Current Search: Lattice Strain (x)
View All Items
- Title
- INVESTIGATION OF THERMAL, ELASTIC AND LOAD-BIASED TRANSFORMATION STRAINS IN NITI SHAPE MEMORY ALLOYS.
- Creator
-
Qiu, Shipeng, Vaidyanathan, Raj, University of Central Florida
- Abstract / Description
-
Polycrystalline NiTi shape memory alloys have the ability to recover their original, pre-deformed shape in the presence of external loads when heated through a solid-solid phase transformation from a lower-symmetry B19' martensite phase to a higher-symmetry B2 austenite phase. The strain associated with a shape memory alloy in an actuator application typically has thermal, elastic and inelastic contributions. The objective of this work was to investigate the aforementioned strains by...
Show morePolycrystalline NiTi shape memory alloys have the ability to recover their original, pre-deformed shape in the presence of external loads when heated through a solid-solid phase transformation from a lower-symmetry B19' martensite phase to a higher-symmetry B2 austenite phase. The strain associated with a shape memory alloy in an actuator application typically has thermal, elastic and inelastic contributions. The objective of this work was to investigate the aforementioned strains by recourse to in situ neutron diffraction experiments during selected combinations of heating, cooling and/or mechanical loading. The primary studies were conducted on polycrystalline Ni49.9Ti50.1 specimens on the Spectrometer for MAterials Research at Temperature and Stress (SMARTS) at Los Alamos National Laboratory. Quantitative information on the phase-specific strain, texture and phase fraction evolution was obtained from the neutron data using Rietveld refinement and single-peak analyses, and compared with macroscopic data from extensometry. First, the lattice strain evolution during heating and cooling in an unloaded sample (i.e., free-recovery experiment) was studied. The lattice strain evolution remained linear with temperature and was not influenced by intergranular stresses, enabling the determination of a thermal expansion tensor that quantified the associated anisotropy due to the symmetry of B19' NiTi. The tensor thus determined was subsequently used to obtain an average coefficient of thermal expansion that was consistent with macroscopic dilatometric measurements and a 30,000 grain polycrystalline self-consistent model. The accommodative nature of B19' NiTi was found to account for macroscopic shape changes lagging (with temperature) the start and finish of the transformation. Second, the elastic response of B19' martensitic NiTi variants during monotonic loading was studied. Emphasis was placed on capturing and quantifying the strain anisotropy which arises from the symmetry of monoclinic martensite and internal stresses resulting from intergranular constraints between individual variants and load re-distribution among variants as the texture evolved during variant reorientation and detwinning. The methodology adopted took into account both tensile and compressive loading given the asymmetric response in the texture evolution. Plane specific elastic moduli were determined from neutron measurements and compared with those determined using a self-consistent polycrystalline deformation model and from recently reported elastic stiffness constants determined via ab initio calculations. The comparison among the three approaches further helped understand the influence of elastic anisotropy, intergranular constraint, and texture evolution on the deformation behavior of polycrystalline B19' NiTi. Connections were additionally made between the assessed elastic properties of martensitic NiTi single crystals (i.e., the single crystal stiffness tensor) and the overall macroscopic response in bulk polycrystalline form. Lastly, the role of upper-cycle temperature, i.e., the maximum temperature reached during thermal cycling, was investigated during load-biased thermal cycling of NiTi shape memory alloys at selected combinations of stress and temperature. Results showed that the upper-cycle temperature, under isobaric conditions, significantly affected the amount of transformation strain and thus the work output available for actuation. With the objective of investigating the underlying microstructural and micromechanical changes due to the influence of the upper-cycle temperature, the texture evolution was systematically analyzed. While the changes in transformation strain were closely related to the evolution in texture of the room temperature martensite, retained martensite in the austenite state could additionally affect the transformation strain. Additionally, multiple thermal cycles were performed under load-biased conditions in both NiTi and NiTiPd alloys, to further assess and understand the role of retained martensite. Dimensional and thermal stabilities of these alloys were correlated with the volume fraction and texture of retained martensite, and the internal strain evolution in these alloys. The role of symmetry, i.e., B19' monoclinic martensite vs. B19 orthorhombic martensite in these alloys was also assessed. This work not only established a methodology to study the thermal and elastic properties of the low symmetry B19' monoclinic martensite, but also provided valuable insight into quantitative micromechanical and microstructural changes responsible for the thermomechanical response of NiTi shape memory alloys. It has immediate implications for optimizing shape memory behavior in the alloys investigated, with extension to high temperature shape memory alloys with ternary and quaternary elemental additions, such as Pd, Pt and Hf. This work was supported by funding from NASAÃÂ's Fundamental Aeronautics Program, Supersonics Project (NNX08AB51A) and NSF (CAREER DMR-0239512). It benefited additionally from the use of the Lujan Neutron Scattering Center at Los Alamos National Laboratory, which is funded by the Office of Basic Energy Sciences (Department of Energy) and is operated by Los Alamos National Security LLC under DOE Contract DE-AC52-06NA25396.
Show less - Date Issued
- 2010
- Identifier
- CFE0003362, ucf:48440
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003362
- Title
- INVESTIGATION OF PS-PVD AND EB-PVD THERMAL BARRIER COATINGS OVER LIFETIME USING SYNCHROTRON X-RAY DIFFRACTION.
- Creator
-
Northam, Matthew, Raghavan, Seetha, Ghosh, Ranajay, Vaidyanathan, Raj, University of Central Florida
- Abstract / Description
-
Extreme operating temperatures within the turbine section of jet engines require sophisticated methods of cooling and material protection. Thermal barrier coatings (TBCs) achieve this through a ceramic coating applied to a substrate material (nickel-based superalloy). Electron-beam physical vapor deposition (EB-PVD) is the industry standard coating used on jet engines. By tailoring the microstructure of an emerging deposition method, Plasma-spray physical vapor deposition (PS-PVD), similar...
Show moreExtreme operating temperatures within the turbine section of jet engines require sophisticated methods of cooling and material protection. Thermal barrier coatings (TBCs) achieve this through a ceramic coating applied to a substrate material (nickel-based superalloy). Electron-beam physical vapor deposition (EB-PVD) is the industry standard coating used on jet engines. By tailoring the microstructure of an emerging deposition method, Plasma-spray physical vapor deposition (PS-PVD), similar microstructures to that of EB-PVD coatings can be fabricated, allowing the benefits of strain tolerance to be obtained while improving coating deposition times. This work investigates the strain through depth of uncycled and cycled samples using these coating techniques with synchrotron X-ray diffraction (XRD). In the TGO, room temperature XRD measurements indicated samples of both deposition methods showed similar in-plane compressive stresses after 300 and 600 thermal cycles. In-situ XRD measurements indicated similar high-temperature in-plane and out-of-plane stress in the TGO and no spallation after 600 thermal cycles for both coatings. Tensile in-plane residual stresses were found in the YSZ uncycled PS-PVD samples, similar to APS coatings. PS-PVD samples showed in most cases, higher compressive residual in-plane stress at the YSZ/TGO interface. These results provide valuable insight for optimizing the PS-PVD processing parameters to obtain strain compliance similar to that of EB-PVD. Additionally, external cooling methods used for thermal management in jet engine turbines were investigated. In this work, an additively manufactured lattice structure providing transpiration cooling holes is designed and residual strains are measured within an AM transpiration cooling sample using XRD. Strains within the lattice structure were found to have greater variation than that of the AM solid wall. These results provide valuable insight into the viability of implementing an AM lattice structure in turbine blades for the use of transpiration cooling.
Show less - Date Issued
- 2019
- Identifier
- CFE0007844, ucf:52830
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007844