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Last Kind Word
Title
Last Kind Word.
Creator
Richardson, Dianne, Poissant, David, Hubbard, Susan, Rushin, Patrick, University of Central Florida
Abstract / Description
Last Kind Word is a novel that explores the ways people seek control and power in the face of the unknowable. Set in the fictional town of Thorpe, South Carolina, the story follows four main characters(-)Donna Neese, Melissa Burnside, Anthony Washington, and Jill McManus(-)struggling in the aftermath of biracial teenager Micah Burnside's disappearance. They search for a replacement for the lost connection to Micah and for a sense of control at a time when their lives seem to lack it, when...
Show moreLast Kind Word is a novel that explores the ways people seek control and power in the face of the unknowable. Set in the fictional town of Thorpe, South Carolina, the story follows four main characters(-)Donna Neese, Melissa Burnside, Anthony Washington, and Jill McManus(-)struggling in the aftermath of biracial teenager Micah Burnside's disappearance. They search for a replacement for the lost connection to Micah and for a sense of control at a time when their lives seem to lack it, when other forces, be they people or circumstances or spirits, hold power over them. In the midst of this, the four of them must decide what life will look like going forward. In Thorpe, theories about what happened to Micah range from the plausible to the fantastical. Those closest to him have their own theories, too, although they are less inclined to share them with the gossip-hungry townspeople. Micah's mother Melissa, reeling from the equally mysterious loss of Micah's father Dan eighteen years earlier and the intense mood swings from her untreated bipolar disorder, is convinced that her son is alive, searching for his father in San Diego. Meanwhile, Micah's grandmother Donna believes that he is dead, murdered by Nick and Nathan Goff, Thorpe's not-so-secret meth dealers who come from a long line of rowdy and dangerous men. Jill, Micah's ex-girlfriend and a recent college drop-out, worries that a prank they played on a hoodoo practitioner is somehow to blame not only for the dissolution of their relationship, but also Micah's disappearance. Jill seeks the aid of a hoodoo conjurer to set things right in the spirit world and, hopefully, her life. Anthony is a black country and blues musician and small-time drug dealer. His work forces him into a tenuous and volatile friendship with the Goffs, one that could explode into anger and violence at any moment. Anthony also thinks the Goffs have something to do with Micah's disappearance, but he believes his friend is alive, just laying low after a lie leads to the Goffs' arrest. These four characters must grapple with long-standing feuds, secrets, and family discord as they try to solve the mystery of Micah's disappearance and come to grips with the possibility that he may never be found.
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Date Issued
2014
Identifier
CFE0005238, ucf:50582
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0005238
Measuring and Modeling NMR and Emission Spectra to Gain New Insight into Challenging Organic Compounds
Title
Measuring and Modeling NMR and Emission Spectra to Gain New Insight into Challenging Organic Compounds.
Creator
Powell, Jacob, Harper, James, Campiglia, Andres, Beazley, Melanie, Richardson, David, Blair, Richard, University of Central Florida
Abstract / Description
The advancement of theoretical methods in recent years has allowed the calculation of highly accurate spectroscopic parameters. Comparing these values to the corresponding experimental data can allow molecular structures to be elucidated. This dissertation details the use of experimental and theoretical data from nuclear magnetic resonance (NMR) and fluorescence spectroscopy to determine structure. Herein the NMR focus is on measuring (&) modeling chemical shift anisotropy and one-bond carbon...
Show moreThe advancement of theoretical methods in recent years has allowed the calculation of highly accurate spectroscopic parameters. Comparing these values to the corresponding experimental data can allow molecular structures to be elucidated. This dissertation details the use of experimental and theoretical data from nuclear magnetic resonance (NMR) and fluorescence spectroscopy to determine structure. Herein the NMR focus is on measuring (&) modeling chemical shift anisotropy and one-bond carbon-carbon J-coupling constants (1JCC). The fluorescence analysis models vibrationally resolved fluorescence spectra.Chemical shift anisotropy techniques were used to study two conflicting crystal structures of the n-alkyl fatty acid, lauric acid. These two crystal structures differ only in their COOH conformation. Lattice-including density functional theory (DFT) refinements of each crystal structure failed to match experimental data leading to the proposal of a third crystal structure with a hydrogen disordered COOH moiety. This disorder strengthens the hydrogen bond providing a new rationalization to the long observed non-monotonic melting behavior of fatty acids having even and odd numbers of carbons.The INADEQUATE is a NMR experiment that directly establishes the skeleton of organic compounds by measuring the 1JCC throughout a molecule. The low occurrence of 13C-13C pairs (1 in 10,000) and breaks in connectivity due to the presence of heteroatoms causes challenges to INADEQUATE analysis. Here, the insensitivity problem is overcome using analysis software that automatically processes data and identifies signals, even when they are comparable in magnitude to noise. When combined with DFT 1JCC predictions,configuration and confirmations of the natural products 5-methylmellein and hydroheptelidic acid are elucidated.Vibrationally resolved fluorescence spectra of high molecular weight PAHs can be accurately calculated through time-dependent density functional theory (TD-DFT) methods. Here, the theoretical spectral profiles of certain PAHs are shown to match experimental high- resolution fluorescence spectra acquired at cryogenic temperatures. However, in all cases, theoretical spectra were systematically offset from experimental spectra. To decrease these uncertainties spectra were empirically corrected and an automated scheme employed to match theoretical spectra with all possible experimental spectra. In all cases the theoretical spectra were correctly matched to the experimental spectra.
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Date Issued
2017
Identifier
CFE0006953, ucf:51680
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0006953