View All Items

Title: Structure and Properties of Polymer-Derived SiBCN Ceramics.
Creator: Chen, Yaohan, An, Linan, Fang, Jiyu, Xu, Chengying, Zhai, Lei, Huo, Qun, Gong, Xun, University of Central Florida
Abstract / Description: Polymer-derived ceramics (PDCs) are a unique class of multifunctional materials synthesized by thermal decomposition of polymeric precursors. Due to their unique and excellent properties and flexible manufacturing capability, PDC is a promising technology to prepare ceramic fibers, coatings, composites and micro-sensors for high-temperature applications. However, the structure-property relationships of PDCs have not been well understood. The lack of such understandings drastically limited the...
Show morePolymer-derived ceramics (PDCs) are a unique class of multifunctional materials synthesized by thermal decomposition of polymeric precursors. Due to their unique and excellent properties and flexible manufacturing capability, PDC is a promising technology to prepare ceramic fibers, coatings, composites and micro-sensors for high-temperature applications. However, the structure-property relationships of PDCs have not been well understood. The lack of such understandings drastically limited the further developments and applications of the materials.In this dissertation, the structure and properties of amorphous polymer-derived silicon carbonitride (SiCN) and silicoboron carbonitride (SiBCN) have been studied. The SiCN was obtained using commercially available polysilazane as pre-ceramic precursor, and the SiBCN ceramics with varied Si-to-B ratio were obtained from polyborosilazanes, which were synthesized by the hydroboration and dehydrocoupling reaction of borane and polysilazane. The structural evolution of polymer-derived SiCN and SiBCN ceramics from polymer to ceramics was investigated by NMR, FTIR, Raman, EPR, TG/DTA, and XRD. The results show a phase-separation of amorphous matrix and a graphitization of (")free(") carbon phase, and suggest that the boron doping has a great influence on the structural evolution. The electric and dielectric properties of the SiCN and SiBCNs were studied by I-V curves, LCR Meter, and network analyzer. A new electronic conduction mechanism and structure model has been proposed to account for the relationships between the observed properties and microstructure of the materials. Furthermore, the SiBCN ceramics showed the improved dielectric properties at characterization temperature up to 1300 (&)#186;C, which allows the fabrication of ultrahigh-temperature wireless microsensors for extreme environments.
Show less
Date Issued: 2012
Identifier: CFE0004195, ucf:49014
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004195

Title: Making An Impression: A Formal Analysis of the Contextual and Iconographic Characteristics of Ancient Mexican Ceramic Stamps.
Creator: Peabody, Elizabeth, Barber, Sarah, Callaghan, Michael, Williams, Lana, Starbuck, John, University of Central Florida
Abstract / Description: Ceramic stamps are a rare, yet widely distributed, artifact class within ancient Mexico. However, there has only been limited scholarly research on these objects and much current research is minimally supported. Depicting a wide range of iconography, including metaphysical, floral, and faunal designs, the function and meaning of these stamps, also known as estampias, pintaderas, and sellos, in ancient Mexican life remain an archaeological mystery. This paper examines the contextual,...
Show moreCeramic stamps are a rare, yet widely distributed, artifact class within ancient Mexico. However, there has only been limited scholarly research on these objects and much current research is minimally supported. Depicting a wide range of iconography, including metaphysical, floral, and faunal designs, the function and meaning of these stamps, also known as estampias, pintaderas, and sellos, in ancient Mexican life remain an archaeological mystery. This paper examines the contextual, chronological, and iconographic characteristics of ancient Mexican ceramic stamps as well as the distributional trends of those characteristics. This study is comprised of 83 stamps of varying design that date to between 1600 B.C.E. and 1520 C.E.: 19 found by the Rio Verde Project in Southern Oaxaca, Mexico, 5 found by Michael Coe in San Lorenzo, and 59 central Mexican stamps with credible, detailed provenience residing in the collection of the American Museum of Natural History and Robert S. Peabody Museum of Archaeology. Examined through the lens of culture history, processual, and postprocessual theory, comparative statistical analysis was conducted to assist the identification of significant trends. These analyses have revealed that stamp use shifted from mainly public to household spaces over time and that stamps predominantly depict nature and metaphysical themed motifs. I have also found that stamps were likely multipurpose artifacts whose use transcended social status. This research greatly expands on the limited literature about Mesoamerican ceramic stamps and provides valuable insight into ancient Mexican household, identity, and possibly religious, practices.
Show less
Date Issued: 2018
Identifier: CFE0007411, ucf:52699
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007411

Title: Ytterbium-doped fiber-seeded thin-disk master oscillator power amplifier laser system.
Creator: Willis-Ott, Christina, Richardson, Martin, Schulzgen, Axel, Delfyett, Peter, Chow, Louis, University of Central Florida
Abstract / Description: Lasers which operate at both high average power and energy are in demand for a wide range of applications such as materials processing, directed energy and EUV generation. Presented in this dissertation is a high-power 1 ?m ytterbium-based hybrid laser system with temporally tailored pulse shaping capability and up to 62 mJ pulses, with the expectation the system can scale to higher pulse energies. This hybrid system consists of a low power fiber seed and pre-amplifier, and a solid state thin...
Show moreLasers which operate at both high average power and energy are in demand for a wide range of applications such as materials processing, directed energy and EUV generation. Presented in this dissertation is a high-power 1 ?m ytterbium-based hybrid laser system with temporally tailored pulse shaping capability and up to 62 mJ pulses, with the expectation the system can scale to higher pulse energies. This hybrid system consists of a low power fiber seed and pre-amplifier, and a solid state thin-disk regenerative amplifier. This system has been designed to generate high power temporally tailored pulses on the nanosecond time scale. Temporal tailoring and spectral control are performed in the low power fiber portion of the system with the high pulse energy being generated in the regenerative amplifier. The seed system consists of a 1030 nm fiber-coupled diode, which is transmitted through a Mach-Zehnder-type modulator in order to temporally vary the pulse shape. Typical pulses are 20-30 ns in duration and have energies of ~0.2 nJ from the modulator. These are amplified in a fiber pre-amplifier stage to ~100 nJ before being used to seed the free-space Yb:YAG thin-disk regenerative amplifier. Output pulses have maximum demonstrated pulse energies of 62 mJ with 20 ns pulse after ~250 passes in the cavity. The effects of thermal distortion in laser and passive optical materials are also. Generally the development of high power and high energy lasers is limited by thermal management strategies, as thermally-induced distortions can degrade laser performance and potentially cause catastrophic damage. Novel materials, such as optical ceramics, can be used to mitigate thermal distortions; however, thorough analysis is required to optimize their fabrication and minimize thermal distortions. Using a Shack-Hartmann wavefront sensor (SHWFS), it is possible to analyze the distortion induced in passive and doped optical elements by high power lasers. For example, the thin-disk used in the regenerative amplifier is examined in-situ during CW operation (up to 2 kW CW pump power). Additionally, passive oxide-based optical materials and Yb:YAG optical ceramics are also examined by pumping at 2 and 1 ?m respectively to induce thermal distortions which are analyzed with the SHWFS. This method has been developed as a diagnostic for the relative assessment of material quality, and to grade differences in ceramic laser materials associated with differences in manufacturing processes and/or the presence of impurities. In summation, this dissertation presents a high energy 1 ?m laser system which is novel in its combination of energy level and temporal tailoring, and an analysis of thermal distortions relevant to the development of high power laser systems.
Show less
Date Issued: 2013
Identifier: CFE0004961, ucf:49588
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004961

Title: SURFACTANT DRIVEN ASSEMBLY OF FREEZE-CASTED, POLYMER-DERIVED CERAMIC NANOPARTICLES ON GRAPEHENE OXIDE SHEETS FOR LITHIUM-ION BATTERY ANODES.
Creator: Khater, Ali Zein, Tetard, Laurene, Zhai, Lei, University of Central Florida
Abstract / Description: Traditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure...
Show moreTraditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure that provides a mechanically stable, light weight material for LIB anodes. Due to its structure, reduced graphene oxide (rGO) is efficiently conductive and resistive to environmental changes. On the other hand, silicon-based anode materials offer the highest theoretical energy density and a high Li-ion loading capacity of various elements [20]. Silicon-based anodes that have previously been studied demonstrated extreme volumetric expansion over long cycles due to lithiation. Polysiloxane may be an interesting alternative as it is a Si-based material that can retain the high Li-ion loading capacity of Si while lacking the unattractive volumetric expansions of Si. Polymer derived ceramic-decorated graphene oxide anodes have been suggested to increase loading capacity, thermal resistance, power density, and mechanical stability of LIBs. Coupled with mechanically stable graphene oxide, polymer derived ceramic nanoparticle decorated graphene oxide anodes are studied to establish their efficiencies under operating conditions.
Show less
Date Issued: 2018
Identifier: CFH2000404, ucf:45765
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH2000404

Title: POLYMER-DERIVED CERAMICS: ELECTRONIC PROPERTIES AND APPLICATION.
Creator: xu, weixing, An, Linan, University of Central Florida
Abstract / Description: In this work, we studied the electronic behavior of polymer-derived ceramics (PDCs) and applied them for the synthesis of carbon nanotube reinforced ceramic nanocomposites and ceramic MEMS (Micro-Electro-Mechanical Systems) structures. Polymer-derived SiCN ceramics were synthesized by pyrolysis of a liquid polyureasilazane with dicumyl peroxide as thermal initiator. The structural evolution during pyrolysis and post-annealing was studied using FTIR, solid state NMR and Raman. The results...
Show moreIn this work, we studied the electronic behavior of polymer-derived ceramics (PDCs) and applied them for the synthesis of carbon nanotube reinforced ceramic nanocomposites and ceramic MEMS (Micro-Electro-Mechanical Systems) structures. Polymer-derived SiCN ceramics were synthesized by pyrolysis of a liquid polyureasilazane with dicumyl peroxide as thermal initiator. The structural evolution during pyrolysis and post-annealing was studied using FTIR, solid state NMR and Raman. The results revealed that the resultant ceramics consisted of SiCxNx-4 as major building units. These units were connected with each other through C-C/C=C bonds or by shearing N/C. The amount of sp2 free carbon strongly depends on composition and processing condition. Electron paramagnetic resonance (EPR) was used to investigate electronic structure of PDCs; the results revealed that the materials contain unpaired electron centers associated with carbons. Electronic behavior of the SiCN ceramics was studied by measuring their I-V curves, temperature dependence of d.c.-conductivities and impendence. The results revealed that the SiCN ceramics exhibited typical amorphous semiconductor behavior, and their conductivity varied in a large range. The results also revealed that the materials contain more than one phase, which have the different electronic behavior. We explored possibility of using polymer-derived ceramics to make ceramic MEMS for harsh environmental applications with a lithography technique. The cure depth of the polymer precursor was measured as a function of UV intensity and exposure time. The experimental data was compared with the available theoretical model. A few typical SiCN parts were fabricated by lithography technique. We also prepared carbon nanotube reinforced ceramic nanocomposites by using PDC processing. The microstructures of the composites were characterized using SEM and TEM; the mechanical properties were studied characterized using nanoindentation. The significant improvement in mechanical properties was observed for the nanocomposites.
Show less
Date Issued: 2006
Identifier: CFE0001228, ucf:46885
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001228

Title: Mechanical Properties of Brittle Ceramics: Case Study of Boron Rich Ceramics and Acropora cervicornis Coral Skeleton.
Creator: Carrasco-Pena, Alejandro, Kwok, Kawai, Orlovskaya, Nina, Gou, Jihua, Uribe Romo, Fernando, University of Central Florida
Abstract / Description: Ceramics are ubiquitous in man-made and natural structures. Their mechanical properties highly depend on their composition, microstructure and level of defects in the bulk of the material, the latter affecting the integrity of the components; such is the case of boron-rich ceramics where large agglomerates create high stressed regions, or coral skeleton where porosity determines their strength against hydrodynamic forces present in the ocean tides. Therefore, studying the properties of...
Show moreCeramics are ubiquitous in man-made and natural structures. Their mechanical properties highly depend on their composition, microstructure and level of defects in the bulk of the material, the latter affecting the integrity of the components; such is the case of boron-rich ceramics where large agglomerates create high stressed regions, or coral skeleton where porosity determines their strength against hydrodynamic forces present in the ocean tides. Therefore, studying the properties of ceramic materials using invasive and non-invasive methods helps in the understanding of the link between the properties and the performance of the structures. The aim of this research was to test the novel ceramic component ZrB2-30wt%SiB6 and Acropora cervicornis coral skeleton using non-conventional techniques that allow for the study of their mechanical properties and their behavior when exposed to external loads present in their environments of application. The first part of this study focuses on understanding the effects of adding SiB6 to enhance the mechanical properties of ZrB2 ceramics for their ultra-high temperature use. The second part will emphasize in the behavior of Acropora cervicornis coral skeleton when exposed to compressive forces and the effects porosity has on this structure when subjected to such loads. It was found that the SiB6 phase was not stable after sintering of the composite and large agglomerates were present in the surface of the material acting as stress concentrators, thus compromising the biaxial strength of the component that resulted to be 224.9 MPa. It was also found that coral skeletons are highly susceptible to porosity which creates variability on the elastic modulus ranging from 60-1 GPa for simulated porosity of 0-90% respectively and a strength of 3.56 (&)#177; 0.31 GPa obtained through Vickers indentation. Finite element models were developed and validated against experimental results for the ZrB2-30wt%SiB6 and Acropora cervicornis coral skeleton.
Show less
Date Issued: 2019
Identifier: CFE0007440, ucf:52696
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007440

Title: INTERFACIAL BEHAVIOR IN POLYMER DERIVED CERAMICS AND SALT WATER PURIFICATION VIA 2D MOS2.
Creator: Li, Hao, An, Linan, Jung, YeonWoong, Zhai, Lei, Feng, Xiaofeng, Yu, Xiaoming, University of Central Florida
Abstract / Description: In the present dissertation, the behavior of the internal potential barrier in a polymer-derived amorphous SiAlCN ceramic was studied by measuring its complex impedance spectra at various dc bias as well as different testing and annealing temperatures. The complex impedancespectra of the polymer-derived a-SiAlCN were measured under various dc bias voltages in a temperature range between 50 and 150?(&)deg;C, as well as different annealing temperatures (1100-1400 (&)deg;C). All spectra,...
Show moreIn the present dissertation, the behavior of the internal potential barrier in a polymer-derived amorphous SiAlCN ceramic was studied by measuring its complex impedance spectra at various dc bias as well as different testing and annealing temperatures. The complex impedancespectra of the polymer-derived a-SiAlCN were measured under various dc bias voltages in a temperature range between 50 and 150?(&)deg;C, as well as different annealing temperatures (1100-1400 (&)deg;C). All spectra, regardless of temperature and bias, consist of two semi-circular arcs,corresponding to the free-carbon phase and the interface, respectively. The impedance of the free-carbon phase is independent of the bias, while that of the interface decreased significantly with increasing dc bias. It is shown that the change of the interfacial capacitance with the bias can be explained using the double Schottky barrier model. The charge-carrier concentration and potential barrier height were estimated by comparing the experimental data and the model.The results revealed that increasing testing temperature led to an increased charge-carrier concentration and a reduced barrier height, both following Arrhenius dependence, whereas the increase in annealing temperature resulted in increased charge-carrier concentration and barrier height. The phenomena were explained in terms of the unique bi-phasic microstructures of the material. The research findings reveal valuable microstructural information of temperaturedependent properties of polymer derived ceramics, and should contribute towards more precise understanding and control of the electrical as well as dielectric properties of polymer derivedceramics. Furthermore, the desalination performances and underlying mechanisms of two-dimensional CVD-grown MoS2 layers membranes have been experimentally assessed. Based on a successful large-area few-layer 2D materials growth, transfer and integration method, the 2D MoS2 layers membranes showed preserved chemical and microstructural integrity after integration. The few-layer 2D MoS2 layers demonstrated superior desalination capability towards various types of seawater salt solutions approaching theoretically-predicted values. Such performances are attributed to the dimensional and geometrical effect, as well as the electrostatic interaction of the inherently-present CVD-induced atomic vacancies for governingboth water permeation and ionic sieving at the solution/2D-layer interfaces.
Show less
Date Issued: 2019
Identifier: CFE0007830, ucf:52813
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007830

Title: Analyzing Pre-Inhumation Breakage Ceramics at Lamanai, Belize: A Conjunctive Approach.
Creator: Enger, Ryan, Callaghan, Michael, Kovacevich, Brigitte, Williams, Lana, University of Central Florida
Abstract / Description: During the Terminal Classic period (9th-10th centuries A.D.), the ancient Maya at Lamanai, Belize, began to practice pre-inhumation breakage of ceramics in mortuary contexts. Previously, the custom had been to bury whole vessels with the deceased. This conspicuous shift in behavior suggests important changes in beliefs regarding the role of ceramics in death and interment at a pivotal moment in ancient Maya culture history. Despite this significant change, there has been no published research...
Show moreDuring the Terminal Classic period (9th-10th centuries A.D.), the ancient Maya at Lamanai, Belize, began to practice pre-inhumation breakage of ceramics in mortuary contexts. Previously, the custom had been to bury whole vessels with the deceased. This conspicuous shift in behavior suggests important changes in beliefs regarding the role of ceramics in death and interment at a pivotal moment in ancient Maya culture history. Despite this significant change, there has been no published research conducted specifically on these vessels. In fact, there has been no clearly delineated set of characteristics for what qualifies as a pre-inhumation breakage vessel (PBV). This study offers a working definition for PBVs and converts the original Lamanai grave descriptions of those that contain PBVs to a classification system for ease of future comparative analyses. Finally, the sex and age of individuals buried with PBVs are considered. The result is a conjunctive analysis that provides data not only on PBV forms and quantities, grave types, and the sex and age of those interred with PBVs, but also several statistically significant correlations among these variables. I argue that the conjoined data suggest that one of the primary purposes for the pre-inhumation breakage of ceramics in mortuary contexts was a strategic one, a method selected by Lamanai leadership, and enacted community-wide, as a way to protect the community from potentially harmful energies and to maintain communal confidence at a time of great uncertainty in the southern Maya lowlands.
Show less
Date Issued: 2019
Identifier: CFE0007801, ucf:52343
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007801

Title: Development of Polymer Derived SiAlCN Ceramic and Its Applications for High-Temperature Sensors.
Creator: Shao, Gang, An, Linan, Fang, Jiyu, Xu, Chengying, Chow, Lee, Deng, Weiwei, University of Central Florida
Abstract / Description: Polymer-derived ceramic (PDC) is the name for a class of materials synthesized by thermal decomposition of polymeric precursors which excellent thermomechanical properties, such as high thermal stability, high oxidation/corrosion resistance and high temperature multifunctionalities. Direct polymer-to-ceramic processing routes of PDCs allow easier fabrication into various components/devices with complex shapes/structures. Due to these unique properties, PDCs are considered as promising...
Show morePolymer-derived ceramic (PDC) is the name for a class of materials synthesized by thermal decomposition of polymeric precursors which excellent thermomechanical properties, such as high thermal stability, high oxidation/corrosion resistance and high temperature multifunctionalities. Direct polymer-to-ceramic processing routes of PDCs allow easier fabrication into various components/devices with complex shapes/structures. Due to these unique properties, PDCs are considered as promising candidates for making high-temperature sensors for harsh environment applications, including high temperatures, high stress, corrosive species and/or radiation. The SiAlCN ceramics were synthesized using the liquid precursor of polysilazane (HTT1800) and aluminum-sec-tri-butoxide (ASB) as starting materials and dicumyl peroxide (DP) as thermal initiator. The as-received SiAlCN ceramics have very good thermal-mechanical properties and no detectable weight loss and large scale crystallization. Solid-state NMR indicates that SiAlCN ceramics have the SiN4, SiO4, SiCN3, and AlN5/AlN6 units. Raman spectra reveals that SiAlCN ceramics contain (")free carbon(") phase with two specific Raman peaks of (")D(") band and (")G(") band at 1350 cm-1 and 1600 cm-1, respectively. The (")free carbon(") becomes more and more ordered with increasing the pyrolysis temperature. EPR results show that the defects in SiAlCN ceramics are carbon-related with a g-factor of 2.0016(&)#177;0.0006. Meanwhile, the defect concentration decreases with increasing sintered temperature, which is consistent with the results obtained from Raman spectra.Electric and dielectric properties of SiAlCN ceramics were characterized. The D.C. conductivity of SiAlCN ceramics increases with increasing sintered temperature and the activation energy is about 5.1 eV which higher than that of SiCN ceramics due to the presence of oxygen. The temperature dependent conductivity indicates that the conducting mechanism is a semiconducting band-gap model and follows the Arrhenius equation with two different sections of activation energy of 0.57 eVand 0.23 eV, respectively. The temperature dependent conductivity makes SiAlCN ceramics suit able for high temperature sensor applications. The dielectric properties were carried out by the Agilent 4298A LRC meter. The results reveal an increase in both dielectric constant and loss with increasing temperature (both pyrolysis and tested). Dielectric loss is dominated by the increasing of conductivity of SiAlCN ceramics at high sintered temperatures.SiAlCN ceramic sensors were fabricated by using the micro-machining method. High temperature wire bonding issues were solved by the integrity embedded method (IEM). It's found that the micro-machining method is a promising and cost-effective way to fabricate PDC high temperature sensors. Moreover IEM is a good method to solve the high temperature wire bonding problems with clear bonding interface between the SiAlCN sensor head and Pt wires. The Wheatstone bridge circuit is well designed by considering the resistance relationship between the matching resistor and the SiAlCN sensor resistor. It was found that the maximum sensitivity can be achieved when the resistance of matching resistor is equal to that of the SiAlCN sensor. The as-received SiAlCN ceramic sensor was tested up to 600 degree C with the relative output voltage changing from -3.932 V to 1.153 V. The results indicate that the relationship between output voltage and test temperature is nonlinear. The tested sensor output voltage agrees well with the simulated results. The durability test was carried out at 510 degree C for more than two hours. It was found that the output voltage remained constant for the first 30 min and then decreased gradually afterward by 0.02, 0.04 and 0.07 V for 1, 1.5 and 2 hours.
Show less
Date Issued: 2013
Identifier: CFE0004937, ucf:49602
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004937

Title: Rhenium, osmium and iridium diborides by mechanochemistry: Synthesis, structure, thermal stability and mechanical properties.
Creator: Xie, Zhilin, Orlovskaya, Nina, Blair, Richard, Gou, Jihua, Raghavan, Seetha, An, Linan, University of Central Florida
Abstract / Description: Borides are implemented in a range of industrial applications due to their unique mechanical, electrical, thermal and catalytic properties. In particular, transition metal diborides are of special interest. In the recent years, borides of rhenium (Re), osmium (Os) and iridium (Ir) have been studied as for their ultra-hardness and superior stiffness. In this dissertation, a mechanochemical method is introduced to produce rhenium diboride (ReB2) powder, a novel hexagonal osmium diboride (h-OsB2...
Show moreBorides are implemented in a range of industrial applications due to their unique mechanical, electrical, thermal and catalytic properties. In particular, transition metal diborides are of special interest. In the recent years, borides of rhenium (Re), osmium (Os) and iridium (Ir) have been studied as for their ultra-hardness and superior stiffness. In this dissertation, a mechanochemical method is introduced to produce rhenium diboride (ReB2) powder, a novel hexagonal osmium diboride (h-OsB2), and iridium boride powders. Densification by Spark Plasma Sintering (SPS), thermal stability and mechanical properties of h-OsB2 were also studied. ReB2 was recently reported to exhibit high hardness and low compressibility, which both are strong functions of its stoichiometry, namely Re to B ratio. Most of the techniques used for ReB2 synthesis reported 1:2.5 Re to B ratio because of the loss of the B during high temperature synthesis. However, as a result of B excess, the amorphous boron, located along the grain boundaries of polycrystalline ReB2, would degrade the ReB2 properties. Therefore, techniques which could allow synthesizing the stoichiometric ReB2 preferably at room temperature are in high demand. ReB2 powder was synthesized at low temperature using mechanochemical route by milling elemental crystalline Re and amorphous B powders in the SPEX 8000 high energy ball mill for 80 hours. The formation of boron and perrhenic acids are also reported after ReB2 powder was exposed to the moist air environment for a twelve month period of time.Hexagonal osmium diboride (h-OsB2), a theoretically predicted high-pressure phase, has been synthesized for the first time by a mechanochemical method, i.e., high energy ball milling. X-ray diffraction (XRD) indicated the formation of h-OsB2 after 2.5 hours of milling, and the reaction reaches equilibrium after 18 hours of milling. The lattice parameters of the h-OsB2 are a=2.916(&)#197; and c=7.376 (&)#197;, with a P63/mmc space group. Transmission electron microscopy confirmed the appearance of the h-OsB2 phase. The thermal stability of h-OsB2 powder was studied by heating under argon up to 876 (&)deg;C and cooling in vacuo down to -225 (&)deg;C. The oxidation mechanism of h-OsB2 has also been proposed. The hexagonal phase partially converted to the orthorhombic phase (20 wt.%) after spark plasma sintering of h-OsB2 at 1500(&)deg;C and 50MPa for 5 minutes. Hardness and Young's modulus of the h-OsB2 were measured to be 31 (&)#177; 9 GPa and 574 (&)#177; 112 GPa, respectively by nanoindentation method.Prior to this research a number of compounds have been prepared in Ir-B system with lower than 2 boron stoichiometry, and no IrB2 phases have been synthesized experimentally. In this dissertation, three new iridium boride phases, ReB2-type IrB2, AlB2-type IrB2 and IrB have been synthesized with a similar mechanochemical method. The formation of these three phases has been confirmed by both X-ray diffraction (XRD) and transmission electron microscope (TEM) after 30 hours of ball milling and 48 hours of annealing. The IrB2 phases have hexagonal crystal structures and the new IrB phase has an orthorhombic crystal structure. The segregation of iridium from iridium borides' lattices has also been studied by high resolution TEM.
Show less
Date Issued: 2014
Identifier: CFE0005911, ucf:50832
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005911

Title: Mechanical Properties and Thermal Residual Stresses of ZrB2-SiC Ceramic Composites for Hypersonic Vehicle Applications.
Creator: Stadelmann, Richard, Orlovskaya, Nina, Kumar, Ranganathan, Raghavan, Seetha, University of Central Florida
Abstract / Description: Ultra High Temperature Ceramic (UHTC) ZrB2- 10, 20, 30wt%SiC composites are of high interest for use in hypersonic air-breathing vehicles. In this work, ZrB2- 10, 20, 30wt%SiC UHTC composites were produced by the Spark Plasma Sintering (SPS) technique. After sintering, almost dense ceramics with ~ 5-8% porosity were produced. Their mechanical properties, such as Young's, shear, and bulk moduli, along with Poisson's ratio, 4-point bending strength, and single edge V-notched beam (SEVNB)...
Show moreUltra High Temperature Ceramic (UHTC) ZrB2- 10, 20, 30wt%SiC composites are of high interest for use in hypersonic air-breathing vehicles. In this work, ZrB2- 10, 20, 30wt%SiC UHTC composites were produced by the Spark Plasma Sintering (SPS) technique. After sintering, almost dense ceramics with ~ 5-8% porosity were produced. Their mechanical properties, such as Young's, shear, and bulk moduli, along with Poisson's ratio, 4-point bending strength, and single edge V-notched beam (SEVNB) fracture toughness were measured. In addition, in-situ bending experiments under a Raman microscope were performed to determine the piezo-spectroscopic coefficients of SiC Raman active peaks for calculation of thermal residual stresses. The results show that these materials are possible candidates for hypersonic air-breathing vehicles due to their high Young's modulus, ability to withstand high temperatures, and relatively low densities.
Show less
Date Issued: 2013
Identifier: CFE0005060, ucf:49945
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005060

Title: Regional Affiliation in the Lower Rio Verde: An Examination of R(&)#237;o Viejo Middens as Evidence for Scaled-up Practice at Surrounding Sites.
Creator: Lucido, Carlo, Barber, Sarah, Chase, Arlen, Walker, John, University of Central Florida
Abstract / Description: This research project analyzes 5 middens from the Lower Rio Verde valley sites of R(&)#237;o Viejo and Yug(&)#252;e, Oaxaca, Mexico, during the Terminal Formative period (150 BC to AD 250). The middens are analyzed to further our understanding of socio-political events in public spaces at both sites during this time. The study suggests a greater distinction in use of public spaces between the two sites than within R(&)#237;o Viejo. Frameworks established by Dietler and Hayden for the analysis...
Show moreThis research project analyzes 5 middens from the Lower Rio Verde valley sites of R(&)#237;o Viejo and Yug(&)#252;e, Oaxaca, Mexico, during the Terminal Formative period (150 BC to AD 250). The middens are analyzed to further our understanding of socio-political events in public spaces at both sites during this time. The study suggests a greater distinction in use of public spaces between the two sites than within R(&)#237;o Viejo. Frameworks established by Dietler and Hayden for the analysis of feasts do not seem to apply well to the middens analyzed here. Although I argue that evidence from Rio Viejo's middens does not dispute the viability of previous arguments regarding Terminal Formative R(&)#237;o Viejo ritual authorities', potentially elites, efforts to create regional-scale political affiliations, the level to which middens at R(&)#237;o Viejo are evidence of (")scaled-up(") versions of local practices at outlying sites is inconclusive. Though there is potential for larger feasts at R(&)#237;o Viejo, taken alone the Yug(&)#252;e midden appears larger. The R(&)#237;o Viejo middens demonstrate greater likelihood for the diminished conspicuousness of status differentiation during the associated events.
Show less
Date Issued: 2015
Identifier: CFE0005653, ucf:50178
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005653

Title: NOVEL CONCEPTUAL DESIGN AND ANLYSIS OF POLYMER DERIVED CERAMIC MEMS SENSORS FOR GAS TURBINE ENVIRONMENT.
Creator: Nagaiah, Narasimha, Kapat, Jay, University of Central Florida
Abstract / Description: Technical challenges for developing micro sensors for Ultra High Temperature and turbine applications lie in that the sensors have to survive extremely harsh working conditions that exist when converting fuel to energy. These conditions include high temperatures (500-1500°C), elevated pressures (200-400 psi), pressure oscillations, corrosive environments (oxidizing conditions, gaseous alkali, and water vapors), surface coating or fouling, and high particulate loading. Several technologies are...
Show moreTechnical challenges for developing micro sensors for Ultra High Temperature and turbine applications lie in that the sensors have to survive extremely harsh working conditions that exist when converting fuel to energy. These conditions include high temperatures (500-1500°C), elevated pressures (200-400 psi), pressure oscillations, corrosive environments (oxidizing conditions, gaseous alkali, and water vapors), surface coating or fouling, and high particulate loading. Several technologies are currently underdeveloped for measuring these parameters in turbine engines. One of them is an optical-based non-contact technology. However, these nondirective measuring technologies lack the necessary accuracy, at least at present state. An alternative way to measure these parameters without disturbing the working environments is using MEMS type sensors. Currently, the techniques under development for such harsh environment applications are silicon carbide (SiC) and silicon nitrite (Si3N4) –based ceramic MEMS sensors. But those technologies present some limitation such as narrow processing method, high cost (materials and processing cost), and limited using temperatures (typically < 800 C). In this research we propose to develop two sensors based on recently developed polymer-derived ceramics (PDCs): Constant Temperature Hot wire Anemometer, temperature/heat-flux sensor for turbine applications. PDC is a new class of high temperature ceramics. As we shall describe below, many unique features of PDCs make them particularly suitable for the proposed sensors, including: excellent thermo-mechanical properties at high temperatures, enable high temperature operation of the devices; various well-developed processing technologies, such as injection molding,photolithography, embossing, DRIE etching and precise machining, can be used for the fabrication of the devices; and tunable electric conductivity, enable the proposed sensors fabricated from similar materials, thus reliability considerations associated with thermal mismatch, which is a big concern when using MEMS-based sensors at elevated temperatures, will be minimized.
Show less
Date Issued: 2006
Identifier: CFE0001285, ucf:46892
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001285

Title: EQUIBIAXIAL FLEXURAL STRENGTH TESTING OF ADVANCE CERAMICS.
Creator: Jordan, Ryan T, Orlovskaya, Nina, Kwok, Kawai; Ghosh, Ranajay, University of Central Florida
Abstract / Description: Ceramics are very important materials with many unique properties used in numerous industrial applications. Ceramics could be very hard and very strong in comparison to metals; however, they are very brittle, thus they are prone to instantaneous and catastrophic failure. Therefore, their reliability is compromised and it is very important to have advanced techniques that allow evaluating their mechanical behavior in many unusual stress states. One of such testing methods is biaxial strength...
Show moreCeramics are very important materials with many unique properties used in numerous industrial applications. Ceramics could be very hard and very strong in comparison to metals; however, they are very brittle, thus they are prone to instantaneous and catastrophic failure. Therefore, their reliability is compromised and it is very important to have advanced techniques that allow evaluating their mechanical behavior in many unusual stress states. One of such testing methods is biaxial strength method, that allows to measure properties not only unidirectional, but also in a biaxial way. The research work for this thesis will be built on design and development of ring-on-ring test jigs that will measure a biaxial strength of thin ceramic disks.
Show less
Date Issued: 2018
Identifier: CFH2000386, ucf:45700
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH2000386

Title: Fabrication and Characterization of Nonlinear Optical Ceramics for Random Quasi-Phase-Matching.
Creator: Chen, Xuan, Gaume, Romain, Richardson, Kathleen, Challapalli, Suryanarayana, Sohn, Yongho, Kuebler, Stephen, University of Central Florida
Abstract / Description: A number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline...
Show moreA number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline aggregates, in a so-called random quasi-phase-matching (rQPM) process. In this dissertation, we examine appropriate fabrication pathways for (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-PT) and ZnSe transparent ceramics for applications in the mid-IR. The main challenge associated with the fabrication of high transparency PMN-PT ceramics is to avoid the parasitic pyrochlore phase. The most effective method to suppress the formation of this undesired phase is to use magnesium niobate (MgNb2O6) as the starting material. We have found that, contrary to commercially available lead oxide powders, nanopowders synthesized in our lab by the combustion method help improve the densification of ceramics and their overall optical quality. The effects of dopants on the microstructure evolution and phase-purity control in PMN-PT ceramics are also investigated and show that La3+ helps control grain-growth and get a pure perovskite phase, thereby improving the samples transparency. With large second order susceptibility coefficients and wide transmission window from 0.45 to 21 (&)#181;m, polycrystalline zinc selenide is also an ideal candidate material for accessing the MWIR spectrum through rQPM nonlinear interaction. We have investigated non-stoichiometric heat-treatment conditions necessary to develop adequate microstructure for rQPM from commercial CVD-grown ZnSe ceramics. We have been able to demonstrate the world's first optical parametric oscillation (OPO) based on rQPM in ZnSe transparent ceramic, enabling broadband frequency combs spanning 3-7.5 (&)#181;m.
Show less
Date Issued: 2018
Identifier: CFE0007748, ucf:52403
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007748

Title: Experimental study and modeling of mechanical micro-machining of particle reinforced heterogeneous materials.
Creator: Liu, Jian, Xu, Chengying, An, Linan, Gordon, Ali, Bai, Yuanli, Gong, Xun, University of Central Florida
Abstract / Description: This study focuses on developing explicit analytical and numerical process models for mechanical micro-machining of heterogeneous materials. These models are used to select suitable process parameters for preparing and micro-machining of these advanced materials. The material system studied in this research is Magnesium Metal Matrix Composites (Mg-MMCs) reinforced with nano-sized and micro-sized silicon carbide (SiC) particles.This research is motivated by increasing demands of miniaturized...
Show moreThis study focuses on developing explicit analytical and numerical process models for mechanical micro-machining of heterogeneous materials. These models are used to select suitable process parameters for preparing and micro-machining of these advanced materials. The material system studied in this research is Magnesium Metal Matrix Composites (Mg-MMCs) reinforced with nano-sized and micro-sized silicon carbide (SiC) particles.This research is motivated by increasing demands of miniaturized components with high mechanical performance in various industries. Mg-MMCs become one of the best candidates due to its light weight, high strength, and high creep/wear resistance. However, the improved strength and abrasive nature of the reinforcements bring great challenges for the subsequent micro-machining process.Systematic experimental investigations on the machinability of Mg-MMCs reinforced with SiC nano-particles have been conducted. The nanocomposites containing 5 Vol.%, 10 Vol.% and 15 Vol.% reinforcements, as well as pure magnesium, are studied by using the Design of Experiment (DOE) method. Cutting forces, surface morphology and surface roughness are characterized to understand the machinability of the four materials. Based on response surface methodology (RSM) design, experimental models and related contour plots have been developed to build a connection between different materials properties and cutting parameters. Those models can be used to predict the cutting force, the surface roughness, and then optimize the machining process.An analytical cutting force model has been developed to predict cutting forces of Mg-MMCs reinforced with nano-sized SiC particles in the micro-milling process. This model is different from previous ones by encompassing the behaviors of reinforcement nanoparticles in three cutting scenarios, i.e., shearing, ploughing and elastic recovery. By using the enhanced yield strength in the cutting force model, three major strengthening factors are incorporated, including load-bearing effect, enhanced dislocation density strengthening effect and Orowan strengthening effect. In this way, the particle size and volume fraction, as significant factors affecting the cutting forces, are explicitly considered. In order to validate the model, various cutting conditions using different size end mills (100 (&)#181;m and 1 mm dia.) have been conducted on Mg-MMCs with volume fraction from 0 (pure magnesium) to 15 Vol.%. The simulated cutting forces show a good agreement with the experimental data. The proposed model can predict the major force amplitude variations and force profile changes as functions of the nanoparticles' volume fraction. Next, a systematic evaluation of six ductile fracture models has been conducted to identify the most suitable fracture criterion for micro-scale cutting simulations. The evaluated fracture models include constant fracture strain, Johnson-Cook, Johnson-Cook coupling criterion, Wilkins, modified Cockcroft-Latham, and Bao-Wierzbicki fracture criterion. By means of a user material subroutine (VUMAT), these fracture models are implemented into a Finite Element (FE) orthogonal cutting model in ABAQUS/Explicit platform. The local parameters (stress, strain, fracture factor, velocity fields) and global variables (chip morphology, cutting forces, temperature, shear angle, and machined surface integrity) are evaluated. Results indicate that by coupling with the damage evolution, the capability of Johnson-Cook and Bao-Wierzbicki can be further extended to predict accurate chip morphology. Bao-Wierzbiki-based coupling model provides the best simulation results in this study. The micro-cutting performance of MMCs materials has also been studied by using FE modeling method. A 2-D FE micro-cutting model has been constructed. Firstly, homogenized material properties are employed to evaluate the effect of particles' volume fraction. Secondly, micro-structures of the two-phase material are modeled in FE cutting models. The effects of the existing micro-sized and nano-sized ceramic particles on micro-cutting performance are carefully evaluated in two case studies. Results show that by using the homogenized material properties based on Johnson-Cook plasticity and fracture model with damage evolution, the micro-cutting performance of nano-reinforced Mg-MMCs can be predicted. Crack generation for SiC particle reinforced MMCs is different from their homogeneous counterparts; the effect of micro-sized particles is different from the one of nano-sized particles.In summary, through this research, a better understanding of the unique cutting mechanism for particle reinforced heterogeneous materials has been obtained. The effect of reinforcements on micro-cutting performance is obtained, which will help material engineers tailor suitable material properties for special mechanical design, associated manufacturing method and application needs. Moreover, the proposed analytical and numerical models provide a guideline to optimize process parameters for preparing and micro-machining of heterogeneous MMCs materials. This will eventually facilitate the automation of MMCs' machining process and realize high-efficiency, high-quality, and low-cost manufacturing of composite materials.
Show less
Date Issued: 2012
Identifier: CFE0004570, ucf:49196
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004570

Title: THE FABRICATION OF POLYMER-DERIVED SICN/SIBCN CERAMIC NANOSTRUCTURES AND INVESTIGATION OF THEIR STRUCTURE-PROPERTY RELATIONSHIP.
Creator: Sarkar, Sourangsu, Zhai, Lei, University of Central Florida
Abstract / Description: Polymer-derived Ceramics (PDCs) represent a unique class of high-temperature stable materials synthesized directly by the thermal decomposition of polymers. This research first focuses on the fabrication of high temperature stable siliconcarbonitride (SiCN) fibers by electrospinning for ceramic matrix composite (CMC) applications. CerasetÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â™ VL20, a commercially available liquid...
Show morePolymer-derived Ceramics (PDCs) represent a unique class of high-temperature stable materials synthesized directly by the thermal decomposition of polymers. This research first focuses on the fabrication of high temperature stable siliconcarbonitride (SiCN) fibers by electrospinning for ceramic matrix composite (CMC) applications. CerasetÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â™ VL20, a commercially available liquid cyclosilazane, was functionalized with aluminum sec-butoxide in order to be electrospinnable. The surface morphology of the electrospun fibers was investigated using the fibers produced from solvents. The electrospun fibers produced from the chloroform/N,N-dimethylformamide solutions had hierarchical structures that led to superhydrophobic surfaces. A ÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â"dry skinÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â" model was proposed to explain the formation of micro/- and nanostructures. The second objective of the research is to align the multiwalled carbon nanotubes (MWCNTs) in PDC fibers. For this purpose, a non-invasive approach to disperse carbon nanotubes in polyaluminasilazane chloroform solutions was developed using a conjugated block copolymer synthesized by ATRP. The effect of the polymer and CNT concentration on the fiber structure and morphology was also examined. Detailed characterization using SEM and TEM was performed to demonstrate the orientation of CNTs inside the ceramic fibers. Additionally, the electrical properties of the ceramic fibers were investigated. Finally, the structural evolution of polymer-derived amorphous siliconborocarbonitride (SiBCN) ceramics with pyrolysis temperatures was studied by solid-state NMR, Raman and EPR spectroscopy. Results suggested the presence of three major components: (i) hexagonal boron nitride (h-BN), (ii) turbostratic boron nitride (t-BN), and (iii) BN2C groups in the final ceramic. The pyrolysis at higher temperature generated boron nitride (BN3) with a simultaneous decomposition of BN2C groups. A thermodynamic model was proposed to quantitatively explain the conversion of BN2C groups into BN3 and ÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â"freeÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â" carbon. Such structure evolution is believed to be the reason that the crystallization of Si4.0B1.0 ceramics starts at 1500 ÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â°C, whereas Si2.0B1.0 ceramics is stable upto 1600 ÃƒÂƒÃ‚Â‚ÃƒÂ‚Ã‚Â°C.
Show less
Date Issued: 2010
Identifier: CFE0003446, ucf:48408
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003446

Title: Design and modeling of a heat exchanger for porous combustor powered steam generators in automotive industry.
Creator: Dasgupta, Apratim, Orlovskaya, Nina, Gou, Jihua, Vasu Sumathi, Subith, University of Central Florida
Abstract / Description: A major challenge faced by automobile manufacturers is to achieve reduction of particulate emission to acceptable standards, as the emission standards become more and more stringent. One of the ecologically friendly options to reduce emissions is to develop external combustion in a steam engine as a replacement of the internal combustion engine. There are multiple factors, other than pollution that need to be considered for developing a substitute for Internal Combustion Engine, like specific...
Show moreA major challenge faced by automobile manufacturers is to achieve reduction of particulate emission to acceptable standards, as the emission standards become more and more stringent. One of the ecologically friendly options to reduce emissions is to develop external combustion in a steam engine as a replacement of the internal combustion engine. There are multiple factors, other than pollution that need to be considered for developing a substitute for Internal Combustion Engine, like specific power, throttle response, torque speed curve, fuel consumption and refueling infrastructure. External combustion in a steam engine seems to be a bright idea, for a cleaner and more environment friendly alternative to the IC engine that can satisfy the multiple technology requirements mentioned. One way of performing external heterogeneous combustion is to use porous ceramic media, which is a modern and innovative technique, used in many practical applications. The heterogeneous combustion inside ceramic porous media provides numerous advantages, as the ceramic, acts as a regenerator that distributes heat from the flue gases to the upstream reactants, resulting in the extended flammability limits of the reactants. The heat exchanger design is the major challenge in developing an external combustion engine because of the space, such systems consume in an automobile. The goal of the research is to develop a compact and efficient heat exchanger for the application. The proposed research uses natural gas as a fuel that is mixed with air for combustion and the generated flue gases are fed to a heat exchanger to generate superheated system for performing engine work to the vehicle. The performed research is focused on designing and modeling of the boiler heat exchanger section. The justification for selection of working fluid and power plant technology is presented as part of the research, where the proposed system consists of an Air and Flue Gas Path and a Water and Steam Path. Models are developed for coupled thermal and fluid analysis of a heat exchanger, consisting of three sections. The first section converts water to a saturated liquid. The second portion consists of a section where water is converted to saturated steam. The third section is the superheater, where saturated steam is converted to superheated steam. The Finite Element Model is appropriately meshed and boundary conditions set up to solve the mass, momentum and energy conservation equations. The k-epsilon model is implemented to take care of turbulence. Analytical calculations following the established codes and standards are also executed to develop the design.
Show less
Date Issued: 2017
Identifier: CFE0006579, ucf:51308
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006579

Title: Design, Development, and Testing of a Miniature Fixture for Uniaxial Compression of Ceramics Coupled with In-Situ Raman Spectrometer.
Creator: Jordan, Ryan, Orlovskaya, Nina, Kwok, Kawai, Ghosh, Ranajay, University of Central Florida
Abstract / Description: This thesis is about the design, development and integration of an in-situ compression stage which interfaces through the Leica optical microscope coupled with a Renishaw InVia micro-Raman spectrometer. This combined compression stage and Raman system will enable structural characterization of ceramics and ceramic composites. The in-situ compression stage incorporates a 440C stainless steel structural components, 6061 aluminum frame, a NEMA 23 stepper motor. Two load screws that allow to...
Show moreThis thesis is about the design, development and integration of an in-situ compression stage which interfaces through the Leica optical microscope coupled with a Renishaw InVia micro-Raman spectrometer. This combined compression stage and Raman system will enable structural characterization of ceramics and ceramic composites. The in-situ compression stage incorporates a 440C stainless steel structural components, 6061 aluminum frame, a NEMA 23 stepper motor. Two load screws that allow to apply compressive loads up to 14,137 N, with negligible off axis loading, achieving target stresses of 500 MPa for samples of up to 6.00 mm in diameter. The system will be used in the future to study the structural changes in ceramics and ceramic composites, as well as to study thermal residual stress redistribution under applied compressive loads. A broad variety of Raman active ceramics, including the traditional structural ceramics 3mol%Y2O3-ZrO2, B4C, SiC, Si3N4, as well as exotic materials such as LaCoO3 and other perovskites will be studied using this system. Calibration of the systems load cell was performed in the configured state using MTS universal testing machines. To ensure residual stresses from mounting the load cell did not invalidate the original calibration, the in-situ compression stage was tested once attached to the Renishaw Raman spectrometer using LaCoO3 ceramic samples. The Raman shift of certain peaks in LaCoO3 was detected indicative of the effect of the applied compressive stress on the ceramics understudy.
Show less
Date Issued: 2019
Identifier: CFE0007824, ucf:52809
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007824

Title: OPTICAL AND PHYSICAL PROPERTIES OF CERAMIC CRYSTAL LASER MATERIALS.
Creator: Simmons, Jed, Bass, Michael, University of Central Florida
Abstract / Description: Historically ceramic crystal laser material has had disadvantages compared to single crystal laser material. However, progress has been made in the last decade and a half to overcome the disadvantages associated with ceramic crystal. Today, because of the promise of ceramic crystal as a high power laser material, investigation into its properties, both physical and optical, is warranted and important. Thermal expansion was measured in this thesis for Nd:YAG (yttrium aluminum garnet) ceramic...
Show moreHistorically ceramic crystal laser material has had disadvantages compared to single crystal laser material. However, progress has been made in the last decade and a half to overcome the disadvantages associated with ceramic crystal. Today, because of the promise of ceramic crystal as a high power laser material, investigation into its properties, both physical and optical, is warranted and important. Thermal expansion was measured in this thesis for Nd:YAG (yttrium aluminum garnet) ceramic crystal using an interferometric method. The interferometer employed a spatially filtered HeNe at 633 nm wavelength. Thermal expansion coefficients measured for the ceramic crystal samples were near the reported values for single crystal Nd:YAG. With a similar experimental setup as that for the thermal expansion measurements, dn/dT for ceramic crystal Nd:YAG was measured and found to be slightly higher than the reported value for single crystal. Depolarization loss due to thermal gradient induced stresses can limit laser performance. As a result this phenomenon was modeled for ceramic crystal materials and compared to single crystals for slab and rod shaped gain media. This was accomplished using COMSOL Multiphysics, and MATLAB. Results indicate a dependence of the depolarization loss on the grain size where the loss decreases with decreased grain size even to the point where lower loss may be expected in ceramic crystals than in single crystal samples when the grain sizes in the ceramic crystal are sufficiently small. Deformation-induced thermal lensing was modeled for a single crystal slab and its relevance to ceramic crystal is discussed. Data indicates the most notable cause of deformation-induced thermal lensing is a consequence of the deformation of the top and bottom surfaces. Also, the strength of the lensing along the thickness is greater than the width and greater than that due to other causes of lensing along the thickness of the slab. Emission spectra, absorption spectra, and fluorescence lifetime were measured for Nd:YAG ceramic crystal and Yb:Lu2O3 ceramic crystal. No apparent inhomogeneous broadening appears to exist in the Nd:YAG ceramic at low concentrations. Concentration and temperature dependence effects on emission spectra were measured and are presented. Laser action in a thin disk of Yb:Y2O3 ceramic crystal was achieved. Pumping was accomplished with a fiber coupled diode laser stack at 938 nm. A slope efficiency of 34% was achieved with maximum output energy of 28.8 mJ/pulse.
Show less
Date Issued: 2007
Identifier: CFE0001764, ucf:47273
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001764

Ceramics (5)	+ -
ceramics (5)	+ -
Polymer Derived Ceramics (3)	+ -
Ceramic Composites (2)	+ -
Finite Element Analysis (2)	+ -

Mechanical Testing (2)	+ -
Polymer derived ceramics (2)	+ -
Polymer-derived ceramics (2)	+ -
SiCN (2)	+ -
ceramic (2)	+ -
?^(2) interaction (1)	+ -
AM (1)	+ -
Acropora cervicornis (1)	+ -
Additive Manufacturing (1)	+ -
Advance Ceramics (1)	+ -
Advanced Ceramics (1)	+ -
Anemometer (1)	+ -
Basalt Fiber (1)	+ -
Biaxial Stress (1)	+ -
Bioarchaeology (1)	+ -
Bone Grafts (1)	+ -
Carbon Nanotubes (1)	+ -
Caribbean (1)	+ -
Ceramic (1)	+ -
Ceramic Age (1)	+ -
Ceramic Matrix Composites (1)	+ -
Ceramic Thin Film (1)	+ -
Ceramic nanofibers (1)	+ -
Chalcogenide (1)	+ -
Chalcogenide Glass (1)	+ -

ETD Collection (37)	+ -
Honors Collection (4)	+ -

University of Central Florida (41)	+ -
An, Linan (12)	+ -
Orlovskaya, Nina (9)	+ -
Zhai, Lei (7)	+ -
Gaume, Romain (5)	+ -

Sohn, Yongho (5)	+ -
Fang, Jiyu (4)	+ -
Gou, Jihua (4)	+ -
Richardson, Kathleen (4)	+ -
Callaghan, Michael (3)	+ -
Coffey, Kevin (3)	+ -
Gong, Xun (3)	+ -
Raghavan, Seetha (3)	+ -
Richardson, Martin (3)	+ -
Williams, Lana (3)	+ -
Xu, Chengying (3)	+ -
Barber, Sarah (2)	+ -
Ghosh, Ranajay (2)	+ -
Huo, Qun (2)	+ -
Kovacevich, Brigitte (2)	+ -
Kumar, Ranganathan (2)	+ -
Kwok, Kawai (2)	+ -
Shah, Lawrence (2)	+ -
Shoulders, William (2)	+ -
Sisken, Laura (2)	+ -
Walker, John (2)	+ -
Bai, Yuanli (1)	+ -
Bass, Michael (1)	+ -
Baudelet, Matthieu (1)	+ -
Bhatt, Himesh (1)	+ -

Search In

Pages

Pages

Sort Results By:

Narrow results by:

Topical Subject

Collection

Type of Resource

Language

Creator

Format

Owner