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Title: MULTILAYERED PLANAR PERIODIC SUBWAVELENGTH MICROSTRUCTURES FOR GENERATING AND DETECTING CIRCULARLY POLARIZED THERMAL INFRARED RADIATION.
Creator: Wadsworth, Samuel, Boreman, Glenn, University of Central Florida
Abstract / Description: Generation and detection of circularly-polarized (CP) radiation in the 8- to 12-[micro]m band of the infrared (IR) spectrum is crucial for polarization sensing and imaging scenarios. There is very little naturally occurring CP radiation in the long-wave IR band, so that useful functionalities may be obtained by exploiting preferential radiation and transmission characteristics of engineered metamaterials. Conventional CP devices in the IR utilize birefringent crystals, which are typically...
Show moreGeneration and detection of circularly-polarized (CP) radiation in the 8- to 12-[micro]m band of the infrared (IR) spectrum is crucial for polarization sensing and imaging scenarios. There is very little naturally occurring CP radiation in the long-wave IR band, so that useful functionalities may be obtained by exploiting preferential radiation and transmission characteristics of engineered metamaterials. Conventional CP devices in the IR utilize birefringent crystals, which are typically bulky and expensive to manufacture. The operation of these devices is generally optimized at a single wavelength. Imaging in the long-wave IR is most often broadband, so that achromatic CP-device behavior is highly desirable from a flux-transfer viewpoint. Also, size, weight and cost are significant drivers in the design of practical IR systems. Thus a solution is sought with a convenient thin planar form factor. This dissertation will demonstrate a novel planar periodic subwavelength-microstructured approach derived from classical radiofrequency meanderline designs that are able to generate CP radiation over a broad IR band while maintaining a low fabrication profile. We investigate issues regarding efficiency as a function of the number of layers in the device structure; reflective, transmissive, and emissive behavior; strategies for broadband achromatization; and thermal-isolation requirements between the active blackbody reservoir and the top of the planar device, to achieve a given degree of polarization. Theoretical, numerical, and experimental findings are presented that confirm the feasibility of this class of devices for use in a wide variety of situations, from polarization imaging and spectroscopy to industrial laser processing and machining.
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Date Issued: 2011
Identifier: CFE0003935, ucf:48686
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003935

Title: Mid-infrared plasmonics.
Creator: Khalilzadeh Rezaie, Farnood, Peale, Robert, Ishigami, Masa, Schoenfeld, Winston, Buchwald, Walter, Abdolvand, Reza, University of Central Florida
Abstract / Description: This dissertation reports investigations into materials for, and applications of, infrared surface plasmon polaritons (SPP). SPPs are inhomogeneous electromagnetic waves that are bound to the surface of a conductor. Tight confinement of electromagnetic energy, the primary virtue of SPPs for so-called (")plasmonic(") applications, requires plasma frequencies for the conductor near the intended infrared operational frequencies. This requires carrier concentrations that are much less than those...
Show moreThis dissertation reports investigations into materials for, and applications of, infrared surface plasmon polaritons (SPP). SPPs are inhomogeneous electromagnetic waves that are bound to the surface of a conductor. Tight confinement of electromagnetic energy, the primary virtue of SPPs for so-called (")plasmonic(") applications, requires plasma frequencies for the conductor near the intended infrared operational frequencies. This requires carrier concentrations that are much less than those of usual metals such as gold and silver. I have investigated the optical properties and SPP excitation resonances of two materials having infrared plasma frequencies, namely the semimetal bismuth and the transparent conducting fluorine-doped tin-oxide (FTO). The complex permittivity spectra for evaporated films of Bi were found to be distinctly different than earlier reports for crystal or polycrystalline films, and SPP excitation resonances on Bi-coated gratings were found to be disappointingly broad. Permittivity spectra for chemical spray deposited FTO were obtained to long-wave IR wavelengths for the first time, and nano-crystalline FTO-coated silicon lamellar gratings show remarkable conformity. SPP excitation resonances for FTO are more promising than for Bi. Thus, FTO appears to be a promising SPP host for infrared plasmonics, e.g. a planer waveguide plasmonic spectral sensor, whose design was elaborated and investigated as part of my research and which requires SPP-host coating on deep vertical side walls of a trench-like analyte interaction region. Additionally, FTO may serve as a useful conducting oxide for a near-IR plasmonic spectral imager that I have investigated theoretically.
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Date Issued: 2015
Identifier: CFE0006222, ucf:51080
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006222

Title: An Exploration of the Feasibility of Functional Near-Infrared Spectroscopy as a Neurofeedback Cueing System for the Mitigation of the Vigilance Decrement.
Creator: Hancock, Gabriella, Szalma, James, Mouloua, Mustapha, Bohil, Corey, Hoffman, Robert, Matthews, Gerald, University of Central Florida
Abstract / Description: Vigilance is the capacity for observers to maintain attention over extended periods of time, and has most often been operationalized as the ability to detect rare and critical signals (Davies (&) Parasuraman, 1982; Parasuraman, 1979; Warm, 1984). Humans, however, have natural physical and cognitive limitations that preclude successful long-term vigilance performance and consequently, without some means of assistance, failures in operator vigilance are likely to occur. Such a decline in...
Show moreVigilance is the capacity for observers to maintain attention over extended periods of time, and has most often been operationalized as the ability to detect rare and critical signals (Davies (&) Parasuraman, 1982; Parasuraman, 1979; Warm, 1984). Humans, however, have natural physical and cognitive limitations that preclude successful long-term vigilance performance and consequently, without some means of assistance, failures in operator vigilance are likely to occur. Such a decline in monitoring performance over time has been a robust finding in vigilance experiments for decades and has been called the vigilance decrement function (Davies (&) Parasuraman, 1982; Mackworth, 1948). One of the most effective countermeasures employed to maintain effective performance has been cueing: providing the operator with a reliable prompt concerning signal onset probability. Most protocols have based such cues on task-related or environmental factors. The present dissertation examines the efficacy of cueing when nominally based on operator state (i.e., blood oxygenation of cortical tissue) in a novel vigilance task incorporating dynamic displays over three studies. Results pertaining to performance outcomes, physiological measures (cortical blood oxygenation and heart rate variability), and perceived workload and stress are interpreted via Signal Detection Theory and the Resource Theory of vigilance.
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Date Issued: 2017
Identifier: CFE0006599, ucf:51286
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006599

Title: Frequency Selective Detection of Infrared Radiation in Uncooled Optical Nano-Antenna Array.
Creator: Modak, Sushrut, Chanda, Debashis, Schoenfeld, Winston, Fathpour, Sasan, University of Central Florida
Abstract / Description: Mid-infrared (mid-IR) detection and imaging over atmospheric transparent 3-5 ?m and 8-12 ?m bands are increasingly becoming important for various space, defense and civilian applications. Various kinds of microbolometers offer uncooled detection of IR radiation. However, broadband absorption of microbolometers makes them less sensitive to spectrally resolved detection of infrared radiation and the fabrication is also very tedious involving multiple complex lithography steps. In this study, we...
Show moreMid-infrared (mid-IR) detection and imaging over atmospheric transparent 3-5 ?m and 8-12 ?m bands are increasingly becoming important for various space, defense and civilian applications. Various kinds of microbolometers offer uncooled detection of IR radiation. However, broadband absorption of microbolometers makes them less sensitive to spectrally resolved detection of infrared radiation and the fabrication is also very tedious involving multiple complex lithography steps. In this study, we designed an optical nano-antenna array based detector with narrow frequency band of operation. The structure consists of a two-element antenna array comprised of a perforated metallic hole array coupled with an underneath disk array which trap incident radiation as dipole currents. The energy is dissipated as electron plasma loss on the hole-disk system inducing close to ~100% absorption of the incident radiation. This near perfect absorption originates from simultaneous zero crossing of real component of permittivity and permeability due to the geometrical arrangement of the two antenna elements which nullifies overall charge and current distributions, prohibiting existence of any propagating electromagnetic modes at resonance. Moreover, the continuous perforated film allows probing of the induced (")micro-current(") plasma loss on each nano hole-disk pair via a weak bias current. Such optical antenna design enables flexible scaling of detector response over the entire mid-infrared regime by change in the antenna dimensions. Furthermore, the development of simple nanoimprint lithography based large area optical antenna array fabrication technique facilitates formation of low cost frequency selective infrared detectors.
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Date Issued: 2014
Identifier: CFE0005845, ucf:50932
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005845

Title: Selective electro-magnetic absorbers based on metal-dielectric-metal thin-film cavities.
Creator: Nath, Janardan, Peale, Robert, Ishigami, Masa, Chernyak, Leonid, Vodopyanov, Konstantin, University of Central Florida
Abstract / Description: Efficient absorption of light is required for a large number of applications such as thermo-photovoltaics,thermal imaging, bio-sensing, thermal emitters, astronomy, and stealth technology. Strong light absorbers found in nature with high intrinsic losses such as carbon black, metal-black, and carbon nano-tubes etc. are bulky, not design-tunable and are hard to pattern for micro- and nano- devices. We developed thin-film, high performance absorbers in the visible, near-, mid-, long-wave - and...
Show moreEfficient absorption of light is required for a large number of applications such as thermo-photovoltaics,thermal imaging, bio-sensing, thermal emitters, astronomy, and stealth technology. Strong light absorbers found in nature with high intrinsic losses such as carbon black, metal-black, and carbon nano-tubes etc. are bulky, not design-tunable and are hard to pattern for micro- and nano- devices. We developed thin-film, high performance absorbers in the visible, near-, mid-, long-wave - and far-IR region based on a 3 layer metal-dielectric-metal (MDM) structure.We fabricated a 3-layerMDMabsorber with large band-widths in the visible and near IR spectral range without any lithographic patterning. This was the first demonstration in the optical range of the Salisbury Screen, which was originally invented for radar absorption. A Fabry-Perotcavity model depending on the thickness of the dielectric, but also the effective permittivity of the semi-transparent top metal gives calculated spectra that agree well with experiment.Secondly, we fabricated long-wave IR and far-IR MDM absorbers comprising surface patterns of periodic metal squares on the dielectric layer. Strong absorption in multiple bands were obtained, and these depended weakly on polarization and angle of incidence. Though such absorbers had been extensively studied by electrodynamic simulations and experiment in the visible to far- R regions, there existed no analytic model that could accurately predict the wavelengths of the multiple resonances. We developed a theoretical model for these absorbers based on standingwave resonances, which accurately predicts resonance wavelengths for experiment and simulation for the first time. Unlike metamaterial theories our model does not depend on the periodicity of the squares but only on their lateral dimension and the thickness of the dielectric. This feature is confirmed by synchrotron-based IR spectral imaging microscopy of single isolated squares.
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Date Issued: 2015
Identifier: CFE0005851, ucf:50907
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005851

Title: Hybrid Integrated Photonic Platforms and Devices.
Creator: Chiles, Jeffrey, Fathpour, Sasan, Vodopyanov, Konstantin, Khajavikhan, Mercedeh, Chanda, Debashis, University of Central Florida
Abstract / Description: Integrated photonics has the potential to revolutionize optical systems by achieving drastic reductions in their size, weight and power. Remote spectroscopy, free-space communications and high-speed telecommunications are critical applications that would benefit directly from these advancements. However, many such applications require extremely wide spectral bandwidths, leading to significant challenges in their integration. The choice of integrated platform influences the optical...
Show moreIntegrated photonics has the potential to revolutionize optical systems by achieving drastic reductions in their size, weight and power. Remote spectroscopy, free-space communications and high-speed telecommunications are critical applications that would benefit directly from these advancements. However, many such applications require extremely wide spectral bandwidths, leading to significant challenges in their integration. The choice of integrated platform influences the optical transparency and functionality which can be ultimately achieved. In this work, several new platforms and technologies have been developed to meet these needs. First, the silicon-on-lithium-niobate (SiLN) platform is discussed, on which the first compact, integrated electro-optic modulator in the mid-infrared has been demonstrated. Next, results are shown in the development of the all-silicon-optical-platform (ASOP), an ultra-stable suspended membrane approach which offers broad optical transparency from 1.2 to 8.5 um and enables efficient nonlinear frequency conversion in the mid-IR. This fabrication approach is then taken further with (")anchored-membrane waveguides,(") (T-Guides) enabling single-mode and single-polarization waveguiding over a span exceeding 1.27 octaves. Afterward, a new photonic technology enabling integrated polarization beam-splitters and polarizers over unprecedented bandwidths is introduced, called topographically anisotropic photonics (TAP). Next, results on high-performance microphotonic chalcogenide glass waveguides are presented. Finally, several integrated photonics concepts suitable for further work will be discussed, such as augmentations to T-Guides and a novel technique for quasi-phase-matching.
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Date Issued: 2016
Identifier: CFE0006447, ucf:51408
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006447

Title: Photothermal Lensing in Mid-Infrared Materials.
Creator: Cook, Justin, Richardson, Martin, Shah, Lawrence, Gaume, Romain, University of Central Florida
Abstract / Description: A thorough understanding of laser-materials interactions is crucial when designing and building optical systems. An ideal test method would probe both the thermal and optical properties simultaneously for materials under large optical loads where detrimental thermal effects emerge. An interesting class of materials are those used for infrared wavelengths due to their wide spectral transmission windows and large optical nonlinearities. Since coherent sources spanning the mid-wave and long-wave...
Show moreA thorough understanding of laser-materials interactions is crucial when designing and building optical systems. An ideal test method would probe both the thermal and optical properties simultaneously for materials under large optical loads where detrimental thermal effects emerge. An interesting class of materials are those used for infrared wavelengths due to their wide spectral transmission windows and large optical nonlinearities. Since coherent sources spanning the mid-wave and long-wave infrared wavelength regions have only become widely available in the past decade, data regarding their thermal and optical responses is lacking in literature.Photothermal Lensing (PTL) technique is an attractive method for characterizing the optical and thermal properties of mid-infrared materials as it is nondestructive and can be implemented using both continuous wave and pulsed irradiation. Analogous to the well-known Z-scan, the PTL technique involves creating a thermal lens within a material and subsequently measuring this distortion with a probe beam. By translating the sample through the focus of the pump laser, information can be obtained regarding the nonlinear absorption, thermal diffusivity and thermo-optic coefficient. This thesis evaluates the effectiveness and scope of the PTL method using numerical simulations of low loss infrared materials. Specifically, the response of silicon, germanium, and As2Se3 glass is explored. The 2 ?m pump and 4.55 ?m probe beam geometries are optimized in order to minimize experimental error. Methodologies for estimating the thermal diffusivity, nonlinear absorption coefficient and thermo-optic coefficient directly from the experimentally measured PTL signal are presented. Finally, the ability to measure the nonlinear absorption coefficient without the need for high-energy or ultrashort optical pulses is demonstrated.
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Date Issued: 2017
Identifier: CFE0006730, ucf:51885
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006730

Title: RESPONSE-CALIBRATION TECHNIQUES FOR ANTENNA-COUPLED INFRARED SENSORS.
Creator: Krenz, Peter, Boreman, Glenn, University of Central Florida
Abstract / Description: Infrared antennas are employed in sensing applications requiring specific spectral, polarization, and directional properties. Because of their inherently small dimensions, there is significant interaction, both thermal and electromagnetic, between the antenna, the antenna-coupled sensor, and the low-frequency readout structures necessary for signal extraction at the baseband modulation frequency. Validation of design models against measurements requires separation of these effects so that the...
Show moreInfrared antennas are employed in sensing applications requiring specific spectral, polarization, and directional properties. Because of their inherently small dimensions, there is significant interaction, both thermal and electromagnetic, between the antenna, the antenna-coupled sensor, and the low-frequency readout structures necessary for signal extraction at the baseband modulation frequency. Validation of design models against measurements requires separation of these effects so that the response of the antenna-coupled sensor alone can be measured in a calibrated manner. Such validations will allow confident extension of design techniques to more complex infrared-antenna configurations. Two general techniques are explored to accomplish this goal. The extraneous signal contributions can be measured separately with calibration structures closely co-located near the devices to be characterized. This approach is demonstrated in two specific embodiments, for removal of cross-polarization effects arising from lead lines in an antenna-coupled infrared dipole, and for removal of distributed thermal effects in an infrared phased-array antenna. The second calibration technique uses scanning near-field microscopy to experimentally determine the spatial dependence of the electric-field distributions on the signal-extraction structures, and to include these measured fields in the computational electromagnetic model of the overall device. This approach is demonstrated for infrared dipole antennas which are connected to coplanar strip lines. Specific situations with open-circuit and short-circuit impedances at the termination of the lines are investigated.
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Date Issued: 2010
Identifier: CFE0003177, ucf:48606
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003177

Title: Spectral Study of Asteroids and Laboratory Simulated Asteroid Organics.
Creator: Hargrove, Kelsey, Colwell, Joshua, Fernandez, Yan, Britt, Daniel, Kelley, Michael, University of Central Florida
Abstract / Description: We investigate the spectra of asteroids at near- and mid-infrared wavelengths. In 2010 and 2011 we reported the detection of 3 ?m and 3.2-3.6 ?m signatures on (24) Themis and (65) Cybele indicative of water-ice and complex organics [1] [2] [3]. We further probed other primitive asteroids in the Cybele dynamical group and Themis family, finding diversity in the shape of their 3 ?m [4] [5] [6] and 10 ?m spectral features [4]. These differences indicated mineralogical and compositional...
Show moreWe investigate the spectra of asteroids at near- and mid-infrared wavelengths. In 2010 and 2011 we reported the detection of 3 ?m and 3.2-3.6 ?m signatures on (24) Themis and (65) Cybele indicative of water-ice and complex organics [1] [2] [3]. We further probed other primitive asteroids in the Cybele dynamical group and Themis family, finding diversity in the shape of their 3 ?m [4] [5] [6] and 10 ?m spectral features [4]. These differences indicated mineralogical and compositional variations within these asteroid populations. Also in the mid-infrared region we studied a larger population of asteroids belonging to the Bus C, D, and S taxanomic classes to understand the relationship between any mineralogy and hydration inferred in the visible and near- infrared with the shape, strength, and slope of the 10 ?m emission. We have discovered that at least 3 of the main Bus taxanomic groups (Cs, Ds, and Ss as defined by their visible spectra) clearly cluster into 3 statistically distinct groups based on their 8-13 ?m spectra. Additionally we have attempted to simulate in a laboratory the possible organic compounds we have detected on two asteroids, using various mixtures containing aromatic and aliphatic hydrocarbons. We find that asteroid (24) Themis and (65) Cybele have ?CH2/?CH3 and NCH2/NCH3 ratios similar to our 3- methylpentane, propane, and hexane residues, suggesting that the organics on these asteroids may be short chained and/or highly branched. The ?CH2/?CH3 and NCH2/NCH3 for asteroid(24)Themis are most consistent with the DISM, and some carbonaceous chondrites. The band centers of the C-H stretch absorptions indicate that both asteroids may have aliphatic carriers chemically bonded to electronegative groups (i.e. aromatics), and some that are not. We also detect a 3.45 ?m feature in the spectra of both asteroids that is present in several dense molecular clouds. Our results suggest an interstellar origin for the organics on (24) Themis, and likely (65) Cybele. The differences in the organics of Themis and Cybele are likely related to variations in thermal processing, irradiation and/or formation region in the solar nebula.
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Date Issued: 2015
Identifier: CFE0005624, ucf:50201
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005624

Title: Characterization of gold black and its application in un-cooled infrared detectors.
Creator: Panjwani, Deep, Peale, Robert, Chow, Lee, Del Barco, Enrique, Schoenfeld, Winston, University of Central Florida
Abstract / Description: Gold black porous coatings were thermally evaporated in the chamber backfilled with inert gas pressure and their optical properties were studied in near-far-IR wavelengths. The porosities of coatings were found to be extremely high around ~ 99%. Different approaches of effective medium theories such as Maxwell-Garnett, Bruggeman, Landau-Lifshitz-Looyenga and Bergman Formalism were utilized to calculate refractive index (n) and extinction coefficient (k). The aging induced changes on...
Show moreGold black porous coatings were thermally evaporated in the chamber backfilled with inert gas pressure and their optical properties were studied in near-far-IR wavelengths. The porosities of coatings were found to be extremely high around ~ 99%. Different approaches of effective medium theories such as Maxwell-Garnett, Bruggeman, Landau-Lifshitz-Looyenga and Bergman Formalism were utilized to calculate refractive index (n) and extinction coefficient (k). The aging induced changes on electrical and optical properties were studied in regular laboratory conditions using transmission electron microscopy, Fourier transform infrared spectroscopy, and fore-probe electrical measurements. A significant decrease in electrical resistance in as deposited coating was found to be consistent with changes in the granular structure with aging at room temperature. Electrical relaxation model was applied to calculate structural relaxation time in the coatings prepared with different porosities. Interestingly, with aging, absorptance of the coatings improved, which is explained using conductivity form of Bergman Formulism. Underlying aim of this work was to utilize gold blacks to improve sensitivity in un-cooled IR sensors consist of pixel arrays. To achieve this, fragile gold blacks were patterned on sub-mm length scale areas using both stenciling and conventional photolithography. Infrared spectral imaging with sub-micron spatial resolution revealed the spatial distribution of absorption across the gold black patterns produced with both the methods. Initial experiments on VOx-Au bolometers showed that, gold black improved the responsivity by 42%. This work successfully establishes promising role of gold black coatings in commercial un-cooled infrared detectors.
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Date Issued: 2015
Identifier: CFE0005680, ucf:50197
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005680

Title: STRUCTURAL TRANSITION DURING FIBRILLOGENESIS OF AMYLOID ? PEPTIDE.
Creator: Sidrak, George, Tatulian, Suren, University of Central Florida
Abstract / Description: Alzheimer's Disease (AD) is a neurodegenerative disease marked by progressive neuronal cell death, leading to dementia. AD is the most common disease that results in dementia and largely affects the elderly, with five million people in the United States diagnosed with the disease as of 2015 and approximately 35 million people worldwide. Diseases resulting in dementia cost the US healthcare system an estimated $172 billion in 2010 and that cost is expected to increase as the population ages...
Show moreAlzheimer's Disease (AD) is a neurodegenerative disease marked by progressive neuronal cell death, leading to dementia. AD is the most common disease that results in dementia and largely affects the elderly, with five million people in the United States diagnosed with the disease as of 2015 and approximately 35 million people worldwide. Diseases resulting in dementia cost the US healthcare system an estimated $172 billion in 2010 and that cost is expected to increase as the population ages and as diagnostic techniques improve so that more people are treated (Holtzman, 2011). The disease was first reported by psychiatrist Alois Alzheimer at the onset of the 20th century, when one of his patients "suffered memory loss, disorientation, hallucinations and delusions and died at the age of 55," then was found to have severe brain atrophy post-mortem (Cipriani, Dolciotti, Picchi, & Bonuccelli, 2011). There are palliative treatments available that marginally slow disease progression but there is currently no cure for the disease (Awasthi, Singh, Pandey, & Dwivedi, 2016). More research is needed to develop effective therapeutic strategies to combat the disease. Currently, AD cytotoxicity is believed to be caused by increased amyloid ? (A?) peptide plaque deposition in the brain, as described by the amyloid cascade hypothesis (Barage & Sonawane, 2015). The current understanding is that oligomers of A? peptide lead to neuronal death through multiple mechanisms, most notably hyper-phosphorylation of the tau protein. Having a better understanding of the structural changes in the fibrillization process of A? will provide a broader insight into mechanisms of cell death and open new possibilities for pharmacological treatments, which is what this research intends to provide.
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Date Issued: 2017
Identifier: CFH2000178, ucf:45994
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH2000178

Title: NEAR-INFRARED OBSERVATIONS OF COMET-ASTEROID TRANSITION OBJECTS.
Creator: Ziffer, Julie, Campins, Humberto, University of Central Florida
Abstract / Description: The primary objective of this research is to characterize the surface composition of five comet-asteroid transition objects via near-infrared spectroscopy. The five targets include two asteroids with Tisserand invariants lower than 3.0 (1373 Cincinnati and 2906 Caltech), one asteroid that is likely an extinct comet (944 Hidalgo), one intermittent activity comet (162P/Siding Spring), and one nearly dormant comet (28P/Neujmin1). Previous research regarding cometary end states and dynamical and...
Show moreThe primary objective of this research is to characterize the surface composition of five comet-asteroid transition objects via near-infrared spectroscopy. The five targets include two asteroids with Tisserand invariants lower than 3.0 (1373 Cincinnati and 2906 Caltech), one asteroid that is likely an extinct comet (944 Hidalgo), one intermittent activity comet (162P/Siding Spring), and one nearly dormant comet (28P/Neujmin1). Previous research regarding cometary end states and dynamical and physical properties of comets and asteroids provides the foundation for this work. Focusing primarily on the 1-2.5 ?m spectral region of the five target objects, this project specifically searches for mineral species such as olivine, pyroxene, hydrated silicates, and organics. Comparisons are made with comets, main belt asteroids, and Trojan asteroids. All our targets have near-infrared spectra with varying "red" slopes from S'=1.7 to 5.3. Slopes in this range are characteristic of both primitive asteroids and comets. Three of our objects, 944 Hidalgo, 162P/Siding Spring, 28P/Neujmin 1, showed relatively featureless near-infrared spectra. The two objects dynamically most likely to be of asteroidal origin, 1373 Cincinnati and 2906 Caltech, both displayed features in the 0.8 to 2.5 micron range, not present in any of our other targets or the comparison cometary nuclei. Spectra of 944 Hidalgo were acquired at several rotational phases and clear rotational variations were found. Hints of spectral variability were also observed in 28P/Neujmin 1 and 162P/Siding Spring. Neither 1373 nor 2906 were examined for rotational variability. Based on our results, we believe that 1373 Cincinnatti and 2906 Caltech are not cometary. The spectral range of our targets and cometary spectra in the near-infrared is the same as that of Trojan asteroids. Recommendations for future investigation are suggested.
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Date Issued: 2006
Identifier: CFE0001152, ucf:46855
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001152

Title: Nanoplasmonics In Two-dimensional Dirac and Three-dimensional Metallic Nanostructure Systems.
Creator: Safaei, Alireza, Chanda, Debashis, Leuenberger, Michael, Mucciolo, Eduardo, Tetard, Laurene, Zhai, Lei, University of Central Florida
Abstract / Description: Surface plasmons are collective oscillation of electrons which are coupled to the incident electric field. Excitation of surface plasmon is a route to engineer the behavior of light in nanometer length scale and amplifying the light-matter interaction. This interaction is an outcome of near-field enhancement close to the metal surface which leads to plasmon damping through radiative decay to outgoing photons and nonradiative decay inside and on the surface of the material to create an...
Show moreSurface plasmons are collective oscillation of electrons which are coupled to the incident electric field. Excitation of surface plasmon is a route to engineer the behavior of light in nanometer length scale and amplifying the light-matter interaction. This interaction is an outcome of near-field enhancement close to the metal surface which leads to plasmon damping through radiative decay to outgoing photons and nonradiative decay inside and on the surface of the material to create an electron-hole pair via interband or intraband Landau damping. Plasmonics in Dirac systems such as graphene show novel features due to massless electrons and holes around the Dirac cones. Linear band structure of Dirac materials in the low-momentum limit gives rise to the unprecedented optical and electrical properties. Electronical tunability of the plasmon resonance frequency through applying a gate voltage, highly confined electric field, and low plasmon damping are the other special propoerties of the Dirac plasmons. In this work, I will summarize the theoretical and experimental aspects of the electrostatical tunable systems made from monolayer graphene working in mid-infrared regime. I will demonstrate how a cavity-coupled nanopatterned graphene excites Dirac plasmons and enhances the light-matter interaction. The resonance frequency of the Dirac plasmons is tunable by applying a gate voltage. I will show how different gate-dielectrics, and the external conditions like the polarization and angle of incident light affect on the optical response of the nanostructure systems. I will then show the application of these nanodevices in infrared detection at room temperature by using plasmon-assisted hot carriers generation. An asymmetric nanopatterned graphene shows a high responsivity at room temperature which is unprecedented. At the end, I will demonstrate the properties of surface plasmons on 3D noble metals and its applications in light-funneling, photodetection, and light-focusing.
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Date Issued: 2019
Identifier: CFE0007904, ucf:52746
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007904

Title: 2 micron fiber lasers: power scaling concepts and limitations.
Creator: Sincore, Alex, Richardson, Martin, Amezcua Correa, Rodrigo, Schulzgen, Axel, Shah, Lawrence, University of Central Florida
Abstract / Description: Thulium- and holmium-doped fiber lasers (TDF and HDF) emitting at 2 micron offer unique benefits and applications compared to common ytterbium-doped 1 micron lasers. This dissertation details the concepts, limitations, design, and performance of four 2 micron fiber laser systems. While these lasers were developed for various end-uses, they also provide further insight into two major power scaling limitations. The first limitation is optical nonlinearities: specifically stimulated Brillouin...
Show moreThulium- and holmium-doped fiber lasers (TDF and HDF) emitting at 2 micron offer unique benefits and applications compared to common ytterbium-doped 1 micron lasers. This dissertation details the concepts, limitations, design, and performance of four 2 micron fiber laser systems. While these lasers were developed for various end-uses, they also provide further insight into two major power scaling limitations. The first limitation is optical nonlinearities: specifically stimulated Brillouin scattering (SBS) and modulation instability (MI). The second limitation is thermal failure due to inefficient pump conversion. First, a 21.5 W single-frequency, single-mode laser with adjustable output from continuous-wave to nanosecond pulses is developed. Measuring the SBS threshold versus pulse duration enables the Brillouin gain coefficient and gain bandwidth to be determined at 2 micron. Second, a 23 W spectrally-broadband, nanosecond pulsed laser is constructed for materials processing applications. The temporally incoherent multi-kW peak power pulses can also efficiently produce MI and supercontinuum generation by adjusting the input spectral linewidth. Third, the measured performance of in-band pumped TDF and HDF lasers are compared with simulations. HDF displays low efficiencies, which is explained by including ion clustering in the simulations. The TDF operates with impressive (>)90% slope efficiencies. Based on this result, a system design for (>)1 kW average power TDF amplifier is described. The designed final amplifier will be in-band pumped to enable high efficiency and low thermal load. The amplifier efficiency, operating bandwidth, thermal load, and nonlinear limits are modeled and analyzed to provide a framework for execution. Overall, this dissertation provides further insight and understanding on the various processes that limit power scaling of 2 micron fiber lasers.
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Date Issued: 2018
Identifier: CFE0007374, ucf:52105
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007374

Title: Intracavity Laser Absorption Spectroscopy using Quantum Cascade Laser and Fabry-Perot Interferometer.
Creator: Medhi, Gautam, Peale, Robert, Ishigami, Marsahir, Chernyak, Leonid, Delfyett, Peter, University of Central Florida
Abstract / Description: Intracavity Laser Absorption Spectroscopy (ICLAS) at IR wavelengths offers an opportunity for spectral sensing of low vapor pressure compounds. We report here an ICLAS system design based on a quantum cascade laser (QCL) at THz (69.9 ?m) and IR wavelengths (9.38 and 8.1 ?m) with an open external cavity. The sensitivity of such a system is potentially very high due to extraordinarily long effective optical paths that can be achieved in an active cavity. Sensitivity estimation by numerical...
Show moreIntracavity Laser Absorption Spectroscopy (ICLAS) at IR wavelengths offers an opportunity for spectral sensing of low vapor pressure compounds. We report here an ICLAS system design based on a quantum cascade laser (QCL) at THz (69.9 ?m) and IR wavelengths (9.38 and 8.1 ?m) with an open external cavity. The sensitivity of such a system is potentially very high due to extraordinarily long effective optical paths that can be achieved in an active cavity. Sensitivity estimation by numerical solution of the laser rate equations for the THz QCL ICLAS system is determined. Experimental development of the external cavity QCL is demonstrated for the two IR wavelengths, as supported by appearance of fine mode structure in the laser spectrum. The 8.1 ?m wavelength exhibits a dramatic change in the output spectrum caused by the weak intracavity absorption of acetone. Numerical solution of the laser rate equations yields a sensitivity estimation of acetone partial pressure of 165 mTorr corresponding to ~ 200 ppm. The system is also found sensitive to the humidity in the laboratory air with an absorption coefficient of just 3 x 10-7 cm-1 indicating a sensitivity of 111 ppm. Reported also is the design of a compact integrated data acquisition and control system. Potential applications include military and commercial sensing for threat compounds such as explosives, chemical gases, biological aerosols, drugs, banned or invasive organisms, bio-medical breath analysis, and terrestrial or planetary atmospheric science.
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Date Issued: 2011
Identifier: CFE0004137, ucf:49040
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004137

Title: NONLINEAR ABSORPTION AND FREE CARRIER RECOMBINATION IN DIRECT GAP SEMICONDUCTORS.
Creator: Olszak, Peter, Van Stryland, Eric, University of Central Florida
Abstract / Description: Nonlinear absorption of Indium Antimonide (InSb) has been studied for many years, yet due to the complexity of absorption mechanisms and experimental difficulties in the infrared, this is still a subject of research. Although measurements have been made in the past, a consistent model that worked for both picosecond and nanosecond pulse widths had not been demonstrated. In this project, temperature dependent two-photon (2PA) and free carrier absorption (FCA) spectra of InSb are measured using...
Show moreNonlinear absorption of Indium Antimonide (InSb) has been studied for many years, yet due to the complexity of absorption mechanisms and experimental difficulties in the infrared, this is still a subject of research. Although measurements have been made in the past, a consistent model that worked for both picosecond and nanosecond pulse widths had not been demonstrated. In this project, temperature dependent two-photon (2PA) and free carrier absorption (FCA) spectra of InSb are measured using femtosecond, picosecond, and nanosecond IR sources. The 2PA spectrum is measured at room temperature with femtosecond pulses, and the temperature dependence of 2PA and FCA is measured at 10.6m using a nanosecond CO2 laser giving results consistent with the temperature dependent measurements at several wavelengths made with a tunable picosecond system. Measurements over this substantial range of pulse widths give results for FCA and 2PA consistent with a recent theoretical model for FCA. While the FCA cross section has been generally accepted in the past to be a constant for the temperatures and wavelengths used in this study, this model predicts that it varies significantly with temperature as well as wavelength. Additionally, the results for 2PA are consistent with the band gap scaling (Eg-3) predicted by a simple two parabolic band model. Using nanosecond pulses from a CO2 laser enables the recombination rates to be determined through nonlinear transmittance measurements. Three-photon absorption is also observed in InSb for photon energies below the 2PA band edge. Prior to this work, data on three-photon absorption (3PA) in semiconductors was scarce and most experiments were performed over narrow spectral ranges, making comparison to the available theoretical models difficult. There was also disagreement between the theoretical results generated by different models, primarily in the spectral behavior. Therefore, we studied the band gap scaling and spectra of 3PA in several semiconductors by the Z-scan technique. The 3PA coefficient is found to vary as (Eg-7), as predicted by the scaling rules of simple two parabolic band models. The spectral behavior, which is considerably more complex than for 2PA, is found to agree well with a recently published theory based on a four-band model.
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Date Issued: 2010
Identifier: CFE0003402, ucf:48418
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003402

Title: The Consequences of a Reduced Superlattice Thickness on Quantum Cascade LASER Performance.
Creator: Figueiredo, Pedro, Lyakh, Arkadiy, Peale, Robert, Klemm, Richard, Fathpour, Sasan, University of Central Florida
Abstract / Description: Coherent infrared radiation sources are essential for the operability of a wide range of scientific, industrial, military and commercial systems. The importance of the mid-infrared spectral region cannot be understated. Numerous molecules have some vibrational band in this range, allowing for identification of species by means of absorption, emission or some other form of spectroscopy. As such, spectroscopy alone has numerous applications ranging from industrial process control to disease...
Show moreCoherent infrared radiation sources are essential for the operability of a wide range of scientific, industrial, military and commercial systems. The importance of the mid-infrared spectral region cannot be understated. Numerous molecules have some vibrational band in this range, allowing for identification of species by means of absorption, emission or some other form of spectroscopy. As such, spectroscopy alone has numerous applications ranging from industrial process control to disease diagnosis utilizing breath analysis. However, despite the discovery of the LASER in the 60s, to this day the amount of coherent sources in this range is limited. It is for this reason that the quantum cascade laser has gained such momentum over the past 23 years.Quantum Cascade LASERS (QCL) are semiconductor LASERS which are based on the principle of bandgap engineering. This incredible technique is a testament to the technological maturity of the semiconductor industry. It has been demonstrated that by having precise control of individual material composition (band gap control), thicknesses on the order of monolayers, and doping levels for each individual layer in a superlattice, we have unprecedented flexibility in designing a LASER or detector in the infrared. And although the technology has matured since it's discovery, there still remain fundamental limitations on device performance. In particular, active region overheating limits QCL performance in a high duty cycle mode of operation.In this dissertation, along with general discussion on the background of the QCL, we propose a solution of where by limiting the growth of the superlattice to a fraction of typical devices, we allow for reduction of the average superlattice temperature under full operational conditions. The consequences of this reduction are explored in theory, experiment and system level applications.
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Date Issued: 2017
Identifier: CFE0006592, ucf:51273
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006592

Title: Comparison Of Casimir , Elastic, Electrostatic Forces For A Micro-Cantilever.
Creator: Alhasan, Ammar, Peale, Robert, Del Barco, Enrique, Chow, Lee, University of Central Florida
Abstract / Description: Casimir force is a cause of stiction (adhesion) between metal surfaces in Micro-Electro Mechanical Systems (MEMS). Casimir Force depends strongly on the separation of the two surfaces and the contact area. This thesis reviews the theory and prior experimental demonstrations of the Casimir force. Then the Casimir attractive force is calculated for a particular MEMS cantilever device, in which the metal cantilever tip is required to repeatedly touch and release from a metal tip pad on the...
Show moreCasimir force is a cause of stiction (adhesion) between metal surfaces in Micro-Electro Mechanical Systems (MEMS). Casimir Force depends strongly on the separation of the two surfaces and the contact area. This thesis reviews the theory and prior experimental demonstrations of the Casimir force. Then the Casimir attractive force is calculated for a particular MEMS cantilever device, in which the metal cantilever tip is required to repeatedly touch and release from a metal tip pad on the substrate surface in response to a periodic driving electrostatic force. The elastic force due to the bending of the cantilever support arms is also a consideration in the device operation. The three forces are calculated analytically and compared as a function of cantilever tip height. Calculation of the electrostatic force uses coefficients of capacitance and electrostatic induction determined numerically by the finite element method, including the effect of permittivity for the structural oxide. A condition on the tip area to allow electrostatic release of the tip from the surface against Casimir sticking and elastic restoring forces is established.
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Date Issued: 2014
Identifier: CFE0005123, ucf:50713
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005123

Title: Vanadium Oxide Microbolometers with Patterned Gold Black or Plasmonic Resonant Absorbers.
Creator: Smith, Evan, Peale, Robert, Khondaker, Saiful, Dove, Adrienne, Boreman, Glenn, University of Central Florida
Abstract / Description: High sensitivity uncooled microbolometers are necessary to meet the needs of the next generation of infrared detectors, which seek low power consumption and production cost without sacrificing performance. Presented here is the design, fabrication, and characterization of a microbolometer with responsivity enhanced by novel highly absorptive coatings. The device utilizes a gold-doped vanadium oxide film in a standard air bridge design. Performance estimations are calculated from current...
Show moreHigh sensitivity uncooled microbolometers are necessary to meet the needs of the next generation of infrared detectors, which seek low power consumption and production cost without sacrificing performance. Presented here is the design, fabrication, and characterization of a microbolometer with responsivity enhanced by novel highly absorptive coatings. The device utilizes a gold-doped vanadium oxide film in a standard air bridge design. Performance estimations are calculated from current theory, and efforts to maximize signal to noise ratio are shown and evaluated. Most notably, presented are the experimental results and analysis from the integration of two different absorptive coatings: a patterned gold black film and a plasmonic resonant structure.Infrared-absorbing gold black was selectively patterned onto the active surfaces of the detector. Patterning by metal lift-off relies on protection of the fragile gold black with an evaporated oxide, which preserves gold black's near unity absorptance. This patterned gold black also survives the dry-etch removal of the sacrificial polyimide used to fabricate the air-bridge bolometers. Infrared responsivity is improved 70% for mid-wave IR and 22% for long-wave IR. The increase in the thermal time constant caused by the additional mass of gold black is a modest 15%. However, this film is sensitive to thermal processing; experimental results indicate a decrease in absorptance upon device heating.Sub-wavelength resonant structures designed for long-wave infrared (LWIR) absorption have also been investigated. Dispersion of the dielectric refractive index provides for multiple overlapping resonances that span the 8-12 ?m LWIR wavelength band, a broader range than can be achieved using the usual resonance quarter-wave cavity engineered into the air-bridge structures. Experimental measurements show an increase in responsivity of 96% for mid-wave IR and 48% for long-wave IR, while thermal response time only increases by 16% due to the increased heat capacity. The resonant structures are not as susceptible to thermal processing as are the gold black films. This work suggests that plasmonic resonant structures can be an ideal method to improve detector performance for microbolometers.
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Date Issued: 2015
Identifier: CFE0006004, ucf:51026
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006004

Title: Agglomeration, Evaporation and Morphological Changes in Droplets with Nanosilica and Nanoalumina Suspensions in an Acoustic Field.
Creator: Tijerino Campollo, Erick, Kumar, Ranganathan, Deng, Weiwei, Chow, Louis, Basu, Saptarshi, University of Central Florida
Abstract / Description: Acoustic levitation permits the study of droplet dynamics without the effects of surface interactions present in other techniques such as pendant droplet methods. Despite the complexities of the interactions of the acoustic field with the suspended droplet, acoustic levitation provides distinct advantages of controlling morphology of droplets with nanosuspensions post precipitation. Droplet morphology is controlled by vaporization, deformation and agglomeration of nanoparticles, and therefore...
Show moreAcoustic levitation permits the study of droplet dynamics without the effects of surface interactions present in other techniques such as pendant droplet methods. Despite the complexities of the interactions of the acoustic field with the suspended droplet, acoustic levitation provides distinct advantages of controlling morphology of droplets with nanosuspensions post precipitation. Droplet morphology is controlled by vaporization, deformation and agglomeration of nanoparticles, and therefore their respective timescales are important to control the final shape. The balance of forces acting on the droplet, such as the acoustic pressure and surface tension, determine the geometry of the levitated droplet. Thus, the morphology of the resultant structure can be controlled by manipulating the amplitude of the levitator and the fluid properties of the precursor nanosuspensions. The interface area in colloidal nanosuspensions is very large even at low particle concentrations. The effects of the presence of this interface have large influence in the properties of the solution even at low concentrations.This thesis focuses on the dynamics of particle agglomeration in acoustically levitated evaporating nanofluid droplets leading to shell structure formation. These experiments were performed by suspending 500(&)#181;m droplets in a pressure node of a standing acoustic wave in a levitator and heating them using a carbon dioxide laser. These radiatively heated functional droplets exhibit three distinct stages, namely, pure evaporation, agglomeration and structure formation. The temporal history of the droplet surface temperature shows two inflection points. Morphology and final precipitation structures of levitated droplets are due to competing mechanisms of particle agglomeration, evaporation and shape deformation. This thesis provides a detailed analysis for each process and proposes two important timescales for evaporation and agglomeration that determine the final diameter of the structure formed. It is seen that both agglomeration and evaporation timescales are similar functions of acoustic amplitude (sound pressure level), droplet size, viscosity and density. However it is shown that while the agglomeration timescale decreases with initial particle concentration, the evaporation timescale shows the opposite trend. The final normalized diameter hence can be shown to be dependent solely on the ratio of agglomeration to evaporation timescales for all concentrations and acoustic amplitudes. The experiments were conducted with 10nm silica, 20nm silica, 20nm alumina and 50nm alumina solutions. The structures exhibit various aspect ratios (bowls, rings, spheroids) which depend on the ratio of the deformation timescale (tdef) and the agglomeration timescale (tg).
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Date Issued: 2012
Identifier: CFE0004610, ucf:49914
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004610

infrared (10)	+ -
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Plasmonics (3)	+ -
fNIRS (3)	+ -

infrared detector (3)	+ -
spectroscopy (3)	+ -
Functional Near-Infrared Spectroscopy (2)	+ -
Integrated photonics (2)	+ -
MEMS (2)	+ -
absorber (2)	+ -
antenna (2)	+ -
detector (2)	+ -
far-infrared (2)	+ -
functional near-infrared spectroscopy (2)	+ -
gold black (2)	+ -
laser (2)	+ -
prefrontal cortex (2)	+ -
surveillance (2)	+ -
thulium (2)	+ -
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944 Hidalgo (1)	+ -
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Acoustic Optic Modulator (1)	+ -
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ETD Collection (51)	+ -
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University of Central Florida (54)	+ -
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Boreman, Glenn (11)	+ -
Schoenfeld, Winston (6)	+ -
Fathpour, Sasan (5)	+ -

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