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Title: Brains behind barbed wire.
Creator: Bund Proletarisch Revolutionärer Schriftsteller Deutschlands, Klein, Herbert Arthur
Date Issued: 1934
Identifier: 369419, CFDT369419, ucf:5442
Format: Document (PDF)
PURL: http://purl.flvc.org/FCLA/DT/369419

Title: CONCENTRATION AND VELOCITY FIELDSTHROUGHOUT THE FLOW FIELD OF SWIRLING FLOWS IN GAS TURBINE MIXERS.
Creator: Turek, Louis James, Chen, Ruey-Hung, University of Central Florida
Abstract / Description: Air velocity and fuel concentration data have been collected throughout the flow fields of two gas turbine mixers in an effort to better understand the mixing of fuel and air in gas turbine mixers. The two gas turbine mixers consisted of an annular flow profile and incorporated swirl vanes to produce a swirling flow to promote fuel/air mixing. The fuel was injected into the bulk flow from the pressure side of the swirl vanes. The first mixer had a swirl angle of 45o, while the second had a...
Show moreAir velocity and fuel concentration data have been collected throughout the flow fields of two gas turbine mixers in an effort to better understand the mixing of fuel and air in gas turbine mixers. The two gas turbine mixers consisted of an annular flow profile and incorporated swirl vanes to produce a swirling flow to promote fuel/air mixing. The fuel was injected into the bulk flow from the pressure side of the swirl vanes. The first mixer had a swirl angle of 45o, while the second had a swirl angle of 55o. In order to examine the effect of the swirl angle on the mixing of fuel and air as the flow progressed through gas turbine mixers, axial and tangential air velocity data was taken using a laser Doppler velocimeter (LDV). Also, fuel concentration data was taken separately using a hydrocarbon concentration probe with methane diluted with air as the fuel. The data were taken at varying axial and varying angular locations in an effort to capture the spatial development of the fuel and velocity profiles. The spectra of the data were analyzed as well in an effort to understand the turbulence of the flow. It was found that the 55o swirler exhibited smaller variations in both velocity and fuel concentration values and that the fuel reached a uniform concentration at axial locations further upstream in the 55o degree mixer than in the 45o mixer. The RMS values of the velocity, which were influenced by the swirl vanes, were higher in the 55o mixer and likely contributed to the better mixing performance of the 55o mixer. The fuel concentration spectrum data showed that the spectra of the two mixers were similar, and that the fluctuations in fuel concentration due to flow emanating from the swirl vanes were seen throughout the length of the two mixers.
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Date Issued: 2004
Identifier: CFE0000078, ucf:46098
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000078

Title: OWNERSHIP DIVERSITY WITHIN THE MEDIA INDUSTRY: TRENDS AND CURRENT CONDITIONS.
Creator: Vizcarrondo, Thomas E, Costain, Gene, University of Central Florida
Abstract / Description: This study seeks to determine if media ownership diversity remains at levels widely considered to be competitive and acceptable, despite consolidation within the media industry. The research augments the many studies analyzing programming diversity within the U. S. media industry. Rather than analyzing programming content, this study addresses ownership diversity by examining the diversity of media ownership within the context U. S. model, considered to be more of a decentralized, market...
Show moreThis study seeks to determine if media ownership diversity remains at levels widely considered to be competitive and acceptable, despite consolidation within the media industry. The research augments the many studies analyzing programming diversity within the U. S. media industry. Rather than analyzing programming content, this study addresses ownership diversity by examining the diversity of media ownership within the context U. S. model, considered to be more of a decentralized, market-driven media industry when compared to other countries such as the United Kingdom or Canada. To measure diversity, the Herfindahl-Hirschman Index (HHI)--a measure of economic diversity widely used by economists as well as government regulatory agencies--is used. Suggestions are presented for the future of media and regulation to insure a competitive, diverse, and healthy media industry.
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Date Issued: 2004
Identifier: CFE0000122, ucf:46189
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000122

Title: CERIUM OXIDE NANOPARTICLES FOR THE DETECTION OF ANTIMICROBIAL RESISTANCE.
Creator: Noll, Alexander, Perez, J. Manuel, University of Central Florida
Abstract / Description: The rise of antimicrobial resistance demands the development of more rapid screening methods for the detection of antimicrobial resistance in clinical samples to both give the patient the proper treatment and expedite the treatment of patients. Cerium oxide nanoparticles may serve a useful role in diagnostics due to their ability to exist in a mixed valence state and act as either oxidizing agents or reducing agents. Considering that cerium oxide nanoparticles have been shown to shift in...
Show moreThe rise of antimicrobial resistance demands the development of more rapid screening methods for the detection of antimicrobial resistance in clinical samples to both give the patient the proper treatment and expedite the treatment of patients. Cerium oxide nanoparticles may serve a useful role in diagnostics due to their ability to exist in a mixed valence state and act as either oxidizing agents or reducing agents. Considering that cerium oxide nanoparticles have been shown to shift in absorbance upon oxidation, a useful method of antimicrobial resistance detection could be based on the oxidation of cerium oxide nanoparticles. Herein, an assay is described whereby cerium oxide nanoparticle oxidation is a function of glucose metabolism of bacterial samples in the presence of an antimicrobial agent. Cerium oxide nanoparticles were shown to have an absorbance in the range of 395nm upon oxidation by hydrogen peroxide whereas mixed valence cerium oxide nanoparticles lacked an absorbance around 395nm. In the presence the hydrogen peroxide-producing glucose oxidase and either increasing concentrations of glucose or bacterial medium supplemented with increasing concentrations of glucose, cerium oxide nanoparticles were shown to increase in absorbance at 395nm. This oxidation assay was capable of measuring differences in the absorbance of E. coli and S. aureus samples grown in the presence of inhibitory and non-inhibitory concentrations of ampicillin in as little as six hours. Therefore, this cerium oxide nanoparticle oxidation assay may be very useful for use in clinical laboratories for the detection of antimicrobial resistance due to the relatively low cost, no requirement for specialized equipment and, most importantly, the reduced incubation time of the assay to as little as six hours compared to current gold standard antimicrobial resistance detection methods that require 24 hours. This assay may thus also help partially circumvent the issue of knowledge of antimicrobial resistance in infected patients before prescribing improper regimens.
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Date Issued: 2011
Identifier: CFH0003760, ucf:44780
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFH0003760

Title: WATER VAPOR AND CARBON DIOXIDE SPECIES MEASUREMENT IN NARROW CHANNELS.
Creator: Lambe, Derek, Basu, Saptarshi, University of Central Florida
Abstract / Description: A novel method has been implemented for measuring the concentration of gas species, water vapor and carbon dioxide, within a narrow channel flow field non-invasively using tunable diode laser absorption spectroscopy (TDLAS) in conjunction with a laser modulated at a high frequency [Wavelength Modulation Spectroscopy (WMS)] tuned to the ro-vibrational transition of the species. This technique measures the absorption profile which is a strong function of the species concentration across short...
Show moreA novel method has been implemented for measuring the concentration of gas species, water vapor and carbon dioxide, within a narrow channel flow field non-invasively using tunable diode laser absorption spectroscopy (TDLAS) in conjunction with a laser modulated at a high frequency [Wavelength Modulation Spectroscopy (WMS)] tuned to the ro-vibrational transition of the species. This technique measures the absorption profile which is a strong function of the species concentration across short path lengths and small time spans, as in PEM fuel cells during high load cycles. This method has been verified in a transparent circular flow 12 cm path length and a 12 mm rectangular flow channel. Distinct absorption peaks for water vapor and carbon dioxide have been identified, and concentrations of water vapor and carbon dioxide within the test cells have been measured in situ with high temporal resolutions. A comparison of the full width at half maximum (FWHM) of the absorption lineshapes to the partial pressure of water vapor and carbon dioxide showed a predominantly linear relationship, except in the lower partial pressure regions. Test section temperature was observed to have very minimal impact on these curves at low partial pressure values. A porous media like a membrane electrode assembly (MEA) similar to those used in PEM fuel cells sandwiched between two rectangular flow channels was also tested. Some of the scattered radiation off the MEA was observed using a photodiode at high gain, allowing for more localized species detection. The technique was used to monitor the humidity on either side of the MEA during both temperature controlled and super-saturated conditions. The measurements were observed to be repeatable to within 10 %.
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Date Issued: 2009
Identifier: CFE0002805, ucf:48096
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002805

Title: EXPERIMENTAL STUDIES OF THE HEAT TRANSFER CHARACTERISTICS OF SILICA NANOPARTICLE WATER-BASED DISPERSION IN POOL BOILING USING NICHROME FLAT RIBBONS AND WIRES.
Creator: Vazquez, Diane, Kumar, Ranganathan, University of Central Florida
Abstract / Description: This work deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using ribbon-type and wire heaters. Previously our group and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions and cross-sectional shapes on pool boiling heat transfer characteristics of water and water-based...
Show moreThis work deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using ribbon-type and wire heaters. Previously our group and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions and cross-sectional shapes on pool boiling heat transfer characteristics of water and water-based nanofluids. CHF and BHF were analyzed for circular and rectangular cross-section nichrome wires and ribbons of increasing sizes in the range of 0.32mm to 2.38mm width, approaching a flat-plate scenario. Experimental trends showed that the CHF and BHF in water pool boiling decrease as heater surface area increases, and for similar surface area, the wire had a 25% higher CHF than that of the ribbon. For concentrations from 0.1vol% to 2vol%, various properties such as viscosity, pH, and surface tension as well as silica deposition on surface and glowing length of ribbon were measured in order to study the possible factors in the heat transfer behavior of nanofluids. The deposition of the particles on the wire allows high heat transfer through inter-agglomerate pores, resulting in a nearly 3-fold increase in burnout heat flux at very low concentrations. Results have shown a maximum of up to 340% CHF enhancement for ribbon-type heaters, and the relationship of CHF with respect to nanoparticle concentration has been found to be non-monotonic with a peak around 0.2vol% to 0.4vol%. Visualization of boiling experiments aided with determination of relative bubble sizes, nucleation, and flow regimes. The surface morphology of the heater was investigated using SEM and EDS analyses, and it was inferred that the 2vol% concentration deposition coating had higher porosity and rate of deposition compared with 0.2vol% case.
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Date Issued: 2010
Identifier: CFE0003141, ucf:48635
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0003141

Title: Polymer Optical Fibers for Luminescent Solar Concentration.
Creator: Banaei, Seyed Esmaeil, Fathpour, Sasan, Gong, Xun, Sundaram, Kalpathy, Malocha, Donald, Abouraddy, Ayman, University of Central Florida
Abstract / Description: Luminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber....
Show moreLuminescent solar concentrators (LSC's) are promising candidates for reducing the cost of solar power generation. Conventional LSC's are slab waveguides coated or doped with luminescence materials for absorption and guiding of light to the slab edges in order to convert optical energy into electricity via attached photovoltaic (PV) cells. Exploiting the advantages of optical fiber production, a fiber LSC (FLSC) is presented in this thesis, in which the waveguide is a polymeric optical fiber. A hybrid fiber structure is proposed for an efficient two-stage concentration of incident light, first into a small doped core using a cylindrical micro-lens that extends along the fiber, and second to the fiber ends by guiding the fluoresced light from the active dopants. Flexible sheets are assembled with fibers that can be bundled and attached to small-area PV cells. Small dimensions and directional guiding of the fibers allow for approximately one order of magnitude geometrical gain improvement over that of existing flat LSC's. In addition, the undesired limit of LSC size is eliminated in one direction.Modeling and optimization of an FLSC design is presented using polarization-ray tracing under realistic conditions with solar spectrum radiation and broad-band absorption and emission spectra of fluorescence materials with their inevitable self-absorption effect.Methods and results of fabrication and accurate optical characterization of such FLSC using two off-the-shelf organic dyes and a commercially available polymer, COP, are discussed in detail. Fiber preforms, fabricated under optimized conditions for low light transport loss, are thermally drawn into sub-millimeter-size fibers. Characterization of several samples with various concentrations of the two dyes shows an optical-to-optical conversion efficiency of 9.1% for a tandem combination of two 2.5-cm-long fibers with the efficiency gradually decreasing to 4.9% with increase in fiber length to 10 cm.
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Date Issued: 2013
Identifier: CFE0005083, ucf:50733
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0005083

Title: POST TREATMENT ALTERNATIVES FOR STABILIZING DESALINATED WATER.
Creator: Douglas, Susaye, Duranceau , Steven, University of Central Florida
Abstract / Description: The use of brackish water and seawater desalination for augmenting potable water supplies has focused primarily on pre-treatment, process optimization, energy efficiency, and concentrate management. Much less has been documented regarding the impact of post-treatment requirements with respect to distribution system. The goals of this study were to review current literature on post-treatment of permeate water, use survey questionnaires to gather information on post-treatment water quality...
Show moreThe use of brackish water and seawater desalination for augmenting potable water supplies has focused primarily on pre-treatment, process optimization, energy efficiency, and concentrate management. Much less has been documented regarding the impact of post-treatment requirements with respect to distribution system. The goals of this study were to review current literature on post-treatment of permeate water, use survey questionnaires to gather information on post-treatment water quality characteristics, gather operation information, review general capital and maintenance cost, and identify appropriate "lessons learned" with regards to post-treatment from water purveyors participating in the Project. A workshop was organized where experts from across the United States, Europe and the Caribbean active in brackish and seawater desalination, gathered to share technical knowledge regarding post-treatment stabilization, identify solutions for utilities experiencing problems with post-treatment, note lessons learned, and develop desalination water post-treatment guidelines. In addition, based on initial workshop discussions, the iodide content of reverse osmosis and nanofiltration permeate from two seawater desalination facilities was determined. The literature review identified that stabilization and disinfection are required desalination post-treatment processes, and typically are considerations when considering 1) blending, 2) re-mineralization, 3) disinfection, and 4) materials used for storage and transport of product water. Addition of chemicals can effectively achieve post-treatment goals although considerations relating to the quality of the chemical, dosage rates, and possible chemical reactions, such as possible formation of disinfection by-products, should be monitored and studied. The survey gathered information on brackish water and seawater desalination facilities with specific regards to their post-treatment operations. The information obtained was divided into seven sections 1) general desalination facility information, 2) plant characteristics with schematics, 3) post-treatment water quality, 4) permeate, blend, and point of entry quality, 5) post-treatment operation, 6) operation and maintenance costs, 7) and lessons learned. A major consideration obtained from the survey was that facilities should conduct post-treatment pilot studies in order to identify operational problems that may impact distributions systems prior to designing the plant. Effective design and regulation considerations will limit issues with permitting for the facility. The expert workshop identified fourteen priority issues pertaining to post-treatment. Priority issues were relating to post-treatment stabilization of permeate water, corrosion control, disinfection and the challenges relating to disinfection by-product (DBP) formation, water quality goals, blending, and the importance of informing the general public. For each priority issues guidelines/recommendations were developed for how facilities can effectively manage such issues if they arise. One of the key priorities identified in the workshop was related to blending of permeate and formation of DBPs. However, it was identified in the workshop that the impact of iodide on iodinated-DBP formation was unknown. Consequently, screening evaluations using a laboratory catalytic reduction method to determine iodide concentrations in the permeate of two of the workshop participants: Tampa Bay and Long Beach seawater desalination facilities. It was found that the permeate did contain iodide, although at levels near the detection limit of the analytical method (8 µg/L).
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Date Issued: 2009
Identifier: CFE0002804, ucf:48121
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0002804

Title: Reducing Sulfuric Acid Pretreatment in a Nanofiltration Process Treating Surficial Groundwater.
Creator: Higgins, Carlyn, Duranceau, Steven, Lee, Woo Hyoung, Sadmani, A H M Anwar, University of Central Florida
Abstract / Description: Nanofiltration (NF) is a pressure driven membrane process employed in drinking water treatment that requires pretreatment for reliable operation. The objective of this research was to determine if NF membranes can proficiently operate with a decreased or eliminated dose of sulfuric acid pretreatment. When used as pretreatment, sulfuric acid prevents calcium carbonate scaling on NF membranes, yet is costly, hazardous, and imparts high sulfate concentrations to NF feed and concentrate streams....
Show moreNanofiltration (NF) is a pressure driven membrane process employed in drinking water treatment that requires pretreatment for reliable operation. The objective of this research was to determine if NF membranes can proficiently operate with a decreased or eliminated dose of sulfuric acid pretreatment. When used as pretreatment, sulfuric acid prevents calcium carbonate scaling on NF membranes, yet is costly, hazardous, and imparts high sulfate concentrations to NF feed and concentrate streams. To conduct this research, a 0.324 million gallon per day (MGD) NF pilot plant was operated for 3,855 run-hours at a flux rate of 15 gallons per square foot-day. The NF pilot unit's process performance, productivity, and water quality were monitored while the sulfuric acid dose was gradually decreased, controlled by monitoring pH that ranged from pH 6.5 (80 mg/L sulfuric acid dose) to pH 7.0 (no sulfuric acid dose). NF pilot productivity, as measured by specific flux, was found to decline when sulfuric acid was eliminated by 2.33 percent, 9.61 percent, and 4.08 percent in the first stage, second stage, and total pilot system, respectively, with no distinguishable increase in pressure drop. Noticeable water quality trends include approximately 75 percent sulfate decrease in feed and concentrate streams, and 20 percent increase of calcium hardness and alkalinity in the permeate stream. After piloting, superimposed elemental imaging analysis revealed that the second stage, tail-end membrane surface was fouled with iron disulfide, calcium carbonate, clay, and natural organic matter. However, flux recovered to normal operating conditions after a membrane cleaning was performed. Results of the pilot study indicated that sulfuric acid could be eliminated from the full-scale NF pretreatment process; however, membrane cleaning frequencies could increase. If applied to the full-scale NF process, elimination of sulfuric acid pretreatment would reduce annual chemical costs by over $70,000.
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Date Issued: 2017
Identifier: CFE0007287, ucf:52148
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007287

Title: Corrosion behaviour of AISI 304 stainless steel in contact with eutectic salt for concentrated solar power plant applications.
Creator: Ahmed, Omar, Sohn, Yongho, Mohajeri, Nahid, Coffey, Kevin, Fang, Jiyu, University of Central Florida
Abstract / Description: In response to the extensive energy demands on national and global levels, concentrated solar power (CSP) plants are designed to harness and convert solar energy to electricity. For such green energy application, robust, reliable and durable materials for CSP constructions are required. The corrosion resistance is among many parameters to consider in these thermal-electrical stations such as for pipes and storage tanks in CSP. In this investigation, the corrosion behavior of AISI 304...
Show moreIn response to the extensive energy demands on national and global levels, concentrated solar power (CSP) plants are designed to harness and convert solar energy to electricity. For such green energy application, robust, reliable and durable materials for CSP constructions are required. The corrosion resistance is among many parameters to consider in these thermal-electrical stations such as for pipes and storage tanks in CSP. In this investigation, the corrosion behavior of AISI 304 stainless steel (18 wt. % Cr, 8 wt. % Ni) with the heat transfer fluid, also known as solar salt, has been examined. The ternary eutectic salt mixture with the composition, 53 wt. % KNO3, 40 wt. % NaNO2, and 7 wt. % NaNO3, that melts at 142(&)deg;C, has a potential use in CSP as a heat transfer fluid. The solar salt was prepared for this corrosion study from reagent grades of high purity nitrites and nitrates. Samples of AISI 304 stainless steel were sectioned from a sheet stock of the alloy and exposed to solar salt at 530(&)deg;C in air at 1 atmospheric pressure. After test intervals of 250, 500, and 750 hours in total immersion condition, AISI 304 stainless steel samples have developed a scale of corrosion products made up of multiple oxides. X-ray diffraction and scanning electron microscopy with X-ray energy-dispersive spectroscopy were employed to examine the extent of corrosion and identify the corrosion products. Transmission electron microscopy was used to verify the corrosion products identity via electron diffraction patterns. Oxides of iron were found to be the primary corrosion products in the presence of the molten alkali nitrates-nitrite salt mixture because of the dissolution of the protective chromium oxide (Cr2O3) scale formed on AISI 304 stainless steel coupons. The corrosion scale was uniform in thickness and made up of sodium iron oxide (NaFeO2), iron oxide, hematite (Fe2O3), and chromium-iron oxide (Cr,Fe)2O3 solid solution. The latter was found near the AISI 304 stainless steel. This indicates that the scale formed, particularly on the upper layers with presence of sodium iron oxide and iron oxide, hematite, is protective, and forms an effective barrier against penetration of fused solar salt. At the alloy interface with the bulk corrosion scale, the corrosion process induced a compositional modification in the grains located at the interface. There are iron rich and iron depleted grains at the interface if compared to the nominal iron content of the alloy. The mode of attack is identified as uniform at the test temperature of 530(&)deg;C, showing a parabolic behavior with a parabolic rate constant (Kp) equals to 1.08(&)#215;10^(-17)(m2/sec). By extrapolation, annual corrosion rate is estimated to reach 0.784 mils per year. Corrosion behavior of AISI 304 stainless steel is discussed in terms of thermodynamics and reaction paths.
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Date Issued: 2013
Identifier: CFE0004969, ucf:49587
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004969

Title: The Characterization of the Effects of Stress Concentrations on the Mechanical Behavior of a Micronic Woven Wire Mesh.
Creator: Kraft, Steven, Gordon, Ali, Bai, Yuanli, Gou, Jihua, University of Central Florida
Abstract / Description: Woven structures are steadily emerging as excellent reinforcing components in dual-phase composite materials subjected to multiaxial loads, thermal shock, and aggressive reactants in the environment. Metallic woven wire mesh materials display good ductility and relatively high specific strength and specific resilience. While use of this class of materials is rapidly expanding, significant gaps in mechanical behavior classification remain. This thesis works to address the mechanics of material...
Show moreWoven structures are steadily emerging as excellent reinforcing components in dual-phase composite materials subjected to multiaxial loads, thermal shock, and aggressive reactants in the environment. Metallic woven wire mesh materials display good ductility and relatively high specific strength and specific resilience. While use of this class of materials is rapidly expanding, significant gaps in mechanical behavior classification remain. This thesis works to address the mechanics of material knowledge gap that exists for characterizing the behavior of a metallic woven structure, composed of stainless steel wires on the order of 25 microns in diameter, and subjected to various loading conditions and stress risers. Uniaxial and biaxial tensile experiments, employing Digital Image Correlation (DIC) as a strain measurement tool, are conducted on woven wire mesh specimens incised in various material orientations, and with various notch geometries. Experimental results, supported by an ample analytic modeling effort, indicate that an orthotropic elastic constitutive model is reasonably capable of governing the macro-scale elasticity of the subject material. Also, the Stress Concentration Factor (SCF) associated with various notch geometries is documented experimentally and analytically, and it is shown that the degree of stress concentration is dependent on both notch and material orientation. The Finite Element Method (FEM) is employed on the macro-scale to expand the experimental test matrix, and to judge the effects of a homogenization assumption when modeling metallic woven structures. Additionally, plasticity of the stainless steel woven wire mesh is considered through experimental determination of the yield surface, and a thorough analytic modeling effort resulting in a modified form of the Hill yield criterion. Finally, meso-scale plasticity of the woven structure is considered, and the form of a multi-scale failure criterion is proposed and exercised numerically.
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Date Issued: 2013
Identifier: CFE0004707, ucf:49825
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004707

Title: THE EFFECT OF COLLOIDAL STABILITY ON THE HEAT TRANSFER CHARACTERISTICS OF NANOSILICA DISPERSED FLUIDS.
Creator: Venkataraman, Manoj, Kumar, Ranganathan, University of Central Florida
Abstract / Description: Addition of nano particles to cooling fluids has shown marked improvement in the heat transfer capabilities. Nanofluids, liquids that contain dispersed nanoparticles, are an emerging class of fluids that have great potential in many applications. There is a need to understand the fundamental behavior of nano dispersed particles with respect to their agglomeration characteristics and how it relates to the heat transfer capability. Such an understanding is important for the development and...
Show moreAddition of nano particles to cooling fluids has shown marked improvement in the heat transfer capabilities. Nanofluids, liquids that contain dispersed nanoparticles, are an emerging class of fluids that have great potential in many applications. There is a need to understand the fundamental behavior of nano dispersed particles with respect to their agglomeration characteristics and how it relates to the heat transfer capability. Such an understanding is important for the development and commercialization of nanofluids. In this work, the stability of nano particles was studied by measuring the zeta potential of colloidal particles, particle concentration and size. Two different sizes of silica nano particles, 10 nm and 20 nm are used in this investigation at 0.2 vol. % and 0.5 vol. % concentrations. The measurements were made in deionized (DI) water, buffer solutions at various pH, DI water plus HCl acid solution (acidic pH) and DI water plus NaOH solution (basic pH). The stability or instability of silica dispersions in these solutions was related to the zeta potential of colloidal particles and confirmed by particle sizing measurements and independently by TEM observations. Low zeta potentials resulted in agglomeration as expected and the measured particle size was greater. The heat transfer characteristics of stable or unstable silica dispersions using the above solutions were experimentally determined by measuring heat flux as a function of temperature differential between a nichrome wire and the surrounding fluid. These experiments allowed the determination of the critical heat flux (CHF), which was then related to the dispersion characteristics of the nanosilica in various fluids described above. The thickness of the diffuse layer on nano particles was computed and experimentally confirmed in selected conditions for which there was no agglomeration. As the thickness of the diffuse layer decreased due to the increase in salt content or the ionic content, the electrostatic force of repulsion cease to exist and Van der Waal's force of agglomeration prevailed causing the particles to agglomerate affecting the CHF. The 10nm size silica particle dispersions showed better heat transfer characteristics compared to 20nm dispersion. It was also observed that at low zeta potential values, where agglomeration prevailed in the dispersion, the silica nano particles had a tendency to deposit on the nickel chromium wire used in CHF experiments. The thickness of the deposition was measured and the results show that with a very high deposition, CHF is enhanced due to the porosity on the wire. The 10nm size silica particles show higher CHF compared to 20nm silica particles. In addition, for both 10nm and 20nm silica particles, 0.5 vol. % concentration yielded higher heat transfer compared to 0.2 vol. % concentration. It is believed that although CHF is significantly increased with nano silica containing fluids compared to pure fluids, formation of particle clusters in unstable slurries will lead to detrimental long time performance, compared to that with stable silica dispersions.
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Date Issued: 2005
Identifier: CFE0000837, ucf:46676
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0000837

Title: Size, Charge and Dose Dependent In-vitro Kinetics of Polystyrene Nanoparticles.
Creator: Abdellatif, Yasmine, Gesquiere, Andre, Kang, Hyeran, Rajaraman, Swaminathan, University of Central Florida
Abstract / Description: The aim of the study described herein is to quantify the in-vitro kinetics of internalization of polystyrene nanoparticles (PS NPs) by cells. We used different charges, sizes and doses of fluorescently labelled PS NPs. Nanoparticles were characterized with UV-Vis, Fluorescence emission Dynamic Light Scattering (DLS) and Zeta potential for knowing their absorption, fluorescence spectra, size, charge, respectively. Additionally, cell viability was tested to know the toxicity of PS NPs. The...
Show moreThe aim of the study described herein is to quantify the in-vitro kinetics of internalization of polystyrene nanoparticles (PS NPs) by cells. We used different charges, sizes and doses of fluorescently labelled PS NPs. Nanoparticles were characterized with UV-Vis, Fluorescence emission Dynamic Light Scattering (DLS) and Zeta potential for knowing their absorption, fluorescence spectra, size, charge, respectively. Additionally, cell viability was tested to know the toxicity of PS NPs. The quantitative uptake, the kinetics profile and rate of uptake were studied by using a new in-vitro fluorescence assay. This was achieved quantitatively and qualitatively by fluorescent plate reader and confocal imaging, respectively. It was found that the amine PS NPs are higher in cytotoxicity than the carboxy PS NPs due to the proton sponge phenomenon. It was observed that the fraction uptake of PS NPs changes by changing the physiochemical properties as charge, size (&) dose. The fraction uptake of neutral and amine PS NPs was higher than that of carboxy PS NPs. For the neutral PS NPs, the uptake depends on the macropinocytosis. For the amine PS NPs, the uptake depends on the electrostatic interaction and the rapid regeneration of new binding sites. Regarding the dose of PS NPs, for the amine PS NPs, it was found that the concentrations lower and higher than 5nM had lower fraction uptake, because the 5nM achieved the balance between the available number of binding sites and the rapid regeneration of new binding sites. For the kinetics profile of the amine and carboxy PS NPs, by comparing both of them, it was observed that the rate of uptake of applied doses lower than 5nM was different, but higher than 5nM was similar. However, for the neutral Ps NPs, they exhibit a steady state of rate of uptake in between the amine and carboxy PS NPs. Also, it was confirmed by the confocal images that as the concentration of amine PS NPs increase, the stress on the cells increase, leading to the cell death. These results were aligned with the results obtained from the cytotoxicity test.
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Date Issued: 2018
Identifier: CFE0007386, ucf:52744
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0007386

Title: Effluent Water Quality Improvement Using Silt Fences and Stormwater Harvesting.
Creator: Gogo-Abite, Ikiensinma, Chopra, Manoj, Wanielista, Martin, Nam, Boo Hyun, Weishampel, John, University of Central Florida
Abstract / Description: Construction sites are among the most common areas to experience soil erosion and sediment transport due to the mandatory foundation tasks such as excavation and land grubbing. Thus, temporary sediment barriers are installed along the perimeter to prevent sediment transport from the site. Erosion and sediment transport control measures may include, but not limited to, physical and chemical processes such as the use of a silt fence and polyacrylamide product. Runoff from construction sites and...
Show moreConstruction sites are among the most common areas to experience soil erosion and sediment transport due to the mandatory foundation tasks such as excavation and land grubbing. Thus, temporary sediment barriers are installed along the perimeter to prevent sediment transport from the site. Erosion and sediment transport control measures may include, but not limited to, physical and chemical processes such as the use of a silt fence and polyacrylamide product. Runoff from construction sites and other impervious surfaces are routinely discharged into ponds for treatment before being released into a receiving water body. Stormwater harvesting from a pond for irrigation of adjacent lands is promoted as one approach to reducing pond discharge while supplementing valuable potable water used for irrigation. The reduction of pond discharge reduces the mass of pollutants in the discharge. In the dissertation, presented is the investigation of the effectiveness of temporary sediment barriers and then, development of a modeling approach to a stormwater harvesting pond to provide a comprehensive stormwater management pollution reduction assessment tool.The first part of the research presents the investigation of the performance efficiencies of silt fence fabrics in turbidity and sediment concentration removal, and the determination of flow-through-rate on simulated construction sites in real time. Two silt fence fabrics, (1) woven and the other (2) nonwoven were subjected to material index property tests and a series of field-scale tests with different rainfall intensities and events for different embankment slopes on a tilting test-bed. Collected influent and effluent samples were analyzed for sediment concentration and turbidity, and the flow-through-rate for each fabric was evaluated. Test results revealed that the woven and nonwoven silt fence achieved 11 and 56 percent average turbidity reduction efficiency, respectively. Each fabric also achieved 20 and 56 percent average sediment concentration removal efficiency, respectively. Fabric flow-through-rates were functions of the rainfall intensity and embankment slope. The nonwoven fabric exhibited higher flow-through-rates than the woven fabric in both field-scale and laboratory tests.In the second part of the study, a Stormwater Harvesting and Assessment for Reduction of Pollution (SHARP) model was developed to predict operation of wet pond used for stormwater harvesting. The model integrates the interaction of surface water and groundwater in a catchment area. The SHARP model was calibrated and validated with actual pond water elevation data from a stormwater pond at Miramar Lakes, Miramar, Florida. Model evaluation showed adequate prediction of pond water elevation with root mean square error between 0.07 and 0.12 m; mean absolute error was between 0.018 and 0.07 m; and relative index of agreement was between 0.74 and 0.98 for both calibration and validation periods. The SHARP model is capable of assessing harvesting safe-yield and discharge from a pond, including the prediction of the percentage of runoff into a harvesting pond that is not discharged.The combination of silt fence and/or polyacrylamide PAM before stormwater harvesting pond in a treatment train for the reduction of pollutants from construction sites has the potential of significantly exceeding a performance standard of 85 percent reduction typically required by local authorities. In fact, the stringent requirement of equaling pre- and post-development pollutant loading is highly achievable by the treatment train approach. The significant contribution from the integration of the SHARP model to the treatment train is that real-time assessment of pollutant loading reduction by volume can be planned and controlled to achieve target performance standards.
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Date Issued: 2012
Identifier: CFE0004539, ucf:49244
Format: Document (PDF)
PURL: http://purl.flvc.org/ucf/fd/CFE0004539

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