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- Title
- REMOVAL OF 2, 4-DINITROPHENOL BY FERRATE.
- Creator
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Cooley, Gianna, Reinhart, Debra, University of Central Florida
- Abstract / Description
-
Ferrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants...
Show moreFerrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants that contain 2, 4-Dinitrophenol (DNP). DNP is listed on the United States Environmental Protection Agency (EPA) Drinking Water Contaminant Candidate List (CCL). This list includes compounds which are not currently regulated at the national level, but there is a growing concern for the harm they may cause to the environment. Therefore, the EPA prioritizes these compounds and conducts extensive research to determine if these compounds should be regulated (USEPA, 2005). The effects of Ferrate on DNP were evaluated during these experiments. The effect of various dosages of Ferrate and different pH values was monitored over 17 minutes using UV 254 to determine the extent of oxidation of 300 mg L-1 DNP. Removal of DNP at all pHs and dosages was noted, however, a pH of 4 and a molar ratio of 14: 1 (Ferrate to DNP) removed the highest percentage of DNP at 87.3. The by-products of the 3.5 and 14: 1 molar ratio of Ferrate to DNP reactions at a pH of 4 and their toxicity were determined by measuring biochemical oxygen demand 5 day (BOD5), dissolved organic carbon (DOC), chlorine residual and chemical oxygen demand (COD), and gas chromatography/mass spectrometry (GC/MS) analysis. The BOD5 indicated toxicity, either from the residual chlorine or the organisms used for seeding not being acclimated to DNP and by-products. DOC of the 3.5 : 1 molar ratio was higher than calculated values indicating more ring breakage than was originally measured by UV 254. DOC of the 14: 1 molar ratio experiment was lower than calculated values, which indicated human error in measuring the DNP concentration. The chlorine residual was high for both experiments, 112 and 594 mg L-1, for the 3.5 and 14: 1 molar ratios, respectively. COD was unable to be measured due to chloride interference. The GC/MS data showed several chlorine-substituted benzene rings as well as carbon tetrachloride for the 3.5:1 molar ratio DNP experiments. The 14:1 GC/MS data indicated much more ring breakage with carbon tetrachloride, a substituted butane chain, many unknown straight chain chlorinated compounds and dichloro-pentane isomers as by-products.
Show less - Date Issued
- 2008
- Identifier
- CFE0002438, ucf:47722
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002438
- Title
- DEWATERING OF BIOSOLIDS BY SODIUM FERRATE.
- Creator
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Rios, Andrea, Reinhart, Debra, University of Central Florida
- Abstract / Description
-
This study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge...
Show moreThis study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge after conditioning were used. For centrifugation the volume reduction and the turbidity of the supernatant after centrifugation were evaluated. For filtration, the Capillary Suction Time test was used. The optimum doses and conditions for dewatering of the sludge using ferrate were determined for each type of sludge. The centrifugation and filtration results were compared with those obtained for polymer doses currently used at the wastewater treatment plants where the samples were collected and with ferric coagulants as well. The results of this research indicated that optimum pH was 7.0. The time required to achieve mechanical equilibrium defined as the time at which the volume occupied by the solids was no more than one percent of the preceding reading was 1800 seconds for both types of sludge. The optimum rotational speeds were 800 and 2400 for waste activated sludge and anaerobic digested sludge, respectively. The optimum ferrate dose for anaerobic digested sludge for centrifugation and filtration was 5000 mg/l. For waste activated sludge a dose of 10 mg/l was found to be effective for filtration and centrifugation. The results indicated that the ferrate product prepared using calcium hypochlorite provides better results for the waste activated sludge than the ferrate prepared using sodium hypochlorite, while for anaerobic digested sludge no significant difference was observed. Finally, the results show that ferrate is a cost-effective alternative for the conditioning and disinfection of waste activated sludge, but not for the conditioning of anaerobic digested sludge.
Show less - Date Issued
- 2004
- Identifier
- CFE0000276, ucf:46235
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0000276
- Title
- EFFECTIVENESS AND KINETICS OF FERRATE AS ADISINFECTANT FOR BALLAST WATER.
- Creator
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Jessen, Andrea, Randall, Andrew, University of Central Florida
- Abstract / Description
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The introduction of aquatic nuisance species (ANS) and bacterial pathogens from discharge of ballast water by sea-faring vessels is an ongoing problem that threatens ecosystems and human health. This study investigates the disinfecting capability of ferrate in a marine environment on several organisms listed in international standards for ballast water management. Organisms were grown in a saline solution and were treated with dosages of ferrate ranging from 0.25-5.0 mg/l. A ferrate dose of 5...
Show moreThe introduction of aquatic nuisance species (ANS) and bacterial pathogens from discharge of ballast water by sea-faring vessels is an ongoing problem that threatens ecosystems and human health. This study investigates the disinfecting capability of ferrate in a marine environment on several organisms listed in international standards for ballast water management. Organisms were grown in a saline solution and were treated with dosages of ferrate ranging from 0.25-5.0 mg/l. A ferrate dose of 5 mg/l resulted in almost complete kill for all organisms tested. Smaller dosages have also been very effective, particularly if all organic material from the nutrient broth used to cultivate them is removed by washing the cells with saline solution. Ferrate appears to act very quickly, with tailing occurring after about 5-15 minutes. Analyses of the data with the CT approach, the Chick-Watson and Hom's models, and an oxidant demand equation derived from equations recommended by the Water Environment Federation (WEF) are in good agreement that ferrate concentration is more important than contact time. The Hom's model appeared to most accurately represent the action of ferrate on these organisms. Salinity and pH did not adversely affect results, and regrowth was not a problem. Two measures to reduce clumping did not eliminate the observed tailing effect, suggesting a different mechanism for this phenomena. These preliminary tests indicate that ferrate could be a very effective disinfectant in the treatment of ballast water, and the short half-life of ferrate is an advantage, since the ballast water is subsequently released into the environment.
Show less - Date Issued
- 2006
- Identifier
- CFE0001287, ucf:46891
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001287
- Title
- COMPARISON OF THM FORMATION DURING DISINFECTION: FERRATE VERSUS FREE CHLORINE FOR DIFFERENT SOURCE WATERS.
- Creator
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Mukattash, Adhem, Randall, Andrew, University of Central Florida
- Abstract / Description
-
The objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition...
Show moreThe objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition samples were tested for Total Coliform Escherichia coli (TC/E.coli), and heterotrophic bacteria using HPC by spreadplating on R2A agar. Dissolved organic carbon (DOC) was measured as well. Dosages of 2, 5, and 10 ppm of hypochlorite and ferrate were used for Lake Claire and Atlantic Ocean water, while 1, 2, and 5 ppm dosages were used for wastewater treatment effluent. Ferrate resulted in 48.3% ± 11.2% less THM produced for the same level of disinfection (i.e. approximately 3 logs reduction in HPC). Oxidation of DOC was relatively small with a 6.1 to 11.6 % decrease in DOC being observed for ferrate doses from 2 to 10 mg/L. Free chlorine oxidation of DOC was negligible.
Show less - Date Issued
- 2007
- Identifier
- CFE0001734, ucf:47324
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001734
- Title
- COMPARISON OF THE EFFECTIVENESS OF ALTERNATIVE FERRATE (VI) SYNTHESIS FORMULAS AS DISINFECTANTS FOR WASTEWATER AND RIVER WATER.
- Creator
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Ginart, Rachelle, Reinhart, Debra, University of Central Florida
- Abstract / Description
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Ferrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of...
Show moreFerrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of hypochlorite (Low Chlorine Formula) while the other ferrate (VI) synthesis formula uses more than the stoichiometric requirement of hypochlorite (Standard Chlorine Formula). For applications requiring low chlorine residual effluent quality, the Low Chlorine Formula intuitively is a more suitable disinfectant than the Standard Formula. For applications where chlorine residual is of little or no significance, the Standard Formula is logically a more suitable disinfectant due to lower production cost and production of higher ferrate (VI) concentrations than the Low Chlorine Formula. The total chlorine concentration, unfiltered and filtered ferrate (VI) concentration, and dissolved organic carbon concentration before and after treatment using both ferrate (VI) formulas in wastewater and Econ River water was measured at a contact time of 30 minutes. Disinfection capabilities were measured by comparing the quantity of Heterotrophic bacteria, Total Coliform, Escherichia coli, and Enterococcus bacteria pre-ferrate (VI) to post-ferrate (VI) at dosages of 2, 4, and 7.5 mg/L as ferrate (VI) using both ferrate (VI) formulas. The rate of disappearance of both ferrate (VI) formulas in wastewater at an unadjusted pH and pH of 6.0-6.35 was determined. In addition the total oxidant absorbance and total chlorine concentration were measured over a 30-minute period. Both ferrate (VI) formulas were effective at inactivating Total Coliform, E. Coli, Enterococcus, and heterotrophic bacteria at a 30-minute contact time and lowering DOC concentrations in Econlockhatchee River water and secondary wastewater. The Standard Formula demonstrated better disinfection at lower dosages than the Low Chlorine Formula. In both ferrate (VI) formulas, there was a presence of an instantaneous demand of ferrate (VI) and a first-order reaction rate of ferrate (VI) over 30 minutes. The chlorine residual of 7.5 mg/L ferrate (VI) dose in wastewater at a 30-minute contact time was 0.2 to 0.6 mg/L Cl2 for the Low Chlorine Formula and 0.8 to 1.4 mg/L Cl2 for the Standard Formula. These experiments indicate that both ferrate (VI) formulas can serve as effective environmentally friendly disinfectants for wastewater and Econ River water.
Show less - Date Issued
- 2008
- Identifier
- CFE0002284, ucf:47843
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002284
- Title
- REMOVAL OF REFRACTORY TKN FROM AN EFFLUENT WASTEWATER USING SODIUM FERRATE.
- Creator
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Lettie, Lucia, Reinhart, Debra, University of Central Florida
- Abstract / Description
-
This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent...
Show moreThis research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated with doses of ferrate ranging from 1 to 50 mg/L as FeO4–2 under unbuffered conditions. TKN removal as high as 70% and COD removal greater than 55% was observed. The TSS production after ferrate treatment was in a range of 12 to 200 mg/L for doses between 10 and 50 mg/L FeO4-2. After an optimum dose of ferrate was determined, three bench-scale reactors were operated under anoxic conditions for 10 to 12 days, two as duplicates containing the treated effluent and one as a control with untreated sample. Two different doses of ferrate were used as optimum dose for these experiments, 10 and 25 mg/L as FeO4-2. The purpose of these reactors was to determine the potential for biological removal of remaining nitrogen after ferrate oxidation of refractory nitrogen. Treated and raw samples were analyzed for Total Kjeldahl Nitrogen (TKN) (filtered and unfiltered), chemical oxygen demand (COD) (filtered and unfiltered), total suspended solids (TSS), nitrate (NO3-N), nitrite (NO2-N), and heterotrophic plate count (HPC). As a result, more than 70% of the soluble TKN was removed by chemical and biological oxidation for a sample treated with a dose of 25 mg/L FeO4-2, and less than 50% when treated with 10 mg/L FeO4-2. For the control samples run parallel to the ferrate treated samples, a maximum of 48% of soluble TKN and a minimum of 12% was removed. A three-log increase was observed in heterotrophic bacteria numbers for both doses during the operation of the reactors. Sodium ferrate was found to be an effective oxidant that can enhance the biodegradability of recalcitrant TKN present in municipal wastewaters. As mentioned before this research was develop using batch reactor units at bench-scale, therefore it is recommended to follow the investigation of the biodegradability of recalcitrant TKN of a ferrate treated sample under continuous flow conditions so that results can be extrapolated to a full-scale treatment facility.
Show less - Date Issued
- 2006
- Identifier
- CFE0001247, ucf:46936
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001247
- Title
- CHEMICAL AND BIOLOGICAL TREATMENT OF MATURE LANDFILLLEACHATE.
- Creator
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Batarseh, Eyad, Reinhart, Debra, University of Central Florida
- Abstract / Description
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This dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells....
Show moreThis dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells. Results from this research demonstrated that ferrate and Fenton's reagent had similar optimum pH ranges (3-5), but different organic removal capacities, ranging from 54 to 79 % of initial leachate organic contents. An advantage of ferrate was that it was relatively effective over a wide pH range (Fenton's reagent lost its reactivity outside optimum pH range). Advantages associated with Fenton's reagent include a higher organic removal capacity, production of more oxidized organic compounds (measured as chemical oxygen demand/dissolved organic carbon), and production of more biodegradable byproducts (measured as 5-day biochemical oxygen demand/chemical oxygen demand). Finally, both treatments were found to oxidize larger molecules (>1000 dalton) and produce smaller molecules, as indicated by an increase in smaller molecule contribution to organic carbon. In part two, effects of Fenton's reagent treatment on biodegradability of three landfill leachates collected from a Florida landfill were evaluated using biochemical oxygen demand (BOD), biochemical methane potential (BMP), and tertamethylammonium hydroxide (TMAH) thermochemolysis gas chromatography/mass spectrometry (GC/MS). The hypothesis was that Fenton's reagent will remove refractory compounds that inhibit biodegradation and will produce smaller, more biodegradable organic molecules which will result in an increase in BOD and BMP values. Both BOD and BMP results demonstrated that Fenton's reagent treatment did not convert mature leachate to biodegradable leachate, as indicated by a low BOD5 expressed as C /dissolved organic carbon (DOC) ratio of almost 0.15 in treated samples and a low net methane production / theoretical methane potential (less than 0.15). Ultimate BOD only slightly increased. However the first-order BOD reaction rate increased by more than five fold, suggesting that Fenton's reagent removed refractory and inhibitory compounds. BMP results demonstrated that the ratio of CO2/CH4 produced during anaerobic biodegradation did not increase in treated leachate (compared to untreated), indicating that small biodegradable organic acids produced by oxidation were removed by coagulation promoted by Fenton's reagent. Finally, the TMAH thermochemolysis results showed that several of the refractory and inhibitory compounds were detected fewer times in treated samples and that carboxylic acids did not appear in treated samples. In the third part of this dissertation the application of flushing/Fenton's reagent oxidation to produce sustainable solid waste cells was evaluated. A treatment similar to pump and treat process utilizing Fenton's reagent on-site treated leachate combined with in-situ aeration was proposed. Treated leachate would be recycled to the landfill cell flushes releasable nonbiodegradable carbon from the cell and oxidizes it externally. This technique was demonstrated to have treatment cost and time benefits over other alternatives for producing completely stable solid waste cells such as anaerobic flushing and biological and/or mechanical pretreatment of solid waste (used in the EU).
Show less - Date Issued
- 2006
- Identifier
- CFE0001276, ucf:46912
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001276
- Title
- EVALUATION OF OXIDIZED MEDIA FILTRATION PROCESSES FOR THE TREATMENT OF HYDROGEN SULFIDE IN GROUNDWATER.
- Creator
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Trupiano, Vito, Duranceau, Steven, University of Central Florida
- Abstract / Description
-
This study evaluated alternative sulfide treatment processes for potable water systems that rely on groundwater supplies. Research for this study was conducted at the Imperial Lakes (IL) and Turner Road (TR) water treatment plants (WTPs) in Polk County, Florida. These WTPs are in the process of refurbishment and expansion, and will require the installation of a new groundwater well. The IL and TR WTPs both rely upon groundwater sources that contain total sulfide at concentrations ranging from...
Show moreThis study evaluated alternative sulfide treatment processes for potable water systems that rely on groundwater supplies. Research for this study was conducted at the Imperial Lakes (IL) and Turner Road (TR) water treatment plants (WTPs) in Polk County, Florida. These WTPs are in the process of refurbishment and expansion, and will require the installation of a new groundwater well. The IL and TR WTPs both rely upon groundwater sources that contain total sulfide at concentrations ranging from 1.4 to 2.6 mg/L. Sulfide is a concern because if left untreated it can impact finished water quality, corrosivity, create undesirable taste and odor, and oxidize to form visible turbidity. For this reason, the raw water will require treatment per Florida Department of Environmental Protection (FDEP) "Sulfide Rule" 62-555.315(5)(a). This rule does not allow the use of conventional tray aeration (currently in use at the IL and TR WTPs) for wells that have significant total sulfide content (0.6 to 3.0 mg/L). This research was commissioned because the potential water treatment method identified in the Sulfide Rule (i.e. forced-draft aeration) would not adequately fit within the confines of the existing sites and would pose undue burden to neighboring residents. In addition, an effective sulfide treatment process was desired that offered a low profile, did not necessitate the need for additional complex chemical feed systems, minimized the extent of electrical infrastructure upgrades, and was inexpensive to construct and operate. To meet these goals, several alternative technologies were evaluated at the desktop and bench-scale; these included anion exchange, various oxidation methods, and alternative media filtration processes. From that effort, several processes were selected for evaluation at the pilot scale: bleach (NaOCl) oxidation preceding electromedia filtration; manganese (IV) oxide (MnO2) filtration continuously regenerated with bleach; and ferrate (Fe(VI)) oxidation. Electromedia and MnO2 filtration were shown to be effective for total sulfide treatment. Both processes reduced total sulfide content to below detection levels (< 0.1 mg/L) for groundwater supplies containing as much as 2.6 mg/L of total sulfide. The use of bleach oxidation ahead of media filtration also produced finished water with low turbidity (< 1.0 NTU) as compared to conventional tray aeration and chlorination processes (6-16 NTU, as observed in this study). It was determined that the media filtration approach (electromedia and MnO2) was effective for sulfide treatment and met the County's site objectives established at the outset of the project. Ferrate was also shown to reduce total sulfide content to below detection levels (< 0.1 mg/L) for groundwater supplies containing as much as 2.6 mg/L of total sulfide. An opinion of probable capital costs for installing a sulfide oxidation/filtration process at either the Imperial Lakes or Turner Road WTP was estimated to range from roughly $830,000 to $1,100,000. That equates to a $/kgal capital cost of $0.10 to $0.32 (at 8% for 20 years). An opinion of annual probable bleach chemical costs was estimated to range from $3,500 to $9,800 for the IL WTP and $3,500 to $5,800 for the TR WTP.
Show less - Date Issued
- 2010
- Identifier
- CFE0003370, ucf:48432
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003370
