Current Search:  Mechanical Behavior. (x)

View All Items

  • CSV Spreadsheet
(1 - 3 of 3)
High Volume Fraction Mg-based Nanocomposites: Processing, Microstructure and Mechanical Behavior
Title
High Volume Fraction Mg-based Nanocomposites: Processing, Microstructure and Mechanical Behavior.
Creator
Liu, Jinling, An, Linan, Suryanarayana, Challapalli, Fang, Jiyu, Bai, Yuanli, Lin, Kuo-Chi, University of Central Florida
Abstract / Description
Mg-based metal matrix nanocomposites (MMNCs) with mechanical properties, superior to those of coarse-grained composites, are promising structural materials for applications in the automotive and aerospace industries. The research in this area was primarily focused earlier on either micro-scaled reinforcements or nano-scaled reinforcements with very low volume fractions. MMNCs with high volume fractions have not been explored yet. In this research, we study the processing, microstructures and...
Show moreMg-based metal matrix nanocomposites (MMNCs) with mechanical properties, superior to those of coarse-grained composites, are promising structural materials for applications in the automotive and aerospace industries. The research in this area was primarily focused earlier on either micro-scaled reinforcements or nano-scaled reinforcements with very low volume fractions. MMNCs with high volume fractions have not been explored yet. In this research, we study the processing, microstructures and properties of MMNCs containing ceramic nanoparticles up to 30 vol.%.We first investigated the mechanical alloying of Al2O3 nanoparticles and pure Mg under high-energy ball milling conditions. The phase evolution and their distribution were evaluated as a function of milling time. Then, the thermal stability of the formed nanocomposites was investigated by annealing it at high temperatures. It indicated that an exchange reaction had occurred to a large extent between Mg and Al2O3 resulting in the formation of Al and MgO phases. Additionally, the reaction between Al and un-reacted Mg led to the formation of Mg-Al intermetallics.Due to the reaction between Mg and Al2O3 during the milling and annealing process, we attempted to synthesize Mg/SiC nanocomposites. The mixed powders containing 0, 5, 10 and 15 vol.% SiC were produced by high energy ball milling and then the powders were consolidated via spark plasma sintering. The phase constitutions and microstructures of the Mg/SiC nanocomposites were characterized. SiC nanoparticles (average particle size ~14 nm) appear to be homogeneously dispersed within the matrix, and the average inter-particle spacings of all the Mg/SiC nanocomposites were smaller than 50 nm. Microscopic methods, even at high magnifications did not reveal any significant porosity in the as-processed MMNCs.Mechanical characterization of the Mg/SiC nanocomposites was conducted using the microindentation test. Besides the microhardness test, different intermediate pause times and loading rates were used to evaluate the stiffness and loading rate sensitivity of our samples. The abnormal microhardness and loading rate sensitivity were showed for the Mg-15 vol.% SiC samples. At the same time, the monotonic increase of stiffness with volume fraction was exhibited in the Mg/SiC nanocomposites.Finally, we investigated the quasi-static and dynamic response of Mg/SiC nanocomposites and microcomposites, and discussed the underlying mechanisms. Strain softening was noticed in the milled Mg sample under quasi-static compression. Similarly, the strengthening effect leveling off was also observed in the Mg-15 vol.% SiC samples under either quasi-static or high-strain rate uniaxial compression conditions. No significant plastic deformation was observed in the Mg/SiC nanocomposites. The estimated strain rate sensitivity of all the Mg/SiC nanocomposites in this work was around 0.03, which is much smaller than 0.3 and 0.6, observed for 100 nm and 45 nm grain size pure Mg individually. In particular, the existing models fail in predicting the inverse volume fraction effect, and other mechanisms are yet to be explored. The presence of SiC nanoparticles may play an important role that leads to this difference.
Show less
Date Issued
2013
Identifier
CFE0004879, ucf:49672
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0004879
POLYMER-DERIVED CERAMICS: ELECTRONIC PROPERTIES AND APPLICATION
Title
POLYMER-DERIVED CERAMICS: ELECTRONIC PROPERTIES AND APPLICATION.
Creator
xu, weixing, An, Linan, University of Central Florida
Abstract / Description
In this work, we studied the electronic behavior of polymer-derived ceramics (PDCs) and applied them for the synthesis of carbon nanotube reinforced ceramic nanocomposites and ceramic MEMS (Micro-Electro-Mechanical Systems) structures. Polymer-derived SiCN ceramics were synthesized by pyrolysis of a liquid polyureasilazane with dicumyl peroxide as thermal initiator. The structural evolution during pyrolysis and post-annealing was studied using FTIR, solid state NMR and Raman. The results...
Show moreIn this work, we studied the electronic behavior of polymer-derived ceramics (PDCs) and applied them for the synthesis of carbon nanotube reinforced ceramic nanocomposites and ceramic MEMS (Micro-Electro-Mechanical Systems) structures. Polymer-derived SiCN ceramics were synthesized by pyrolysis of a liquid polyureasilazane with dicumyl peroxide as thermal initiator. The structural evolution during pyrolysis and post-annealing was studied using FTIR, solid state NMR and Raman. The results revealed that the resultant ceramics consisted of SiCxNx-4 as major building units. These units were connected with each other through C-C/C=C bonds or by shearing N/C. The amount of sp2 free carbon strongly depends on composition and processing condition. Electron paramagnetic resonance (EPR) was used to investigate electronic structure of PDCs; the results revealed that the materials contain unpaired electron centers associated with carbons. Electronic behavior of the SiCN ceramics was studied by measuring their I-V curves, temperature dependence of d.c.-conductivities and impendence. The results revealed that the SiCN ceramics exhibited typical amorphous semiconductor behavior, and their conductivity varied in a large range. The results also revealed that the materials contain more than one phase, which have the different electronic behavior. We explored possibility of using polymer-derived ceramics to make ceramic MEMS for harsh environmental applications with a lithography technique. The cure depth of the polymer precursor was measured as a function of UV intensity and exposure time. The experimental data was compared with the available theoretical model. A few typical SiCN parts were fabricated by lithography technique. We also prepared carbon nanotube reinforced ceramic nanocomposites by using PDC processing. The microstructures of the composites were characterized using SEM and TEM; the mechanical properties were studied characterized using nanoindentation. The significant improvement in mechanical properties was observed for the nanocomposites.
Show less
Date Issued
2006
Identifier
CFE0001228, ucf:46885
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0001228
Mechanical Study on Edge-Oxidized Graphene Oxide (EOGO) Reinforced Concrete
Title
Mechanical Study on Edge-Oxidized Graphene Oxide (EOGO) Reinforced Concrete.
Creator
Khawaji, Mohammad, Nam, Boo Hyun, Chopra, Manoj, Zaurin, Ricardo, Kwok, Kawai, University of Central Florida
Abstract / Description
It is known that graphene oxide (GO) has superior mechanical properties and can enhance mechanical properties of cement composites. However, Hummer produced conventional GOs have been limited to small-scale specimens (e.g., cement paste and mortar) and applications to concrete have not been implemented due to their high cost and large volume of concrete. Edge-oxidized graphene oxide (EOGO) is a low-cost, carbon-based nanomaterial produced by a mechanochemical process with ball milling and a...
Show moreIt is known that graphene oxide (GO) has superior mechanical properties and can enhance mechanical properties of cement composites. However, Hummer produced conventional GOs have been limited to small-scale specimens (e.g., cement paste and mortar) and applications to concrete have not been implemented due to their high cost and large volume of concrete. Edge-oxidized graphene oxide (EOGO) is a low-cost, carbon-based nanomaterial produced by a mechanochemical process with ball milling and a non-toxic oxidizing agent. The low cost (less than $50/kg) of EOGO enables its use in bulk-scale concrete materials/structures, which is a prerequisite for the field implementation. In this study, EOGO was applied to macroscopic concrete to investigate mechanical and workability performance of EOGO reinforced concrete. Interestingly, it was observed that the addition of EOGO to normal concrete increases concrete slump, which opposes the conventional GO study on cement paste. To maximize the benefits of the improved workability, EOGO was then applied to fiber reinforced concretes (FRCs) to compensate their low workability. Two different types of fibers were used, including basalt and steel fibers. The results indicated that EOGO is not effective in basalt fiber reinforced concrete (BFRC) perhaps due to the high absorption of basalt fibers. However, adding EOGO to steel fiber reinforced concrete (SFRC) exhibited significant enhancement in workability and strength compared with control specimens. Subsequently, the effect of EOGO on flexural fatigue behavior of cement composite mixtures (cement mortar and concrete) was investigated. The flexural fatigue results show that adding EOGO to cement composites enhances flexural fatigue performance. Lastly, the impact of EOGO on pavement structure was investigated based on Mechanistic-Empirical Design Guide (MEPDG). The results show EOGO significantly extends service life and minimizes the required thickness of surface layer.
Show less
Date Issued
2019
Identifier
CFE0007826, ucf:52821
Format
Document (PDF)
PURL
http://purl.flvc.org/ucf/fd/CFE0007826