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Title: Closure of unlined landfills.
Creator: Westhorp, Brenda J., Reinhart, Debra R., Engineering
Abstract / Description: University of Central Florida College of Engineering Thesis
Date Issued: 1990
Identifier: CFR0008145, ucf:52954
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFR0008145

Title: REMOVAL OF REFRACTORY TKN FROM AN EFFLUENT WASTEWATER USING SODIUM FERRATE.
Creator: Lettie, Lucia, Reinhart, Debra, University of Central Florida
Abstract / Description: This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent...
Show moreThis research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated with doses of ferrate ranging from 1 to 50 mg/L as FeO4–2 under unbuffered conditions. TKN removal as high as 70% and COD removal greater than 55% was observed. The TSS production after ferrate treatment was in a range of 12 to 200 mg/L for doses between 10 and 50 mg/L FeO4-2. After an optimum dose of ferrate was determined, three bench-scale reactors were operated under anoxic conditions for 10 to 12 days, two as duplicates containing the treated effluent and one as a control with untreated sample. Two different doses of ferrate were used as optimum dose for these experiments, 10 and 25 mg/L as FeO4-2. The purpose of these reactors was to determine the potential for biological removal of remaining nitrogen after ferrate oxidation of refractory nitrogen. Treated and raw samples were analyzed for Total Kjeldahl Nitrogen (TKN) (filtered and unfiltered), chemical oxygen demand (COD) (filtered and unfiltered), total suspended solids (TSS), nitrate (NO3-N), nitrite (NO2-N), and heterotrophic plate count (HPC). As a result, more than 70% of the soluble TKN was removed by chemical and biological oxidation for a sample treated with a dose of 25 mg/L FeO4-2, and less than 50% when treated with 10 mg/L FeO4-2. For the control samples run parallel to the ferrate treated samples, a maximum of 48% of soluble TKN and a minimum of 12% was removed. A three-log increase was observed in heterotrophic bacteria numbers for both doses during the operation of the reactors. Sodium ferrate was found to be an effective oxidant that can enhance the biodegradability of recalcitrant TKN present in municipal wastewaters. As mentioned before this research was develop using batch reactor units at bench-scale, therefore it is recommended to follow the investigation of the biodegradability of recalcitrant TKN of a ferrate treated sample under continuous flow conditions so that results can be extrapolated to a full-scale treatment facility.
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Date Issued: 2006
Identifier: CFE0001247, ucf:46936
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001247

Title: TEMPERATURE INSIDE THE LANDFILL:EFFECTS OF LIQUID INJECTION AND AMBIENT TEMPERATURE.
Creator: kumar, Amit, Reinhart, Debra, University of Central Florida
Abstract / Description: This study represents an analysis of comprehensive temperature and moisture content data collected from the anaerobic portion of a bioreactor landfill at the New River Regional Landfill, Florida, USA. The main focus of the study was the analysis of effects of the liquid injection on the temperature inside the landfill. When the leachate or groundwater at lower temperature than the landfilled waste is injected into the landfill, it has an initial cooling effect on the waste until the...
Show moreThis study represents an analysis of comprehensive temperature and moisture content data collected from the anaerobic portion of a bioreactor landfill at the New River Regional Landfill, Florida, USA. The main focus of the study was the analysis of effects of the liquid injection on the temperature inside the landfill. When the leachate or groundwater at lower temperature than the landfilled waste is injected into the landfill, it has an initial cooling effect on the waste until the biological activity, enhanced by the additional moisture, releases heat. This cooling effect was tested in the study to determine whether it could be used to track moisture arrival as an alternative to moisture sensors. First of all, this hypothesis of cooling effect was tested at the injection wells by correlating temperature drops at the injection wells with known injection events. Then the temperature drop events were identified at monitoring locations where temperature and moisture sensors were co-located. The identification step at the monitoring wells was more difficult than in the case of the injection wells because the cooling effect at the injection well is more pronounced than at the monitoring sites, located 7.62 m away from the point of injection. From the analysis it was found out that, overall, the temperature drop at monitoring locations brought about by the injected liquid is a good criterion for tracking the moisture arrival, however only at the first arrival of moisture. Of all of the cases studied, temperature was able to indicate the moisture arrival for 85% of the times at the first injection as opposed to 36% overall. The difference was attributed to the stimulation of biological activity and subsequent heating of the injected liquid as it moves through the waste. Another focus of the research was the estimation of the waste quantity (volume) wetted from the injection. It was assumed that complete mixing takes places between injected liquid and the moisture already present in the waste and that the temperature of the injected liquid is the ambient temperature. According to the results, there was a significant gap between the expected and the actual wetted volume. The waste volume actually wetted was < 1% to 9% of the total waste volume expected to be wetted. Also studied was the effect of ambient temperature on the waste temperature. It was observed that the ambient temperature has no effect on the global temperature inside a bioreactor landfill even at a shallow depth of 4.6 m. While analyzing the trend of waste temperature inside the landfill, liquid injection was found to lead to an increase in temperature.
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Date Issued: 2007
Identifier: CFE0001905, ucf:47498
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001905

Title: URBAN INFILLING IMPACTS ON FLORIDA SOLID WASTE FACILITIES.
Creator: Nalamothu, Ravi, Reinhart, Debra, University of Central Florida
Abstract / Description: Increasing urbanization in the US is leading to development or re-development of lands adjacent to solid waste facilities and these lands are being considered for residential communities and commercial projects. Thus, the potential for nuisance complaints against the pre-existing solid waste facility operations has become an increasing reality. The objective of this study was to develop a methodology to gather scientific and quantifiable data related to potential nuisances caused by landfills...
Show moreIncreasing urbanization in the US is leading to development or re-development of lands adjacent to solid waste facilities and these lands are being considered for residential communities and commercial projects. Thus, the potential for nuisance complaints against the pre-existing solid waste facility operations has become an increasing reality. The objective of this study was to develop a methodology to gather scientific and quantifiable data related to potential nuisances caused by landfills to determine setbacks and buffer zones near landfill and transfer station operations. Appropriate recommendations for these setbacks were made from case studies conducted at two landfills in Florida. The study involved making measurements related to odor, noise, litter and dust. Impact on housing prices was also evaluated by analyzing publicly available house price data. In this study volatile organic compound (VOC) concentration was used as a surrogate measure for gaseous impacts. The mass flux of VOCs was measured on the landfills using the dynamic flux chamber method. The ultimate purpose of flux measurements was to provide input data for dispersion modeling to analyze the extent of odor impact around the landfills, which is outside the scope of this study. Ambient measurements were also made around Landfill A for validating the dispersion model. Although there are no significant health and odor impacts caused by the landfill, higher background concentration extend 1.2-1.5 km from the landfill center on the Southeast side of the landfill. Litter from the road sides around the landfills was collected and catalogued based on size and material type. Litter count per site obtained for both landfills was less than the 2001 and 2002 state-wide counts. The difference was statistically significant. Noise measurements were made at landfills during incineration and landfilling. Based on average measurements (Leq) obtained at various distances from WTE facility and landfilling activity, and considering EPA recommended noise level of 55 dB(A) for a quiet neighborhood, a set back distance of 1.6-1.9 km was recommended. Impact on house prices near the landfills was done for four landfills in Florida. Analysis showed that three out of four landfills had significantly impacted the house price within 0.6-0.8 km from the edge of the landfill. Dust measurements were made at Landfill B using particulate samplers, quantifying the dust associated with landfilling. Measured values were below National Ambient Air quality Standard (NAAQ) for PM10. Finally, recommendations were developed to mitigate some of these nuisances
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Date Issued: 2007
Identifier: CFE0001948, ucf:47444
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001948

Title: REMOVAL OF 2, 4-DINITROPHENOL BY FERRATE.
Creator: Cooley, Gianna, Reinhart, Debra, University of Central Florida
Abstract / Description: Ferrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants...
Show moreFerrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants that contain 2, 4-Dinitrophenol (DNP). DNP is listed on the United States Environmental Protection Agency (EPA) Drinking Water Contaminant Candidate List (CCL). This list includes compounds which are not currently regulated at the national level, but there is a growing concern for the harm they may cause to the environment. Therefore, the EPA prioritizes these compounds and conducts extensive research to determine if these compounds should be regulated (USEPA, 2005). The effects of Ferrate on DNP were evaluated during these experiments. The effect of various dosages of Ferrate and different pH values was monitored over 17 minutes using UV 254 to determine the extent of oxidation of 300 mg L-1 DNP. Removal of DNP at all pHs and dosages was noted, however, a pH of 4 and a molar ratio of 14: 1 (Ferrate to DNP) removed the highest percentage of DNP at 87.3. The by-products of the 3.5 and 14: 1 molar ratio of Ferrate to DNP reactions at a pH of 4 and their toxicity were determined by measuring biochemical oxygen demand 5 day (BOD5), dissolved organic carbon (DOC), chlorine residual and chemical oxygen demand (COD), and gas chromatography/mass spectrometry (GC/MS) analysis. The BOD5 indicated toxicity, either from the residual chlorine or the organisms used for seeding not being acclimated to DNP and by-products. DOC of the 3.5 : 1 molar ratio was higher than calculated values indicating more ring breakage than was originally measured by UV 254. DOC of the 14: 1 molar ratio experiment was lower than calculated values, which indicated human error in measuring the DNP concentration. The chlorine residual was high for both experiments, 112 and 594 mg L-1, for the 3.5 and 14: 1 molar ratios, respectively. COD was unable to be measured due to chloride interference. The GC/MS data showed several chlorine-substituted benzene rings as well as carbon tetrachloride for the 3.5:1 molar ratio DNP experiments. The 14:1 GC/MS data indicated much more ring breakage with carbon tetrachloride, a substituted butane chain, many unknown straight chain chlorinated compounds and dichloro-pentane isomers as by-products.
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Date Issued: 2008
Identifier: CFE0002438, ucf:47722
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002438

Title: PERFORMANCE BASED DECISION SYSTEM IN DETERMINING POST CLOSURE CARE (PCC) DURATION IN FLORIDA LANDFILLS.
Creator: kulkarni, Asawari, Reinhart, Debra, University of Central Florida
Abstract / Description: This study is an evaluation of Post Closure Care (PCC) duration of landfills using performance based methodology. The post closure care phase begins once the landfill is closed. As required by the Resource Conservation Recovery Act (RCRA) Subtitle D, PCC duration for municipal solid waste landfills is 30 years. During the PCC period, the landfill operator/owner is required to conduct monitoring for leachate, landfill gas, and ground-water and maintain the integrity of the cap so that the...
Show moreThis study is an evaluation of Post Closure Care (PCC) duration of landfills using performance based methodology. The post closure care phase begins once the landfill is closed. As required by the Resource Conservation Recovery Act (RCRA) Subtitle D, PCC duration for municipal solid waste landfills is 30 years. During the PCC period, the landfill operator/owner is required to conduct monitoring for leachate, landfill gas, and ground-water and maintain the integrity of the cap so that the landfill does not impose a threat to surrounding human health and environment (HH&E). The duration of PCC can be reduced by the director of an approved State if an owner/operator of a landfill demonstrates that the landfill exhibits no threat to the surrounding HH&E or can be increased if the director of the approved State determines that an increased PCC period is required for the protection of HH&E. RCRA provides flexibility in optimizing PCC duration of landfills, although it does not identify the criteria/methodology which can be used in demonstrating the status of a landfill from the point of PCC. Researchers worldwide recognize that the threat imposed by a landfill after closure depends on the extent of degradation occurring inside the landfill. The increased functional stability of landfills reduces its risk to the surrounding HH&E. However, there is a wide range of opinions in defining functional stability of a landfill. The present thesis applies performance based methodology, developed by Environmental Research and Education Foundation (EREF), to making a decision on the PCC of landfills. Performance based methodology is a modular approach encompassing all four PCC components of landfills (Leachate, gas, groundwater and cap maintenance). This methodology was applied to Alachua County Southwest Landfill (ACSWLF) in Alachua County, Florida. Each module was analyzed individually and recommendations on the PCC monitoring at the landfill site were provided.
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Date Issued: 2008
Identifier: CFE0002471, ucf:47700
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002471

Title: DEWATERING OF BIOSOLIDS BY SODIUM FERRATE.
Creator: Rios, Andrea, Reinhart, Debra, University of Central Florida
Abstract / Description: This study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge...
Show moreThis study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge after conditioning were used. For centrifugation the volume reduction and the turbidity of the supernatant after centrifugation were evaluated. For filtration, the Capillary Suction Time test was used. The optimum doses and conditions for dewatering of the sludge using ferrate were determined for each type of sludge. The centrifugation and filtration results were compared with those obtained for polymer doses currently used at the wastewater treatment plants where the samples were collected and with ferric coagulants as well. The results of this research indicated that optimum pH was 7.0. The time required to achieve mechanical equilibrium defined as the time at which the volume occupied by the solids was no more than one percent of the preceding reading was 1800 seconds for both types of sludge. The optimum rotational speeds were 800 and 2400 for waste activated sludge and anaerobic digested sludge, respectively. The optimum ferrate dose for anaerobic digested sludge for centrifugation and filtration was 5000 mg/l. For waste activated sludge a dose of 10 mg/l was found to be effective for filtration and centrifugation. The results indicated that the ferrate product prepared using calcium hypochlorite provides better results for the waste activated sludge than the ferrate prepared using sodium hypochlorite, while for anaerobic digested sludge no significant difference was observed. Finally, the results show that ferrate is a cost-effective alternative for the conditioning and disinfection of waste activated sludge, but not for the conditioning of anaerobic digested sludge.
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Date Issued: 2004
Identifier: CFE0000276, ucf:46235
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000276

Title: IN-SITU AMMONIA REMOVAL OF LEACHATE FROM BIOREACTOR LANDFILLS.
Creator: Berge, Nicole, Reinhart, Debra, University of Central Florida
Abstract / Description: A new and promising trend in solid waste management is to operate the landfill as a bioreactor. Bioreactor landfills are controlled systems in which moisture addition and/or air injection are used as enhancements to create a solid waste environment capable of actively degrading the biodegradable organic fraction of the waste. Although there are many advantages associated with bioreactor landfills, some challenges remain. One such challenge is the ammonia-nitrogen concentration found in the...
Show moreA new and promising trend in solid waste management is to operate the landfill as a bioreactor. Bioreactor landfills are controlled systems in which moisture addition and/or air injection are used as enhancements to create a solid waste environment capable of actively degrading the biodegradable organic fraction of the waste. Although there are many advantages associated with bioreactor landfills, some challenges remain. One such challenge is the ammonia-nitrogen concentration found in the leachate. The concentrations of ammonia-nitrogen tend to increase beyond concentrations found in leachate from conventional landfills because recirculating leachate increases the rate of ammonification and results in accumulation of higher levels of ammonia-nitrogen concentrations, even after the organic fraction of the waste is stabilized. Because ammonia-nitrogen persists even after the organic fraction of the waste is stabilized, and because of its toxic nature, it is likely that ammonia-nitrogen will determine when the landfill is biologically stable and when post-closure monitoring may end. Thus an understanding of the fate of nitrogen in bioreactor landfills is critical to a successful and economic operation. Ammonia-nitrogen is typically removed from leachate outside of the landfill. However, additional costs are associated with ex-situ treatment of ammonia, as separate treatment units on site must be maintained or the leachate must be pumped to a publicly owned wastewater treatment facility. Therefore, the development of an in-situ nitrogen removal technique would be an attractive alternative. Several recent in-situ treatment approaches have been explored, but lacked the information necessary for field-scale implementation. The objectives of this study were to develop information necessary to implement in-situ ammonia removal at the field-scale. Research was conducted to evaluate the kinetics of in-situ ammonia removal and to subsequently develop guidance for field-scale implementation. An aerobic reactor and microcosms containing digested municipal solid waste were operated and parameters were measured to determine nitrification kinetics under conditions likely found in bioreactor landfills. The environmental conditions evaluated include: ammonia concentration (500 and 1000mg N/L), temperature (25o, 35o and 45oC), and oxygen concentration in the gas-phase (5, 17 and 100%). Results suggest that in-situ nitrification is feasible and that the potential for simultaneous nitrification and denitrification in field-scale bioreactor landfills is significant due to the presence of both aerobic and anoxic areas. All rate data were fitted to the Monod equation, resulting in an equation that describes the impact of pH, oxygen concentration, ammonia concentration, and temperature on ammonia removal. In order to provide design information for a field-scale study, a simple mass balance model was constructed in FORTRAN to forecast the fate of ammonia injected into a nitrifying portion of a landfill. Based on model results, an economic analysis of the in-situ treatment method was conducted and compared to current ex-situ leachate treatment costs. In-situ nitrification is a cost effective method for removing ammonia-nitrogen when employed in older waste environments. Compared to reported on-site treatment costs, the costs associated with the in-situ ammonia removal process fall within and are on the lower end of the range found in the literature. When compared to treating the leachate off-site, the costs of the in-situ ammonia removal process are always significantly lower. Validation of the laboratory results with a field-scale study is needed.
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Date Issued: 2006
Identifier: CFE0000963, ucf:46695
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000963

Title: CHEMICAL AND BIOLOGICAL TREATMENT OF MATURE LANDFILLLEACHATE.
Creator: Batarseh, Eyad, Reinhart, Debra, University of Central Florida
Abstract / Description: This dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells....
Show moreThis dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells. Results from this research demonstrated that ferrate and Fenton's reagent had similar optimum pH ranges (3-5), but different organic removal capacities, ranging from 54 to 79 % of initial leachate organic contents. An advantage of ferrate was that it was relatively effective over a wide pH range (Fenton's reagent lost its reactivity outside optimum pH range). Advantages associated with Fenton's reagent include a higher organic removal capacity, production of more oxidized organic compounds (measured as chemical oxygen demand/dissolved organic carbon), and production of more biodegradable byproducts (measured as 5-day biochemical oxygen demand/chemical oxygen demand). Finally, both treatments were found to oxidize larger molecules (>1000 dalton) and produce smaller molecules, as indicated by an increase in smaller molecule contribution to organic carbon. In part two, effects of Fenton's reagent treatment on biodegradability of three landfill leachates collected from a Florida landfill were evaluated using biochemical oxygen demand (BOD), biochemical methane potential (BMP), and tertamethylammonium hydroxide (TMAH) thermochemolysis gas chromatography/mass spectrometry (GC/MS). The hypothesis was that Fenton's reagent will remove refractory compounds that inhibit biodegradation and will produce smaller, more biodegradable organic molecules which will result in an increase in BOD and BMP values. Both BOD and BMP results demonstrated that Fenton's reagent treatment did not convert mature leachate to biodegradable leachate, as indicated by a low BOD5 expressed as C /dissolved organic carbon (DOC) ratio of almost 0.15 in treated samples and a low net methane production / theoretical methane potential (less than 0.15). Ultimate BOD only slightly increased. However the first-order BOD reaction rate increased by more than five fold, suggesting that Fenton's reagent removed refractory and inhibitory compounds. BMP results demonstrated that the ratio of CO2/CH4 produced during anaerobic biodegradation did not increase in treated leachate (compared to untreated), indicating that small biodegradable organic acids produced by oxidation were removed by coagulation promoted by Fenton's reagent. Finally, the TMAH thermochemolysis results showed that several of the refractory and inhibitory compounds were detected fewer times in treated samples and that carboxylic acids did not appear in treated samples. In the third part of this dissertation the application of flushing/Fenton's reagent oxidation to produce sustainable solid waste cells was evaluated. A treatment similar to pump and treat process utilizing Fenton's reagent on-site treated leachate combined with in-situ aeration was proposed. Treated leachate would be recycled to the landfill cell flushes releasable nonbiodegradable carbon from the cell and oxidizes it externally. This technique was demonstrated to have treatment cost and time benefits over other alternatives for producing completely stable solid waste cells such as anaerobic flushing and biological and/or mechanical pretreatment of solid waste (used in the EU).
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Date Issued: 2006
Identifier: CFE0001276, ucf:46912
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001276

Title: ORGANIZATIONAL ACCOUNTABILITY IN THE WATER AND SANITATION HYGIENE SECTOR: INTEGRATING SUSTAINABILITY FACTORS INTO THE DEFINITION OF SUCCESS.
Creator: Jeanis, Kaitlyn, Reinhart, Debra, University of Central Florida
Abstract / Description: The world's poorest people, most of whom reside in under-developed nations, lack access to clean water and sanitation facilities, nutritious food, and education (UMP, 2005). These conditions are linked to malnutrition, disease, and low life expectancies (WHO). In an effort to reduce global poverty, the United Nations (UN) adopted the Millennium Development Goals (MDGs). Under Goal 7c the UN denotes that by 2015 the population without sustainable access to safe drinking water and basic...
Show moreThe world's poorest people, most of whom reside in under-developed nations, lack access to clean water and sanitation facilities, nutritious food, and education (UMP, 2005). These conditions are linked to malnutrition, disease, and low life expectancies (WHO). In an effort to reduce global poverty, the United Nations (UN) adopted the Millennium Development Goals (MDGs). Under Goal 7c the UN denotes that by 2015 the population without sustainable access to safe drinking water and basic sanitation as compared to the proportion who do should be halved. As a response to this objective the international development (ID) sector has implemented projects aimed at increasing access to clean water and sanitation facilities, yet reports of high rate of project failure continue (Ika, 2012). In this thesis factors contributing to project failures are outlined based on the literature. In response to these findings this thesis explores the components of sustainability as it relates to the WASH sector and creates a framework for minimum standards that should be met in order for a WASH project to be considered successful. These standards are adapted based on the World Health Organization (WHO), a project funded by the Bill and Melinda Gates Foundation that evaluates WASH projects called WASHCost, as well as the standards proposed by Carter et al (1999). Furthermore, it is argued that if implementing organizations are expected to monitor, evaluate and report on the environmental, social, economic as well as technical components of their implemented project, it will create a level of transparency that promotes organizational accountability that will inherently cause a shift towards more effective WASH projects.
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Date Issued: 2014
Identifier: CFH0004632, ucf:45258
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH0004632

Title: COMPARISON OF THE EFFECTIVENESS OF ALTERNATIVE FERRATE (VI) SYNTHESIS FORMULAS AS DISINFECTANTS FOR WASTEWATER AND RIVER WATER.
Creator: Ginart, Rachelle, Reinhart, Debra, University of Central Florida
Abstract / Description: Ferrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of...
Show moreFerrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of hypochlorite (Low Chlorine Formula) while the other ferrate (VI) synthesis formula uses more than the stoichiometric requirement of hypochlorite (Standard Chlorine Formula). For applications requiring low chlorine residual effluent quality, the Low Chlorine Formula intuitively is a more suitable disinfectant than the Standard Formula. For applications where chlorine residual is of little or no significance, the Standard Formula is logically a more suitable disinfectant due to lower production cost and production of higher ferrate (VI) concentrations than the Low Chlorine Formula. The total chlorine concentration, unfiltered and filtered ferrate (VI) concentration, and dissolved organic carbon concentration before and after treatment using both ferrate (VI) formulas in wastewater and Econ River water was measured at a contact time of 30 minutes. Disinfection capabilities were measured by comparing the quantity of Heterotrophic bacteria, Total Coliform, Escherichia coli, and Enterococcus bacteria pre-ferrate (VI) to post-ferrate (VI) at dosages of 2, 4, and 7.5 mg/L as ferrate (VI) using both ferrate (VI) formulas. The rate of disappearance of both ferrate (VI) formulas in wastewater at an unadjusted pH and pH of 6.0-6.35 was determined. In addition the total oxidant absorbance and total chlorine concentration were measured over a 30-minute period. Both ferrate (VI) formulas were effective at inactivating Total Coliform, E. Coli, Enterococcus, and heterotrophic bacteria at a 30-minute contact time and lowering DOC concentrations in Econlockhatchee River water and secondary wastewater. The Standard Formula demonstrated better disinfection at lower dosages than the Low Chlorine Formula. In both ferrate (VI) formulas, there was a presence of an instantaneous demand of ferrate (VI) and a first-order reaction rate of ferrate (VI) over 30 minutes. The chlorine residual of 7.5 mg/L ferrate (VI) dose in wastewater at a 30-minute contact time was 0.2 to 0.6 mg/L Cl2 for the Low Chlorine Formula and 0.8 to 1.4 mg/L Cl2 for the Standard Formula. These experiments indicate that both ferrate (VI) formulas can serve as effective environmentally friendly disinfectants for wastewater and Econ River water.
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Date Issued: 2008
Identifier: CFE0002284, ucf:47843
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002284

Title: HYDROGEN SULFIDE FLUX MEASUREMENTS AND DISPERSION MODELING FROM CONSTRUCTION AND DEMOLITION (C&D) DEBRIS LANDFILLS.
Creator: Eun, Sangho, Reinhart, Debra, University of Central Florida
Abstract / Description: Odor problems are a common complaint from residents living near landfills. Many compounds can cause malodorous conditions. However, hydrogen sulfide (h2s) has been identified as a principal odorous component from construction and demolition (c&d)debris landfills. Although several studies have reported the ambient concentrations of h2s near c&d landfills, few studies have quantified emission rates of h2s. The most widely used and proven technique for measuring gas emission rates from...
Show moreOdor problems are a common complaint from residents living near landfills. Many compounds can cause malodorous conditions. However, hydrogen sulfide (h2s) has been identified as a principal odorous component from construction and demolition (c&d)debris landfills. Although several studies have reported the ambient concentrations of h2s near c&d landfills, few studies have quantified emission rates of h2s. The most widely used and proven technique for measuring gas emission rates from landfills is the flux chamber method. Typically the flux chamber is a cylindrical enclosure device with a spherical top which limits the gas emission area. Pure zero grade air is introduced into the chamber, allowed to mix with emitting gases captured from the landfill surface, and then transported to the exit port where concentrations can be measured. Flux measurements using the flux chamber were performed at five different c&d landfills from june to august, 2003. The flux rates of h2s measured in this research were three to six orders of magnitude lower than the flux rates of methane reported in the literature. In addition to the h2s flux measurements, dispersion modeling was conducted, using the epa dispersion model, industrial source complex short term (iscst3), in order to evaluate impacts on landfill workers and communities around the landfills. The modeling results were analyzed to estimate the potential ground level maximum h2s concentrations for 1-hr and 3-min periods and the frequency (occurrences per year) above the h2s odor detection threshold for each landfill. Odor complaints could be expected from four among five landfills selected for this study, based on 0.5-ppb odor detection threshold.
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Date Issued: 2004
Identifier: CFE0000169, ucf:52837
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000169

Title: CONTROL OF HYDROGEN SULFIDE EMISSIONSUSING AUTOTROPHIC DENITRIFICATIONLANDFILL BIOCOVERS.
Creator: Sungthong, Daoroong, Reinhart, Debra, University of Central Florida
Abstract / Description: Hydrogen sulfide (H2S), a major odorous component emitted from construction and demolition debris landfills, has received increasing attention. Besides its unpleasant odor, long-term exposure to a very low concentration of H2S can cause a public health issue. Although cover materials such as soil and compost are recommended to be used routinely to control an odor problem from the landfills, the problem still remains. Autotrophic denitrification may have environmental applications including...
Show moreHydrogen sulfide (H2S), a major odorous component emitted from construction and demolition debris landfills, has received increasing attention. Besides its unpleasant odor, long-term exposure to a very low concentration of H2S can cause a public health issue. Although cover materials such as soil and compost are recommended to be used routinely to control an odor problem from the landfills, the problem still remains. Autotrophic denitrification may have environmental applications including treatment of water, groundwater, wastewater or gaseous streams contaminated with sulfur and/or nitrogen compounds. However, there have been no studies reported in the literature on H2S removal using autotrophic denitrification from landfills. This study, therefore, investigated the application of autotrophic denitrification incorporated into landfill covers in order to evaluate the feasibility of controlling H2S emissions generated from landfills. Research was investigated by two techniques, microcosm and laboratory-scale column studies. The microcosm experiments were conducted to evaluate the kinetics of autotrophic denitrification in various cover materials with H2S-nitrate as electron donor-acceptor couple. Cover materials including soil, compost and sand were tested and nitrate was added. Based on the microcosm study results, the addition of nitrate into soil and compost can stimulate indigenous autotrophic denitrifying bacteria which are capable of H2S oxidation biologically under anoxic conditions. Results also demonstrated that some amount of H2S can be removed physically and chemically by soil or compost. There was no H2S removal observed in sand microcosms. Rapid H2S oxidation to sulfate was achieved, especially in soil. Zero-order kinetics described the H2S oxidation rate in soil and compost microcosms. The rates of sulfide oxidation under autotrophic denitrification in soil and compost were 2.57 mg H2S/d-g dry soil and 0.17 mg H2S/d-g dry compost, respectively. To further explore H2S removal in a landfill biocover, two sets of column experiments were run. The first set of columns contained seven cm of soil. The autotrophic column was prepared with 1.94 mg KNO3/g dry soil; an identical control column was prepared without nitrate. A gas stream was introduced to the columns with a H2S concentration of 930 ppm. The second set contained seven cm of soil, with both an autotrophic (0.499 mg KNO3/g dry soil) and a control column. Influent H2S concentration was 140 ppm for the second set. Column studies supported the results of microcosm studies; removal of H2S was observed in all columns due to the capacity for soil to absorb H2S, however autotrophic columns removed significantly more. The higher concentration of H2S resulted in partial oxidation to elemental sulfur, while sulfate was found at levels predicted by stoichiometric relationships at the lower concentration. H2S oxidation in the column with higher loading was found to follow zero-order kinetics. The rate of H2S oxidation was 0.46 mg H2S removed/d-g dry soil. Economic comparison of cover systems including autotrophic denitrification, soil amended with lime, fine concrete, and compost covers were analyzed. Based on a case-study landfill area of 0.04 km2, the estimated H2S emissions of 80,900 kg over the 15-year period and costs of active cover system components (ammonium nitrate fertilizer, lime, concrete and compost), autotrophic denitrification cover was determined to be the most cost-effective method for controlling H2S emissions from landfills.
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Date Issued: 2010
Identifier: CFE0003283, ucf:48537
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003283

Title: LANDFILL GAS TO ENERGY: INCENTIVES & BENEFITS.
Creator: Amini, Hamid, Reinhart, Debra, University of Central Florida
Abstract / Description: Municipal solid waste (MSW) management strategies typically include a combination of three approaches, recycling, combustion, and landfill disposal. In the US approximately 54% of the generated MSW was landfilled in 2008, mainly because of its simplicity and cost-effectiveness. However, landfills remain a major concern due to potential landfill gas (LFG) emissions, generated from the chemical and biological processes occurring in the disposed waste. The main components of LFG are methane (50...
Show moreMunicipal solid waste (MSW) management strategies typically include a combination of three approaches, recycling, combustion, and landfill disposal. In the US approximately 54% of the generated MSW was landfilled in 2008, mainly because of its simplicity and cost-effectiveness. However, landfills remain a major concern due to potential landfill gas (LFG) emissions, generated from the chemical and biological processes occurring in the disposed waste. The main components of LFG are methane (50-60%) and carbon dioxide (40-50%). Although LFG poses a threat to the environment, if managed properly it is a valuable energy resource due to the methane content. Currently there are over 550 active LFG to energy (LFGTE) facilities in the US, producing renewable energy from LFG. A major challenge in designing/operating a LFGTE facility is the uncertainty in LFG generation rate predictions. LFG generation rates are currently estimated using models that are dependent upon the waste disposal history, moisture content, cover type, and gas collection system, which are associated with significant uncertainties. The objectives of this research were to: (1) Evaluate various approaches of estimating LFG generation and to quantify the uncertainty of the model outcomes based on case-study analysis, (2) Present a methodology to predict long-term LFGTE potential under various operating practices on a regional scale, and (3) Investigate costs and benefits of emitting vs. collecting LFG emissions with regards to operation strategies and regulations. The first-order empirical model appeared to be insensitive to the approach taken in quantifying the model parameters, suggesting that the model may be inadequate to accurately describe LFG generation and collection. The uncertainty values for the model were, in general, at their lowest within five years after waste placement ended. Because of the exponential nature, the uncertainty increased as LFG generation declined to low values decades after the end of waste placement. A methodology was presented to estimate LFGTE potential on a regional scale over a 25-year timeframe with consideration of modeling uncertainties. The methodology was demonstrated for the US state of Florida, and showed that Florida could increase the annual LFGTE production by more than threefold by 2035 through installation of LFGTE facilities at all landfills. Results showed that diverting food waste could significantly reduce fugitive LFG emissions, while having minimal effect on the LFGTE potential. Estimates showed that with enhanced landfill operation and energy production practices, LFGTE power density could be comparable to technologies such as wind, tidal, and geothermal. More aggressive operations must be considered to avoid fugitive LFG emissions, which could significantly affect the economic viability of landfills. With little economic motivation for US landfill owners to voluntarily reduce fugitive emissions, regulations are necessary to increase the cost of emitting GHGs. In light of the recent economic recession, it is not likely that a carbon tax will be established; while a carbon trading program will enforce emission caps and provide a tool to offset some costs and improve emission-reduction systems. Immediate action establishing a US carbon trading market with carbon credit pricing and trading supervised by the federal government may be the solution. Costs of achieving high lifetime LFG collection efficiencies are unlikely to be covered with revenues from tipping fee, electricity sales, tax credits, or carbon credit trading. Under scenarios of highly regulated LFG emissions, sustainable landfilling will require research, development, and application of technologies to reduce the marginal abatement cost, including: (1) Diverting rapidly decomposable waste to alternative treatment methods, (2) Reducing fugitive emissions through usage daily/intermediate covers with high oxidation potential, (3) Increasing the lifetime LFG collection efficiency, and (4) Increasing LFG energy value - for instance by producing high-methane gas through biologically altering the LFG generation pathway.
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Date Issued: 2011
Identifier: CFE0003960, ucf:48682
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003960

Title: USE OF VEGETATIVE MULCH AS DAILY AND INTERMEDIATE LANDFILL COVER.
Creator: Haddad, Assal, Reinhart, Debra, University of Central Florida
Abstract / Description: Management of yard waste is a significant challenge in the US, where in 2008 13.2% of the 250 million tons of municipal solid waste (MSW) was reported to be yard waste. This study describes research conducted in the laboratory and field to examine the application of vegetative mulch as daily and intermediate landfill cover. Mulch was found to exhibit stronger physical properties than soil, leading to a more stable landfill slope. Compaction of mulch was found to be significantly greater than...
Show moreManagement of yard waste is a significant challenge in the US, where in 2008 13.2% of the 250 million tons of municipal solid waste (MSW) was reported to be yard waste. This study describes research conducted in the laboratory and field to examine the application of vegetative mulch as daily and intermediate landfill cover. Mulch was found to exhibit stronger physical properties than soil, leading to a more stable landfill slope. Compaction of mulch was found to be significantly greater than soil, potentially resulting in airspace recovery. Degradation of mulch produced a soil-like material; degradation resulted in lower physical strength and hydraulic conductivity and higher bulk density when compared with fresh mulch. Mulch covers in the field permitted higher infiltration rates at high rain intensities than soil covers, and also generated less runoff due to greater porosity and hydraulic conductivity as compared to soil. Mulch covers appear to promote methane oxidation more than soil covers, although it should be noted that methane input to mulch covers was more than an order of magnitude greater than to soil plots. Life cycle assessment (LCA) showed that, considering carbon sequestration, use of green waste as landfill cover saves GHG emissions and is a better environmental management option compared to composting and use of green waste as biofuel.
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Date Issued: 2011
Identifier: CFE0003605, ucf:48880
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003605

Title: CHARACTERIZING SPONTANEOUS FIRES IN LANDFILLS.
Creator: Moqbel, Shadi, Reinhart, Debra, University of Central Florida
Abstract / Description: Landfill fires are relatively common incidents that landfill operators encounter which have great impact on landfill structure and the environment. According to a U.S. Fire Administration report in 2001, an average of 8,300 landfill fires occurs each year in the United States, most of them in the spring and summer months. Subsurface spontaneous fires are considered the most dangerous and difficult to detect and extinguish among landfill fires. Few studies have been conducted on spontaneous...
Show moreLandfill fires are relatively common incidents that landfill operators encounter which have great impact on landfill structure and the environment. According to a U.S. Fire Administration report in 2001, an average of 8,300 landfill fires occurs each year in the United States, most of them in the spring and summer months. Subsurface spontaneous fires are considered the most dangerous and difficult to detect and extinguish among landfill fires. Few studies have been conducted on spontaneous fires in landfills. Information regarding the thermal behavior of solid waste is not available nor have measurements been made to evaluate spontaneous ignition of solid waste. The purpose of this research was to provide information concerning the initiation of spontaneous ignition incidents in landfills, and investigate the conditions favoring their occurrence. This study enabled better understanding of the self-heating process and spontaneous combustion in landfills. Effects of parameters critical to landfill operation on spontaneous combustion were determined. Spontaneous combustion occurs when materials are heated beyond the ignition temperature. Temperature rise occurs inside the landfill due to exothermic reactions which cause self-heating of the solid waste. Oxygen introduction leading to biological waste degradation and chemical oxidation is believed to be the main cause of rising solid waste temperatures to the point of ignition. A survey was distributed to landfill operators collecting information regarding spontaneous firs incidents in their landfills. Survey results raised new questions necessitating further study of subsurface fires incidents. Subsurface spontaneous fires were not restricted to any landfill geometry or type of waste (municipal, industrial, commercial, and construction and demolition). Results showed that landfill fires occur in landfills that do and do not recirculate leachate. Although new methods have been developed to detect subsurface fires, landfill operators depend primarily on visual observation of smoke or steam to detect the subsurface fires. Also, survey results indicated that excavating and covering with soil are the most widespread methods for extinguishing subsurface fires. Methane often has been suspected for initiating spontaneous subsurface firs in the landfill. However, combustible mixture of methane and oxygen requires very high temperature to ignite. In this study it was shown that spontaneous fires are initiated by solid materials with lower ignition points. Laboratory tests were conducted evaluating the effect of moisture content, oxygen concentration and leachate on spontaneous ignition of solid waste. A new procedure for testing spontaneous ignition is described based on the crossing-point method. The procedure was used to study the spontaneous combustion of solid waste and determine the auto-ignition temperature of the solid waste components and a synthesized solid waste. Correlations have been established between auto-ignition temperature, specific weight and energy content and between self-heating temperature and specific weight. Correlations indicated that compaction can help avoid spontaneous combustion in the landfill. Dense materials require higher energy to increase in temperature and limit the accessibility of oxygen. In the experimental work, moisture was found to promote both biological and chemical self-heating. Increasing moisture content lowers the solid waste permeability and absorbs more energy as it evaporates. Dissolved solids in leachate were found to promote self-heating and ignition more than distilled water. Varying oxygen concentrations indicated that heat generation occurs due to chemical oxidation even at oxygen concentration as low as 10% by volume. However, at 10% by volume oxygen, solid waste did not exhibit thermal runaway nor flammable combustion. At 0% by volume oxygen, tests results indicated occurrence of self-heating due to slow pyrolysis. A numerical one-dimensional energy model was created to simulate temperature rise in landfill for four different scenarios. Using the results from the laboratory experiment, the model estimated the heat generation in solid waste due to chemical reactions. Results from the scenario simulations indicated that moisture evaporation is the major heat sink in the landfill. The model showed that gas flow has a cooling effect due to increasing amount of evaporated water and can control the temperature inside the landfill. The model showed that a temperature higher than the biological limit can be maintained in the landfill without initiating spontaneous fire.
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Date Issued: 2009
Identifier: CFE0002589, ucf:48275
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002589

Title: MODELING MICROBIOLOGICAL AND CHEMICAL PROCESSES IN MUNICIPAL SOLID WASTE BIOREACTOR: DEVELOPMENT AND APPLICATIONS OF A THREE-PHASE NUMERICAL MODEL BIOKEMOD-3P.
Creator: Gawande, Nitin, Reinhart, Debra, University of Central Florida
Abstract / Description: The numerical computer models that simulate municipal solid waste (MSW) bioreactor landfills have mainly two components – a biodegradation process module and a multi-phase flow module. The biodegradation model describes the chemical and microbiological processes of solid waste biodegradation. The models available to date include predefined solid waste biodegradation reactions and participating species. In a bioreactor landfill several processes, such as anaerobic and aerobic...
Show moreThe numerical computer models that simulate municipal solid waste (MSW) bioreactor landfills have mainly two components – a biodegradation process module and a multi-phase flow module. The biodegradation model describes the chemical and microbiological processes of solid waste biodegradation. The models available to date include predefined solid waste biodegradation reactions and participating species. In a bioreactor landfill several processes, such as anaerobic and aerobic biodegradation, nitrogen and sulfate cycling, precipitation and dissolution of metals, and adsorption and gasification of various anthropogenic organic compounds, occur simultaneously. These processes may involve reactions of several species and the available biochemical models for solid waste biodegradation do not provide users with the flexibility to selectively simulate these processes. This research work includes the development of a generalized biochemical process model, BIOKEMOD-3P, which can accommodate a large number of species and process reactions. This model is able to simulate bioreactor landfill processes in a completely mixed condition; when coupled with a multi-phase model it will be able to simulate a full-scale bioreactor landfill. This generalized biochemical model can simulate laboratory and pilot-scale operations which are important to determine biochemical parameters important for simulation of full-scale operations. To illustrate application of BIOKEMOD-3P, two sets of laboratory MSW bioreactors were simulated in this research work. The first demonstrated simulation of data from anaerobic biodegradation of MSW in experimental bioreactors. In another application, simultaneous nitrification and denitrification processes in MSW bioreactors were simulated. The results from these simulations generated information about various modeling parameters that would help implement these processes in a full-scale bioreactor landfill operation.
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Date Issued: 2009
Identifier: CFE0002659, ucf:48227
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002659

Title: Characterization of Florida Landfills with Elevated Temperatures.
Creator: Joslyn, Ryan, Reinhart, Debra, Lee, Woo Hyoung, Randall, Andrew, University of Central Florida
Abstract / Description: The occurrence of elevated temperatures within landfills is a very challenging issue for landfill operators to detect and correct. Little is known regarding the causes of elevated temperatures (ETs) and the number of landfills currently operating under such conditions. Therefore, the goal of this research was to determine which landfills within Florida have been impacted by ETs, and to develop a more complete understanding of the factors that may lead to these landfills becoming elevated...
Show moreThe occurrence of elevated temperatures within landfills is a very challenging issue for landfill operators to detect and correct. Little is known regarding the causes of elevated temperatures (ETs) and the number of landfills currently operating under such conditions. Therefore, the goal of this research was to determine which landfills within Florida have been impacted by ETs, and to develop a more complete understanding of the factors that may lead to these landfills becoming elevated temperature landfills (ETLFs). Historical landfill gas wellhead data, waste deposition reports, and landfill site geometry were collected for 27 landfill cells through the FDEP OCULUS database and from landfill operators and owners. These data were evaluated to quantify the statistical characteristics that result in landfills becoming 'elevated' in temperature. Gas data included landfill gas temperatures, methane content, carbon dioxide content, and balance gas readings. Waste deposition information was gathered through solid waste reports for each landfill. Landfill site geometry was found through landfill permits, topographical landfill diagrams, and annual operation reports. Furthermore, landfill maps were created in ArcGIS to observe spatial distribution of ETs in landfills over time.Upon analysis of the landfill gas wellhead data, it was discovered that 74% of studied landfill cells had ET readings; regulatory limits specify a maximum allowable gas temperature of 55 degrees C (131 degrees F). When studying the solid waste reports, it was discovered that 37% of landfill cells contained MSW ash; of these cells, 90% of them are considered ETLFs. Regarding site geometry, it was found that ETLF cells are on-average double the site area and approximately 20 feet deeper than the average non-ETLF cell. Furthermore, results suggest that heat propagation in most landfills is limited; however, heat propagation is possible if gas wells are turned off for an extensive time period.
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Date Issued: 2019
Identifier: CFE0007471, ucf:52690
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007471

Title: Construction and Demolition Debris Recovery and Recycling in Orange County, FL.
Creator: Toth, Michael, Reinhart, Debra, Behzadan, Amir, Randall, Andrew, University of Central Florida
Abstract / Description: In 2008, the State of Florida established a recycling goal of 75% to be achieved by 2020. In response to the Florida goal Orange County (OC), Florida has made the development and implementation of an efficient strategy for landfill diversion of its solid waste a top priority. The Florida Department of Environmental Protection (FDEP) estimated that 23% of municipal solid waste was generated by construction and demolition (C&D) activities in 2009, with only 30 percent of C&D debris being...
Show moreIn 2008, the State of Florida established a recycling goal of 75% to be achieved by 2020. In response to the Florida goal Orange County (OC), Florida has made the development and implementation of an efficient strategy for landfill diversion of its solid waste a top priority. The Florida Department of Environmental Protection (FDEP) estimated that 23% of municipal solid waste was generated by construction and demolition (C&D) activities in 2009, with only 30 percent of C&D debris being recycled. Therefore, OC decided to create a solid waste integrated resource plan (SWIRP) initially focused on the recovery and recycling of C&D materials (2010). For SWIRP development, OC decision makers need the best available data regarding C&D debris generation and composition and an understanding of the potential markets available for recycled materials. In this investigation debris generation was estimated over the period of 2001 to 2009 for the largest single governing body within OC, unincorporated OC (UOC), representing 65 percent of county population. The debris generation model was constructed for years 2001-2010 using area values for C&D activities in six sectors obtained from building permits and debris generation multipliers obtained from literature values. The benefit of the model is that as building permit information is received, debris generation estimations can also be expediently updated. Material composition fractions obtained from waste characterization studies of landfills in the Central Florida area were applied to the debris generation model resulting in a material composition for all sectors for years 2001-2010. The material composition of the debris stream was found to be, on average, concrete (53%) drywall (20%), wood (12%), a miscellaneous fraction (8%), asphalt roofing material (4%), metal (2%), cardboard (1%) and carpet and padding (1%). A market analysis was performed for concrete, drywall, wood, asphalt roofing shingles and residual screened materials (RSM). It was found that statewide, markets existed for 100 percent of the materials studied and could replace significant amounts of natural material feedstocks, but that the development of more local markets was vital to meeting OC's diversion goal to minimize the cost of transporting recyclables.
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Date Issued: 2012
Identifier: CFE0004241, ucf:52871
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004241

Title: Cost and Environmental Impacts of Leachate Nitrogen/Phosphorus Management Approaches.
Creator: Alanezi, Alaa, Reinhart, Debra, Randall, Andrew, Sadmani, A H M Anwar, University of Central Florida
Abstract / Description: Landfill leachate is a challenging wastewater to discharge into municipal wastewater treatment plants (WWTPs), the most common approach for leachate management, due to the presence of contaminants that may affect the performance of the treatment plant. Treatment, disposal, and transportation of leachate are expensive and therefore a concern. Currently, sidestream treatment is becoming increasingly common in WWTPs prior to returning the liquid to the plant influent. For this research, a new...
Show moreLandfill leachate is a challenging wastewater to discharge into municipal wastewater treatment plants (WWTPs), the most common approach for leachate management, due to the presence of contaminants that may affect the performance of the treatment plant. Treatment, disposal, and transportation of leachate are expensive and therefore a concern. Currently, sidestream treatment is becoming increasingly common in WWTPs prior to returning the liquid to the plant influent. For this research, a new treatment scheme is introduced combining centrate and leachate to reduce contaminants, recover phosphorous and nitrogen through struvite precipitation, and reduce energy requirements through anaerobic ammonium oxidation (Anammox). By combining the two waste streams, the respective limited nutrients (nitrogen in centrate and nitrogen in leachate) can be removed in a low cost chemical treatment resources can be recovered. Carbon contaminants and remaining nutrients can be removed in subsequent innovative biological treatment units. The objective of this thesis is to conduct a cost analysis and environmental assessment of the proposed novel treatment approach and to compare it to more traditional landfill on-site leachate treatment approaches (e.g., membrane bioreactors (MBR) and sequencing batch reactors (SBR)). The study was completed with the use of spreadsheet-based models. Spreadsheets have been developed to evaluate treatment costs (Capital + O(&)M) for both the proposed nutrient recovery/biological and traditional on-site leachate treatments. Transportation costs of leachate to the WWTP have been studied and analyzed by the use of a spreadsheet model as a function of distance. Results suggest that treatment using Struvite (-) Aerobic Granular Sludge (-) Anammox (SGA) was higher in cost compared to traditional approaches. However, positive outcomes from this process include: lower N_2 O emissions, lower power consumption, struvite fertilizer, and overall recovery of nitrogen and phosphorus with the combination of centrate and leachate.
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Date Issued: 2018
Identifier: CFE0007147, ucf:52310
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007147

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University of Central Florida (28)	+ -
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