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VAPORIZATION CHARACTERISTICS OF PURE AND BLENDED BIOFUEL DROPLET INJECTED INTO HOT STREAM OF AIR
Title
VAPORIZATION CHARACTERISTICS OF PURE AND BLENDED BIOFUEL DROPLET INJECTED INTO HOT STREAM OF AIR.
Creator
Saha, Abhishek, Kumar, Ranganathan, University of Central Florida
Abstract / Description
The combustion dynamics and stability are dependent on the quality of mixing and vaporization of the liquid fuel in the pre-mixer. The vaporization characteristics of different blends of biofuel droplets injected into the air stream in the pre-mixer are modeled in this current study. The focus of this work is on the blended alternate fuels which are lately being considered for commercial use. Two major alternate fuels analyzed are ethanol and Rapeseed Methyl Esters (RME). Ethanol is being...
Show moreThe combustion dynamics and stability are dependent on the quality of mixing and vaporization of the liquid fuel in the pre-mixer. The vaporization characteristics of different blends of biofuel droplets injected into the air stream in the pre-mixer are modeled in this current study. The focus of this work is on the blended alternate fuels which are lately being considered for commercial use. Two major alternate fuels analyzed are ethanol and Rapeseed Methyl Esters (RME). Ethanol is being used as a substitute for gasoline, while RME is an alternative for diesel. In the current work, the vaporization characteristics of a single droplet in a simple pre-mixer has been studied for pure ethanol and RME in a hot air jet at a temperature of 800 K. In addition, the behavior of the fuels when they are mixed with conventional fuels like gasoline and diesel is also studied. Temperature gradients and vaporization efficiency for different blends of bio-conventional fuel mixture are compared with one another. The model was validated using an experiment involving convection heating of acoustically levitated fuel droplets and IR-thermography to visualize and quantify the vaporization characteristics of different biofuel blends downstream of the pre-mixer. Results show that the 20 μm droplets of ethanol-gasoline 50-50 blend is completely evaporated in 1.1 msec, while 400 μm droplets vaporized only 65% in 80 msec. In gasoline-ethanol blends, pure gasoline is more volatile than pure ethanol. In spite of having higher vapor pressure, ethanol vaporizes slowly compared to gasoline, due to the fact that latent heat of vaporization is higher for ethanol. For gasoline-ethanol blended fuels, ethanol component vaporizes faster. This is because in blended fuels gasoline and ethanol attain the same temperature and ethanol vapor pressure is higher than that for gasoline. In the case of RME-diesel blends, initially diesel vaporizes faster up to 550K, and above this temperature, vapor pressure of RME becomes dominant resulting in faster vaporization of RME. Current work also looks into the effect of non-volatile impurities present in biofuels. Depending on source and extraction process, fuels carry impurities which impact vaporization process. In this work these effects on ethanol blended fuel have been studied for different concentration of impurities. The presence of non-volatile impurities reduces the vaporization rate by reducing the mass fraction of the volatile component at the surface. However, impurities also increase the surface temperature of the droplet. Finally, the effects of hot and cold spots in the prevaporizer have been investigated. Due to inefficient design, prevaporizer may have local zones where the temperature of air increases or decreases very sharply. Droplets going through these abnormal temperature zones would vaporize at a different rate than others. Current study looks into these droplets to understand the vaporization pattern.
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Date Issued
2010
Identifier
CFE0003253, ucf:48514
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0003253
Evaporation, Precipitation Dynamics and Instability of Acoustically Levitated Functional Droplets
Title
Evaporation, Precipitation Dynamics and Instability of Acoustically Levitated Functional Droplets.
Creator
Saha, Abhishek, Kumar, Ranganathan, Basu, Saptarshi, Kapat, Jayanta, Deng, Weiwei, Shivamoggi, Bhimsen, University of Central Florida
Abstract / Description
Evaporation of pure and binary liquid droplets is of interest in thermal sprays and spray drying of food, ceramics and pharmaceutical products. Understanding the rate of heat and mass transfer in any drying process is important not only to enhance evaporation rate or vapor-gas mixing, but also to predict and control the final morphology and microstructure of the precipitates. Acoustic levitation is an alternative method to study micron-sized droplets without wall effects, which eliminates...
Show moreEvaporation of pure and binary liquid droplets is of interest in thermal sprays and spray drying of food, ceramics and pharmaceutical products. Understanding the rate of heat and mass transfer in any drying process is important not only to enhance evaporation rate or vapor-gas mixing, but also to predict and control the final morphology and microstructure of the precipitates. Acoustic levitation is an alternative method to study micron-sized droplets without wall effects, which eliminates chemical and thermal contamination with surfaces. This work uses an ultrasonic levitation technique to investigate the vaporization dynamics under radiative heating, with focus on evaporation characteristics, precipitation kinetics, particle agglomeration, structure formation and droplet stability. Timescale and temperature scales are developed to compare convective heating in actual sprays and radiative heating in the current experiments. These relationships show that simple experiments can be conducted in a levitator to extrapolate information in realistic convective environments in spray drying. The effect of acoustic streaming, droplet size and liquid properties on internal flow is important to understand as the heat and mass transfer and particle motion within the droplet is significantly controlled by internal motion. Therefore, the droplet internal flow is characterized by Particle Image Velocimetry for different dropsize and viscosity. Nanosuspension droplets suspended under levitation show preferential accumulation and agglomeration kinetics. Under certain conditions, they form bowl shaped structures upon complete evaporation. At higher concentrations, this initial bowl shaped structure morphs into a ring structure. Nanoparticle migration due to internal recirculation forms a density stratification, the location of which depends on initial particle concentration. The time scale of density stratification is similar to that of perikinetic-driven agglomeration of particle flocculation. The density stratification ultimately leads to force imbalance leading to a unique bowl-shaped structure. Chemically active precursor droplet under acoustic levitation shows events such as vaporization, precipitation and chemical reaction leading to nanoceria formation with a porous morphology. The cerium nitrate droplet undergoes phase and shape changes throughout the vaporization process followed by formation of precipitate. Ex-situ analyses using TEM and SEM reveal highly porous morphology with trapped gas pockets and nanoceria crystalline structures at 70 degree C. Inhomogeneity in acoustic pressure around the heated droplet can induce thermal instability. Short wavelength (Kelvin-Helmholtz) instability for diesel and bio-diesel droplets triggers this secondary atomization, which occurs due to relative velocity between liquid and gas phase at the droplet equator. On the other hand, liquids such as Kerosene and FC43 show uncontrollable stretching followed by a catastrophic break-up due to reduction in surface tension and viscosity coupled with inhomogeneity of pressure around the droplet. Finally, a scaling analysis has been established between vaporizing droplets in a convective and radiative environment. The transient temperature normalized by the respective scales exhibits a unified profile for both modes of heating. The analysis allows for the prediction of required laser flux in the levitator experiments to show its equivalence in a corresponding heated gas stream. The theoretical equivalence shows good agreement with experiments for a range of droplet sizes.
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Date Issued
2012
Identifier
CFE0004436, ucf:49346
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004436