Current Search: Luminescence (x)
View All Items
- Title
- SILICON-SENSITIZED ERBIUM EXCITATION IN SILICON-RICH SILICA FOR INTEGRATED PHOTONICS.
- Creator
-
Savchyn, Oleksandr, Kik, Pieter, University of Central Florida
- Abstract / Description
-
It is widely accepted that the continued increase of processor performance requires at least partial replacement of electronic interconnects with their photonic counterparts. The implementation of optical interconnects requires the realization of a silicon-based light source, which is challenging task due to the low emission efficiency of silicon. One of the main approaches to address this challenge is the use of doping of silicon based matrices with optical centers, including erbium ions....
Show moreIt is widely accepted that the continued increase of processor performance requires at least partial replacement of electronic interconnects with their photonic counterparts. The implementation of optical interconnects requires the realization of a silicon-based light source, which is challenging task due to the low emission efficiency of silicon. One of the main approaches to address this challenge is the use of doping of silicon based matrices with optical centers, including erbium ions. Erbium ions incorporated in various hosts assume the trivalent state (Er3+) and demonstrate a transition at 1.54 μm, coinciding with optical transmission windows in both silicon and silica. Due to the low absorption cross-section and discrete energy levels of the Er3+ ion, indirect excitation is necessary. In late 90s it was demonstrated that the incorporation of excess silicon in erbium-doped silica results in strong erbium sensitization, leading to an increase of the effective absorption cross-section by orders of magnitude. The sensitization was considered to occur via silicon nanocrystals that formed at high annealing temperatures. While a large increase of the absorption cross-section was demonstrated, the incorporation of Si nanocrystals was found to result in a low concentration of excited erbium, as well as silicon related free-carrier absorption. The focus of this dissertation is the investigation of the nature of the sensitization mechanism of erbium in silicon-rich silica. The results presented in the dissertation demonstrate that erbium in silicon-rich silica is predominantly excited by silicon-excess-related luminescence centers, as opposed to the commonly considered silicon nanocrystals. This is a remarkable conclusion that changes the view on the exact origin of erbium sensitization, and that resolves several technical challenges that exist for nanocrystal-based sensitization. The work shows that the density of indirectly excited erbium ions is significantly larger in samples without silicon nanocrystals (annealed at T < 1000oC) as opposed to samples with silicon nanocrystals (annealed at T > 1000oC). The density of indirectly excited erbium ions, defining the maximum achievable gain, was demonstrated to be approximately excitation wavelength independent, while the effective erbium absorption cross-section was shown to significantly depend on the excitation wavelength. The excitation mechanism of erbium by luminescence centers was shown to be fast (< 30 ns) and capable of erbium sensitization to different energy levels. This multilevel nature of erbium excitation was demonstrated to result in two different mechanisms of the excitation of the first excited state of erbium: fast (< 30 ns) direct excitation by the luminescence centers, and slow (> 2.3 μs) excitation due to the relaxation of erbium ions excited into higher energy levels to the first excited state. Based on photoluminescence studies conducted in the temperature range 15 - 300K it was shown that the relaxation efficiency of erbium from the second excited state to the first excited state (responsible for the slow excitation mechanism) is temperature independent and approaches unity. The relative stability of the optical properties demonstrated in the temperature range 20 - 200oC, implies that relatively stable optical gain can be achieved under realistic on-chip operating conditions. The optimum Si excess concentration corresponding to the highest density of sensitized Er3+ ions is shown to be relatively insensitive to the presence of Si nanocrystals and is ~ 14.5 at.% and ~ 11.5 at.% for samples without and with Si nanocrystals respectively. The presented results and conclusions have significant implications for silicon photonics and the industrial application of Er-doped SiO2. The work shows that in order to sensitize erbium ions in silicon-rich silica there is no need for the presence of silicon nanocrystals, and consequently lower fabrication temperatures can be used. More importantly, the results strongly suggest that higher gain values can be acquired in samples annealed at lower temperature (without silicon nanocrystals) as compared to samples annealed at high temperatures (with silicon nanocrystals). In addition, the maximum gain is predicted to be relatively independent of excitation wavelength, significantly relaxing the requirements on the pump source. Based on the experimental results it is predicted that relatively stable performance of erbium-doped silicon-rich silica is possible up to typical processor operating temperatures of ~ 80 - 90oC making it a viable material for on-chip devices. The results suggest that low temperature annealed erbium-doped silicon-rich silica is a preferable material for on-chip photonic devices as compared with its high temperature annealed counterpart.
Show less - Date Issued
- 2010
- Identifier
- CFE0003312, ucf:48492
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003312
- Title
- NONDESTRUCTIVE EVALUATION OF THERMAL BARRIER COATINGS WITH THERMAL WAVE IMAGING AND PHOTOSTIMULATED LUMINESCENCE SPECTROSCOPY.
- Creator
-
Franke, Barbara, Sohn, Yong-ho, University of Central Florida
- Abstract / Description
-
Gas Turbine manufacturers strive for increased operating temperatures of gas turbine engines to improve efficiency and performance. One method of increasing the temperature beyond material limits is by applying thermal barrier coatings (TBCs) to hot section components. TBCs provide a thermal gradient between the hot gases and metallic substrate, and allow an increase in turbine inlet temperatures of 100-150ºC. However, spallation of TBCs can cause catastrophic failure of turbine engines...
Show moreGas Turbine manufacturers strive for increased operating temperatures of gas turbine engines to improve efficiency and performance. One method of increasing the temperature beyond material limits is by applying thermal barrier coatings (TBCs) to hot section components. TBCs provide a thermal gradient between the hot gases and metallic substrate, and allow an increase in turbine inlet temperatures of 100-150ºC. However, spallation of TBCs can cause catastrophic failure of turbine engines by incipient melting of the substrate. To prevent such an occurrence, non-destructive evaluation (NDE) techniques are critical for quality control, health monitoring, and life assessment of TBCs. Two techniques in development for this purpose are thermal wave imaging (TWI) and photostimulated luminescence (PL) spectroscopy. TWI is a promising NDE technique with the ability to detect integrity and thickness of TBCs. In this study, TWI was employed as an NDE technique to examine as-coated TBCs with varying thicknesses, and thermally-cycled TBCs for initiation and progression of subcritical-subsurface damage as a function of thermal cycling. TWI and thermal response amplitude were correlated to the microstructural characteristics and damage progression of TBCs based on phenomenological expressions of thermal diffusion. The TBC specimens examined consisted of air plasma sprayed ZrO2 - 7wt.% Y2O3 on NiCoCrAlY bond coats with Haynes 230 superalloy substrate. As-coated specimens of varying thicknesses were evaluated by TWI to examine its applicability as a thickness measurement tool. It was found that heat dissipation through the TBC following pulsed excitation by xenon flash lamps initially followed the 1-D law of conduction and deviated from it as a function of thickness and time. The deviation resulted from quick dissipation of heat into the conductive metallic substrate. Therefore, with calibration, TWI can be used as a tool for YSZ thickness measurements of APS TBCs in the as-coated condition for quality control measures. Specimens of uniform thickness were evaluated as a function of thermal cyclic oxidation for subcritical-subsurface damage detection. Thermal cycling was carried out in air with 30-minute heat-up, 10-hour dwell at 1150°C, 30-minute air-quench and 1-hour hold at room temperature. During thermal cycling, TBC specimens were evaluated non-destructively by TWI at room temperature every 10 to 20 thermal cycles, and selected specimens were removed from thermal cycling for microstructural analysis by scanning electron microscopy (SEM). Higher thermal response amplitude associated with disrupted heat transfer was observed where localized spallation at or near the YSZ/TGO interface occurred. The health of the TBC was monitored by a rise in thermal response amplitude which may indicate a coalescence of microcracks to a detectable level. PL has been developed to measure stress, and detect subsurface damage and polymorphic transformation within the thermally grown oxide (TGO) of TBCs. PL was employed in this study as an NDE technique for TBCs to correlate subsurface damage as a function of thermal cyclic oxidation. The TBCs consisted of ZrO2 7 wt.% Y2O3 applied by electron beam physical vapor deposition with an as-coated (Ni,Pt)Al bond coat on a CMSX-4 superalloy substrate. Specimens were thermally cycled with a 10 minute ramp to a peak temperature of 1121°C, 40 minute hold at peak temperature, and 10 minute forced air quench. The TBCs were periodically removed from thermal cycling for NDE using PL until failure. Two specimens were removed from thermal oxidation after 10% and 70% of the average lifetime for microstructural analysis by SEM. During initial thermal cycling, metastable phases and polymorphic transformations of the Al2O3 scale were examined by PL. The polymorphic transformation from a metastable phase to equilibrium a-Al2O3 was detected. Since metastable phases are thought to be detrimental to coating lifetime, detection of these phases by PL can be used as a quality control tool. Nearing end-of-life, relief of the TGO from the compressive residual stress arising from thermal expansion mismatch was detected with PL and confirmed with microstructural analysis that revealed damage initiation (e.g. microcracking within the TGO scale parallel to the interfaces.) Rise in luminescence near the R-line frequency for polycrystalline a-Al2O3 without any residual stress (i.e. n = 14402 cm-1 and n = 14432 cm-1) corresponded to regions where cracked TGO was adhered to YSZ and not exposed to compressive stresses from thermal expansion mismatch upon cooling.
Show less - Date Issued
- 2005
- Identifier
- CFE0000717, ucf:46613
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0000717
- Title
- Polymer Optical Fibers for Luminescent Solar Concentration.
- Creator
-
Banaei, Seyed Esmaeil, Fathpour, Sasan, Gong, Xun, Sundaram, Kalpathy, Malocha, Donald, Abouraddy, Ayman, University of Central Florida
- Abstract / Description
-
Luminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber....
Show moreLuminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber. A hybrid fiber structure is proposed for an efficient two-stage concentration of incident light, first into a small doped core using a cylindrical micro-lens that extends along the fiber, and second to the fiber ends by guiding the fluoresced light from the active dopants. Flexible sheets are assembled with fibers that can be bundled and attached to small-area PV cells. Small dimensions and directional guiding of the fibers allow for approximately one order of magnitude geometrical gain improvement over that of existing flat LSC's. In addition, the undesired limit of LSC size is eliminated in one direction.Modeling and optimization of an FLSC design is presented using polarization-ray tracing under realistic conditions with solar spectrum radiation and broad-band absorption and emission spectra of fluorescence materials with their inevitable self-absorption effect.Methods and results of fabrication and accurate optical characterization of such FLSC using two off-the-shelf organic dyes and a commercially available polymer, COP, are discussed in detail. Fiber preforms, fabricated under optimized conditions for low light transport loss, are thermally drawn into sub-millimeter-size fibers. Characterization of several samples with various concentrations of the two dyes shows an optical-to-optical conversion efficiency of 9.1% for a tandem combination of two 2.5-cm-long fibers with the efficiency gradually decreasing to 4.9% with increase in fiber length to 10 cm.
Show less - Date Issued
- 2013
- Identifier
- CFE0005083, ucf:50733
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005083
- Title
- SINGLET OXYGEN GENERATION USING NEW FLUORENE-BASED PHOTOSENSITIZERS UNDER ONE- AND TWO-PHOTON EXCITATION.
- Creator
-
Andrasik, Stephen, Belfield, Kevin, University of Central Florida
- Abstract / Description
-
Molecular oxygen in its lowest electronically excited state plays an important roll in the field of chemistry. This excited state is often referred to as singlet oxygen and can be generated in a photosensitized process under one- or two-photon excitation of a photosensitizer. It is particularly useful in the field of photodynamic cancer therapy (PDT) where singlet oxygen formation can be used to destroy cancerous tumors. The use of two-photon activated photosensitizers possesses great...
Show moreMolecular oxygen in its lowest electronically excited state plays an important roll in the field of chemistry. This excited state is often referred to as singlet oxygen and can be generated in a photosensitized process under one- or two-photon excitation of a photosensitizer. It is particularly useful in the field of photodynamic cancer therapy (PDT) where singlet oxygen formation can be used to destroy cancerous tumors. The use of two-photon activated photosensitizers possesses great potential in the field of PDT since near-IR light is used to activate the sensitizer, resulting in deeper penetration of light into biological tissue, less photo-bleaching of the sensitizer, and greatly improved resolution of excitation. The synthesis and photophysical characterization of new fluorene-based photosensitizers for efficient singlet oxygen production were investigated. The spectral properties for singlet oxygen production were measured at room temperature and 77 K. Two-photon absorption (2PA) cross-sections of the fluorene derivatives were measured by the open aperture Z-scan method. The quantum yields of singlet oxygen generation under one- and two-photon excitation (ΦΔ and 2PAΦΔ, respectively) were determined by the direct measurement of singlet oxygen luminescence at ≈ 1270 nm. The values of ΦΔ were independent of excitation wavelength, ranging from 0.6 - 0.9. The singlet oxygen quantum yields under two-photon excitation were 2PAΦΔ ≈ ½ΦΔ, indicating that the two processes exhibited the same mechanism of singlet oxygen production, independent of the mechanism of photon absorption.
Show less - Date Issued
- 2007
- Identifier
- CFE0001860, ucf:47411
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001860
- Title
- UP-CONVERSION IN RARE-EARTH DOPED MICRO-PARTICLES APPLIED TO NEW EMISSIVE 2D DISLAYS.
- Creator
-
Milliez, Anne, Bass, Michael, University of Central Florida
- Abstract / Description
-
Up-conversion (UC) in rare-earth co-doped fluorides to convert diode laser light in the near infrared to red, green and blue visible light is applied to make possible high performance emissive displays. The infrared-to-visible UC in the materials we study is a sequential form of non-linear two photon absorption in which a strong absorbing constituent absorbs two low energy photons and transfers this energy to another constituent which emits visible light. Some of the UC emitters' most...
Show moreUp-conversion (UC) in rare-earth co-doped fluorides to convert diode laser light in the near infrared to red, green and blue visible light is applied to make possible high performance emissive displays. The infrared-to-visible UC in the materials we study is a sequential form of non-linear two photon absorption in which a strong absorbing constituent absorbs two low energy photons and transfers this energy to another constituent which emits visible light. Some of the UC emitters' most appealing characteristics for displays are: a wide color gamut with very saturated colors, very high brightness operation without damage to the emitters, long lifetimes and efficiencies comparable to those of existing technologies. Other advantages include simplicity of fabrication, versatility of operating modes, and the potential for greatly reduced display weight and depth. Thanks to recent advances in material science and diode laser technology at the excitation wavelength, UC selected materials can be very efficient visible emitters. However, optimal UC efficiencies strongly depend on chosing proper operating conditions. In this thesis, we studied the conditions required for optimization. We demonstrated that high efficiency UC depends on high pump irradiance, low temperature and low scattering. With this understanding we can predict how to optimally use UC emitters in a wide range of applications. In particular, we showed how our very efficient UC emitters can be applied to make full color displays and very efficient white light sources.
Show less - Date Issued
- 2006
- Identifier
- CFE0001058, ucf:46828
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001058
- Title
- Load Transfer in an Isolated Particle Embedded within an Epoxy Matrix.
- Creator
-
Durnberg, Erik, Raghavan, Seetha, Gou, Jihua, Bai, Yuanli, University of Central Florida
- Abstract / Description
-
Particulate composites are widely used in many aerospace applications such as protective coatings, adhesives, or structural members of a body and their mechanical properties and behavior have gained increasing significance. The addition of modifiers such as alumina generally leads to improved mechanical properties. This addition also enables the non-invasive study of the load transfer between the particle and the matrix. Understanding the load transfer between the particulate and the matrix...
Show moreParticulate composites are widely used in many aerospace applications such as protective coatings, adhesives, or structural members of a body and their mechanical properties and behavior have gained increasing significance. The addition of modifiers such as alumina generally leads to improved mechanical properties. This addition also enables the non-invasive study of the load transfer between the particle and the matrix. Understanding the load transfer between the particulate and the matrix material is the first step to understanding the behavior and mechanical properties of the composite as a whole. In this work, samples with an isolated alumina particle embedded in an epoxy matrix were created to replicate the ideal assumptions for many particulate mechanics models. In separate experiments, both photo stimulated luminescent spectroscopy (PSLS) and synchrotron radiation were used to collect the spectral emission and diffraction rings, respectively, from the mechanically loaded samples. The PSLS data and XRD data are shown to be in qualitative agreement that as particle size is increased, the load transferred to the particle also increased for the range of particle sizes tested. This trend of increasing load transfer with increasing particle size is compared with the classical Eshelby model. Results from this work provide experimental insight into the load transfer properties of particulate composites and can serve to experimentally validate the theoretical load transfer models that currently exist.
Show less - Date Issued
- 2014
- Identifier
- CFE0005326, ucf:50535
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005326
- Title
- EVOLUTION OF MICROSTRUCTURE AND RESIDUAL STRESS IN DISC-SHAPE EB-PVD THERMAL BARRIER COATINGS AND TEMPERATURE PROFILE OF HIGH PRESSURE TURBINE BLADE.
- Creator
-
Mukherjee, Sriparna, Sohn, Yongho, University of Central Florida
- Abstract / Description
-
A detailed understanding of failure mechanisms in thermal barrier coatings (TBCs) can help develop reliable and durable TBCs for advanced gas turbine engines. One of the characteristics of failure in electron beam physical vapor deposited (EB-PVD) TBCs is the development of instability, named rumpling, at the interface between (Ni, Pt)Al bond coat and thermally grown oxide (TGO). In this study, thermal cycling at 1100[degrees]C with 1 hr dwell time was carried out on 25.4mm disc specimens of...
Show moreA detailed understanding of failure mechanisms in thermal barrier coatings (TBCs) can help develop reliable and durable TBCs for advanced gas turbine engines. One of the characteristics of failure in electron beam physical vapor deposited (EB-PVD) TBCs is the development of instability, named rumpling, at the interface between (Ni, Pt)Al bond coat and thermally grown oxide (TGO). In this study, thermal cycling at 1100[degrees]C with 1 hr dwell time was carried out on 25.4mm disc specimens of TBCs that consisted of EB-PVD coated ZrO2-7wt.%Y2O3, (Pt,Ni)Al bond coat, and CMSX-4 Ni-based superalloy. At specific fraction of lifetime,TBCs were examined by electron microscopy and photostimulated luminescence (PL). Changes in the average compressive residual stress of the TGO determined by PL and the magnitude of rumpling, determined by tortuosity from quantitative microstructural analyses, were examined with respect to the furnace thermal cyclic lifetime and microstructural evolution of TBCs. The combination of elastic strain energy within the TGO and interfacial energy at the interface between the TGO and the bond coat was defined as the TGO energy, and its variation with cyclic oxidation time was found to remain approximately constant ~135J/m2 during thermal cycling from 10% to 80% thermal cyclic lifetime. Parametric study at ~135J/m2 was performed and variation in residual stress with rumpling for different oxide scale thicknesses was examined. This study showed that the contribution of rumpling in residual stress relaxation decreased with an increase in TGO thickness. High pressure turbine blades serviced for 2843 hours and in the as coated form were also examined using electron microscopy and photostimulated luminescence. The difference in residual stress values obtained using PL on the suction and pressure sides of as-coated turbine blade were discussed. The presence of a thick layer of deposit on the serviced blade gave signals from stress free alpha-Al2O3 in the deposit, not from the TGO. The TGO growth constant data from the disc-shape TBCs, thermally cycled at 1100[degrees]C, and studies by other authors at different temperatures but on similar EB-PVD coated TBCs with (Pt, Ni)Al bond coat and CMSX-4 Ni- based superalloy were used to determine the temperature profile at the YSZ/bond coat interface. The interfacial temperature profiles of the serviced blade and the YSZ thickness profile were compared to document the variable temperature exposure at the leading edge, trailing edge, suction and the pressure side.
Show less - Date Issued
- 2011
- Identifier
- CFE0003927, ucf:48700
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003927
- Title
- DEVELOPMENT OF LUMINESCENT RUTHENIUM COMPLEXES FOR IN-VITRO FLUORESCENCE IMAGING OF ANGIOGENESIS WITH THE RGD PEPTIDE.
- Creator
-
Victoria, Rosmery, Hinkle, Charles R., University of Central Florida
- Abstract / Description
-
Herein we report the synthesis of an RGD-ruthenium bipyridine 2+ complex aimed at the detection of angiogenesis. Angiogenesis plays a critical role in many pathophysiological processes, such as tumor growth. The alpha v-integrins (alpha v beta 3, alpha v beta 5) are currently used as molecular targeting sites for anti-angiogenic therapies. The 2+ complex is an organometallic luminescent probe, which enables noninvasive, in vitro imaging of alpha v beta 3 expression. Peptides containing the...
Show moreHerein we report the synthesis of an RGD-ruthenium bipyridine 2+ complex aimed at the detection of angiogenesis. Angiogenesis plays a critical role in many pathophysiological processes, such as tumor growth. The alpha v-integrins (alpha v beta 3, alpha v beta 5) are currently used as molecular targeting sites for anti-angiogenic therapies. The 2+ complex is an organometallic luminescent probe, which enables noninvasive, in vitro imaging of alpha v beta 3 expression. Peptides containing the arginine-glycine-aspartic acid (RGD) sequence have been shown to bind strongly to the alpha v beta 3 integrin. The RuBpy probes are soluble in water, display long lifetimes, and are photochemically stable. These properties enable the Ru(tris-bpy) complexes to be useful in numerous applications in biophysical and cell biology. The 2+ complex was synthesized by combining the succinimidyl ester on the RuBpy complex with the lysine of the c(RGDfK) peptide. The results of the one-photon fluorescence bioimaging showed selective binding of the cyclic RGD to alpha v beta 3 integrin, which supports previous literature. The high luminescence intensity, long lifetimes, and low cell toxicity levels of dye 2+, illustrates the potential usage of this probe for future biological applications.
Show less - Date Issued
- 2012
- Identifier
- CFH0004234, ucf:44898
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFH0004234
- Title
- Improvements on Instrumentation to Explore the Multidimensionality of Luminescence Spectroscopy.
- Creator
-
Moore, Anthony, Campiglia, Andres, Chumbimuni Torres, Karin, Harper, James, Rex, Matthew, Lee, Woo Hyoung, University of Central Florida
- Abstract / Description
-
This dissertation presents experimental and instrumentation developments that take full advantage of the multidimensional nature of line narrowing spectroscopy at liquid nitrogen (77 K) and liquid helium (4.2 K) temperatures. The inconvenience of sample freezing procedures is eliminated with the aid of cryogenic fiber optic probes. Rapid collection of multidimensional data formats such as wavelength time matrices, excitation emission matrices, time-resolved excitation emission matrices and...
Show moreThis dissertation presents experimental and instrumentation developments that take full advantage of the multidimensional nature of line narrowing spectroscopy at liquid nitrogen (77 K) and liquid helium (4.2 K) temperatures. The inconvenience of sample freezing procedures is eliminated with the aid of cryogenic fiber optic probes. Rapid collection of multidimensional data formats such as wavelength time matrices, excitation emission matrices, time-resolved excitation emission matrices and time resolved excitation emission cubes is made possible with the combination of a pulsed tunable dye laser, a spectrograph and an intensifier-charged coupled device. These data formats provide unique opportunities for processing vibrational luminescence data with second order multivariate calibration algorithms. The use of cryogenic fiber optic probes is extended to commercial instrumentation. An attractive feature of spectrofluorimeters with excitation and emission monochromators is the possibility to record synchronous spectra. The advantages of this approach, which include narrowing of spectral bandwidth and simplification of emission spectra, were demonstrated with the direct analysis of highly toxic dibenzopyrene isomers. The same is true for the collection of steady-state fluorescence excitation-emission matrices. These approaches provide a general solution to unpredictable spectral interference, a ubiquitous problem for the analysis of organic pollutants in environmental samples of unknown composition. Since commercial spectrofluorimeters are readily available in most academic institutions, industrial settings and research institutes, the developments presented here should facilitate the widespread application of line-narrowing spectroscopic techniques to the direct determination, no chromatographic separation, of highly toxic compounds in complex environmental matrixes of unknown composition.
Show less - Date Issued
- 2015
- Identifier
- CFE0005847, ucf:50934
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005847