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(1 - 12 of 12)
- Title
- EVALUATION OF PREFERMENTATION AS A UNIT PROCESS UPON BIOLOGICAL NUTRIENT REMOVAL INCLUDING BIOKINETIC AND WASTEWATER PARAMETERS.
- Creator
-
McCue, Terrence, Randall, Andrew, University of Central Florida
- Abstract / Description
-
The objective of this dissertation was to provide a controlled comparison of identical continuous flow BNR processes both with and without prefermentation in order to provide a stronger, more quantitative, technical basis for design engineers to evaluate the potential benefits of prefermentation to EBPR in treating domestic wastewater. In addition, the even less understood effect of prefermentation on denitrification kinetics and anoxic phosphorus (P) uptake was studied and quantified. Other...
Show moreThe objective of this dissertation was to provide a controlled comparison of identical continuous flow BNR processes both with and without prefermentation in order to provide a stronger, more quantitative, technical basis for design engineers to evaluate the potential benefits of prefermentation to EBPR in treating domestic wastewater. In addition, the even less understood effect of prefermentation on denitrification kinetics and anoxic phosphorus (P) uptake was studied and quantified. Other aspects of BNR performance, which might change due to use of prefermentation, will also be addressed, including anaerobic stabilization. Potential benefits to BNR processes derived from prefermentation are compared and contrasted with the more well-known benefits of primary clarification. Finally, some biokinetic parameters necessary to successfully model both the activated sludge systems and the prefermenter were determined and compared for the prefermented versus the non-prefermented system. Important findings developed during the course of this dissertation regarding the impact of prefermentation upon the performance of activated sludge treatment systems are summarized below: • For a septic COD-limited (TCOD:TP < 40:1) wastewater, prefermentation was found to enhance EPBR by 27.7% at a statistical significance level of alpha=0.05 (95% confidence level). • For septic P-limited (TCOD:TP > 40:1) wastewaters, prefermentation was not found to improve EBPR at a statistical significance level of alpha=0.05 (95% confidence level). • The increased anaerobic P release and aerobic P uptakes due to prefermentation correlated with greater PHA formation and glycogen consumption during anaerobiosis of prefermented influent. • Improvements in biological P removal of septic, non-P limited wastewater occurred even when all additional VFA production exceeded VFA requirements using typical design criteria (e.g. 6 g VFA per 1 g P removal). • Prefermentation increased RBCOD content by an average of 28.8% and VFA content by an average of 18.8%, even for a septic domestic wastewater. • Prefermentation increased specific anoxic denitrification rates for both COD-limited (14.6%) and P-limited (5.4%) influent wastewaters. This increase was statistically significant at alpha=0.05 for COD-limited wastewater, but not for P-limited wastewater.
Show less - Date Issued
- 2006
- Identifier
- CFE0001418, ucf:47052
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001418
- Title
- NUTRIENT REMOVAL FROM STORMWATER BY USING GREEN SORPTION MEDIA.
- Creator
-
HOSSAIN, FAHIM, Chang, Dr. Ni-Bin, University of Central Florida
- Abstract / Description
-
High nitrogen and phosphorus content in storm water runoff has affected groundwater, springs and surface water by impacting ecosystem integrity and human health. Nitrate may be toxic and can cause human health problem such as methemoglobinemia, liver damage and even cancers. Phosphorus may trigger the eutrophication issues in fresh water bodies, which could result in toxic algae and eventually endanger the source of drinking waters. Sorption media with mixes of some recycled materials, such...
Show moreHigh nitrogen and phosphorus content in storm water runoff has affected groundwater, springs and surface water by impacting ecosystem integrity and human health. Nitrate may be toxic and can cause human health problem such as methemoglobinemia, liver damage and even cancers. Phosphorus may trigger the eutrophication issues in fresh water bodies, which could result in toxic algae and eventually endanger the source of drinking waters. Sorption media with mixes of some recycled materials, such as sawdust and tire crumb, combined with sand/silt and limestone, becomes appealing for nutrient removal in environmental management. This paper presented is a specific type of functionalized filtration media, Langmuir and Freundlich isotherms with reaction kinetics for nutrient removal using a suite of batch tests represented. Pollutants of concern include ammonia, nitrite, nitrate, orthophosphate and total dissolved phosphorus. Application potential in storm water management facilities, such as dry ponds, is emphasized in terms of life expectancy and reaction kinetics. As compared to the natural soil that is selected as the control case in the column test, our green sorption media mixture is proved relatively effective in terms of removing most of the target pollutants under various influent waste loads.
Show less - Date Issued
- 2008
- Identifier
- CFE0002370, ucf:47803
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002370
- Title
- REDUCING EFFLUENT PHOSPHORUS AND NITROGEN CONCENTRATIONS FROM A STORMWATER DETENTION POND USING A CHAMBER UPFLOW FILTER AND SKIMMER (CUFS) WITH BLACK AND GOLDTM MEDIA.
- Creator
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Ryan, Patrick, Chang, Ni-Bin, University of Central Florida
- Abstract / Description
-
Stormwater runoff is a known pollutant source capable of causing surface water degradation, especially in highly populated areas such as Central Florida. Wet detention ponds manage this stormwater, but most of the ponds do not remove enough nutrients, specifically nitrogen and phosphorus, to meet TMDL regulations. This research provides a possible addition to a detention pond in Seminole County, Florida using a Chamber Upflow Filter and Skimmer (CUFS), which can increase the removal of...
Show moreStormwater runoff is a known pollutant source capable of causing surface water degradation, especially in highly populated areas such as Central Florida. Wet detention ponds manage this stormwater, but most of the ponds do not remove enough nutrients, specifically nitrogen and phosphorus, to meet TMDL regulations. This research provides a possible addition to a detention pond in Seminole County, Florida using a Chamber Upflow Filter and Skimmer (CUFS), which can increase the removal of phosphorus and nitrogen by the system. Water enters the system through the skimmer, which floats on the surface of the detention pond. It travels from the skimmer to the bottom of the chamber, where heavier particles settle out before entering the upflow filter. The upflow filter contains twenty-four inches of Black and GoldTM media to remove nitrogen and phosphorus under anoxic conditions. Water flows up through the filter and out of the system, and eventually travels to Lake Jesup, a eutrophic lake. A total of twenty-eight storm events and seven baseflows were sampled from the site in Seminole County, and ten storm events were sampled from a pilot study CUFS. The results of this research show significant reductions by the Seminole County CUFS in turbidity, orthophosphorus, total phosphorus, and total suspended solids when the means were compared at a 95% confidence interval. Reductions also occurred for total nitrogen, but could not be proved by the mean comparison. The pilot scale application of the CUFS significantly reduced total nitrogen at a 95% confidence interval.
Show less - Date Issued
- 2008
- Identifier
- CFE0002235, ucf:47883
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002235
- Title
- PILOT STUDY OF NUTRIENT LOADING IN A WET DETENTION LAKE.
- Creator
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Gurr, Eric, Nnadi, Fidelia, University of Central Florida
- Abstract / Description
-
Florida is surrounded by water, and its many internal lakes and rivers have long been recognized for their excellent fishing and boating. This notoriety draws land developers to the lake shores to establish residential and commercial infrastructure. This land development brings with it flood plain alteration, water level stabilization, and increased nutrients which cause adverse impacts to our lakes. In response, the United States Environmental Protection Agency (EPA) passed the Federal Clean...
Show moreFlorida is surrounded by water, and its many internal lakes and rivers have long been recognized for their excellent fishing and boating. This notoriety draws land developers to the lake shores to establish residential and commercial infrastructure. This land development brings with it flood plain alteration, water level stabilization, and increased nutrients which cause adverse impacts to our lakes. In response, the United States Environmental Protection Agency (EPA) passed the Federal Clean Water Act (CWA) in 1972 which set the framework for the water quality standards for the entire United States. As a result of the CWA many point sources were eliminated, but in the process it became apparent that nonpoint source loads represented even more of a threat. To further study the physical and chemical characteristics of urban runoff the Nationwide Urban Runoff Program (NURP) was established in 1978. This research lead to a series of management options, named Best Management Practices (BMPs) which proposed various structural and non-structural methods to reduce nutrient loads. But the research and data collection on the effectiveness of these systems to remove nutrients is in its infancy. The main objective of this study was to generate accurate and effective water quality and water quantity data that future stormwater management decisions can be based upon. More specific, this study established automatic monitoring sites throughout the City of Kissimmee, Florida to determine the pollutant loadings into the tributaries of Lake Tohopekaliga. These monitoring sites are located such that inflows from outside the city limits can be isolated and external pollutant loads quantified. Also, additional internal monitoring sites were established to determine the pollutant loads of internal sections of the city. Data from these internal monitoring sites will also be used to determine the variable pollutant removal efficiencies and hydraulic fluctuations of natural, irregular riverine systems. The secondary objective of this study was to perform a pilot study using the discrete grab samples in tandem with the continuous hydraulic and hydrologic data from the monitoring stations. An existing lake within the project limits was chosen for the pilot study area. Monitoring stations are located at the influent and effluent sections of the lake which provided data on the hydraulic and hydrologic parameters. The pilot study determined the nutrient loads to and from the lake and checked for any seasonal variations in pollutant loading or removal efficiencies. For the purpose of this pilot study, only total nitrogen and total phosphorous were examined for two monitoring sites. The nutrient removal efficiency was performed using both the event mean concentration method and the summation of loads method to check for seasonal variation. There were no storm event concentrations available for used in this analysis, however, there were 25 discrete grab samples collected on a bi-monthly basis over a twelve month period. This data was used with corresponding five-minute rainfall and flow data from both the inflow and outflow points. The results of this study did not reveal any seasonal variation in the nutrient concentrations either flowing into or out from the lake. Although there were some relatively lower values in late spring, the concentration levels of total nitrogen did not seem to vary significantly from its mean value of 0.90 mg/l throughout the year. The concentration levels of total phosphorus did range from 0.02 mg/l to 0.48 mg/l, but not in relation to either season or flow volume fluctuations. The lake showed no net removals of total nitrogen and was actually found to be releasing total phosphorus to the downstream receiving waters. The findings of this study are limited due to the fact that the period of pilot study was only for twelve months and there were no rainfall events used in the analysis. Rainfall events are typically high sources of nutrient loads to a lake. The lower efficiencies were probably due to missing the actual higher nutrient load concentrations during the rainfall event. However, even considering the lack of event data, the nutrient removal efficiency for the pond was still low. This analysis did serve well as a basis for performing future analysis once additional data, including rainfall events, has been collected.
Show less - Date Issued
- 2007
- Identifier
- CFE0001912, ucf:47474
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001912
- Title
- Comparative nutrient removal with innovative green soprtion media for groundwater and stormwater co-treatment.
- Creator
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Wen, Dan, Chang, Ni-bin, Nam, Boo Hyun, Kibler, Kelly, Wanielista, Martin, Zheng, Qipeng, University of Central Florida
- Abstract / Description
-
As indicated by the National Academy of Engineering, the understanding of nitrogen cycle has been deemed as one of 14 grand challenges in engineering of the 21st century. Due to rapid population growth and urbanization, the stormwater runoff increased in quantity as well as its nutrient concentrations, which may trigger serious environmental issues such as eutrophication in aquatic systems and ecosystem degradation. This study focuses on stormwater and groundwater quality control via...
Show moreAs indicated by the National Academy of Engineering, the understanding of nitrogen cycle has been deemed as one of 14 grand challenges in engineering of the 21st century. Due to rapid population growth and urbanization, the stormwater runoff increased in quantity as well as its nutrient concentrations, which may trigger serious environmental issues such as eutrophication in aquatic systems and ecosystem degradation. This study focuses on stormwater and groundwater quality control via Biosorption Activated Media (BAM) which can be applied to enhance the nutrient removal potential as an emerging Best Management Practices (BMPs). BAM was tested in this study with respect to two changing environmental factors including the presence of toxins such as copper and the addition of carbon sources that may affect the removal effectiveness. In addition, the impacts on microbial ecology in BAM within the nitrification and denitrification processes due to those changing environmental conditions were explored through the identification of microbial population dynamics under different environmental conditions. To further enhance the recovery and reuse of the adsorbed ammonia as possible soil amendment or even fertilizer, a new media called Iron Filing Green Environmental Media (IFGEM) was developed based on BAM, with the inclusion of iron filings as a key component for nitrate reduction. The functionality of IFGEM was analyzed through a serious column studies with respect to several key factors, including varying influent nutrient concentrations, pH values, and temperature. The results of the column studies demonstrate promising nutrient removal and recovery potential simultaneously under changing factors.
Show less - Date Issued
- 2018
- Identifier
- CFE0007770, ucf:52394
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007770
- Title
- REMOVAL OF REFRACTORY TKN FROM AN EFFLUENT WASTEWATER USING SODIUM FERRATE.
- Creator
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Lettie, Lucia, Reinhart, Debra, University of Central Florida
- Abstract / Description
-
This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent...
Show moreThis research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated with doses of ferrate ranging from 1 to 50 mg/L as FeO4–2 under unbuffered conditions. TKN removal as high as 70% and COD removal greater than 55% was observed. The TSS production after ferrate treatment was in a range of 12 to 200 mg/L for doses between 10 and 50 mg/L FeO4-2. After an optimum dose of ferrate was determined, three bench-scale reactors were operated under anoxic conditions for 10 to 12 days, two as duplicates containing the treated effluent and one as a control with untreated sample. Two different doses of ferrate were used as optimum dose for these experiments, 10 and 25 mg/L as FeO4-2. The purpose of these reactors was to determine the potential for biological removal of remaining nitrogen after ferrate oxidation of refractory nitrogen. Treated and raw samples were analyzed for Total Kjeldahl Nitrogen (TKN) (filtered and unfiltered), chemical oxygen demand (COD) (filtered and unfiltered), total suspended solids (TSS), nitrate (NO3-N), nitrite (NO2-N), and heterotrophic plate count (HPC). As a result, more than 70% of the soluble TKN was removed by chemical and biological oxidation for a sample treated with a dose of 25 mg/L FeO4-2, and less than 50% when treated with 10 mg/L FeO4-2. For the control samples run parallel to the ferrate treated samples, a maximum of 48% of soluble TKN and a minimum of 12% was removed. A three-log increase was observed in heterotrophic bacteria numbers for both doses during the operation of the reactors. Sodium ferrate was found to be an effective oxidant that can enhance the biodegradability of recalcitrant TKN present in municipal wastewaters. As mentioned before this research was develop using batch reactor units at bench-scale, therefore it is recommended to follow the investigation of the biodegradability of recalcitrant TKN of a ferrate treated sample under continuous flow conditions so that results can be extrapolated to a full-scale treatment facility.
Show less - Date Issued
- 2006
- Identifier
- CFE0001247, ucf:46936
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001247
- Title
- Biological Nutrient Removal (BNR) Process Optimization and Recovery of Embedded Energy Using Biodiesel By-product.
- Creator
-
Salamah, Sultan, Randall, Andrew, Duranceau, Steven, Chopra, Manoj, University of Central Florida
- Abstract / Description
-
Enhanced biological phosphorus removal (EBPR) as well as biological nitrogen removal require a carbon source to be carried out. Volatile fatty acid (VFAs) (mainly acetic and propionic acids) are the major driving force for EBPR. Many domestic wastewaters have an insufficient amount of VFAs. However, carbon sources such as acetic and propionic acids can be produced using primary solids fermentation process. Due to the cost of VFA production, an external carbon source can be added to the...
Show moreEnhanced biological phosphorus removal (EBPR) as well as biological nitrogen removal require a carbon source to be carried out. Volatile fatty acid (VFAs) (mainly acetic and propionic acids) are the major driving force for EBPR. Many domestic wastewaters have an insufficient amount of VFAs. However, carbon sources such as acetic and propionic acids can be produced using primary solids fermentation process. Due to the cost of VFA production, an external carbon source can be added to the biological nutrient removal (BNR) system that can be fermented to provide the desired VFAs. Glycerol (biodiesel by-product) offers a solution to reduce carbon addition cost if can be fermented to acetic and propionic acid or can be used directly as an external carbon substrate for EBPR and denitrification. Using glycerol in wastewater treatment can also offset the biodiesel plant disposal cost and reduce the BNR chemical cost. The main objective of this study was to optimize the prefermentation process and optimize the BNR system using glycerol as an external carbon source. In this work, Optimization of the prefermentation process using glycerol, mixing, and hydrogen gas addition was evaluated. EBPR performance within an A2O-BNR system was evaluated using either a direct glycerol method to the anaerobic zone or by co-fermentation with primary solids. Also, optimization of the nitrogen removal (specifically denitrification) efficiency of a 5-stage BardenphoTM BNR system using either a direct glycerol method to the second anoxic zone or by co-fermentation with primary solids was evaluated. It was found in this study that glycerol was an efficient external carbon substrate for EBPR as well as biological nitrogen removal. The prefermentation experiment showed that glycerol co-fermentation with primary solids produced significantly higher (p(<)0.05) VFAs than primary solids fermentation alone, even more than the possible value from the added glycerol (427 mg-COD/L). The increased VFAs imply that the glycerol addition stimulated additional fermentation of primary solids. Lowering the prefermenter mixing energy (50 to 7 rpm) resulted in a significant increase in VFAs production (80%). Also, purging the headspace of the prefermenter with hydrogen gas did not lead to more VFAs, but significantly (p(<)0.05) increased the propionic acid to acetic acid ratio by 41%. In the A2O-BNR pilot plant experiment, it was found that glycerol is a suitable renewable external substrate to drive enhanced EBPR as well as denitrification. The results from both locations of glycerol addition (direct vs. fermented) were beneficial to the BNR system. Both systems had similar effluent quality and achieved total nitrogen (TN) and total phosphorus (TP) removals up to 86% and 92% respectively. The 5-stage BardenphoTM BNR experiment investigated the location of glycerol addition (direct vs. fermented) on the performance of denitrification in the second anoxic zone and the overall performance. The results from both systems were that glycerol was beneficial to the BNR system and had virtually similar effluent quality. Both systems achieve complete denitrification and excellent removal of TN and TP up to 95% and 89% respectively. Also, the pilot that received fermented glycerol had significantly higher VFAs loading and lower observed yield. The side-stream prefermenter effluent flowing to the second anoxic reactor did not cause high effluent ammonia (NH3) concentration. In summary, the location at which glycerol was added did not affect effluent quality for nitrogen and phosphorus. However, glycerol addition and mixing energy did impact prefermenter performance and effluent quality.
Show less - Date Issued
- 2017
- Identifier
- CFE0006788, ucf:51826
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0006788
- Title
- COMPARISON OF TRADITIONAL STANDARD DRAINFIELD WITH INNOVATIVE B&G TREATMENT BED FOR NUTRIENT REMOVAL FROM SEPTIC TANK WASTEWATER.
- Creator
-
Hossain, Fahim, Chang, Ni-Bin, University of Central Florida
- Abstract / Description
-
Nowadays people are more alert about conservation of water and water scarcity. The amount of usable water is decreasing due to unavailability of pure water for day to day use. Both surface and groundwater is contaminated by untreated wastewater discharged from improper onsite wastewater treatment system, nutrient laden agricultural runoff and increasing use of fertilizer in fields. This elevated nutrient level is increasing the maintenance and operation cost of water treatment plant. So it is...
Show moreNowadays people are more alert about conservation of water and water scarcity. The amount of usable water is decreasing due to unavailability of pure water for day to day use. Both surface and groundwater is contaminated by untreated wastewater discharged from improper onsite wastewater treatment system, nutrient laden agricultural runoff and increasing use of fertilizer in fields. This elevated nutrient level is increasing the maintenance and operation cost of water treatment plant. So it is an important task to remove those nutrients from wastewater and other water bodies by applying environmental friendly process. In the USA, about 25% homes are still depending on on-site wastewater treatment (OSWT) due to unavailability of centralized treatment process. In Florida, OSWT is managed by the Florida Department of Health (FDOH). By realizing the importance of water conservation, USEPA already determined the maximum contaminant level (MCL) for nitrate and nitrite in water bodies. Many researches are conducted to evaluate the performance of EPA recommended treatment process (i.e. traditional standard drain field) for OSWT. The UCF research group also performed an experiment to understand the efficiency of traditional standard drain field. At the same time the research group developed an innovative wastewater treatment process named B&G treatment bed as a comparison with traditional standard drain field. This paper mainly focuses on performance of these two treatment processes. The B&G is a novel treatment process by its functionality for nutrient removal. The process generally used a media mixture developed by the research group of UCF. This mixture will act as organic carbon source to support denitrification process while nitrification process does not demand such carbon source. Evan it is observed that this mixture can remove nutrient by physical-chemical process. The recirculation sand filter (RSF) of traditional drain field is also filled by another mixture of media. Both media mixtures are developed by batch experiment in UCF laboratory. The performance of the B&G is compared with the traditional treatment process practiced in USA. These media mixtures can be good supporting media for microorganismsÂÂ' growth and development. All the major nitrogen and phosphorus species removal is observed by collecting sample in a weekly fashion. The pathogens removal efficiency is also observed. The sample is analyzed by a certified laboratory (i.e. Environmental Research and Design, ERD) in Orlando, Florida to maintain the best quality of this research. The presence of microorganisms is identified by using PCR. The B&G drainfield is very effective for removing both nitrogen and phosphorus species from wastewater. It is also very efficient to remove pathogens too. Standard drainfield is very effective for pathogen removal but it cannot remove nutrients effectively. Nitrate removal in B&G drainfield is well compared to standard drainfield.
Show less - Date Issued
- 2010
- Identifier
- CFE0003271, ucf:52842
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003271
- Title
- The effect of glycerol on readily biodegradable chemical oxygen demand (RBCOD) in a wastewater stream.
- Creator
-
Rawut, Rojina, Sadmani, A H M Anwar, Lee, Woo Hyoung, Duranceau, Steven, University of Central Florida
- Abstract / Description
-
This study evaluated the short-term effects of glycerol addition on readily biodegradable (RB) chemical oxygen demand (COD) in a carbon limited wastewater influent. The presence of an RB fraction provides with a suitable substrate for microorganisms to produce volatile fatty acids (VFA). The oxygen utilization rate (OUR) has been used to evaluate the oxygen consumption for RB substrate in wastewater. Wastewater with low organic content contains limited RB substrate, and thus, additional...
Show moreThis study evaluated the short-term effects of glycerol addition on readily biodegradable (RB) chemical oxygen demand (COD) in a carbon limited wastewater influent. The presence of an RB fraction provides with a suitable substrate for microorganisms to produce volatile fatty acids (VFA). The oxygen utilization rate (OUR) has been used to evaluate the oxygen consumption for RB substrate in wastewater. Wastewater with low organic content contains limited RB substrate, and thus, additional carbon source is required to improve biological treatment capability. Acetate, propionate, methanol, and glycerol are the commonly available carbon sources for biological treatment process. However, the cost of acetate and propionate are relatively high, and it is not economical to use these carbon sources in the wastewater plant. The use of methanol as a carbon source inherently poses safety issues in field applications due to its toxic and flammable properties. On the other hand, crude glycerol is the byproduct of biodiesel, which is an excellent carbon source alternative. However, crude glycerol contains impurities and requires a certain degree of purification to enhance the performance. The samples for the study were collected from the Iron Bridge Wastewater Reclamation Facility (Oviedo, FL) designed for treating municipal wastewater. The total COD (TCOD) of the sample influent was in the range of 237 to 408 mg COD/L, and RBCOD value was between 38 and 80.5 mg COD/L, containing up to 10 mg COD/L of VFA. This study also demonstrates the relationship between the glycerol concentration and OURs during the diauxic growth phase from the addition of glycerol. The growth was due to the existence of RB substrate and availability of glycerol for the microorganisms. TCOD increased from 284 to 378 mg COD/L and from 284 mg COD/L to 323 mg COD/L by spiking approximately 30 and 15 mL of glycerol stock solution (6.67 g/L), respectively. RBCOD increased from 45 to 89 mg COD/L and 55 mg COD/ L by spiking 30 mL and 15 ml glycerol stock solution, respectively. The initial influent heterotrophic active biomass (ZBH) increased from 5.4 to 15.8 mg VSS/L (8 to 23.4 mg COD/L) due to the addition of glycerol, indicating that the glycerol may be an adequate carbon source. The COD of wastewater with limited VFA (e.g., 10 mg COD/L) increased up to 2,502 mg COD/L where propionic acid (2,468 mg COD/L) exists as the primary end product with a small quantity of acetic acid (34 mg COD/L). Propionic acid was the main VFA component fermented from the glycerol addition. Glycerol addition led to increased RBCOD accompanied by high VFA production. This research investigated the short-term effect of glycerol addition on existing RBCOD in wastewater. It is recommended to explore the effect of increased RBCOD by the addition of glycerol to the effluent N and P for future study.
Show less - Date Issued
- 2016
- Identifier
- CFE0006543, ucf:51324
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0006543
- Title
- Evaluating Floating Treatment Wetlands to Improve Nitrogen Removal in a Wet Detention Pond.
- Creator
-
Marimon, Zachary, Chang, Ni-bin, Fauth, John, Bohlen, Patrick, University of Central Florida
- Abstract / Description
-
Wet detention ponds are used for stormwater treatment across the United States and reduce most pollutants by at least 60%, but only remove 30% of total nitrogen. Floating Treatment Wetlands (FTWs) are an emerging technology that uses aquatic plants suspended in the pelagic zone to remove nitrogen through vegetative assimilation and microbial denitrification. A before-after field experiment evaluated nitrogen removal in a an existing pond in Orlando, FL, retrofitted with BioHaven(&)#174; FTWs...
Show moreWet detention ponds are used for stormwater treatment across the United States and reduce most pollutants by at least 60%, but only remove 30% of total nitrogen. Floating Treatment Wetlands (FTWs) are an emerging technology that uses aquatic plants suspended in the pelagic zone to remove nitrogen through vegetative assimilation and microbial denitrification. A before-after field experiment evaluated nitrogen removal in a an existing pond in Orlando, FL, retrofitted with BioHaven(&)#174; FTWs planted with the aquatic macrophytes Juncus effusus (Soft Rush) and Pontederia cordata (Pickerelweed). Surface water samples were used to compare the nitrogen-removal performance of the pond under both storm and non-storm conditions during a pre-analysis phase (control) to post-analysis after FTW deployment. The evaluation revealed similar TN removals in non-storm conditions during pre-analysis and post-analysis periods (-1% and -3%, respectively). During storm conditions, there was a negative TN removal of -26% in the pre-analysis compared to the positive 29% removal post-analysis. In addition, nitrogen concentrations for organic-nitrogen, ammonia/ammonium, and nitrites/nitrates were used as input for calibrating and validating a system dynamics model to predict multiple, interacting nitrogen species' transformation and translocation across the abiotic and biotic components of water, sediment, plants, and atmosphere. The validated model created in STELLA v.9.4.1 was used to simulate alternative designs to achieve maximum nitrogen removal based on the treatment efficiency in the evaluation. Simulations predicted 60% FTW coverage at the experimental planting density (22 per square meter) could achieve maximum nitrogen removal. Alternatively, similar nitrogen removal could be achieved at only 15% FTW coverage by increasing plant density. The model can be used as a low-cost tool for designing FTW technology applications and monitoring nitrogen transport.
Show less - Date Issued
- 2016
- Identifier
- CFE0006140, ucf:51168
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0006140
- Title
- Chemophysical Characteristics and Application of Biosorption Activated Media (BAM) for Copper and Nutrient Removal in Stormwater Management.
- Creator
-
Jones, Jamie, Chang, Ni-bin, Bohlen, Patrick, Wanielista, Martin, University of Central Florida
- Abstract / Description
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For high groundwater table areas, stormwater wet detention ponds are utilized as the preferred stormwater management throughout the state of Florida. Previous research has found that accumulations of nutrients, algae, heavy metals, pesticides, chlorophyll a, fecal coliform bacteria and low concentrations of dissolved oxygen (DO) are common characteristics of stormwater wet detention ponds. Although these pollutant levels are not regulated within the ponds, states are required to compute the...
Show moreFor high groundwater table areas, stormwater wet detention ponds are utilized as the preferred stormwater management throughout the state of Florida. Previous research has found that accumulations of nutrients, algae, heavy metals, pesticides, chlorophyll a, fecal coliform bacteria and low concentrations of dissolved oxygen (DO) are common characteristics of stormwater wet detention ponds. Although these pollutant levels are not regulated within the ponds, states are required to compute the pollutant load reductions through total maximum daily load (TMDL) programs to meet the water quality requirements addressed by the Clean Water Act (CWA). In this study, field sampling data of stormwater ponds throughout Florida are presented to identify concentration levels of the main contaminants of concern in the discharge of wet detention ponds. Sampling was done to identify possible sources, in addition to possible removal mechanisms via the use of specific sorption media. Nutrients were found as a main problematic pollutant, of which orthophosphate, total phosphorus, ammonia, nitrate, and total nitrogen were targeted whereas heavy metals exhibited minor concerns. Accumulation of high nutrient concentrations may be mitigated by the adoption of best management practices (BMPs) utilizing biosorption activated media (BAM) to remove phosphorus and nitrogen species through physical, chemical, and biological processes. This study aims to increase overall scientific understanding of phosphorus removal dynamics in sorption media systems via Langmuir and Freundlich isotherms and column studies. The removal of phosphorus (P) was proven effective primarily through chemophysical processes. The maximum orthophosphate adsorption capacities were determined under varying conditions of the media within the columns, which were found up to 0.000534 mg-P adsorbed per gram BAM with influent concentrations of 1 mg?L-1 orthophosphate in distilled water and 1 hour hydraulic residence time (HRT). When using spiked pond water under the same conditions, the adsorption capacity was increased about 30 times to 0.01507 mg-P?g-1 BAM presumably due to the properties and concentrations of ions affecting the diffusion rate regulating the surface orthophosphate reactions. These equilibrium media uptake values (q) were used to calculate the life expectancies of the media under varying HRT and influent concentrations of treatment. Chemophysical and biological removal capabilities of the media for total nitrogen, ammonia, and nitrate were effective in columns using 1100 g of BAM. In flow-through column conditions, ammonia had a consistent ~95% removal while effluent nitrate concentrations were highly variable due to the simultaneous nitrification-denitrification processes once an aerobic-anaerobic environment was established. Batch column experiments simulating no-flow conditions within a media bed reactor resulted in orthophosphate removals comparable with the continuous flow conditions, increased total phosphorus effluents indicative of chemical precipitation of orthophosphate, decreased ammonia removal, and increased nitrate removal. Due to a biofilm's sensitivity to even low copper concentrations and accumulation in ponds, a copper sorption media mix of (")green(") materials was generated. Freundlich and Langmuir isotherm tests concluded a successful mix resulting in copper removal efficiencies up to 96%.
Show less - Date Issued
- 2013
- Identifier
- CFE0005009, ucf:49995
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005009
- Title
- An Assessment of Biosorption Activated Media for the Removal of Pollutants in Up-Flow Stormwater Treatment Systems.
- Creator
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Hood, Andrew, Randall, Andrew, Wanielista, Martin, Chopra, Manoj, O'Reilly, Andrew, Moore, Sean, University of Central Florida
- Abstract / Description
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Nitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical...
Show moreNitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical in ultra-urban environments where above ground space is limited. Upflow filters utilizing biosorption activated media (BAM) that can be placed underground offer a small footprint alternative. Additionally, BAM upflow filters can be installed at the discharge point of traditional stormwater ponds to provide further treatment. This research simulated stormwater that had already been treated for solids removal; thus, most of the nutrients and solids in the influent were assumed to be as non-settable suspended solids or dissolved solids. Three different BAM mixtures in an upflow filter configuration were compared for the parameters of nitrogen, phosphorus, total coliform, E. coli, and heterotrophic plate count (HPC). Additionally, genetic testing was conducted using Polymerase Chain Reaction (PCR), in conjunction with a nitrogen mass balance, to determine if Anammox was a significant player in the nitrogen removal. The columns were run at both 22-minute and 220-minute Empty Bed Contact Times (EBCTs). All the BAM mixtures analyzed were shown to be capable at the removal of nitrogen, phosphorus, and total coliform during both the 22-minute and 220-minute EBCTs, with BAM #1 having the highest removal performance for all three parameters during both EBCTs. All BAM mixtures experienced an increase in HPC. Additionally, PCR analysis confirmed the presence of Anammox in the biofilm and via mass balance it was determined that the biological nitrogen removal was due to Anammox and endogenous denitrification with Anammox being a significant mechanism.
Show less - Date Issued
- 2019
- Identifier
- CFE0007817, ucf:52875
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007817
