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Title: Modeling wastewater indicators and effects of contaminant removal strategies on groundwater and spring discharge in a karst aquifer.
Creator: Reed, Erin, Duranceau, Steven, Wang, Dingbao, Sadmani, A H M Anwar, Rowney, Alexander, University of Central Florida
Abstract / Description: This dissertation reports on research related to groundwater and contaminant transport to the Volusia Blue Spring (VBS), an Outstanding Florida Water Body located in Volusia County (Florida). The integration of springshed water quality and contaminant fate and transport (CFT) modeling played key roles in the evaluation of anthropogenic recharge impacts on VBS. To study anthropogenic recharge into the karst limestone aquifer, wastewater effluent, golf course ponds, septic tanks, groundwater...
Show moreThis dissertation reports on research related to groundwater and contaminant transport to the Volusia Blue Spring (VBS), an Outstanding Florida Water Body located in Volusia County (Florida). The integration of springshed water quality and contaminant fate and transport (CFT) modeling played key roles in the evaluation of anthropogenic recharge impacts on VBS. To study anthropogenic recharge into the karst limestone aquifer, wastewater effluent, golf course ponds, septic tanks, groundwater monitoring wells, and VBS discharge were sampled for boron, nitrate-nitrogen, nitrate-oxygen and their isotopes spatially throughout the VBS springshed. Data related to natural water features, rainfall, land use, water use, treated wastewater discharge, and septic tank effluent flows was used as inputs to the three-dimensional CFT model developed from an integration of MODFLOW-2000 and MT3DMS. The model was calibrated and validated from field observed water levels and water quality taken throughout the springshed. The purpose of this model is to understand groundwater and spring water quality throughout the VBS springshed. Water quality and model results indicate that water from the surficial aquifer in surrounding urban areas contributed to the flow and water quality at the spring's boil. Protection scenarios that included wetland treatment systems and the conversion of targeted septic systems to sewer were simulated to estimate future reductions of anthropogenic nutrients transported to the Spring. Of the scenarios evaluated in this study, targeted septic system removal results in the greatest benefit with a 36% nitrate decrease in a forty-year projection of spring discharge water quality. Results from this combined water quality and model development approach is expected to contribute an understanding of anthropogenic impacts from the urbanized developments overlying and surrounding the karst VBS aquifer.
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Date Issued: 2016
Identifier: CFE0006701, ucf:51903
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006701

Title: REMOVAL OF REFRACTORY TKN FROM AN EFFLUENT WASTEWATER USING SODIUM FERRATE.
Creator: Lettie, Lucia, Reinhart, Debra, University of Central Florida
Abstract / Description: This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent...
Show moreThis research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated with doses of ferrate ranging from 1 to 50 mg/L as FeO4–2 under unbuffered conditions. TKN removal as high as 70% and COD removal greater than 55% was observed. The TSS production after ferrate treatment was in a range of 12 to 200 mg/L for doses between 10 and 50 mg/L FeO4-2. After an optimum dose of ferrate was determined, three bench-scale reactors were operated under anoxic conditions for 10 to 12 days, two as duplicates containing the treated effluent and one as a control with untreated sample. Two different doses of ferrate were used as optimum dose for these experiments, 10 and 25 mg/L as FeO4-2. The purpose of these reactors was to determine the potential for biological removal of remaining nitrogen after ferrate oxidation of refractory nitrogen. Treated and raw samples were analyzed for Total Kjeldahl Nitrogen (TKN) (filtered and unfiltered), chemical oxygen demand (COD) (filtered and unfiltered), total suspended solids (TSS), nitrate (NO3-N), nitrite (NO2-N), and heterotrophic plate count (HPC). As a result, more than 70% of the soluble TKN was removed by chemical and biological oxidation for a sample treated with a dose of 25 mg/L FeO4-2, and less than 50% when treated with 10 mg/L FeO4-2. For the control samples run parallel to the ferrate treated samples, a maximum of 48% of soluble TKN and a minimum of 12% was removed. A three-log increase was observed in heterotrophic bacteria numbers for both doses during the operation of the reactors. Sodium ferrate was found to be an effective oxidant that can enhance the biodegradability of recalcitrant TKN present in municipal wastewaters. As mentioned before this research was develop using batch reactor units at bench-scale, therefore it is recommended to follow the investigation of the biodegradability of recalcitrant TKN of a ferrate treated sample under continuous flow conditions so that results can be extrapolated to a full-scale treatment facility.
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Date Issued: 2006
Identifier: CFE0001247, ucf:46936
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001247

Title: THE EFFECTS OF PH ON ENHANCED BIOLOGICAL PHOSPHORUS REMOVAL (EBPR) WITH PROPIONIC ACID AS THE DOMINANT VOLATILE FATTY ACID (VFA).
Creator: malekjahani, seyed, Randall, Andrew, University of Central Florida
Abstract / Description: pH control is a tool to improve some aspects of Enhanced Biological Phosphorus Removal (EBPR) process. Filipe et al (2001a, 2001b, and 2001c) found strong evidence that the stability of EBPR systems can be improved by increasing the pH of the anaerobic zone, thereby creating conditions where phosphorus-accumulating organisms (PAOs) are able to take up acetate faster than glycogen-accumulating organisms (GAOs). They explained this observation by comparing the growth rate of phosphorus...
Show morepH control is a tool to improve some aspects of Enhanced Biological Phosphorus Removal (EBPR) process. Filipe et al (2001a, 2001b, and 2001c) found strong evidence that the stability of EBPR systems can be improved by increasing the pH of the anaerobic zone, thereby creating conditions where phosphorus-accumulating organisms (PAOs) are able to take up acetate faster than glycogen-accumulating organisms (GAOs). They explained this observation by comparing the growth rate of phosphorus-accumulating organisms (PAOs) and glycogen-accumulating organisms (GAOs) and found that pH has little effect on PAOs growth rate but adversely affects GAOs growth rate when it increases (at pH values greater than 7.25, PAOs would take acetate faster than GAOs would). They used synthetic wastewater rich in acetic acid. In this study, we used real wastewater and the dominant volatile fatty acid available to microorganisms was propionic acid in continuous EBPR system. It was found that lower anaerobic zone pH (6.5 vs. 7.2) reduced the anaerobic P release both on an MLVSS specific basis and also on a non-specific (absolute value for the process) basis. In addition, the observed yield was significantly decreased. Aerobic P uptake was lower in the low-pH system (on a non-specific basis) due to the lower observed yield, and thus lower MLVSS concentration. Net P uptake was hard to interpret because of the effect of P release in the secondary clarifier of Train 2 (high pH). However, on a specific basis it was clear that net P uptake was either equal or better in the low-pH system regardless of how the secondary clarifier data was interpreted. Carbon transformations were not impacted in as consistent a fashion as anaerobic P release was. On a specific basis, PHA content remained unchanged although the PHV/PHB ratio was impacted with much lower PHV content in the low-pH system. Glycogen content and the amount of labile glycogen (delta glycogen) were higher in the low-pH system, in spite of the fact that MLVSS P content did not decrease. However, due to the impact of the low observed yield at low pH, absolute values resulted in higher PHA content for the process reactors as a whole, higher glycogen content, and unchanged labile glycogen. Low pH resulted in increased biomass P content, however the lower observed yield offset this on a process basis so that effluent P levels were nearly equal. So low pH improved P removal on a specific basis, but not on a process basis. Since it is unknown if the low observed yield is repeatable, and due to the impact of the secondary clarifier in the high pH system, it cannot be concluded that the effect of low pH on net P removal would be similar in other EBPR systems.
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Date Issued: 2006
Identifier: CFE0001433, ucf:47042
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0001433

Title: EFFECTS OF REDUCED RAS AND VOLUME ON ANAEROBIC ZONE PERFORMANCE FOR A SEPTIC WASTEWATER BIOLOGICAL PHOSPHOROUS REMOVAL SYSTEM.
Creator: Magro, Daniel, Randall, Andrew, University of Central Florida
Abstract / Description: Enhanced Biological Phosphorous Removal (EBPR) performance was found to be adequate with reduced Return Activated Sludge (RAS) flows (50% of available RAS) to the anaerobic tank and smaller than typical anaerobic zone volume (1.08 hours hydraulic retention time or HRT). Three identical parallel biological nutrient removal (BNR) pilot plants were fed with strong, highly fermented (160 mg/L VFAs), domestic/industrial wastewater from a full scale wastewater treatment facility (WWTF). The pilot...
Show moreEnhanced Biological Phosphorous Removal (EBPR) performance was found to be adequate with reduced Return Activated Sludge (RAS) flows (50% of available RAS) to the anaerobic tank and smaller than typical anaerobic zone volume (1.08 hours hydraulic retention time or HRT). Three identical parallel biological nutrient removal (BNR) pilot plants were fed with strong, highly fermented (160 mg/L VFAs), domestic/industrial wastewater from a full scale wastewater treatment facility (WWTF). The pilot plants were operated at 100%, 50%, 40% and 25% RAS (percent of available RAS) flows to the anaerobic tank with the remaining RAS to the anoxic tank. In addition, varying anaerobic HRT (1.08 and 1.5 hours), and increased hydraulic loading (35% increase) was examined. The study was divided in four Phases, and the effect of these process variations on EBPR were studied by having one different variable between two identical systems. The most significant conclusions were that only bringing part of the RAS to the anaerobic zone did not decrease EBPR performance, instead changing the location of P release and uptake. Bringing less RAS to the anaerobic and more to the anoxic tank decreased anaerobic P release and increased anoxic P release (or decreased anoxic P uptake). Equally important is that with VFA rich influent wastewater, excessive anaerobic volume was shown to hurt overall P removal even when it resulted in increased anaerobic P release. Computer modeling with BioWin and UCTPHO was found to predict similar results to the pilot test results. Modeling was done with reduced RAS flows to the anaerobic zone (100%, 50%, and 25% RAS), increased anaerobic volume, and increased hydraulic loading. The most significant conclusions were that both models predicted EBPR did not deteriorate with less RAS to the anaerobic zone, in fact, improvements in EBPR were observed. Additional scenarios were also consistent with pilot test data in that increased anaerobic volume did not improve EBPR and increased hydraulic loading did not adversely affect EBPR.
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Date Issued: 2005
Identifier: CFE0000329, ucf:46285
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000329

Title: COMPARISON OF THE EFFECTIVENESS OF ALTERNATIVE FERRATE (VI) SYNTHESIS FORMULAS AS DISINFECTANTS FOR WASTEWATER AND RIVER WATER.
Creator: Ginart, Rachelle, Reinhart, Debra, University of Central Florida
Abstract / Description: Ferrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of...
Show moreFerrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of hypochlorite (Low Chlorine Formula) while the other ferrate (VI) synthesis formula uses more than the stoichiometric requirement of hypochlorite (Standard Chlorine Formula). For applications requiring low chlorine residual effluent quality, the Low Chlorine Formula intuitively is a more suitable disinfectant than the Standard Formula. For applications where chlorine residual is of little or no significance, the Standard Formula is logically a more suitable disinfectant due to lower production cost and production of higher ferrate (VI) concentrations than the Low Chlorine Formula. The total chlorine concentration, unfiltered and filtered ferrate (VI) concentration, and dissolved organic carbon concentration before and after treatment using both ferrate (VI) formulas in wastewater and Econ River water was measured at a contact time of 30 minutes. Disinfection capabilities were measured by comparing the quantity of Heterotrophic bacteria, Total Coliform, Escherichia coli, and Enterococcus bacteria pre-ferrate (VI) to post-ferrate (VI) at dosages of 2, 4, and 7.5 mg/L as ferrate (VI) using both ferrate (VI) formulas. The rate of disappearance of both ferrate (VI) formulas in wastewater at an unadjusted pH and pH of 6.0-6.35 was determined. In addition the total oxidant absorbance and total chlorine concentration were measured over a 30-minute period. Both ferrate (VI) formulas were effective at inactivating Total Coliform, E. Coli, Enterococcus, and heterotrophic bacteria at a 30-minute contact time and lowering DOC concentrations in Econlockhatchee River water and secondary wastewater. The Standard Formula demonstrated better disinfection at lower dosages than the Low Chlorine Formula. In both ferrate (VI) formulas, there was a presence of an instantaneous demand of ferrate (VI) and a first-order reaction rate of ferrate (VI) over 30 minutes. The chlorine residual of 7.5 mg/L ferrate (VI) dose in wastewater at a 30-minute contact time was 0.2 to 0.6 mg/L Cl2 for the Low Chlorine Formula and 0.8 to 1.4 mg/L Cl2 for the Standard Formula. These experiments indicate that both ferrate (VI) formulas can serve as effective environmentally friendly disinfectants for wastewater and Econ River water.
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Date Issued: 2008
Identifier: CFE0002284, ucf:47843
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002284

Title: Electrochemical Microsensors for In Situ Monitoring of Chemical Compounds in Engineered and Natural Aquatic Systems.
Creator: Church, Jared, Lee, Woo Hyoung, Randall, Andrew, Duranceau, Steven, University of Central Florida
Abstract / Description: The adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20(&)#181;m) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using...
Show moreThe adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20(&)#181;m) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using conventional analytical tools. However, their applications have been primarily limited to understanding mass transport dynamics and kinetics in biofilms. With the advancement of sensor fabrication and utilization techniques, their potential applications can surpass conventional biofilm processes. In this dissertation, microsensors were utilized to elucidate mass transport and chemical reactions in multidisciplinary research areas including biological nutrient uptake, oily wastewater treatment, photocatalytic disinfection, and plant disease management, which have not yet explored using this emerging technology. The main objective of this work was to develop novel microsensors and use them for better understanding various natural and engineered aquatic systems. These include; 1) investigating localized photo-aeration and algal-bacterial symbiotic interaction in an advanced algal-bacterial biofilm process for nutrient removal from wastewater, 2) characterizing oil-in-water emulsions for better understanding bilge water emulsion stability, 3) evaluating sun-light driven photocatalytic reactions using a novel MoS2 nanofilm for water disinfection and microcystins-LR removal, 4) developing a zinc ion-selective microsensor and applying them for monitoring the transport of zinc in citrus trees, and 5) integrating heavy metal detection using anodic stripping voltammetry (ASV) in a microelectrode platform for plant applications.
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Date Issued: 2018
Identifier: CFE0007565, ucf:52576
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007565

Title: COMPARISON OF TRADITIONAL STANDARD DRAINFIELD WITH INNOVATIVE B&G TREATMENT BED FOR NUTRIENT REMOVAL FROM SEPTIC TANK WASTEWATER.
Creator: Hossain, Fahim, Chang, Ni-Bin, University of Central Florida
Abstract / Description: Nowadays people are more alert about conservation of water and water scarcity. The amount of usable water is decreasing due to unavailability of pure water for day to day use. Both surface and groundwater is contaminated by untreated wastewater discharged from improper onsite wastewater treatment system, nutrient laden agricultural runoff and increasing use of fertilizer in fields. This elevated nutrient level is increasing the maintenance and operation cost of water treatment plant. So it is...
Show moreNowadays people are more alert about conservation of water and water scarcity. The amount of usable water is decreasing due to unavailability of pure water for day to day use. Both surface and groundwater is contaminated by untreated wastewater discharged from improper onsite wastewater treatment system, nutrient laden agricultural runoff and increasing use of fertilizer in fields. This elevated nutrient level is increasing the maintenance and operation cost of water treatment plant. So it is an important task to remove those nutrients from wastewater and other water bodies by applying environmental friendly process. In the USA, about 25% homes are still depending on on-site wastewater treatment (OSWT) due to unavailability of centralized treatment process. In Florida, OSWT is managed by the Florida Department of Health (FDOH). By realizing the importance of water conservation, USEPA already determined the maximum contaminant level (MCL) for nitrate and nitrite in water bodies. Many researches are conducted to evaluate the performance of EPA recommended treatment process (i.e. traditional standard drain field) for OSWT. The UCF research group also performed an experiment to understand the efficiency of traditional standard drain field. At the same time the research group developed an innovative wastewater treatment process named B&G treatment bed as a comparison with traditional standard drain field. This paper mainly focuses on performance of these two treatment processes. The B&G is a novel treatment process by its functionality for nutrient removal. The process generally used a media mixture developed by the research group of UCF. This mixture will act as organic carbon source to support denitrification process while nitrification process does not demand such carbon source. Evan it is observed that this mixture can remove nutrient by physical-chemical process. The recirculation sand filter (RSF) of traditional drain field is also filled by another mixture of media. Both media mixtures are developed by batch experiment in UCF laboratory. The performance of the B&G is compared with the traditional treatment process practiced in USA. These media mixtures can be good supporting media for microorganismsÃ‚Â' growth and development. All the major nitrogen and phosphorus species removal is observed by collecting sample in a weekly fashion. The pathogens removal efficiency is also observed. The sample is analyzed by a certified laboratory (i.e. Environmental Research and Design, ERD) in Orlando, Florida to maintain the best quality of this research. The presence of microorganisms is identified by using PCR. The B&G drainfield is very effective for removing both nitrogen and phosphorus species from wastewater. It is also very efficient to remove pathogens too. Standard drainfield is very effective for pathogen removal but it cannot remove nutrients effectively. Nitrate removal in B&G drainfield is well compared to standard drainfield.
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Date Issued: 2010
Identifier: CFE0003271, ucf:52842
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003271

Title: NUTRIENT AND PATHOGEN REMOVAL IN A SUBSURFACE UPFLOW WETLAND SYSTEM USING GREEN SORPTION MEDIA.
Creator: Xuan, Zhemin, Chang, Ni-Bin, University of Central Florida
Abstract / Description: Due to environmental health and nutrient impact concerns, the conventional on-site sewage collection, treatment, and disposal systems are no longer able to meet the nutrient reduction requirements for wastewater effluent and may represent a large fraction of pollutant loads. The loads include not only nitrogen (N) and phosphorus (P), but also pathogens such as fecal coliform and E. coli which indicate the presence of other disease-causing bacteria flowing into aquatic system that adversely...
Show moreDue to environmental health and nutrient impact concerns, the conventional on-site sewage collection, treatment, and disposal systems are no longer able to meet the nutrient reduction requirements for wastewater effluent and may represent a large fraction of pollutant loads. The loads include not only nitrogen (N) and phosphorus (P), but also pathogens such as fecal coliform and E. coli which indicate the presence of other disease-causing bacteria flowing into aquatic system that adversely affect public health. A subsurface upflow wetland, which is an effective small-scale wastewater treatment system with low energy and maintenance requirements and operational costs, fits the current nutrient and pathogen removal situation having received wide attention throughout the world. Within this research study, a subsurface upflow wetland system (SUW), including four parallel SUW (three planted versus one unplanted), were constructed as a key component of the septic tank system receiving 454 liters per day (120 GPD) influent using the green sorption media along with selected plant species. It was proved effective in removing both nutrients and pathogens. During a one month test run, the planted wetlands achieved a removal efficiency of 84.2%, 97.3 %, 98.93 % and 99.92%, compared to the control wetland, 10.5%, 85.7 %, 99.74 % and 100.0 %, in total nitrogen (TN), total phosphorus (TP), fecal coli and E.Coli, respectively. Denitrification was proved to be the dominant pathway for removing N as evidenced by the mass balance and real-time PCR analyses. A simplified compartmental dynamics simulation model of constructed subsurface upflow wetlands was also developed to provide a dependable reference and tool for design of constructed subsurface upflow wetland.
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Date Issued: 2009
Identifier: CFE0002967, ucf:47964
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002967

Title: The effect of glycerol on readily biodegradable chemical oxygen demand (RBCOD) in a wastewater stream.
Creator: Rawut, Rojina, Sadmani, A H M Anwar, Lee, Woo Hyoung, Duranceau, Steven, University of Central Florida
Abstract / Description: This study evaluated the short-term effects of glycerol addition on readily biodegradable (RB) chemical oxygen demand (COD) in a carbon limited wastewater influent. The presence of an RB fraction provides with a suitable substrate for microorganisms to produce volatile fatty acids (VFA). The oxygen utilization rate (OUR) has been used to evaluate the oxygen consumption for RB substrate in wastewater. Wastewater with low organic content contains limited RB substrate, and thus, additional...
Show moreThis study evaluated the short-term effects of glycerol addition on readily biodegradable (RB) chemical oxygen demand (COD) in a carbon limited wastewater influent. The presence of an RB fraction provides with a suitable substrate for microorganisms to produce volatile fatty acids (VFA). The oxygen utilization rate (OUR) has been used to evaluate the oxygen consumption for RB substrate in wastewater. Wastewater with low organic content contains limited RB substrate, and thus, additional carbon source is required to improve biological treatment capability. Acetate, propionate, methanol, and glycerol are the commonly available carbon sources for biological treatment process. However, the cost of acetate and propionate are relatively high, and it is not economical to use these carbon sources in the wastewater plant. The use of methanol as a carbon source inherently poses safety issues in field applications due to its toxic and flammable properties. On the other hand, crude glycerol is the byproduct of biodiesel, which is an excellent carbon source alternative. However, crude glycerol contains impurities and requires a certain degree of purification to enhance the performance. The samples for the study were collected from the Iron Bridge Wastewater Reclamation Facility (Oviedo, FL) designed for treating municipal wastewater. The total COD (TCOD) of the sample influent was in the range of 237 to 408 mg COD/L, and RBCOD value was between 38 and 80.5 mg COD/L, containing up to 10 mg COD/L of VFA. This study also demonstrates the relationship between the glycerol concentration and OURs during the diauxic growth phase from the addition of glycerol. The growth was due to the existence of RB substrate and availability of glycerol for the microorganisms. TCOD increased from 284 to 378 mg COD/L and from 284 mg COD/L to 323 mg COD/L by spiking approximately 30 and 15 mL of glycerol stock solution (6.67 g/L), respectively. RBCOD increased from 45 to 89 mg COD/L and 55 mg COD/ L by spiking 30 mL and 15 ml glycerol stock solution, respectively. The initial influent heterotrophic active biomass (ZBH) increased from 5.4 to 15.8 mg VSS/L (8 to 23.4 mg COD/L) due to the addition of glycerol, indicating that the glycerol may be an adequate carbon source. The COD of wastewater with limited VFA (e.g., 10 mg COD/L) increased up to 2,502 mg COD/L where propionic acid (2,468 mg COD/L) exists as the primary end product with a small quantity of acetic acid (34 mg COD/L). Propionic acid was the main VFA component fermented from the glycerol addition. Glycerol addition led to increased RBCOD accompanied by high VFA production. This research investigated the short-term effect of glycerol addition on existing RBCOD in wastewater. It is recommended to explore the effect of increased RBCOD by the addition of glycerol to the effluent N and P for future study.
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Date Issued: 2016
Identifier: CFE0006543, ucf:51324
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006543

Title: DECOLORIZATION OF AN AZO AND ANTHRAQUINONE TEXTILE DYE BY A MIXTURE OF LIVING AND NON-LIVING TRAMETES VERSICOLOR FUNGUS.
Creator: Dykstra, Christine, Randall, Andrew, University of Central Florida
Abstract / Description: Wastewater from the textile industry is difficult to treat effectively due to the prevalent use and wide variety of synthetic dyes that are resistant to conventional treatment methods. White-rot fungi, such as Trametes versicolor, have been found to be effective in decolorizing many of these synthetic dyes and current research is focusing on their application to wastewater treatment. Although numerous studies have been conducted on the ability of both living and nonliving Trametes versicolor...
Show moreWastewater from the textile industry is difficult to treat effectively due to the prevalent use and wide variety of synthetic dyes that are resistant to conventional treatment methods. White-rot fungi, such as Trametes versicolor, have been found to be effective in decolorizing many of these synthetic dyes and current research is focusing on their application to wastewater treatment. Although numerous studies have been conducted on the ability of both living and nonliving Trametes versicolor to separately decolorize textile dyes, no studies were found to have investigated the use of a mixture of live and dead fungus for decolorization. This study explored potential interactions between live and dead, autoclaved Trametes versicolor biomass in a mixed system by utilizing a series of batch tests with two structurally different synthetic textile dyes. Samples were analyzed by spectrophotometer and compared with controls to determine the effect of any interactions on decolorization. The results of this study indicate that an interaction between living and nonliving biomass occurred that affected the specific dye removal for both Reactive Blue 19, an anthraquinone textile dye, and Reactive Orange 16, an azo textile dye. This interaction was seen to improve the specific dye removal during the first 10-46 hours of experimentation but then diminish the specific dye removal after this period. This effect could be due to hydrophobins, which are surface-active proteins excreted by live fungi that may alter hydrophobicity. Additionally, the presence of adsorptive dead biomass could affect dye contact with degrading enzymes released from the live fungus. By expanding current knowledge of the interactions that take place in a fungal bioreactor and their effect on textile dye decolorization, this research aims to inspire more effective and less costly bioreactor designs for the treatment of textile wastewater.
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Date Issued: 2011
Identifier: CFH0003823, ucf:44720
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH0003823

Title: Viability of a Residential Integrated Stormwater, Graywater, and Wastewater Treatment System.
Creator: Goolsby, Matthew, Chopra, Manoj, Wanielista, Martin, Randall, Andrew, Chang, Ni-bin, University of Central Florida
Abstract / Description: The subject of water scarcity and the rate of water consumption have become popular over the last few decades. Within the topic of water consumption, there are two separate issues from a residential standpoint. The first concern is the steadily increasing need for viable alternative water sources to be utilized for non-potable applications in an effort to reduce potable water demands. The second concern is the need to significantly reduce of nutrient-laden wastewater effluent discharge from...
Show moreThe subject of water scarcity and the rate of water consumption have become popular over the last few decades. Within the topic of water consumption, there are two separate issues from a residential standpoint. The first concern is the steadily increasing need for viable alternative water sources to be utilized for non-potable applications in an effort to reduce potable water demands. The second concern is the need to significantly reduce of nutrient-laden wastewater effluent discharge from septic systems in order to sustain groundwater quality and prevent adverse ecological impacts. This study addresses both issues with two separate systems integrated into one environmentally functional home that emphasizes low impact development (LID) practices. The first objective of the study is to quantify the performance of the passive treatment Bold (&) GoldTM reactive filter bed (FDOH classified (")innovative system(")) for nutrient removal. The second objective is to monitor the water quality of the combined graywater/stormwater cistern for non-potable use and asses all components (green roof, gutters, graywater treatment, AC condensate, well water, stormwater contribution). The performance of the passive innovative system is compared to past studies and regulatory standards. Also, a bench scale model of the OSTDS is constructed at the University of Central Florida (UCF) Stormwater Management Academy Research and Testing Lab (SMART Lab) and tested to provide effluent data at two different residence times. Complex physical, biological, and chemical theories are applied to the analysis of wastewater treatment performance. The data from the OSTDS and stormwater/graywater cistern both systems are also assessed using statistical analysis. The results of the OSTDS are compared to FDOH regulatory requirements for (")Secondary Treatment Standards("), and (")Advanced Secondary Treatment Standards(") with positive results. The bench scale results verify that both biological nutrient removal and physiochemical sorption are occurring within the filter media and quantified the relationship between removal rates and hydraulic residence time (HRT).The combined graywater/stormwater cistern contains acceptable water quality and operates efficiently. The demand on the cistern results in about 50% capacity utilization of the cistern and there is a consistent dependency on the artesian well. The salinity content and high sodium adsorption ratio (SAR) of the cistern water did not produce any noticeable adverse impacts on the home other than scale formation in the toilet. The results of the research determined that the implementation of the integrated system is a viable option at the residential level.
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Date Issued: 2011
Identifier: CFE0004114, ucf:49094
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004114

Title: Application of Landfill Treatment Approaches for the Stabilization of Municipal Solid Waste.
Creator: Bolyard, Stephanie, Reinhart, Debra, Santra, Swadeshmukul, Randall, Andrew, University of Central Florida
Abstract / Description: This research focused on the fundamental requirements of stabilizing a mature landfill using three treatment approaches as well as the implications of discharging leachate organic matter (LOM) to wastewater treatment plants (WWTPs). Three treatment approaches aimed at removing releasable carbon and nitrogen from mature landfills including flushing with clean water, leachate recirculation with ex-situ chemical oxidation, and leachate recirculation with ex-situ chemical oxidation and in-situ...
Show moreThis research focused on the fundamental requirements of stabilizing a mature landfill using three treatment approaches as well as the implications of discharging leachate organic matter (LOM) to wastewater treatment plants (WWTPs). Three treatment approaches aimed at removing releasable carbon and nitrogen from mature landfills including flushing with clean water, leachate recirculation with ex-situ chemical oxidation, and leachate recirculation with ex-situ chemical oxidation and in-situ aeration were evaluated. After extensive treatment of the waste in the flushing bioreactor (FB) scenarios, the overall biodegradable fraction was reduced relative to mature waste. Leachate quality improved for all FBs but through different mechanisms. Flushing was the most effective approach at removing biodegradable components and improving leachate quality. A mass balance on carbon and nitrogen revealed that a significant fraction still remained in the waste. Solid waste and leachate samples from the anaerobic bioreactors and FBs were characterized using Fourier Transform Infrared (FTIR) to provide a better understanding of changes in waste characteristics when waste transitions from mature to stabilized. Organic functional groups associated with aliphatic methylene were present in leachate and solid waste samples during the early stages of anaerobic degradation and disappeared once these wastes underwent treatment. Once the waste was stabilized, the FTIR spectra of leachate and solid waste were dominated by inorganic functional groups (carboxylic acid/carbonate group, carbonate, quartz, and clay minerals). Leachate is commonly co-treated with domestic wastewater due to the cost and complexity of on-site treatment. The organic constituents in leachate can be problematic for WWTPs as their recalcitrant components pass through conventional treatment processes, impacting effluent quality. Twelve leachates where characterized for total nitrogen (TN) and dissolved organic nitrogen (DON). The average concentration of TN and DON in leachate was 1,160 and 40.7 mg/L, respectively. Leachates were fractionated based on hydrophobic (recalcitrant; rDON) and hydrophilic (bioavailable; bDON) properties. The average concentrations of bDON and rDON were 16.5 and 18.4 mg/L, respectively. Multiple leachate and wastewater co-treatment simulations were carried out to assess the treatment of leachate nitrogen at historic nitrogen removal levels of four WWTPs and the effects on wastewater effluent quality for four WWTPs. The effluent quality exceeded typical TN limits of 3 to 10 mg/L at leachate volumetric contributions of 10%. The maximum calculated pass through concentrations of rDON and DON at 10% volumetric contribution for the twelve leachates was 4.77 and 9.71 mg/L, respectively. The effects of LOM on wastewater effluent quality was further evaluated in the field. Results showed that leachate detection for each field study could be determined using UV254 nm absorbance. DON and dissolved organic carbon (DOC) concentrations increased at significant levels in leachate-impacted wastewater samples. The DON decreased through the treatment train, suggesting that this parameter was effectively removed, while DOC persisted. DOC pass through coincided with an increase in color and UV254 nm absorption. In effluents, the UV254 nm transmittance was just below the minimum 65% disinfection requirement at dilutions greater than 1%. Leachate-impacted wastewater showed a higher concentration of humic-like peaks during fluorescence measurements than wastewater without leachate.
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Date Issued: 2016
Identifier: CFE0006076, ucf:50959
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0006076

wastewater (6)	+ -
EBPR (2)	+ -
Wastewater (2)	+ -
Wastewater treatment (2)	+ -
B&G treatment bed (1)	+ -

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Green sorption media (1)	+ -
Humic Acid (1)	+ -
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NMR (1)	+ -
Nutrient and pathogen control (1)	+ -
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Reactive Blue 19 (1)	+ -
Reactive Orange 16 (1)	+ -
Recalcitrant Dissolved Organic Nitrogen (1)	+ -
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University of Central Florida (12)	+ -
Randall, Andrew (6)	+ -
Duranceau, Steven (3)	+ -
Reinhart, Debra (3)	+ -
Chang, Ni-Bin (2)	+ -

Lee, Woo Hyoung (2)	+ -
Sadmani, A H M Anwar (2)	+ -
Bolyard, Stephanie (1)	+ -
Chang, Ni-bin (1)	+ -
Chopra, Manoj (1)	+ -
Church, Jared (1)	+ -
Dykstra, Christine (1)	+ -
Ginart, Rachelle (1)	+ -
Goolsby, Matthew (1)	+ -
Hossain, Fahim (1)	+ -
Lettie, Lucia (1)	+ -
Magro, Daniel (1)	+ -
Rawut, Rojina (1)	+ -
Reed, Erin (1)	+ -
Rowney, Alexander (1)	+ -
Santra, Swadeshmukul (1)	+ -
Wang, Dingbao (1)	+ -
Wanielista, Martin (1)	+ -
Xuan, Zhemin (1)	+ -
malekjahani, seyed (1)	+ -

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