Current Search: nitrogen removal (x)
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- Title
- PILOT STUDY OF NUTRIENT LOADING IN A WET DETENTION LAKE.
- Creator
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Gurr, Eric, Nnadi, Fidelia, University of Central Florida
- Abstract / Description
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Florida is surrounded by water, and its many internal lakes and rivers have long been recognized for their excellent fishing and boating. This notoriety draws land developers to the lake shores to establish residential and commercial infrastructure. This land development brings with it flood plain alteration, water level stabilization, and increased nutrients which cause adverse impacts to our lakes. In response, the United States Environmental Protection Agency (EPA) passed the Federal Clean...
Show moreFlorida is surrounded by water, and its many internal lakes and rivers have long been recognized for their excellent fishing and boating. This notoriety draws land developers to the lake shores to establish residential and commercial infrastructure. This land development brings with it flood plain alteration, water level stabilization, and increased nutrients which cause adverse impacts to our lakes. In response, the United States Environmental Protection Agency (EPA) passed the Federal Clean Water Act (CWA) in 1972 which set the framework for the water quality standards for the entire United States. As a result of the CWA many point sources were eliminated, but in the process it became apparent that nonpoint source loads represented even more of a threat. To further study the physical and chemical characteristics of urban runoff the Nationwide Urban Runoff Program (NURP) was established in 1978. This research lead to a series of management options, named Best Management Practices (BMPs) which proposed various structural and non-structural methods to reduce nutrient loads. But the research and data collection on the effectiveness of these systems to remove nutrients is in its infancy. The main objective of this study was to generate accurate and effective water quality and water quantity data that future stormwater management decisions can be based upon. More specific, this study established automatic monitoring sites throughout the City of Kissimmee, Florida to determine the pollutant loadings into the tributaries of Lake Tohopekaliga. These monitoring sites are located such that inflows from outside the city limits can be isolated and external pollutant loads quantified. Also, additional internal monitoring sites were established to determine the pollutant loads of internal sections of the city. Data from these internal monitoring sites will also be used to determine the variable pollutant removal efficiencies and hydraulic fluctuations of natural, irregular riverine systems. The secondary objective of this study was to perform a pilot study using the discrete grab samples in tandem with the continuous hydraulic and hydrologic data from the monitoring stations. An existing lake within the project limits was chosen for the pilot study area. Monitoring stations are located at the influent and effluent sections of the lake which provided data on the hydraulic and hydrologic parameters. The pilot study determined the nutrient loads to and from the lake and checked for any seasonal variations in pollutant loading or removal efficiencies. For the purpose of this pilot study, only total nitrogen and total phosphorous were examined for two monitoring sites. The nutrient removal efficiency was performed using both the event mean concentration method and the summation of loads method to check for seasonal variation. There were no storm event concentrations available for used in this analysis, however, there were 25 discrete grab samples collected on a bi-monthly basis over a twelve month period. This data was used with corresponding five-minute rainfall and flow data from both the inflow and outflow points. The results of this study did not reveal any seasonal variation in the nutrient concentrations either flowing into or out from the lake. Although there were some relatively lower values in late spring, the concentration levels of total nitrogen did not seem to vary significantly from its mean value of 0.90 mg/l throughout the year. The concentration levels of total phosphorus did range from 0.02 mg/l to 0.48 mg/l, but not in relation to either season or flow volume fluctuations. The lake showed no net removals of total nitrogen and was actually found to be releasing total phosphorus to the downstream receiving waters. The findings of this study are limited due to the fact that the period of pilot study was only for twelve months and there were no rainfall events used in the analysis. Rainfall events are typically high sources of nutrient loads to a lake. The lower efficiencies were probably due to missing the actual higher nutrient load concentrations during the rainfall event. However, even considering the lack of event data, the nutrient removal efficiency for the pond was still low. This analysis did serve well as a basis for performing future analysis once additional data, including rainfall events, has been collected.
Show less - Date Issued
- 2007
- Identifier
- CFE0001912, ucf:47474
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001912
- Title
- REMOVAL OF REFRACTORY TKN FROM AN EFFLUENT WASTEWATER USING SODIUM FERRATE.
- Creator
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Lettie, Lucia, Reinhart, Debra, University of Central Florida
- Abstract / Description
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This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent...
Show moreThis research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated with doses of ferrate ranging from 1 to 50 mg/L as FeO42 under unbuffered conditions. TKN removal as high as 70% and COD removal greater than 55% was observed. The TSS production after ferrate treatment was in a range of 12 to 200 mg/L for doses between 10 and 50 mg/L FeO4-2. After an optimum dose of ferrate was determined, three bench-scale reactors were operated under anoxic conditions for 10 to 12 days, two as duplicates containing the treated effluent and one as a control with untreated sample. Two different doses of ferrate were used as optimum dose for these experiments, 10 and 25 mg/L as FeO4-2. The purpose of these reactors was to determine the potential for biological removal of remaining nitrogen after ferrate oxidation of refractory nitrogen. Treated and raw samples were analyzed for Total Kjeldahl Nitrogen (TKN) (filtered and unfiltered), chemical oxygen demand (COD) (filtered and unfiltered), total suspended solids (TSS), nitrate (NO3-N), nitrite (NO2-N), and heterotrophic plate count (HPC). As a result, more than 70% of the soluble TKN was removed by chemical and biological oxidation for a sample treated with a dose of 25 mg/L FeO4-2, and less than 50% when treated with 10 mg/L FeO4-2. For the control samples run parallel to the ferrate treated samples, a maximum of 48% of soluble TKN and a minimum of 12% was removed. A three-log increase was observed in heterotrophic bacteria numbers for both doses during the operation of the reactors. Sodium ferrate was found to be an effective oxidant that can enhance the biodegradability of recalcitrant TKN present in municipal wastewaters. As mentioned before this research was develop using batch reactor units at bench-scale, therefore it is recommended to follow the investigation of the biodegradability of recalcitrant TKN of a ferrate treated sample under continuous flow conditions so that results can be extrapolated to a full-scale treatment facility.
Show less - Date Issued
- 2006
- Identifier
- CFE0001247, ucf:46936
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001247
- Title
- An Assessment of Biosorption Activated Media for the Removal of Pollutants in Up-Flow Stormwater Treatment Systems.
- Creator
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Hood, Andrew, Randall, Andrew, Wanielista, Martin, Chopra, Manoj, O'Reilly, Andrew, Moore, Sean, University of Central Florida
- Abstract / Description
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Nitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical...
Show moreNitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical in ultra-urban environments where above ground space is limited. Upflow filters utilizing biosorption activated media (BAM) that can be placed underground offer a small footprint alternative. Additionally, BAM upflow filters can be installed at the discharge point of traditional stormwater ponds to provide further treatment. This research simulated stormwater that had already been treated for solids removal; thus, most of the nutrients and solids in the influent were assumed to be as non-settable suspended solids or dissolved solids. Three different BAM mixtures in an upflow filter configuration were compared for the parameters of nitrogen, phosphorus, total coliform, E. coli, and heterotrophic plate count (HPC). Additionally, genetic testing was conducted using Polymerase Chain Reaction (PCR), in conjunction with a nitrogen mass balance, to determine if Anammox was a significant player in the nitrogen removal. The columns were run at both 22-minute and 220-minute Empty Bed Contact Times (EBCTs). All the BAM mixtures analyzed were shown to be capable at the removal of nitrogen, phosphorus, and total coliform during both the 22-minute and 220-minute EBCTs, with BAM #1 having the highest removal performance for all three parameters during both EBCTs. All BAM mixtures experienced an increase in HPC. Additionally, PCR analysis confirmed the presence of Anammox in the biofilm and via mass balance it was determined that the biological nitrogen removal was due to Anammox and endogenous denitrification with Anammox being a significant mechanism.
Show less - Date Issued
- 2019
- Identifier
- CFE0007817, ucf:52875
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007817