Current Search: optical (x)
Pages
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Title
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HYBRID AND HIERARCHICAL IMAGE REGISTRATION TECHNIQUES.
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Creator
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Xu, Dongjiang, Kasparis, Takis, University of Central Florida
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Abstract / Description
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A large number of image registration techniques have been developed for various types of sensors and applications, with the aim to improve the accuracy, computational complexity, generality, and robustness. They can be broadly classified into two categories: intensity-based and feature-based methods. The primary drawback of the intensity-based approaches is that it may fail unless the two images are misaligned by a moderate difference in scale, rotation, and translation. In addition,...
Show moreA large number of image registration techniques have been developed for various types of sensors and applications, with the aim to improve the accuracy, computational complexity, generality, and robustness. They can be broadly classified into two categories: intensity-based and feature-based methods. The primary drawback of the intensity-based approaches is that it may fail unless the two images are misaligned by a moderate difference in scale, rotation, and translation. In addition, intensity-based methods lack the robustness in the presence of non-spatial distortions due to different imaging conditions between images. In this dissertation, the image registration is formulated as a two-stage hybrid approach combining both an initial matching and a final matching in a coarse-to-fine manner. In the proposed hybrid framework, the initial matching algorithm is applied at the coarsest scale of images, where the approximate transformation parameters could be first estimated. Subsequently, the robust gradient-based estimation algorithm is incorporated into the proposed hybrid approach using a multi-resolution scheme. Several novel and effective initial matching algorithms have been proposed for the first stage. The variations of the intensity characteristics between images may be large and non-uniform because of non-spatial distortions. Therefore, in order to effectively incorporate the gradient-based robust estimation into our proposed framework, one of the fundamental questions should be addressed: what is a good image representation to work with using gradient-based robust estimation under non-spatial distortions. With the initial matching algorithms applied at the highest level of decomposition, the proposed hybrid approach exhibits superior range of convergence. The gradient-based algorithms in the second stage yield a robust solution that precisely registers images with sub-pixel accuracy. A hierarchical iterative searching further enhances the convergence range and rate. The simulation results demonstrated that the proposed techniques provide significant benefits to the performance of image registration.
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Date Issued
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2004
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Identifier
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CFE0000317, ucf:46294
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0000317
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Title
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AUTONOMOUS REPAIR OF OPTICAL CHARACTER RECOGNITION DATA THROUGH SIMPLE VOTING AND MULTI-DIMENSIONAL INDEXING TECHNIQUES.
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Creator
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Sprague, Christopher, Weeks, Arthur, University of Central Florida
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Abstract / Description
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The three major optical character recognition (OCR) engines (ExperVision, Scansoft OCR, and Abby OCR) in use today are all capable of recognizing text at near perfect percentages. The remaining errors however have proven very difficult to identify within a single engine. Recent research has shown that a comparison between the errors of the three engines proved to have very little correlation, and thus, when used in conjunction, may be useful to increase accuracy of the final result. This...
Show moreThe three major optical character recognition (OCR) engines (ExperVision, Scansoft OCR, and Abby OCR) in use today are all capable of recognizing text at near perfect percentages. The remaining errors however have proven very difficult to identify within a single engine. Recent research has shown that a comparison between the errors of the three engines proved to have very little correlation, and thus, when used in conjunction, may be useful to increase accuracy of the final result. This document discusses the implementation and results of a simple voting system designed to prove the hypothesis and show a statistical improvement in overall accuracy. Additional aspects of implementing an improved OCR scheme such as dealing with multiple engine data output alignment and recognizing application specific solutions are also addressed in this research. Although voting systems are currently in use by many major OCR engine developers, this research focuses on the addition of a collaborative system which is able to utilize the various positive aspects of multiple engines while also addressing the immediate need for practical industry applications such as litigation and forms processing. Doculex TM, a major developer and leader in the document imaging industry, has provided the funding for this research.
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Date Issued
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2005
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Identifier
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CFE0000380, ucf:46337
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0000380
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Title
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TUNABLE NANOSTRUCTURE ANTI-REFLECTIVE COATINGS.
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Creator
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Brinley, Erik, Seal, Sudipta, University of Central Florida
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Abstract / Description
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Research was conducted on broadband, anti-reflective coatings for fused silica and chalcogenide substrates in the infrared region of light. Using chemical preparation to create nano-porous through nano-particle based sol-gel solutions, the alteration of optical properties including refractive index and optical thickness was conducted. The nano-particles can modify the coating surface to allow only zero-order diffracted wave propagation reducing scattering while a partially graded profile of...
Show moreResearch was conducted on broadband, anti-reflective coatings for fused silica and chalcogenide substrates in the infrared region of light. Using chemical preparation to create nano-porous through nano-particle based sol-gel solutions, the alteration of optical properties including refractive index and optical thickness was conducted. The nano-particles can modify the coating surface to allow only zero-order diffracted wave propagation reducing scattering while a partially graded profile of refractive index due surface evaporation lessened the precise phase relations of typical homogeneous coatings. My study of silica and titania sol-gel, and hybrid mixtures of the two were used to obtain the optical properties of the materials. The choice of experiments were rooted in theoretically calculated values, and parameters were selected based on quarter wavelength thickness and square root of refractive index theories of destructive cancellation of rebound waves for reduction of reflection. The fused silica system required anti-reflection in the region of 1.0-1.6 micrometer wavelength of the near-infrared. The base, uncoated transmission in this region is ~91%. A maximum transmission of 98% and no less than 97.3% over the entire region of interest was achieved. The chalcogenide system required anti-reflection in the regions of 1.0-1.6 and 3.5-5.0 micrometers of the near- and mid-infrared. The base, uncoated transmission of these regions is 61.9%. A maximum of 95% transmission was achieved for the 1.0-1.6 region and 87% for the 3.5-5.0 region. Solutions and coatings were characterized by Scanning Electron Microscope, Atomic Force Microscopy, X-ray Photoelectron Spectroscopy, particle size, elipsometry, UV-Vis-NIR, and FTIR to reveal the science behind the development and synthesis of nano optical coatings.
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Date Issued
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2007
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Identifier
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CFE0001641, ucf:47247
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001641
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Title
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MODELING OF LIQUID CRYSTAL DISPLAY AND PHOTONIC DEVICES.
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Creator
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Ge, Zhibing, Wu, Shin-Tson, University of Central Florida
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Abstract / Description
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Liquid crystal (LC) materials have been widely applied in electro-optical devices, among which display is the most successful playground and numerous new applications in photonic areas (such as laser beam steering devices) are also emerging. To well guide the device design for optimum performance, accurate modeling is of prior and practical importance. Generally, the modeling of LC devices includes two parts in sequence: accurate LC molecule deformation extraction under external electric...
Show moreLiquid crystal (LC) materials have been widely applied in electro-optical devices, among which display is the most successful playground and numerous new applications in photonic areas (such as laser beam steering devices) are also emerging. To well guide the device design for optimum performance, accurate modeling is of prior and practical importance. Generally, the modeling of LC devices includes two parts in sequence: accurate LC molecule deformation extraction under external electric fields and optical calculation thereafter for the corresponding electro-optical behaviors. In this dissertation, first, hybrid finite element method and finite difference method are developed to minimize the free energy of the LC systems. In this part of study, with computer-aided derivation, the full forms of the LC free energy equations without any simplification can be obtained. Besides, Galerkin's method and weak form technique are further introduced to successfully degrade the high order nonlinear derivative terms associated with the free energy equations into ones that can be treated by first order interpolation functions for high accuracy. The developed modeling methods for LC deformation are further employed to study display structures, such as 2D and 3D in-plane switching LC cells, and provides accurate results. Followed is the optical modeling using extended Jones matrix and beam propagation method to calculate the electro-optical performances of different devices, according to their amplitude modulation property or diffractive one. The developed methods are further taken to assist the understanding, development, and optimization of the display and photonic devices. For their application in the display area, sunlight readable transflective LCDs for mobile devices and the related optical films for wide viewing angle are developed and studied. New cell structure using vertically aligned liquid crystal mode is developed and studied to obtain a single cell gap, high light efficiency transflective LCD that can be driven by one gray scale control circuit for both transmissive and reflective modes. And employing an internal wire grid polarizer into a fringe field switching cell produces a single cell gap and wide viewing angle display with workable reflective mode under merely two linear polarizers. To solve the limited viewing angle of conventional circular polarizers, Poincaré sphere as an effective tool is taken to trace and understand the polarization change of the incident light throughout the whole LC system. This study further guides the design of high performance circular polarizers that can consist of purely uniaxial plates or a combination of uniaxial and biaxial plates. The developed circular polarizers greatly enhance the viewing angle of transflective LCDs. Especially, the circular polarizer design using a biaxial film can even provide comparable wide viewing angle performance for the same vertically aligned cell as it is used between merely two linear polarizers, while using circular polarizers can greatly boost the display brightness. As for the beam steering device modeling, the developed LC deformation method is taken to accurately calculate the associated LC director distribution in the spatial light modulator, while beam propagation method and Fourier transformation technique are combined to calculate the near and far fields from such devices. The modeling helps to better understand the origins and formations of the disclinations associated with the fringe fields, which further result in reduced steering efficiency and output asymmetric polarizations between positive and negative diffractions. Optimization in both voltage profile and driving methods is conducted to well tune the LC deformation under strong fringe fields and improve the light efficiency.
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Date Issued
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2007
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Identifier
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CFE0001908, ucf:47481
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001908
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Title
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STABLE OPTICAL FREQUENCY COMB GENERATION AND APPLICATIONS IN ARBITRARY WAVEFORM GENERATION, SIGNAL PROCESSING AND OPTICAL DATA MINING.
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Creator
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Ozharar, Sarper, Delfyett, Peter, University of Central Florida
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Abstract / Description
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This thesis focuses on the generation and applications of stable optical frequency combs. Optical frequency combs are defined as equally spaced optical frequencies with a fixed phase relation among themselves. The conventional source of optical frequency combs is the optical spectrum of the modelocked lasers. In this work, we investigated alternative methods for optical comb generation, such as dual sine wave phase modulation, which is more practical and cost effective compared to modelocked...
Show moreThis thesis focuses on the generation and applications of stable optical frequency combs. Optical frequency combs are defined as equally spaced optical frequencies with a fixed phase relation among themselves. The conventional source of optical frequency combs is the optical spectrum of the modelocked lasers. In this work, we investigated alternative methods for optical comb generation, such as dual sine wave phase modulation, which is more practical and cost effective compared to modelocked lasers stabilized to a reference. Incorporating these comblines, we have generated tunable RF tones using the serrodyne technique. The tuning range was ±1 MHz, limited by the electronic waveform generator, and the RF carrier frequency is limited by the bandwidth of the photodetector. Similarly, using parabolic phase modulation together with time division multiplexing, RF chirp extension has been realized. Another application of the optical frequency combs studied in this thesis is real time data mining in a bit stream. A novel optoelectronic logic gate has been developed for this application and used to detect an 8 bit long target pattern. Also another approach based on orthogonal Hadamard codes have been proposed and explained in detail. Also novel intracavity modulation schemes have been investigated and applied for various applications such as a) improving rational harmonic modelocking for repetition rate multiplication and pulse to pulse amplitude equalization, b) frequency skewed pulse generation for ranging and c) intracavity active phase modulation in amplitude modulated modelocked lasers for supermode noise spur suppression and integrated jitter reduction. The thesis concludes with comments on the future work and next steps to improve some of the results presented in this work.
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Date Issued
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2008
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Identifier
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CFE0002388, ucf:47744
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002388
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Title
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EVALUATION OF THE PHOTO-INDUCED STRUCTURAL MECHANISMS IN CHALCOGENIDE GLASS MATERIALS.
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Creator
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Lopez, Cedric, Richardson, Kathleen, University of Central Florida
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Abstract / Description
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Chalcogenide glasses and their use in a wide range of optical, electronic and memory applications, has created a need for a more thorough understanding of material property variation as a function of composition and in geometries representative of actual devices. This study evaluates compositional dependencies and photo-induced structural mechanisms in As-S-Se chalcogenide glasses. An effective fabrication method for the reproducible processing of bulk chalcogenide materials has been...
Show moreChalcogenide glasses and their use in a wide range of optical, electronic and memory applications, has created a need for a more thorough understanding of material property variation as a function of composition and in geometries representative of actual devices. This study evaluates compositional dependencies and photo-induced structural mechanisms in As-S-Se chalcogenide glasses. An effective fabrication method for the reproducible processing of bulk chalcogenide materials has been demonstrated and an array of tools developed, for the systematic characterization of the resulting material's physical and optical properties. The influence of compositional variation on the physical properties of 13 glasses within the As-S-Se system has been established. Key structural and optical differences have been observed and quantified between bulk glasses and their corresponding as-deposited films. The importance of annealing and aging of the film material and the impact on photosentivity and long term behavior important to subsequent device stability have been evaluated. Photo-induced structures have been created in the thin films using bandgap cw and sub-bandgap femtosecond laser sources and the exposure conditions and their influence on the post-exposure material properties, have been found to have different limitations and driving mechanisms. These mechanisms largely depend on both structural and/or electronic defects, whether initially present in the chalcogenide material or created upon exposure. These defect processes, largely studied previously in individual binary material systems, have now been shown to be consistently present, but varying in extent, across the ternary glass compositions and exposure conditions examined. We thus establish the varying photo-response of these defects as being the major reason for the optical variations observed. Nonlinear optical material properties, as related to the multiphoton processes used in our exposure studies, have been modeled and a tentative explanation for their variation in the context of composition and method of evaluation is presented.
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Date Issued
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2004
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Identifier
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CFE0000196, ucf:46177
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0000196
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Title
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SELECTIVE MODE EXCITATION IN SPECIALTY WAVEGUIDES USING MICRO OPTICAL ELEMENTS.
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Creator
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Mohammed, Waleed, Johnosn, Eric, University of Central Florida
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Abstract / Description
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Although optical fibers and specialty waveguides are the base of majority of today's telecom and light delivery applications, fabrication deformation, nonlinearity and attenuation limit the bandwidth of the data being transmitted or the amount of power carried by these systems. One-way to overcome these limitations without changing the fibers design or fabrication is to engineer the input light in order to excite a certain mode or a group of modes with unique optical properties. Diffractive...
Show moreAlthough optical fibers and specialty waveguides are the base of majority of today's telecom and light delivery applications, fabrication deformation, nonlinearity and attenuation limit the bandwidth of the data being transmitted or the amount of power carried by these systems. One-way to overcome these limitations without changing the fibers design or fabrication is to engineer the input light in order to excite a certain mode or a group of modes with unique optical properties. Diffractive and micro optics are highly effective for selectively coupling light to specific modes. Using micro optics, mode selective coupling can be achieved through several matching schemes: phase only, phase and amplitude, or phase, amplitude and polarization. The main scope of this work is the design and fabrication of novel optical elements that overcome the limitations of these light delivery systems, as well as the characterization and analysis of their performance both experimentally and using numerical simulation
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Date Issued
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2004
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Identifier
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CFE0000171, ucf:46163
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0000171
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Title
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DIRECT NONLINEAR OPTICS MEASUREMENTS OF RAMAN GAIN IN BULK GLASSES AND ESTIMATES OF FIBER PERFORMANCE.
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Creator
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Stegeman, Robert, Delfyett, Peter, University of Central Florida
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Abstract / Description
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The need for more bandwidth in communications has stimulated the search for new fiberizable materials with properties superior to fused silica which is the current state-of-the-art. One of the key properties is Raman gain by which a pump beam amplifies a signal beam of longer wavelength. An apparatus capable of directly measuring the spectral dependence and absolute magnitude of the material Raman gain coefficient using nonlinear optics techniques has been built. Using radiation from a 1064...
Show moreThe need for more bandwidth in communications has stimulated the search for new fiberizable materials with properties superior to fused silica which is the current state-of-the-art. One of the key properties is Raman gain by which a pump beam amplifies a signal beam of longer wavelength. An apparatus capable of directly measuring the spectral dependence and absolute magnitude of the material Raman gain coefficient using nonlinear optics techniques has been built. Using radiation from a 1064 nm Nd:YAG laser as the pump and from a tunable Optical Parametric Generator and Amplifier as the signal, the Raman gain spectrum was measured for different families of glass samples with millimeter thickness. A number of glass families were investigated. Tellurites with added oxides of tungsten, niobium, and thallium produced the largest Raman gain coefficients of any oxide family reported to date, typically 30-50 times higher than that of fused silica. On the other hand, phosphate families were found with spectrally broad Raman gain response, 5 times broader than fused silica and flat to b3dB over the full spectral range in some compositions. Although the chalcogenides were found to photodamage easily, coefficients 50 - 80 times that of fused silica were measured. Finally, a numerical study was undertaken to predict the theoretical performance and noise properties of tellurite fibers for communications. Included in the computer modeling were linear loss; the interaction among multiple pumps and signals; forward and/or backward propagating pump beams; forward, backward and double Rayleigh scattering; noise properties of amplifiers; excess noise, etc. This led to a comparison of the optical signal-to-noise characteristics for Raman gain in a tellurite versus a silica fiber.
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Date Issued
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2006
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Identifier
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CFE0000928, ucf:46739
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0000928
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Title
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DESIGN AND OPTIMIZATION OF NANO-OPTICAL ELEMENTS BY COUPLING FABRICATION TO OPTICAL BEHAVIOR.
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Creator
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Rumpf, Raymond, Johnson, Eric, University of Central Florida
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Abstract / Description
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Photonic crystals and nanophotonics have received a great deal of attention over the last decade, largely due to improved numerical modeling and advances in fabrication technologies. To this day, fabrication and optical behavior remain decoupled during the design phase and numerous assumptions are made about "perfect" geometry. As research moves from theory to real devices, predicting device behavior based on realistic geometry becomes critical. In this dissertation, a set of numerical tools...
Show morePhotonic crystals and nanophotonics have received a great deal of attention over the last decade, largely due to improved numerical modeling and advances in fabrication technologies. To this day, fabrication and optical behavior remain decoupled during the design phase and numerous assumptions are made about "perfect" geometry. As research moves from theory to real devices, predicting device behavior based on realistic geometry becomes critical. In this dissertation, a set of numerical tools was developed to model micro and nano fabrication processes. They were combined with equally capable tools to model optical performance of the simulated structures. Using these tools, it was predicted and demonstrated that 3D nanostructures may be formed on a standard mask aligner. A space-variant photonic crystal filter was designed and optimized based on a simple fabrication method of etching holes through hetero-structured substrates. It was found that hole taper limited their optical performance and a method was developed to compensate. A method was developed to tune the spectral response of guided-mode resonance filters at the time of fabrication using models of etching and deposition. Autocloning was modeled and shown that it could be used to form extremely high aspect ratio structures to improve performance of form-birefringent devices. Finally, the numerical tools were applied to metallic photonic crystal devices.
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Date Issued
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2006
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Identifier
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CFE0001159, ucf:46849
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001159
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Title
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APPLICATIONS OF LINEAR AND NONLINEAR OPTICAL EFFECTS IN LIQUID CRYSTALS.
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Creator
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Sarkissian, Hakob, Zeldovich, Boris, University of Central Florida
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Abstract / Description
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Liquid crystals have been a major subject of research for the past decades. Aside from the variety of structures they can form, they exhibit a vast range of optical phenomena. Many of these phenomena found applications in technology and became an essential part of it. In this dissertation thesis we continue the line to propose a number of new applications of optical effects in liquid crystals and develop their theoretical framework. One such application is the possibility of beam combining...
Show moreLiquid crystals have been a major subject of research for the past decades. Aside from the variety of structures they can form, they exhibit a vast range of optical phenomena. Many of these phenomena found applications in technology and became an essential part of it. In this dissertation thesis we continue the line to propose a number of new applications of optical effects in liquid crystals and develop their theoretical framework. One such application is the possibility of beam combining using Orientational Stimulated Scattering in a nematic liquid crystal cell. Our numerical study of the OSS process shows that normally this possibility does not exist. However, we found that if a number of special conditions is satisfied efficient beam combining with OSS can be done. These conditions require a combination of special geometric arrangement of incident beams, their profiles, nematic material, and more. When these conditions are fulfilled, power of the beamlets can be coherently combined into a single beam, with high conversion efficiency while the shape and wave-front of the output beam are still of good quality. We also studied the dynamics of the OSS process itself and observed (in a numerical model) a number of notorious instabilities caused by effects of back-conversion iv process. Additionally, there was found a numerical solitary-wave solution associated with this back-conversion process. As a liquid crystal display application, we consider a nematic liquid crystal layer with the anisotropy axis modulated at a fixed rate in the transverse direction with respect to light propagation direction. If the layer locally constitutes a half-wave plate, then the thinscreen approximation predicts 100% -efficient diffraction of normal incident wave. If this diffracted light is blocked by an aperture only transmitting the zero-th order, the cell is in dark state. If now the periodic structure is washed out by applying voltage across the cell and light passes through the cell undiffracted, the light will pass through the aperture as well and the cell will be in its bright state. Such properties of this periodically aligned nematic layer suggest it as a candidate element in projection display cells. We studied the possibility to implement such layer through anchoring at both surfaces of the cell. It was found that each cell has a thickness threshold for which the periodic structure can exist. The anchored periodic structure cannot exist if thickness of the cell exceeds this threshold. For the case when the periodic structure exists, we found the structure distortion in comparison with the preferable ideal sinusoidal profile. To complete description of the electromechanical properties of the periodic cell, we studied its behavior at Freedericksz transition. Optical performance was successfully described with the coupled-mode theory. While influence of director distortion is shown to be negligibly small, the walk-off effects appear to be larger. In summary, there are good prospects for use of this periodically v aligned cell as a pixel in projection displays but experimental study and optimization need to be performed. In the next part we discuss another modulated liquid crystal structure in which the director periodically swings in the direction of light propagation. The main characteristic of such structure is the presence of bandgap. Cholesteric liquid crystals are known to possess bandgap for one of two circular polarizations of light. However, unlike the cholesterics the bandgap of the proposed structure is independent of polarization of normally incident light. This means that no preparation of light is needed in order for the structure to work in, for example, liquid crystal displays. The polarization universality comes at the cost of bandgap size, whose maximum possible value ∆ωPTN compared to that of cholesterics ∆ωCh is approximately twice smaller: ∆ωPTN ≈ 0.58∆ωCh if modulation profile is sinusoidal, and ∆ωPTN ≈ 0.64∆ωCh if it is rectangular. This structure has not yet been experimentally demonstrated, and we discuss possible ways to make it.
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Date Issued
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2006
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Identifier
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CFE0001164, ucf:46856
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001164
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Title
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MOLECULAR STRUCTURE NONLINEAR OPTICAL PROPERTY RELATIONSHIPS FOR A SERIES OF POLYMETHINE AND SQUARAINE MOLECULES.
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Creator
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Fu, Jie, Van Stryland, Eric, University of Central Florida
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Abstract / Description
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This dissertation reports on the investigation of the relationships between molecular structure and two-photon absorption (2PA) properties for a series of polymethine and squaraine molecules. Current and emerging applications exploiting the quadratic dependence upon laser intensity, such as two-photon fluorescence imaging, three-dimensional microfabrication, optical data storage and optical limiting, have motivated researchers to find novel materials exhibiting strong 2PA. Organic materials...
Show moreThis dissertation reports on the investigation of the relationships between molecular structure and two-photon absorption (2PA) properties for a series of polymethine and squaraine molecules. Current and emerging applications exploiting the quadratic dependence upon laser intensity, such as two-photon fluorescence imaging, three-dimensional microfabrication, optical data storage and optical limiting, have motivated researchers to find novel materials exhibiting strong 2PA. Organic materials are promising candidates because their linear and nonlinear optical properties can be optimized for applications by changing their structures through molecular engineering. Polymethine and squaraine dyes are particularly interesting because they are fluorescent and showing large 2PA. We used three independent nonlinear spectroscopic techniques (Z-scan, two-photon fluorescence and white-light continuum pump-probe spectroscopy) to obtain the 2PA spectra revealing 2PA bands, and we confirm the experimental data by comparing the results from the different methods mentioned. By systematically altering the structure of polyemthines and squaraines, we studied the effects of molecular symmetry, strength of donor terminal groups, conjugation length of the chromophore chain, polarity of solvents, and the effects of placing bridge molecules inside the chromophore chain on the 2PA properties. We also compared polymethine, squaraine, croconium and tetraon dyes with the same terminal groups to study the effects of the different additions inserted within the chromophore chain on their optical properties. Near IR absorbing squaraine dyes were experimentally observed to show extremely large 2PA cross sections ( 30000GM). A simplified three-level model was used to fit the measured 2PA spectra and detailed quantum chemical calculations revealed the reasons for the squaraine to exhibit strong 2PA. In addition, two-photon excitation fluorescence anisotropy spectra were measured through multiple 2PA transitions. A theoretical model based on four-levels with two intermediate states was derived and used for analysis of the experimental data.
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Date Issued
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2006
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Identifier
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CFE0001350, ucf:46967
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001350
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Title
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DIGITAL SIGNAL PROCESSING TECHNIQUES FOR COHERENT OPTICAL COMMUNICATION.
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Creator
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Goldfarb, Gilad, Li, Guifang, University of Central Florida
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Abstract / Description
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Coherent detection with subsequent digital signal processing (DSP) is developed, analyzed theoretically and numerically and experimentally demonstrated in various fiber‐optic transmission scenarios. The use of DSP in conjunction with coherent detection unleashes the benefits of coherent detection which rely on the preservation of full information of the incoming field. These benefits include high receiver sensitivity, the ability to achieve high spectral‐efficiency and the use of...
Show moreCoherent detection with subsequent digital signal processing (DSP) is developed, analyzed theoretically and numerically and experimentally demonstrated in various fiber‐optic transmission scenarios. The use of DSP in conjunction with coherent detection unleashes the benefits of coherent detection which rely on the preservation of full information of the incoming field. These benefits include high receiver sensitivity, the ability to achieve high spectral‐efficiency and the use of advanced modulation formats. With the immense advancements in DSP speeds, many of the problems hindering the use of coherent detection in optical transmission systems have been eliminated. Most notably, DSP alleviates the need for hardware phase‐locking and polarization tracking, which can now be achieved in the digital domain. The complexity previously associated with coherent detection is hence significantly diminished and coherent detection is once again considered a feasible detection alternative. In this thesis, several aspects of coherent detection (with or without subsequent DSP) are addressed. Coherent detection is presented as a means to extend the dispersion limit of a duobinary signal using an analog decision‐directed phase‐lock loop. Analytical bit‐error ratio estimation for quadrature phase‐shift keying signals is derived. To validate the promise for high spectral efficiency, the orthogonal‐wavelength‐division multiplexing scheme is suggested. In this scheme the WDM channels are spaced at the symbol rate, thus achieving the spectral efficiency limit. Theory, simulation and experimental results demonstrate the feasibility of this approach. Infinite impulse response filtering is shown to be an efficient alternative to finite impulse response filtering for chromatic dispersion compensation. Theory, design considerations, simulation and experimental results relating to this topic are presented. Interaction between fiber dispersion and nonlinearity remains the last major challenge deterministic effects pose for long‐haul optical data transmission. Experimental results which demonstrate the possibility to digitally mitigate both dispersion and nonlinearity are presented. Impairment compensation is achieved using backward propagation by implementing the split‐step method. Efficient realizations of the dispersion compensation operator used in this implementation are considered. Infinite‐impulse response and wavelet‐based filtering are both investigated as a means to reduce the required computational load associated with signal backward‐propagation. Possible future research directions conclude this dissertation.
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Date Issued
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2008
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Identifier
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CFE0002384, ucf:47763
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002384
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Title
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INTEGRATED OPTICAL SPR (SURFACE PLASMON RESONANCE) SENSOR BASED ON OPTOELECTRONIC PLATFORM.
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Creator
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Bang, Hyungseok, LiKamWa, Patrick, University of Central Florida
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Abstract / Description
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Current major demands in SPR sensor development are system miniaturization and throughput improvement. Structuring an array of integrated optical SPR sensor heads on a semiconductor based optoelectronic platform could be a promising solution for those issues, since integrated optical waveguides have highly miniaturized dimension and the optoelectronic platform enables on-chip optical-to-electrical signal conversion. Utilizing a semiconductor based platform to achieve optoelectronic...
Show moreCurrent major demands in SPR sensor development are system miniaturization and throughput improvement. Structuring an array of integrated optical SPR sensor heads on a semiconductor based optoelectronic platform could be a promising solution for those issues, since integrated optical waveguides have highly miniaturized dimension and the optoelectronic platform enables on-chip optical-to-electrical signal conversion. Utilizing a semiconductor based platform to achieve optoelectronic functionality poses requirements to the senor head; the sensor head needs to have reasonably small size while it should have reasonable sensitivity and fabrication tolerance. This research proposes a novel type of SPR sensor head and demonstrates a fabricated device with an array of integrated optical SPR sensor heads endowed with optoelectronic functionality. The novel integrated optical SPR sensor head relies on mode conversion efficiency for its operational principle. The beauty of this type of sensor head is it can produce clear contrast in SPR spectrum with a highly miniaturized and simple structure, in contrast to several-millimeter-scale conventional absorption type or interferometer type sensor heads. The integrated optical SPR sensor with optoelectronic functionality has been realized by structuring a dielectric waveguide based SPR sensor head on a photodetector-integrated semiconductor substrate. A large number of unit sensors have been fabricated on a substrate with a batch fabrication process, which promises a high throughput SPR sensor system or low-priced disposable sensors.
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Date Issued
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2008
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Identifier
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CFE0002312, ucf:47841
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002312
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Title
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Electronic, Optical, and Magnetic Properties of Graphene and Single-Layer Transition Metal Dichalcogenides in the Presence of Defects.
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Creator
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Khan, Mahtab, Leuenberger, Michael, Mucciolo, Eduardo, Saha, Haripada, Tetard, Laurene, Schoenfeld, Winston, University of Central Florida
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Abstract / Description
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Two-dimensional (2D) materials, such as graphene and single-layer (SL) transition metal dichalcogenides (TMDCs), have attracted a lot of attention due to their fascinating electronic and optical properties. Graphene was the first 2D material that has successfully been exfoliated from bulk graphite in 2004. In graphene, charge carriers interacting with the honeycomb lattice of carbonatoms of graphene to appear as massless Dirac fermions. Massless quasiparticles with linear dispersion are also...
Show moreTwo-dimensional (2D) materials, such as graphene and single-layer (SL) transition metal dichalcogenides (TMDCs), have attracted a lot of attention due to their fascinating electronic and optical properties. Graphene was the first 2D material that has successfully been exfoliated from bulk graphite in 2004. In graphene, charge carriers interacting with the honeycomb lattice of carbonatoms of graphene to appear as massless Dirac fermions. Massless quasiparticles with linear dispersion are also observed in surface states of 3D topological insulators and quantum Hall edgestates. My first project deals with the two-dimensional Hong-Ou-Mandel (HOM) type interferenceexperiment for massless Dirac fermions in graphene and 3D topological insulators. Since masslessDirac fermions exhibit linear dispersion, similar to photons in vacuum, they can be used to observethe HOM interference intensity pattern as a function of the delay time between two massless Dirac fermions. My further projects and the major part of this dissertation deal with single-layer (SL) transition metal dichalcogenides (TMDCs), such as MoS$_2$, WS$_2$, MoSe$_2$ and WSe$_2$, which have recently emerged as a new family of two-dimensional (2D) materials with great interest, not only from the fundamental point of view, but also because of their potential application to ultrathin electronic and optoelectronic devices. In contrast to graphene, SL TMDCs are direct band semiconductors and exhibit large intrinsic spin-orbit coupling (SOC), originating from the d orbitals of transition metal atoms. Wafer-scale production of SL TMDCs is required for industrial applications. It has been shown that artificially grown samples of SL TMDCs through various experimental techniques, such as physical vapor deposition (PVD), chemical vapor deposition (CVD), and molecular beam epitaxy (MBE), are not perfect, instead certain type of imperfections such as point defects are always found to be present in the grown samples. Defects compromise the crystallinity of the sample, which results in reduced carrier mobility and deteriorated optical efficiency. However, defects are not always unwanted; in fact, defects can play an important role in tailoring electronic, optical, and magnetic properties of materials. Using Density functional theory we investigate the impact of point defects on the electronic, optical, and magnetic properties of SL TMDCs. First, we show that certain vacancy defects lead to localized defect states, which in turn give rise to sharp transitions in in-plane and out-of-plane optical susceptibilities of SL TMDCs. Secondly, we show that a naturally occurring antisite defect Mo$_S$ in PVD grown MoS$_2$ is magnetic in nature with a magneticmoment of 2$\mu_B$, and remarkably exhibit an exceptionally large atomic scale magnetic anisotropy energy (MAE) of ~ 500 eV. Both magnetic moment and MAE can be tuned by shifting the position of the Fermi level which can be achieved either by gate voltage or by chemical doping. Thirdly, we argue that the antisite defect Se$_W$ in WSe$_2$ leads to long lived localized excited states, which can explain the observed single quantum emitters in CVD grown WSe$_2$ samples, with potential application to quantum cryptography.
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Date Issued
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2018
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Identifier
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CFE0007030, ucf:52047
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007030
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Title
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Broadband Mid-infrared Frequency Combs Generated via Frequency Division.
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Creator
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Ru, Qitian, Vodopyanov, Konstantin, Fathpour, Sasan, Wu, Shintson, Peale, Robert, University of Central Florida
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Abstract / Description
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Frequency combs have revolutionized metrology and demonstrated numerous applications in science and technology. Combs operating in the mid-infrared region could be beneficial for molecular spectroscopy for several reasons. First, numerous molecules have their spectroscopic signatures in this region. Furthermore, the atmospheric window (3-5(&)#181;m and 8-14(&)#181;m) is located here. Additionally, a mid-infrared frequency comb could be employed as a diagnostic tool for the many components of...
Show moreFrequency combs have revolutionized metrology and demonstrated numerous applications in science and technology. Combs operating in the mid-infrared region could be beneficial for molecular spectroscopy for several reasons. First, numerous molecules have their spectroscopic signatures in this region. Furthermore, the atmospheric window (3-5(&)#181;m and 8-14(&)#181;m) is located here. Additionally, a mid-infrared frequency comb could be employed as a diagnostic tool for the many components of human breath, as well as for detection of harmful gases and contaminants in the atmosphere. In this thesis, I used synchronously pumped subharmonic optical parametric oscillators (OPOs) operating at degeneracy to produce ultra-broadband outputs near half of the pump laser frequency. One attractive property of the subharmonic OPOs is that the signal/idler waves of the OPO are frequency- and phase-locked to the pump frequency comb. We explored three new nonlinear materials in the subharmonic OPO and demonstrated a broadband spectrum for mid-infrared frequency comb generation. (1) Orientation-patterned (OP) gallium arsenide (GaAs) was selected as the first material because it has high nonlinearity. We found that the OP-GaAs based OPO yielded an approximately two-octave wide spectrum (2.8(-)11(&)#181;m). (2) Gallium phosphide (GaP) has near zero group velocity dispersion (GVD) at 4.7 (&)#181;m and a large bandgap. The OP-GaP OPO yielded a spectrum of more than two octaves (3(-)12.5(&)#181;m). Also, because of the large bandgap, GaP is suitable for telecom 1.56-(&)#181;m pumping, having the advantage of much smaller GVD than in periodically-poled-lithium-niobite (PPLN). The telecom laser (1.56(&)#181;m) pumped OP-GaP OPO was demonstrated with more than one octave wide spectrum. (3) Finally, we explored the phenomenon of random phase matching in the zinc selenide (ZnSe) polycrystalline material. The first random phase matched OPO was demonstrated with more than one octave spectrum (3.1(-) 9(&)#181;m), which is also the first OPO based on ZnSe.
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Date Issued
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2019
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Identifier
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CFE0007718, ucf:52430
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007718
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Title
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Wavelength scale resonant structures for integrated photonic applications.
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Creator
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Weed, Matthew, Schoenfeld, Winston, Moharam, M., Likamwa, Patrick, Delfyett, Peter, Leuenberger, Michael, University of Central Florida
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Abstract / Description
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An approach to integrated frequency-comb filtering is presented, building from a background in photonic crystal cavity design and fabrication. Previous work in the development of quantum information processing devices through integrated photonic crystals consists of photonic band gap engineering and methods of on-chip photon transfer. This work leads directly to research into coupled-resonator optical waveguides which stands as a basis for the primary line of investigation. These coupled...
Show moreAn approach to integrated frequency-comb filtering is presented, building from a background in photonic crystal cavity design and fabrication. Previous work in the development of quantum information processing devices through integrated photonic crystals consists of photonic band gap engineering and methods of on-chip photon transfer. This work leads directly to research into coupled-resonator optical waveguides which stands as a basis for the primary line of investigation. These coupled cavity systems offer the designer slow light propagation which increases photon lifetime, reduces size limitations toward on-chip integration, and offers enhanced light-matter interaction. A unique resonant structure explained by various numerical models enables comb-like resonant clusters in systems that otherwise have no such regular resonant landscape (e.g. photonic crystal cavities). Through design, simulation, fabrication and test, the work presented here is a thorough validation for the future potential of coupled-resonator filters in frequency comb laser sources.
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Date Issued
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2013
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Identifier
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CFE0004957, ucf:49568
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004957
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Title
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Non-Reciprocal Wave Transmission in Integrated Waveguide Array Isolators.
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Creator
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Ho, Yat, Likamwa, Patrick, Christodoulides, Demetrios, Vanstryland, Eric, Kaup, David, University of Central Florida
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Abstract / Description
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Non-reciprocal wave transmission is a phenomenon witnessed in certain photonic devices when the wave propagation dynamics through the device along one direction differs greatly from the dynamics along the counter-propagating direction. Specifically, it refers to significant power transfer occurring in one direction, and greatly reduced power transfer in the opposite direction. The resulting effect is to isolate the directionality of wave propagation, allowing transmission to occur along one...
Show moreNon-reciprocal wave transmission is a phenomenon witnessed in certain photonic devices when the wave propagation dynamics through the device along one direction differs greatly from the dynamics along the counter-propagating direction. Specifically, it refers to significant power transfer occurring in one direction, and greatly reduced power transfer in the opposite direction. The resulting effect is to isolate the directionality of wave propagation, allowing transmission to occur along one direction only.Given the popularity of photonic integrated circuits (PIC), in which all the optical components are fabricated on the same chip so that the entire optical system can be made more compact, it is desirable to have an easily integrated optical isolator. Common free-space optical isolator designs, which rely on the Faraday effect, are limited by the availability of suitable magnetic materials. This research proposes a novel integrated optical isolator based on an array of closely spaced, identical waveguides. Because of the nonlinear optical properties of the material, this device exploits the differing behaviors of such an array when illuminated with either a high power or a low power beam to achieve non-reciprocal wave transmission in the forwards and backwards directions, respectively. The switching can be controlled electro-optically via an integrated gain section which provides optical amplification before the input to the array. The design, fabrication, characterization and testing of this optical isolator are covered in this dissertation. We study the switching dynamics of this device and present its optimum operating conditions. ?
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Date Issued
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2012
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Identifier
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CFE0004305, ucf:49495
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004305
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Title
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NONLINEAR FEMTOSECOND NEAR INFRARED LASER STRUCTURING IN OXIDE GLASSES.
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Creator
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Royon, Arnaud, Richardson, Martin, University of Central Florida
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Abstract / Description
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Three-dimensional femtosecond laser structuring has a growing interest because of its ease of implementation and the numerous possible applications in the domain of photonic components. Structures such as waveguides, diffraction gratings, optical memories or photonic crystals can be fabricated thanks to this technique. Its use with oxide glasses is promising because of several advantages; they are resistant to flux and ageing, their chemical composition can easily be changed to fit the well...
Show moreThree-dimensional femtosecond laser structuring has a growing interest because of its ease of implementation and the numerous possible applications in the domain of photonic components. Structures such as waveguides, diffraction gratings, optical memories or photonic crystals can be fabricated thanks to this technique. Its use with oxide glasses is promising because of several advantages; they are resistant to flux and ageing, their chemical composition can easily be changed to fit the well-defined requirements of an application. They can already be found in Raman amplifiers, optical fibers, fiber lasers, and other devices. This thesis is based on two axes. The first axis consists in characterizing the linear and nonlinear optical properties of bulk vitreous materials in order to optimize their composition with a particular application in view. Within this context, the nonlinear optical properties, their physical origins (electronic and nuclear) as well as their characteristic response times (from a few femtoseconds to a few hundreds of picoseconds) are described within the Born-Oppenheimer approximation. Fused silica and several sodium-borophosphate glasses containing different concentrations in niobium oxide have been studied. Results show that the nonlinear optical properties of fused silica are mainly from electronic origin, whereas in the sodium-borophosphate glasses, the contribution from nuclear origin becomes predominant when the concentration of niobium oxide exceeds 30%. The second axis is based on the structuring of materials. Three commercially available fused silica samples presenting different fabrication conditions (therefore distinct impurity levels) and irradiated with a near infrared femtosecond laser have been studied. The laser induced defects have been identified by means of several spectroscopic techniques. They show the formation of color centers as well as a densification inside the irradiated area. Their linear refractive index and nonlinear third-order susceptibility properties have been measured. Moreover, the structuring of fused silica at the subwavelength scale into "nanogratings" is observed and the form of birefringence induced by these structures is discussed. In addition to the fused silica samples, several oxide glasses presenting very distinct chemical compositions have been studied. A sodium-borophosphate glass containing niobium oxide exhibits micro-cracks and nano-crystallites following irradiation. A silicate glass with or without a silver component reveals fluorescent rings or "nanograting" structures. A zinc phosphate glass containing silver also presents fluorescent ring structures, with a size of the order of 80 nm, well below the diffraction limit. Pump-probe microscope techniques have been performed on this glass to investigate the laser-glass interaction. The absorption mechanism is determined to be four-photon absorption. The generated free electron density is ~ 1017 cm-3, which suggests the conclusion that an electron gas rather than a plasma is formed during the laser irradiation.
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Date Issued
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2009
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Identifier
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CFE0002666, ucf:48200
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002666
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Title
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SIMULATION OF PHOTOCHROMIC COMPOUNDS USING DENSITY FUNCTIONAL THEORY METHODS.
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Creator
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Patel, Pansy, Masunov, Artem, University of Central Florida
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Abstract / Description
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This Thesis describes the systematic theoretical study aimed at prediction of the essential properties for the functional organic molecules that belong to diarylethene (DA) family of compounds. Diarylethenes present the distinct ability to change color under the influence of light, known as photochromism. This change is due to ultrafast chemical transition from open to closed ring isomers (photocyclization). It can be used for optical data storage, photoswitching, and other photonic...
Show moreThis Thesis describes the systematic theoretical study aimed at prediction of the essential properties for the functional organic molecules that belong to diarylethene (DA) family of compounds. Diarylethenes present the distinct ability to change color under the influence of light, known as photochromism. This change is due to ultrafast chemical transition from open to closed ring isomers (photocyclization). It can be used for optical data storage, photoswitching, and other photonic applications. In this work we apply Density Functional Theory methods to predict 6 of the related properties: (i) molecular geometry; (ii) resonant wavelength; (iii) thermal stability; (iv) fatigue resistance; (v) quantum yield and (vi) nanoscale organization of the material. In order to study sensitivity at diode laser wavelengths, we optimized geometry and calculated vertical absorption spectra for a benchmark set of 28 diarylethenes. Bond length alternation (BLA) parameters and maximum absorption wavelengths (λmax) are compared to the data presently available from X-ray diffraction and spectroscopy experiments. We conclude that TD-M05/6-31G*/PCM//M05-2X/6-31G*/PCM level of theory gives the best agreement for both the parameters. For our predictions the root mean square deviation (RMSD) are below 0.014 ÃÂ
for the BLAs and 25 nm for λmax. The polarization functions in the basis set and solvent effects are both important for this agreement. Next we consider thermal stability. Our results suggest that UB3LYP and UM05-2X functionals predict the activation barrier for the cycloreversion reaction within 3-4 kcal/mol from experimental value for a set of 7 photochromic compounds. We also study thermal fatigue, defined as the rate of undesirable photochemical side reactions. In order to predict the kinetics of photochemical fatigue, we investigate the mechanism of by-product formation. It has been established experimentally that the by-product is formed from the closed isomer; however the mechanism was not known. We found that the thermal by-product pathway involves the bicyclohexane (BCH) ring formation as a stable intermediate, while the photochemical by-product formation pathway may involve the methylcyclopentene diradical (MCPD) intermediate. At UM05-2X/6-31G* level, the calculated barrier between the closed form and the BCH intermediate is 51.2 kcal/mol and the barrier between the BCH intermediate and the by-product 16.2 kcal/mol. Next we investigate two theoretical approaches to the prediction of quantum yield (QY) for a set of 14 diarylethene derivatives at the validated M05-2X/6-31G* theory level. These include population of ground-state conformers and location of the pericycylic minimum on the potential energy surface 2-A state. Finally, we investigate the possibility of nanoscale organization of the photochromic material based on DNA template, as an alternative to the amorphous polymer matrix. Here we demonstrate that Molecular Dynamic methods are capable to describe the intercalation of π-conjugated systems between DNA base pairs and accurately reproduced the available photophysical properties of these nanocomposites. In summary, our results are in good agreement with the experimental data for the benchmark set of molecules we conclude that Density Functional Theory methods could be successfully used as an important component of material design strategy in prediction of accurate molecular geometry, absorption spectra, thermal stability of isomers, fatigue resistance, quantum yield of photocyclization and photophysical properties of nanocomposites.
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Date Issued
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2010
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Identifier
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CFE0003136, ucf:48633
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003136
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Title
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LASER PLASMA RADIATION STUDIES FOR DROPLET SOURCES IN THE EXTREME ULTRAVIOLET.
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Creator
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Kamtaprasad, Reuvani, Richardson, Martin, University of Central Florida
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Abstract / Description
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The advancement of laboratory based Extreme Ultraviolet (EUV) radiation has escalated with the desire to use EUV as a source for semiconductor device printing. Laser plasmas based on a mass-limited target concept, developed within the Laser Plasma Laboratory demonstrate a much needed versatility for satisfying rigorous source requirements. This concept produces minimal debris concerns and allows for the attainment of high repetition rates as well as the accommodation of various laser and...
Show moreThe advancement of laboratory based Extreme Ultraviolet (EUV) radiation has escalated with the desire to use EUV as a source for semiconductor device printing. Laser plasmas based on a mass-limited target concept, developed within the Laser Plasma Laboratory demonstrate a much needed versatility for satisfying rigorous source requirements. This concept produces minimal debris concerns and allows for the attainment of high repetition rates as well as the accommodation of various laser and target configurations. This work demonstrates the generation of EUV radiation by creating laser plasmas from mass-limited targets with indium, tin, and antimony doped droplets. Spectral emission from the laser plasmas is quantified using a flat-field spectrometer. COWAN code oscillator strength predications for each of the dopants were convolved with narrow Gaussian functions creating synthetic spectra for the EUV region between 10 nm - 20 nm. A preliminary comparison was made between the theoretical spectra and experimental results. From this comparison, ion stage transitions for each of the hot dense plasmas generated were assessed.
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Date Issued
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2010
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Identifier
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CFE0003168, ucf:48597
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003168
Pages