated in this study experimentally and computationally. This study aims to further understand how exit boundary conditions affect the performance of a diffuser system as well as the accuracy of industry standard computational models. A design of experiments approach was taken using a Box-Behnken design method for investigating three geometric parameters of the ECB. In this investigation, the exhaust diffuser remained constant through each test, with only the ECB being varied. A system performance analysis was conducted for each geometry using the total pressure loss and static pressure recovery from the diffuser inlet to the ECB exit. Velocity and total pressure profiles obtained with a hotwire anemometer and Kiel probe at the exit of the diffuser and at the exit of the ECB are also presented in this study. A total of 13 different ECB geometries are investigated at a Reynolds number of 60,000. Results obtained from these experimental tests are used to investigate the accuracy of a 3-dimensional RANS with realizable k-? turbulence model from the commercial software package Star-CCM+. The study confirms the existence of strong counter-rotating helical vortices within the ECB which significantly affect the flow within the diffuser. Evidence of a strong recirculation zone within the ECB was found to force separation within the exhaust diffuser which imposed a circumferentially asymmetric pressure field at the inlet of the diffuser. Increasing the ECB width proved to decrease the magnitude of this effect, increasing the diffuser protrusion reduced this effect to a lesser degree. The combined effect of increasing the ECB Length and Width increased the expansion area ratio, proving to increase the system pressure recovery by as much as 19% over the nominal case. Additionally, the realizable k-? turbulence model was able to accurately rank all 13 cases in order by performance; however the predicted magnitudes of the pressure recovery and total pressure loss were poor for the cases with strong vortices. For the large volume cases with weak vortices, the CFD was able to accurately represent the total pressure loss of the system within 5%.
Show less - Date Issued
- 2012
- Identifier
- CFE0004517, ucf:49296
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004517
- Title
- The Effect of Magnetic Bearing on the Vibration and Friction of a Wind Turbine.
- Creator
-
Vorwaller, Mark, Lin, Kuo-Chi, Raghavan, Seetha, Gou, Jihua, University of Central Florida
- Abstract / Description
-
Demands for sustainable energy have resulted in increased interest in wind turbines. Thus, despite widespread economic difficulties, global installed wind power increased by over 20% in 2011 alone. Recently, magnetic bearing technology has been proposed to improve wind turbine performance by mitigating vibration and reducing frictional losses. While magnetic bearing has been shown to reduce friction in other applications, little data has been presented to establish its effect on vibration and...
Show moreDemands for sustainable energy have resulted in increased interest in wind turbines. Thus, despite widespread economic difficulties, global installed wind power increased by over 20% in 2011 alone. Recently, magnetic bearing technology has been proposed to improve wind turbine performance by mitigating vibration and reducing frictional losses. While magnetic bearing has been shown to reduce friction in other applications, little data has been presented to establish its effect on vibration and friction in wind turbines. Accordingly, this study provides a functional method for experimentally evaluating the effect of a magnetic bearing on the vibration and efficiency characteristics of a wind turbine, along with associated results and conclusions.The magnetic bearing under examination is a passive, concentric ring design. Vibration levels, dominant frequency components, and efficiency results are reported for the bearing as tested in two systems: a precision test fixture, and a small commercially available wind turbine. Data is also presented for a geometrically equivalent ball bearing, providing a benchmark for the magnetic bearing's performance. The magnetic bearing is conclusively shown to reduce frictional losses as predicted by the original hypothesis. However, while reducing vibration in the precision test fixture, the magnetic bearing demonstrates increased vibration in the small wind turbine. This is explained in terms of the stiffness and damping of the passive test bearing. Thus, magnetic bearing technology promises to improve wind turbine performance, provided that application specific stiffness and damping characteristics are considered in the bearing design.
Show less - Date Issued
- 2012
- Identifier
- CFE0004452, ucf:49326
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004452
- Title
- Characterization of Dynamic and Static Mechanical Behavior of Polyetherimide.
- Creator
-
Mutter, Nathan, Gordon, Ali, Raghavan, Seetha, Xu, Chengying, University of Central Florida
- Abstract / Description
-
Polymers are increasingly being used in engineering designs due to their favorable mechanical properties such as high specific strength, corrosive resistance, manufacturing flexibility. The understanding of the mechanical behavior of these polymers under both static and dynamic loading is critical for their optimal implementation in engineering applications. One such polymer utilized in a wide variety of applications from medical instrumentation to munitions is Polyetherimide, referred to as...
Show morePolymers are increasingly being used in engineering designs due to their favorable mechanical properties such as high specific strength, corrosive resistance, manufacturing flexibility. The understanding of the mechanical behavior of these polymers under both static and dynamic loading is critical for their optimal implementation in engineering applications. One such polymer utilized in a wide variety of applications from medical instrumentation to munitions is Polyetherimide, referred to as Ultem. This thesis characterizes both the static and dynamic mechanical behavior of Ultem 1000 through experimental methods and numerical simulations. Standard compression experiments were conducted on and MTS test frame to characterize the elastic-plastic behavior of Ultem 1000 under quasi-static conditions. The dynamic response of the material was investigated at very high strain rates using a custom built miniaturized Kolsky bar apparatus. The smaller Kolsky bar configuration was chosen over the conventional Kolsky device to increase the maximum capable strain rates and to reduce common experimental problems such as wave dispersion, friction, and stress equilibrium. Since a universal test standard for this apparatus is not available, the details of the design, construction, and experimental procedures of this device are provided. The results of the high strain rate testing revealed a bilinear relationship between the material yield stress and strain rate. This relationship was modeled using the Ree-Eyring two stage activation process equation.
Show less - Date Issued
- 2012
- Identifier
- CFE0004238, ucf:49533
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004238
- Title
- Thermomechanical Fatigue Life Prediction of Notched 304 Stainless Steel.
- Creator
-
Karl, Justin, Gordon, Ali, Bai, Yuanli, Raghavan, Seetha, Nicholson, David, University of Central Florida
- Abstract / Description
-
The behavior of materials as they are subjected to combined thermal and mechanical fatigue loads is an area of research that carries great significance in a number of engineering applications. Power generation, petrochemical, and aerospace industries operate machinery with expensive components that undergo repeated applications of force while simultaneously being exposed to variable temperature working fluids. A case of considerable importance is found in steam turbines, which subject blades...
Show moreThe behavior of materials as they are subjected to combined thermal and mechanical fatigue loads is an area of research that carries great significance in a number of engineering applications. Power generation, petrochemical, and aerospace industries operate machinery with expensive components that undergo repeated applications of force while simultaneously being exposed to variable temperature working fluids. A case of considerable importance is found in steam turbines, which subject blades to cyclic loads from rotation as well as the passing of heated gases. The complex strain and temperature histories from this type of operation, combined with the geometric profile of the blades, make accurate prediction of service life for such components challenging. Development of a deterministic life prediction model backed by physical data would allow design and operation of turbines with higher efficiency and greater regard for reliability. The majority of thermomechanical fatigue (TMF) life prediction modeling research attempts to correlate basic material property data with simplistic strain and thermal histories. With the exception of very limited cases, these types of efforts have been insufficient and imprecise in their capabilities. Early researchers did not account for the multiple damage mechanisms that operate and interact within a material during TMF loads, and did not adequately address the extent of the relationship between smooth and notched parts. More recent research that adequately recognizes the multivariate nature of TMF develops models that handle life reduction through summation of constitutive damage terms. It is feasible that a modification to the damage-based approach can sufficiently include cases that involve complex geometry. The focus of this research is to construct an experimentally-backed extension of the damage-based approach that improves handling of geometric discontinuities. Smooth and notched specimens of Type 304 stainless steel were subjected to several types of idealized fatigue conditions to assemble a clear picture of the types of damage occurring in a steam turbine and similarly-loaded mechanical systems. These results were compared with a number of idealized TMF experiments, and supplemented by numerical simulation and microscopic observation. A non-uniform damage-summation constitutive model was developed primarily based on physical observations. An additional simplistic model was developed based on phenomenological effect. Findings from this study will be applicable to life prediction efforts in other similar material and load cases.
Show less - Date Issued
- 2013
- Identifier
- CFE0004870, ucf:49666
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004870
- Title
- ZrB2-SiC BASED ULTRA HIGH TEMPERATURE CERAMIC COMPOSITES: MECHANICAL PERFORMANCE AND MEASUREMENT AND DESIGN OF THERMAL RESIDUAL STRESSES FOR HYPERSONIC VEHICLE APPLICATIONS.
- Creator
-
Stadelmann, Richard, Orlovskaya, Nina, Kumar, Ranganathan, Raghavan, Seetha, University of Central Florida
- Abstract / Description
-
Ultra-high temperature ceramics (UHTCs), such as ZrB2-based ceramic composites, have been identified as next generation candidate materials for leading edges and nose cones in hypersonic air breathing vehicles. Mechanical performance of ceramic composites play an important role in the ultra-high temperature applications, therefore SiC is added to ZrB2 as a strengthening phase to enhance its mechanical performance. The high melting temperatures of both ZrB2 and SiC, as well as the ability of...
Show moreUltra-high temperature ceramics (UHTCs), such as ZrB2-based ceramic composites, have been identified as next generation candidate materials for leading edges and nose cones in hypersonic air breathing vehicles. Mechanical performance of ceramic composites play an important role in the ultra-high temperature applications, therefore SiC is added to ZrB2 as a strengthening phase to enhance its mechanical performance. The high melting temperatures of both ZrB2 and SiC, as well as the ability of SiC to form SiO2 refractory oxide layers upon oxidation make ZrB2-SiC ceramics very suitable for aerospace applications. Thermal residual stresses appearing during processing are unavoidable in sintered ZrB2-SiC ceramic composites. Residual microstresses appear at the microstructural level (intergranular microstresses) or at the crystal structure level (intragranular microstresses). These microstresses are of enormous importance for the failure mechanisms in ZrB2-SiC ceramics, such as ratio of the trans- and intergranular fracture; crack branching or bridging, microcracking, subcritical crack growth and others, as they govern crack propagation(-)induced energy dissipation and affect the toughness and strength of the ceramic material. Therefore, understanding the evolution of residual stress state in processed ZrB2-SiC ceramic composites and accurate measurements of these stresses are of high priority. In the present research the ZrB2-17vol%SiC, ZrB2-32vol%SiC, and ZrB2-45vol%SiC ultra-high temperature particulate ceramic composites were sintered using both Hot Pressing (HP) and Spark Plasma Sintering (SPS) techniques. The mechanical performance of the ZrB2-SiC composites was investigated using 3- and 4-point bending techniques for measurements of instantaneous fracture strength and fracture toughness. Resonant Ultrasound Spectroscopy was used for measurement of Young's, shear, and bulk moduli as well as Poisson's ratio of the composites. The distribution of thermal residual stresses and the effect of the applied external load on their re-distribution was studied using micro-Raman spectroscopy. Piezospectroscopic coefficients were determined for all compositions of ZrB2-SiC ceramic under study and their experimentally obtained values were compared with the piezospectroscopic coefficients both published in the literature and calculated using theoretical approach. Finally, the novel ZrB2-IrB2-SiC ceramic composites were also produced using Spark Plasma Sintering (SPS), where IrB2 powder was synthesized using mechanochemical route. It is expected that the IrB2 additive phase might contribute to the improved overall oxidation resistance of ZrB2 based ultra-high temperature ceramic composites.
Show less - Date Issued
- 2015
- Identifier
- CFE0006008, ucf:51004
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0006008