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- Title
- Volume Phase Masks in Photo-Thermo-Refractive Glass.
- Creator
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Segall, Marc, Glebov, Leonid, Zeldovich, Boris, Dogariu, Aristide, Rahman, Talat, Bass, Michael, University of Central Florida
- Abstract / Description
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In many applications such as beam shaping, mode conversion, and phase encoding it is necessary to alter the spatial phase profile of a beam via a phase mask. Conventional techniques to accomplish this either involve surface relief profiling in thin films such as PMMA or refractive index modulation in bulk photorefractive crystals such as lithium niobate. These materials have been used extensively for the past several decades and perform admirably in low power conditions. However, in high...
Show moreIn many applications such as beam shaping, mode conversion, and phase encoding it is necessary to alter the spatial phase profile of a beam via a phase mask. Conventional techniques to accomplish this either involve surface relief profiling in thin films such as PMMA or refractive index modulation in bulk photorefractive crystals such as lithium niobate. These materials have been used extensively for the past several decades and perform admirably in low power conditions. However, in high power systems these materials will be destroyed, requiring a new means of producing phase masks. In this dissertation a method for producing robust phase masks in the bulk of photo-thermo-refractive glass is developed and successfully demonstrated. Three main applications of phase masks were studied in detail. The first is mode conversion, where binary phase masks convert a Gaussian beam to higher order modes. The second is beam shaping, where phase masks are used as focusing elements and for optical vortex generation. Near-theoretical conversion efficiency was achieved for all elements in these cases. The third application is aberration analysis and correction. Here the degradation of volume Bragg gratings recorded in an aberrated holographic system was modeled, with the simulations indicating that correcting elements are generally necessary for high-quality production of gratings. Corrective phase masks are designed which can selectively correct one or multiple aberrations of varying magnitudes are shown. A new type of optical element is also developed in which a phase mask is encoded into a transmitting Bragg grating. This technique combines the local phase modulation of a phase mask with the multiplexing ability of transmitting Bragg gratings, allowing for multiple phase masks to be recorded in a single element. These masks may be used at any wavelength satisfying the Bragg condition, increasing the useful wavelength regime of a single element by orders of magnitude.
Show less - Date Issued
- 2013
- Identifier
- CFE0005414, ucf:50431
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005414
- Title
- METHOD FOR DETERMINATION OF SINGLET OXYGEN QUANTUM YIELDS FOR NEW FLUORENE-BASED PHOTOSENSITIZERS IN AQUEOUS MEDIA FOR THE ADVANCEMENT OF PHOTODYNAMIC THERAPY.
- Creator
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Grabow, Wade William, Belfield, Kevin, University of Central Florida
- Abstract / Description
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Photodynamic therapy (PDT) has been investigated over the past three decades and is currently an approved therapeutic modality for skin cancer, the treatment of superficial bladder, early lung and advanced esophageal cancers, and age-related macular degeneration in a number of countries. In PDT, the absorption of light by a chromophore generates cytotoxic species such as reactive singlet oxygen, leading to irreversible destruction of the treated tissue. The measurement of the singlet oxygen...
Show morePhotodynamic therapy (PDT) has been investigated over the past three decades and is currently an approved therapeutic modality for skin cancer, the treatment of superficial bladder, early lung and advanced esophageal cancers, and age-related macular degeneration in a number of countries. In PDT, the absorption of light by a chromophore generates cytotoxic species such as reactive singlet oxygen, leading to irreversible destruction of the treated tissue. The measurement of the singlet oxygen quantum yield is an important determinant used to evaluate the efficiency of new photodynamic therapy agents developed in the laboratory, to screen potential photosensitizers in aqueous media.The singlet oxygen quantum yield is a quantitative measurement of the efficiency in which photosensitizers are able to use energy, in the form of light, to convert oxygen in the ground state to the reactive species singlet oxygen useful in photodynamic therapy. Singlet oxygen quantum yields of photosensitizers differ when measured in different solvents. The majority of the existing quantum yield values found in literature for various photosensitizers are documented with the sensitizers in organic solvents though values in aqueous media are more valuable for actual applications. Determination of accurate and precise quantum yield values in aqueous solution is a much more difficult problem than in organic media. Problems in aqueous solution arise primarily from the physicochemical properties of singlet oxygen in water. Singlet oxygen has a much shorter lifetime in water than it does in organic solvents, causing challenges with respect to quantitative detection of singlet oxygen.The ensuing pages are an attempt to explore the theory and document the procedures developed to provide the accurate measurement of singlet oxygen in aqueous media. Details of this experimental method and singlet oxygen quantum yield results of new compounds relative to established photosensitizers will be presented.
Show less - Date Issued
- 2004
- Identifier
- CFE0000029, ucf:46138
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0000029
- Title
- SINGLET OXYGEN GENERATION USING NEW FLUORENE-BASED PHOTOSENSITIZERS UNDER ONE- AND TWO-PHOTON EXCITATION.
- Creator
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Andrasik, Stephen, Belfield, Kevin, University of Central Florida
- Abstract / Description
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Molecular oxygen in its lowest electronically excited state plays an important roll in the field of chemistry. This excited state is often referred to as singlet oxygen and can be generated in a photosensitized process under one- or two-photon excitation of a photosensitizer. It is particularly useful in the field of photodynamic cancer therapy (PDT) where singlet oxygen formation can be used to destroy cancerous tumors. The use of two-photon activated photosensitizers possesses great...
Show moreMolecular oxygen in its lowest electronically excited state plays an important roll in the field of chemistry. This excited state is often referred to as singlet oxygen and can be generated in a photosensitized process under one- or two-photon excitation of a photosensitizer. It is particularly useful in the field of photodynamic cancer therapy (PDT) where singlet oxygen formation can be used to destroy cancerous tumors. The use of two-photon activated photosensitizers possesses great potential in the field of PDT since near-IR light is used to activate the sensitizer, resulting in deeper penetration of light into biological tissue, less photo-bleaching of the sensitizer, and greatly improved resolution of excitation. The synthesis and photophysical characterization of new fluorene-based photosensitizers for efficient singlet oxygen production were investigated. The spectral properties for singlet oxygen production were measured at room temperature and 77 K. Two-photon absorption (2PA) cross-sections of the fluorene derivatives were measured by the open aperture Z-scan method. The quantum yields of singlet oxygen generation under one- and two-photon excitation (ΦΔ and 2PAΦΔ, respectively) were determined by the direct measurement of singlet oxygen luminescence at ≈ 1270 nm. The values of ΦΔ were independent of excitation wavelength, ranging from 0.6 - 0.9. The singlet oxygen quantum yields under two-photon excitation were 2PAΦΔ ≈ ½ΦΔ, indicating that the two processes exhibited the same mechanism of singlet oxygen production, independent of the mechanism of photon absorption.
Show less - Date Issued
- 2007
- Identifier
- CFE0001860, ucf:47411
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001860
- Title
- Holographic optical elements for visible light applications in photo-thermo-refractive glass.
- Creator
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Kompan, Fedor, Glebov, Leonid, Schulzgen, Axel, Richardson, Kathleen, Rahman, Talat, University of Central Florida
- Abstract / Description
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This dissertation reports on design and fabrication of various optical elements in Photo-thermo-refractive (PTR) glass. An ability to produce complex holographic optical elements (HOEs) for the visible spectral region appears very beneficial for variety of applications, however, it is limited due to photosensitivity of the glass confined within the UV region. First two parts of this dissertation present two independent approaches to the problem of holographic recording using visible radiation...
Show moreThis dissertation reports on design and fabrication of various optical elements in Photo-thermo-refractive (PTR) glass. An ability to produce complex holographic optical elements (HOEs) for the visible spectral region appears very beneficial for variety of applications, however, it is limited due to photosensitivity of the glass confined within the UV region. First two parts of this dissertation present two independent approaches to the problem of holographic recording using visible radiation. The first method involves modification of the original PTR glass rendering it photosensitive to radiation in the visible spectral region and, thus, making possible the recording of holograms in PTR glass with visible radiation. The mechanism of photoionization in this case is based on an excited state absorption upconversion process in the glass when doped with Tb3+. By contrast, the second approach uses the original Ce3+ doped PTR glass and introduces a new modified technique for hologram formation that allows for holographic recording with visible light. Complex HOEs including holographic lenses and holographic curved mirrors were fabricated in PTR glass with visible light using both techniques. The third part of the dissertation takes a step in a different direction and discusses the development of the methods for fabrication of phase masks in PTR glass. A method for relatively straightforward and inexpensive fabrication of phase masks with the aid of a Digital Micromirror Device is presented. This method enabled to produce phase masks containing complex greyscale phase distributions for generation of vortex (helical) beams. A phase mask can be holographically encoded into a transmission Bragg grating where a holographic phase mask (HPM) is formed. HPM has an advantage over a regular phase mask of being capable of multi-wavelength operation. All optical elements recorded in PTR glass preserve the advantages peculiar to VBGs recorded in PTR glass such as stability to heating and illumination with high-power laser beams.
Show less - Date Issued
- 2019
- Identifier
- CFE0007665, ucf:52480
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007665
