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- Title
- PREVENTION OF ENVIRONMENTALLY INDUCED DEGRADATION IN CARBON/EPOXY COMPOSITE MATERIAL VIA IMPLEMENTATION OF A POLYMER BASED COATING SYSTEM.
- Creator
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Tipton, Bradford, Sohn, Yongho, University of Central Florida
- Abstract / Description
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As the use of fiber reinforced plastics increases in such industries as aerospace, wind energy, and sporting goods, factors effecting long-term durability, such as environmental exposure, are of increasing interest. The primary objectives of this study were to examine the effects of extensive environmental exposure (specifically UV radiation and moisture) on carbon/epoxy composite laminate structures and to determine the relative effectiveness of polymer-based coatings at mitigating...
Show moreAs the use of fiber reinforced plastics increases in such industries as aerospace, wind energy, and sporting goods, factors effecting long-term durability, such as environmental exposure, are of increasing interest. The primary objectives of this study were to examine the effects of extensive environmental exposure (specifically UV radiation and moisture) on carbon/epoxy composite laminate structures and to determine the relative effectiveness of polymer-based coatings at mitigating degradation incurred due to such exposure. Carbon/epoxy composite specimens, both coated and uncoated, were subjected to accelerated weathering in which prolonged outdoor exposure was simulated by controlling the radiation wavelength (in the UV region), temperature, and humidity. Mechanical test data obtained for the uncoated specimens indicated a reduction in strength of approximately 6% after an environmental exposure duration of 750 hours. Test data revealed that no further degradation occurred with increased exposure duration. This reduction resulted from the erosion of the epoxy matrix in additional to the formation of matrix microcracks. The protective coatings evaluated were all epoxy based and included two different surfacing films applied during initial cure of the carbon/epoxy composite laminate and a chromate containing epoxy based paint primer applied after the cure was complete. Although the chromate primer performed well initially, degradation of the underlying substrate was detected with extended exposure durations. In contrast, the surfacing films provided superior protection against environmentally induced degradation. Although similar degradation attributes were identified in the surfacing film as observed in the uncoated composite, it is likely that this degradation was either confined within the surfacing film layer or only penetrated the very near surface of the carbon/epoxy substrate, as it did not result in a substantial reduction in mechanical strength.
Show less - Date Issued
- 2008
- Identifier
- CFE0002406, ucf:47731
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002406
- Title
- POLYURETHANE FIBER REINFORCED POLYMER STRENGTHENING OF SHEAR DEFICIENT REINFORCED CONCRETE BEAMS.
- Creator
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Al-Lebban, Yasir, Mackie, Kevin, Chopra, Manoj, Makris, Nicos, Gou, Jihua, University of Central Florida
- Abstract / Description
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The use of externally-bonded fiber-reinforced polymer (FRP) composites has been established as an effective means for the strengthening of shear-deficient reinforced concrete (RC) flexural members. Epoxy-based wet layup systems were predominantly employed in previous studies. In this study, carbon FRP pre-impregnated with polyurethane resin is utilized in strengthening shear-deficient RC beams and compared to an epoxy resin. Fourteen small-scale (96 in span, 6 in width, and 12 in height) and...
Show moreThe use of externally-bonded fiber-reinforced polymer (FRP) composites has been established as an effective means for the strengthening of shear-deficient reinforced concrete (RC) flexural members. Epoxy-based wet layup systems were predominantly employed in previous studies. In this study, carbon FRP pre-impregnated with polyurethane resin is utilized in strengthening shear-deficient RC beams and compared to an epoxy resin. Fourteen small-scale (96 in span, 6 in width, and 12 in height) and five large-scale (132 in span, 12 in width, and 17 in height) flexural specimens were tested, considering FRP system type (polyurethane versus epoxy), size effect, shear span-to-depth ratio, FRP configuration (U-wraps versus side bonding), and FRP scheme (sheets versus strips with 45o or 90o). Experimental strength testing under four-point loading demonstrated similar or enhanced shear capacity when strengthening by the polyurethane compared to the epoxy composite systems.The shear behavior of polyurethane-based FRP composite system is investigated in this research using analytical and numerical approaches. A closed-form mechanics-based analytical model, utilizing the principle of effective FRP stress and upper-bound theorem, illustrated that the shear behavior and debonding mechanism were dependent on both FRP composite and bond characteristics. The analytical model is expressed in terms of shear crack opening crossed by the FRP laminate and gives good agreement with experimental results. The finite element analysis (FEA) model shows that the stresses in the FRP are not in single direction as in the coupon tests, and the biaxial stress states should be taken into consideration.The structural behavior of RC members strengthened with externally-bonded FRP composites is mobilized through the composite action technique. Bond stress can be defined as the shear stress acting in the interface between FRP and concrete. It is of crucial importance to evaluate the failure mode behavior. Debonding (loss of adhesion) failure is one of the most common modes of failure encountered in shear strengthening RC members in practice. Numerous constitutive bond-slip models have been proposed and derived numerically and mathematically based on experimental data with an assumption that the FRP width bp is taken as a variable and all stresses or strains at the same longitudinal coordinate (L direction) are uniform. No attention has been given to study the bond states of stress which are mainly altered by the inclined shear cracks in concrete. A new bond-slip law was proposed to address the biaxial two-dimensional (2D) states of stress problem. Numerical solution by finite difference (FD) was conducted to solve four partial differential equations per node (2 for FRP and 2 for concrete in each direction) with appropriate boundary conditions to obtain the stresses, slips, and strains based on the proposed bond-slip model. A new experimental setup was proposed to represent the 2D bond-slip model by lap shear tests in both directions by laminating two perpendicular strips on concrete blocks with the proposed strain profile. Experimental calibration has been carried out by using nonlinear least-squares regression (fitting) of the experimental strain data with the numerical FD equations to obtain the bond-slip parameters for the 2D FRP-to-concrete polyurethane interface system.
Show less - Date Issued
- 2017
- Identifier
- CFE0006852, ucf:51737
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0006852
- Title
- Fiber-Reinforced Polymer (FRP) Composites in Retrofitting of Concrete Structures: Polyurethane Systems Versus Epoxy Systems.
- Creator
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El Zghayar, Elie, Mackie, Kevin, Catbas, Necati, Chopra, Manoj, University of Central Florida
- Abstract / Description
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Fiber reinforced polymer (FRP) composites have been of interest to the structural engineering society since the earliest days of FRP composites industry. The use of such systems has been implemented in both new construction and for repair and rehabilitation of existing structures. Since the 1980s, researchers have developed a significant body of knowledge to use FRP composites in infrastructure applications; however, most of this established knowledge was concentrated on the use of...
Show moreFiber reinforced polymer (FRP) composites have been of interest to the structural engineering society since the earliest days of FRP composites industry. The use of such systems has been implemented in both new construction and for repair and rehabilitation of existing structures. Since the 1980s, researchers have developed a significant body of knowledge to use FRP composites in infrastructure applications; however, most of this established knowledge was concentrated on the use of traditional epoxy (EP) systems (epoxy matrix FRPs and epoxy adhesives). FRP composites with polyurethane (PU) matrices and adhesives have recently attracted the attention of a few researchers due to their potential advantages in constructibility and mechanical properties. The deployment of these systems is currently limited by a lack of knowledge on mechanical and durability performance. The objective of this research is to quantify the mechanical behavior of PU composites utilized in externally-bonded repair of common flexural and flexural-axial reinforced concrete systems. In addition, the mechanical performance, strength, and failure modes are compared directly with an epoxy-based composite by subjecting reinforced concrete specimens utilizing each of the matrix types (EP and PU) to the same protocols. The study presented therefore allows an objective comparison (advantages and disadvantages) between the two composite system used for repair and rehabilitation of concrete infrastructure. An experimental research program was designed with different length scales. Small-scale experiments were utilized to characterize the component level properties of the materials and bond to concrete, which include the flexural behavior as well as the pure shear behavior. The results of these small scale experiments were used to calibrate analytical models of the interface behavior between FRP laminate and concrete, and paved the way for the next level of the research which studied the behavior of each composite system at larger scales. The large scale experiments included flexural retrofitting of reinforced concrete girders and retrofitting of circular columns using FRP laminates. The large-scale experimental specimens were mechanically damaged prior to FRP repair and testing, making the testing more appropriate compared to common practice of repairing undamaged specimens.
Show less - Date Issued
- 2015
- Identifier
- CFE0005942, ucf:50820
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005942
