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- Title
- EMPIRICAL RELATIONSHIPS BETWEENLOAD TEST DATA AND PREDICTED COMPRESSION CAPACITY OF AUGERED CAST-IN-PLACE PILES IN PREDOMINANTLY COHESIONLESS SOILS.
- Creator
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McCarthy, Donald, Kuo, Shiou-San, University of Central Florida
- Abstract / Description
-
Augered Cast-In-Place (ACIP) Piles are used in areas were the loading from a superstructure exceeds the soil bearing capacity for usage of a shallow foundation. In Northwest Florida and along the Gulf Coast, ACIP piles are often utilized as foundation alternatives for multi-story condominium projects. Data from 25 compression load tests at 13 different project sites in Florida and Alabama were analyzed to determine their individual relationships between anticipated and determined compression...
Show moreAugered Cast-In-Place (ACIP) Piles are used in areas were the loading from a superstructure exceeds the soil bearing capacity for usage of a shallow foundation. In Northwest Florida and along the Gulf Coast, ACIP piles are often utilized as foundation alternatives for multi-story condominium projects. Data from 25 compression load tests at 13 different project sites in Florida and Alabama were analyzed to determine their individual relationships between anticipated and determined compression load capacity. The anticipated capacity of the ACIP pile is routinely overestimated due to uncertainties involved with the process of estimating the compressive capacity and procedures of placing the piles; therefore, larger diameter and deeper piles are often used to offset this lack of understanding. The findings established in this study will provide a better empirical relationship between predicted behaviors and actual behaviors of ACIP piles in cohesionless soils. These conclusions will provide the engineer with a better understanding of ACIP pile behaviors and provide a more feasible approach to more accurately determine the pile-soil interaction in mostly cohesionless soils.
Show less - Date Issued
- 2008
- Identifier
- CFE0002286, ucf:47848
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002286
- Title
- DEVELOPMENT OF HYDRAULIC AND SOIL PROPERTIES FOR SOIL AMENDMENTS AND NATIVE SOILS FOR RETENTION PONDS IN MARION COUNTY, FLORIDA.
- Creator
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Naujock, Lisa, Chopra, Manoj, University of Central Florida
- Abstract / Description
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The vadose zone plays an important role in managing stormwater. Predicting the water balance and water movement is crucial in ground water remediation to keep water suitable for use. To aid in understanding soils ability to transmit and store water, soil and hydraulic properties were analyzed for soils in Marion County, Florida, and potential soil amendments. Soil and hydraulic properties were examined for two soil amendments and for the soils in Marion County, Florida, at the South Oak and...
Show moreThe vadose zone plays an important role in managing stormwater. Predicting the water balance and water movement is crucial in ground water remediation to keep water suitable for use. To aid in understanding soils ability to transmit and store water, soil and hydraulic properties were analyzed for soils in Marion County, Florida, and potential soil amendments. Soil and hydraulic properties were examined for two soil amendments and for the soils in Marion County, Florida, at the South Oak and the Hunter's Trace locations. The hydraulic properties measured were the soil moisture retention curve (SMRC) and saturated hydraulic conductivity (Ks). The soil properties measured were the particle-size distribution (PSD) and the specific gravity. From these, the bulk density and porosity were calculated. The SMRC corresponds to the water holding capacities, while the Ks corresponds to the soils ability to transmit water. Both are dependent on the soil properties. The SMRC for the soil amendments and native soils were developed in the laboratory using a Tempe Cell apparatus. In addition, the SMRC was measured in the field at the Hunter's Trace location with time domain reflectometry (TDR) and tensiometer equipment at three depths of 1-ft, 2-ft, and 3-ft over approximate a two month period. The SMRC obtained in the laboratory was compared to two analytical models, Brooks and Corey and van Genuchten, and to the field data. There is a strong correlation between the laboratory, analytical, and field SMRC for both South Oak and Hunter's Trace. In addition, there is a strong correlation between the laboratory SMRC and analytical models for the soil amendments. The Arya and Paris (AP) model, a pedotransfer function, was examined for its accuracy in predicting the SMRC for the soils at South Oak and Hunter's Trace, in addition to the soil amendments. Measuring the SMRC in the lab is a time consuming process; therefore, inferring the SMRC from textural and structural soil properties which are easier measured characteristics would be advantageous.
Show less - Date Issued
- 2008
- Identifier
- CFE0002410, ucf:47750
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002410
- Title
- Infiltration in Stormwater Detention/ Percolation Basin Design.
- Creator
-
Beaver, Robert D., Hartman, J Paul, Engineering
- Abstract / Description
-
Florida Technological University College of Engineering Thesis; Investigations of soil parameters, infiltration testing, and storm observations are used to determine the infiltration characteristics for three Central Florida stormwater holding basins. Basic soil parameters are investigated and a value for available soil water storage is computed from these data. In-situ permeability and infiltration tests are used to obtain field permeability and infiltration rates. Infiltration test results...
Show moreFlorida Technological University College of Engineering Thesis; Investigations of soil parameters, infiltration testing, and storm observations are used to determine the infiltration characteristics for three Central Florida stormwater holding basins. Basic soil parameters are investigated and a value for available soil water storage is computed from these data. In-situ permeability and infiltration tests are used to obtain field permeability and infiltration rates. Infiltration test results may be applied to infiltration theory. Data from infiltration tests may be verified using available soil water storage computed from soil parameters. The effect of soil cover conditions is noted and investigated using the drum infiltrometer. Storm observations are used to confirm infiltration models. Infrequency of rainfall activity limited the number and reliability of observations. The effects of precipitation frequency and input intensity to the pond also noted in storm observations. A design procedure incorporating infiltration in stormwater retention basins is presented. This design procedure is based on infiltration theory and observed pond operation.
Show less - Date Issued
- 1977
- Identifier
- CFR0008151, ucf:52946
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFR0008151
- Title
- EFFECT OF HORIZONTAL PILES ON THE SOIL BEARING CAPACITY FOR CIRCULAR FOOTING ABOVE CAVITY.
- Creator
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Arosemena, Rafael, Kuo, Shiou-San, University of Central Florida
- Abstract / Description
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The design of foundation in normal soil conditions is governed by bearing capacity, minimum depth of foundation and settlement. However, foundation design in karst regions needs to consider an additional criterion associated to the possibility of subsurface subsidence and ravelling sinkholes. Under this environment, alternative techniques are needed to improve the subsurface soil. In this study general background information is given to understand the geological characteristics of Central...
Show moreThe design of foundation in normal soil conditions is governed by bearing capacity, minimum depth of foundation and settlement. However, foundation design in karst regions needs to consider an additional criterion associated to the possibility of subsurface subsidence and ravelling sinkholes. Under this environment, alternative techniques are needed to improve the subsurface soil. In this study general background information is given to understand the geological characteristics of Central Florida and why this area is considered to be a karst region and susceptible to sinkholes formation. Traditional foundation design techniques on karst regions are addressed in this paper. Finally, the use of a network of three subsurface horizontal piles is proposed and the effect on stress increase and soil bearing capacity for footing due to the horizontal piles is investigated. Finite element computer software is used to analyze the stress distribution under different conditions and the results are discussed. The objective of this study is to determine whether or not horizontal piles under a circular footing at the sinkhole site is a viable solution to reduce the stress increase in the soil induced by the footing load. The horizontal piles located at a certain depth below the center of the footing intercepts the cone of pressure due to the footing load. Also, it is the purpose of this research to determine the effect on the soil bearing capacity for footing due to the proposed horizontal piles at the sinkhole prone area. In 1983 Baus, R.L and Wang, M.C published a research paper on soil bearing capacity for strip footing above voids. In their research, a chart for soil bearing capacity for strip footing located above a void was presented. However, in this paper we present a chart for circular footing size as a function void location and a design chart for circular footing size with a network of three underground piles. The result indicates that with the horizontal piles placed above the cavity, the stress increase caused by the footing load substantially decreases as compared to the situation of no horizontal piles, thus increases the soil bearing capacity for the normal design of footing size. The approach of using the horizontal piles placed in between the footing and the subsurface cavity is a new concept that has not been experienced previously. The results are strictly based on the analytical model of finite element program. Before full implementation for the construction practice, further research and experimental work should be conducted.
Show less - Date Issued
- 2007
- Identifier
- CFE0001643, ucf:47224
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001643
- Title
- Geographic and Environmental Influence on Maya Settlement Patterns of the Northwest Yucatan: An Explanation for the Sparsely Settled Western Cenote Zone.
- Creator
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Rohrer, Patrick, Chase, Arlen, Chase, Diane, Walker, John, University of Central Florida
- Abstract / Description
-
Most settlement pattern research and GIS analysis of the ancient Maya of the Northern Yucatan have focused on water availability in a dry landscape where cenotes are often the only water source. While water is of paramount importance, permanent settlement secondarily requires farmable soil, a resource often as precious as water in many parts of the Yucatan. The dynamics between these resources reveal areas of ideal settlement and more challenging landscapes for which the Maya developed...
Show moreMost settlement pattern research and GIS analysis of the ancient Maya of the Northern Yucatan have focused on water availability in a dry landscape where cenotes are often the only water source. While water is of paramount importance, permanent settlement secondarily requires farmable soil, a resource often as precious as water in many parts of the Yucatan. The dynamics between these resources reveal areas of ideal settlement and more challenging landscapes for which the Maya developed strategies to overcome environmental conditions. A region of the southwest "Cenote Zone", however, appears to have presented the ancient Maya with insurmountably poor environmental conditions despite abundant water resources. The lack of dense population and stone architecture in this area emphasizes the lack of a simple correlation between cenotes and settlement. This thesis uses GIS analysis to identify and explore such problematic settlement areas to better understand the factors and complexities involved in the more successful settlements of neighboring regions.
Show less - Date Issued
- 2012
- Identifier
- CFE0004589, ucf:49205
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004589
- Title
- FAR-INFRARED/MILLIMETER WAVE SOURCE AND COMPONENT DEVELOPMENT FOR IMAGING AND SPECTROSCOPY.
- Creator
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Du Bosq, Todd, Boreman, Glenn, University of Central Florida
- Abstract / Description
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The far-infrared and millimeter wave (FIR/mmW) (wavelength 75 micrometer to 10 mm) portion of the electromagnetic spectrum is fairly underdeveloped technologically, owing to the large amount of atmospheric attenuation in that range. At present, the FIR/mmW region is lacking in compact, high-brightness radiation sources and practical imaging systems. This dissertation focuses on development of two complementary technologies in this area an active mmW imaging system and high-reflectivity...
Show moreThe far-infrared and millimeter wave (FIR/mmW) (wavelength 75 micrometer to 10 mm) portion of the electromagnetic spectrum is fairly underdeveloped technologically, owing to the large amount of atmospheric attenuation in that range. At present, the FIR/mmW region is lacking in compact, high-brightness radiation sources and practical imaging systems. This dissertation focuses on development of two complementary technologies in this area an active mmW imaging system and high-reflectivity Bragg mirrors for the FIR p-Ge laser. The imaging system uses a vector network analyzer in the frequency range of 90-140 GHz as the radiation source and receiver. Raster scanning is used to map a two-dimensional field of view, demonstrating the detection and imaging of buried plastic landmines. Principal components analysis is used for hyperspectral signal processing, where a series of images is taken at discrete frequencies. Results are obtained as a function of depth and disturbance of the soil surface. In support of this study, various types of soils were characterized for scattering loss across the mmW/FIR region, with measured results compared to theory. This mmW imaging system was also used to demonstrate imaging through walls and other obscuring materials, as well as for imaging of rocks beneath volcanic sand, simulating the conditions encountered by an imaging system on a Mars rover vehicle. Furthermore, a high-reflectivity Si-etalon FIR mirror design was developed and demonstrated as a cavity mirror for the p-Ge laser. These components stand to have a number of systems-level impacts on FIR imagers. In the context of an active illuminator, they may allow narrowband selection from the broad emission spectrum of the p-Ge laser source. These mirrors can also be used in a Fabry-Perot FIR scanning spectrometer, where the resulting high finesse would give discrimination advantages in chemical sensing and astrophysical spectroscopy applications.
Show less - Date Issued
- 2007
- Identifier
- CFE0001665, ucf:47222
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001665
- Title
- MULTISENSOR FUSION REMOTE SENSING TECHNOLOGY FOR ASSESSING MULTITEMPORAL RESPONSES IN ECOHYDROLOGICAL SYSTEMS.
- Creator
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Makkeasorn, Ammarin, Chang, Ni-Bin, University of Central Florida
- Abstract / Description
-
Earth ecosystems and environment have been changing rapidly due to the advanced technologies and developments of humans. Impacts caused by human activities and developments are difficult to acquire for evaluations due to the rapid changes. Remote sensing (RS) technology has been implemented for environmental managements. A new and promising trend in remote sensing for environment is widely used to measure and monitor the earth environment and its changes. RS allows large-scaled measurements...
Show moreEarth ecosystems and environment have been changing rapidly due to the advanced technologies and developments of humans. Impacts caused by human activities and developments are difficult to acquire for evaluations due to the rapid changes. Remote sensing (RS) technology has been implemented for environmental managements. A new and promising trend in remote sensing for environment is widely used to measure and monitor the earth environment and its changes. RS allows large-scaled measurements over a large region within a very short period of time. Continuous and repeatable measurements are the very indispensable features of RS. Soil moisture is a critical element in the hydrological cycle especially in a semiarid or arid region. Point measurement to comprehend the soil moisture distribution contiguously in a vast watershed is difficult because the soil moisture patterns might greatly vary temporally and spatially. Space-borne radar imaging satellites have been popular because they have the capability to exhibit all weather observations. Yet the estimation methods of soil moisture based on the active or passive satellite imageries remain uncertain. This study aims at presenting a systematic soil moisture estimation method for the Choke Canyon Reservoir Watershed (CCRW), a semiarid watershed with an area of over 14,200 km2 in south Texas. With the aid of five corner reflectors, the RADARSAT-1 Synthetic Aperture Radar (SAR) imageries of the study area acquired in April and September 2004 were processed by both radiometric and geometric calibrations at first. New soil moisture estimation models derived by genetic programming (GP) technique were then developed and applied to support the soil moisture distribution analysis. The GP-based nonlinear function derived in the evolutionary process uniquely links a series of crucial topographic and geographic features. Included in this process are slope, aspect, vegetation cover, and soil permeability to compliment the well-calibrated SAR data. Research indicates that the novel application of GP proved useful for generating a highly nonlinear structure in regression regime, which exhibits very strong correlations statistically between the model estimates and the ground truth measurements (volumetric water content) on the basis of the unseen data sets. In an effort to produce the soil moisture distributions over seasons, it eventually leads to characterizing local- to regional-scale soil moisture variability and performing the possible estimation of water storages of the terrestrial hydrosphere. A new evolutionary computational, supervised classification scheme (Riparian Classification Algorithm, RICAL) was developed and used to identify the change of riparian zones in a semi-arid watershed temporally and spatially. The case study uniquely demonstrates an effort to incorporating both vegetation index and soil moisture estimates based on Landsat 5 TM and RADARSAT-1 imageries while trying to improve the riparian classification in the Choke Canyon Reservoir Watershed (CCRW), South Texas. The CCRW was selected as the study area contributing to the reservoir, which is mostly agricultural and range land in a semi-arid coastal environment. This makes the change detection of riparian buffers significant due to their interception capability of non-point source impacts within the riparian buffer zones and the maintenance of ecosystem integrity region wide. The estimation of soil moisture based on RADARSAT-1 Synthetic Aperture Radar (SAR) satellite imagery as previously developed was used. Eight commonly used vegetation indices were calculated from the reflectance obtained from Landsat 5 TM satellite images. The vegetation indices were individually used to classify vegetation cover in association with genetic programming algorithm. The soil moisture and vegetation indices were integrated into Landsat TM images based on a pre-pixel channel approach for riparian classification. Two different classification algorithms were used including genetic programming, and a combination of ISODATA and maximum likelihood supervised classification. The white box feature of genetic programming revealed the comparative advantage of all input parameters. The GP algorithm yielded more than 90% accuracy, based on unseen ground data, using vegetation index and Landsat reflectance band 1, 2, 3, and 4. The detection of changes in the buffer zone was proved to be technically feasible with high accuracy. Overall, the development of the RICAL algorithm may lead to the formulation of more effective management strategies for the handling of non-point source pollution control, bird habitat monitoring, and grazing and live stock management in the future. Soil properties, landscapes, channels, fault lines, erosion/deposition patches, and bedload transport history show geologic and geomorphologic features in a variety of watersheds. In response to these unique watershed characteristics, the hydrology of large-scale watersheds is often very complex. Precipitation, infiltration and percolation, stream flow, plant transpiration, soil moisture changes, and groundwater recharge are intimately related with each other to form water balance dynamics on the surface of these watersheds. Within this chapter, depicted is an optimal site selection technology using a grey integer programming (GIP) model to assimilate remote sensing-based geo-environmental patterns in an uncertain environment with respect to some technical and resources constraints. It enables us to retrieve the hydrological trends and pinpoint the most critical locations for the deployment of monitoring stations in a vast watershed. Geo-environmental information amassed in this study includes soil permeability, surface temperature, soil moisture, precipitation, leaf area index (LAI) and normalized difference vegetation index (NDVI). With the aid of a remote sensingbased GIP analysis, only five locations out of more than 800 candidate sites were selected by the spatial analysis, and then confirmed by a field investigation. The methodology developed in this remote sensing-based GIP analysis will significantly advance the state-of-the-art technology in optimum arrangement/distribution of water sensor platforms for maximum sensing coverage and information-extraction capacity. Effective water resources management is a critically important priority across the globe. While water scarcity limits the uses of water in many ways, floods also have caused so many damages and lives. To more efficiently use the limited amount of water or to resourcefully provide adequate time for flood warning, the results have led us to seek advanced techniques for improving streamflow forecasting. The objective of this section of research is to incorporate sea surface temperature (SST), Next Generation Radar (NEXRAD) and meteorological characteristics with historical stream data to forecast the actual streamflow using genetic programming. This study case concerns the forecasting of stream discharge of a complex-terrain, semi-arid watershed. This study elicits microclimatological factors and the resultant stream flow rate in river system given the influence of dynamic basin features such as soil moisture, soil temperature, ambient relative humidity, air temperature, sea surface temperature, and precipitation. Evaluations of the forecasting results are expressed in terms of the percentage error (PE), the root-mean-square error (RMSE), and the square of the Pearson product moment correlation coefficient (r-squared value). The developed models can predict streamflow with very good accuracy with an r-square of 0.84 and PE of 1% for a 30-day prediction.
Show less - Date Issued
- 2007
- Identifier
- CFE0001767, ucf:47267
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0001767
- Title
- The Development of Soil Compressibility Prediction Models and Application to Site Settlement.
- Creator
-
Kirts, Scott, Nam, Boo Hyun, Chopra, Manoj, Sallam, Amr, Xanthopoulos, Petros, University of Central Florida
- Abstract / Description
-
The magnitude of the overall settlement depends on several variables such as the Compression Index, Cc, and Recompression Index, Cr, which are determined by a consolidation test; however, the test is time consuming and labor intensive. Correlations have been developed to approximate these compressibility indexes. In this study, a data driven approach has been employed in order to estimate Cc and Cr. Support Vector Machines classification is used to determine the number of distinct models to...
Show moreThe magnitude of the overall settlement depends on several variables such as the Compression Index, Cc, and Recompression Index, Cr, which are determined by a consolidation test; however, the test is time consuming and labor intensive. Correlations have been developed to approximate these compressibility indexes. In this study, a data driven approach has been employed in order to estimate Cc and Cr. Support Vector Machines classification is used to determine the number of distinct models to be developed. The statistical models are built through a forward selection stepwise regression procedure. Ten variables were used, including the moisture content (w), initial void ratio (eo), dry unit weight (?dry), wet unit weight (?wet), automatic hammer SPT blow count (N), overburden stress (?), fines content (-200), liquid limit (LL), plasticity index (PI), and specific gravity (Gs). The results confirm the need for separate models for three out of four soil types, these being Coarse Grained, Fine Grained, and Organic Peat. The models for each classification have varying degrees of accuracy. The correlations were tested through a series of field tests, settlement analysis, and comparison to known site settlement. The first analysis incorporates developed correlations for Cr, and the second utilizes measured Cc and Cr for each soil layer. The predicted settlements from these two analyses were compared to the measured settlement taken in close proximity. Upon conclusion of the analyses, the results indicate that settlement predictions applying a rule of thumb equating Cc to Cr, accounting for elastic settlement, and using a conventional influence zone of settlement, compares more favorably to measured settlement than that of predictions using measured compressibility index(s). Accuracy of settlement predictions is contingent on a thorough field investigation.
Show less - Date Issued
- 2018
- Identifier
- CFE0007208, ucf:52284
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007208
- Title
- Factors limiting native species establishment on former agricultural lands.
- Creator
-
Weiler-Lazarz, Annalisa, VonHolle, Mary, Quintana-Ascencio, Pedro, Neill, Christopher, Nickerson, David, University of Central Florida
- Abstract / Description
-
Restoration of abandoned, nonnative species-dominated agricultural lands provides opportunities for conserving declining shrubland and grassland ecosystems. Land-use legacies, such as elevated soil fertility and pH from agricultural amendments, often persist for years and can favor nonnative species at the expense of native species. Understanding the factors that limit native species establishment on abandoned agricultural lands can provide important insights for restoration and conservation...
Show moreRestoration of abandoned, nonnative species-dominated agricultural lands provides opportunities for conserving declining shrubland and grassland ecosystems. Land-use legacies, such as elevated soil fertility and pH from agricultural amendments, often persist for years and can favor nonnative species at the expense of native species. Understanding the factors that limit native species establishment on abandoned agricultural lands can provide important insights for restoration and conservation of native species on human-modified lands. I conducted two field experiments on abandoned agricultural lands: a former pasture on Martha's Vineyard, MA and a former citrus grove at Merritt Island National Wildlife Refuge (MINWR) in Titusville, FL. In these experiments I tested how soil chemical properties affect native and nonnative species abundance and how different methods of removing nonnative, invasive species affect native and nonnative species abundance. In the first experiment, specifically I tested how restoration treatments affect competition between existing nonnative agricultural plant species and native plant species that are targets for sandplain grassland restoration on Martha's Vineyard, MA. At MINWR, I examined how lowering soil fertility with carbon additions and lowering soil pH by applying sulfur affects nonnative species richness and cover (in two former citrus groves that were historically scrub/scrubby flatwoods. Overall, I found that biotic factors, such as competition with nonnative species, play a stronger role in limiting native species establishment than soil chemical properties. Likewise, control of nonnative, invasive species is most effective with mechanical treatments to physically reduce cover, rather than altering soil chemical properties.
Show less - Date Issued
- 2012
- Identifier
- CFE0004323, ucf:49462
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004323
- Title
- Biogeochemical effects of sea level rise-induced transitions within coastal wetlands.
- Creator
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Steinmuller, Havalend, Chambers, Lisa, Hinkle, Ross, Bohlen, Patrick, Beazley, Melanie, University of Central Florida
- Abstract / Description
-
As sea level rise (SLR) affects coastal wetlands, ecosystem responses can include vertical accretion, landward transgression, or submergence. Sea level rise-induced transitions can alter key biogeochemical transformations within wetland soils, impacting the ability of these systems to provide ecosystem services, specifically carbon (C) storage and water quality regulation. Through a series of complementary laboratory and field-based studies, biogeochemical responses to salinity, vegetation...
Show moreAs sea level rise (SLR) affects coastal wetlands, ecosystem responses can include vertical accretion, landward transgression, or submergence. Sea level rise-induced transitions can alter key biogeochemical transformations within wetland soils, impacting the ability of these systems to provide ecosystem services, specifically carbon (C) storage and water quality regulation. Through a series of complementary laboratory and field-based studies, biogeochemical responses to salinity, vegetation shifts, and submergence were investigated. Changes in nutrient dynamics associated with saltwater intrusion were evaluated by artificially adding saline water to different freshwater wetland soil types, indicating that potential exports of critical nutrients (forms of nitrogen, phosphorus, and C) out of freshwater wetland soils is mediated by soil type. A controlled laboratory experiment was conducted to determine the potential degradability of C stored within submerging coastal wetland soils under both aerobic and anaerobic conditions. Under aerobic conditions, 66% more carbon dioxide was produced than under anaerobic conditions and 4x greater carbon dioxide was produced at 90-100cm depths than at the surface. At the same site, the degradability of carbon stores was examined through organic matter fractionation, stable isotopic examination, and determining the abundance of key microbial genes. Both total soil C and stores of bioavailable nutrients increased with depth, while organic matter quality decreased. Finally, the biogeochemical impacts of two separate vegetation transitions occurring co-incidentally with sea level rise were investigated: mangrove encroachment into salt marsh, and more salt- and inundation-tolerant herbaceous encroachment into herbaceous marsh. Conclusions from these studies demonstrate that vegetation transitions alter both soil nutrient storage and fast-cycling nutrient pools, indicating that biogeochemical transitions occur in advance of changes in vegetative species dominance. Results from these chapters holistically address how biogeochemical functioning, specifically nutrient cycling, regulation of water quality, and C sequestration, within coastal wetlands responds to stressors associated with SLR.
Show less - Date Issued
- 2019
- Identifier
- CFE0007536, ucf:52584
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007536
- Title
- Garden Soils: Reviewing the Viability of Soil Phosphate Analyses in the Archaeological Identification of Ancient Maya Kitchen Gardens.
- Creator
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Foster, Cheryl, Chase, Arlen, Chase, Diane, Walker, John, University of Central Florida
- Abstract / Description
-
The study of ancient Maya intensive, intra-site agricultural systems, such as kitchen gardens, has gained new interest in recent years as a valuable way of interpreting numerous aspects of the ancient Maya's daily life (e.g. subsistence and settlement patterns, population growth, diet and nutrition, gender roles). However, while contemporary Maya kitchen gardens can often be easily identified and studied by cultural anthropologists and archaeologists, ancient kitchen gardens are usually much...
Show moreThe study of ancient Maya intensive, intra-site agricultural systems, such as kitchen gardens, has gained new interest in recent years as a valuable way of interpreting numerous aspects of the ancient Maya's daily life (e.g. subsistence and settlement patterns, population growth, diet and nutrition, gender roles). However, while contemporary Maya kitchen gardens can often be easily identified and studied by cultural anthropologists and archaeologists, ancient kitchen gardens are usually much harder to identify by traditional archaeological techniques because of their lack of architectural structures and other identifying features. To compensate for this limitation, various forms of chemical testing (primarily phosphate analysis) are being used to positively identify kitchen gardens and other specific anthropogenically modified spaces that are invisible to standard archaeological techniques. The archaeological community trusts these methods to be a reliable way of testing soils in archaeological sites for specific agricultural features, even though there has been little research conducted to conclusively prove this assertion. In response to this lack of research, this thesis investigates the viability of phosphate analysis and other chemical tests through a comprehensive literary review of previous and current research and an analysis of the data presented within it. While soil phosphate analysis has been used in past and current research to identify general agricultural features with great success, the chemical signatures produced from this method only give vague information about the soil and what was done to it, making soil Phosphate analysis unreliable to definitively discern specific agricultural areas, such as kitchen gardens, from general agricultural areas.
Show less - Date Issued
- 2015
- Identifier
- CFE0005949, ucf:50811
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005949
- Title
- Biogeochemical Cycling and Nutrient Control Strategies for Groundwater at Stormwater Infiltration Basins.
- Creator
-
O'Reilly, Andrew, Chang, Ni-bin, Wanielista, Martin, Chopra, Manoj, Wang, Dingbao, Katz, Brian, University of Central Florida
- Abstract / Description
-
Elevated concentrations of nutrients, particularly nitrate, in groundwater and springs in Florida are a growing resource management concern. Stormwater infiltration basins, which are a common stormwater management practice in the well-drained karst terrain areas of Florida, are a potentially important source of nutrients to the groundwater system because stormwater exits the basin by only evaporation or infiltration. To better understand the biogeochemical processes integrating stormwater...
Show moreElevated concentrations of nutrients, particularly nitrate, in groundwater and springs in Florida are a growing resource management concern. Stormwater infiltration basins, which are a common stormwater management practice in the well-drained karst terrain areas of Florida, are a potentially important source of nutrients to the groundwater system because stormwater exits the basin by only evaporation or infiltration. To better understand the biogeochemical processes integrating stormwater infiltration impacts on groundwater resources in a field-scale setting, a combination of hydrologic, soil chemistry, water chemistry, dissolved and soil gas, isotope, and microbiological data was collected from 2007 through 2010 at two stormwater infiltration basins receiving runoff from predominantly residential watersheds in north-central Florida. Substantially different biogeochemical processes affecting nitrogen fate and transport were observed beneath the two stormwater infiltration basins. Differences are related to soil textural properties that deeply link hydroclimatic conditions with soil moisture variations in a humid, subtropical climate. During 2008, shallow groundwater beneath the basin with predominantly clayey soils (median 41% silt+clay content) exhibited decreases in dissolved oxygen from 3.8 to 0.1 mg/L and decreases in nitrate-nitrogen from 2.7 mg/L to less than 0.016 mg/L, followed by manganese and iron reduction, sulfate reduction, and methanogenesis. In contrast, beneath the basin with predominantly sandy soils (median 2% silt+clay content), aerobic conditions persisted from 2007 through 2009 (dissolved oxygen of 5.0(-)7.8 mg/L), resulting in nitrate-nitrogen of 1.3(-)3.3 mg/L in shallow groundwater. Soil extractable nitrate-nitrogen was significantly lower and the copper-containing nitrite reductase gene density was significantly higher beneath the clayey basin. Differences in moisture retention capacity between fine- and coarse-textured soils resulted in median volumetric gas-phase contents of 0.04 beneath the clayey basin and 0.19 beneath the sandy basin, inhibiting surface/subsurface oxygen exchange beneath the clayey basin. Subsurface biogeochemical processes at the clayey stormwater infiltration basin were further analyzed to better understand the effects of the highly variable hydrologic conditions common in humid, subtropical climates. Cyclic variations in biogeochemical processes generally coincided with wet and dry hydroclimatic conditions. Oxidizing conditions in the subsurface persisted for about one month or less at the beginning of wet periods with dissolved oxygen and nitrate showing similar temporal patterns. Reducing conditions in the subsurface evolved during prolonged flooding of the basin. At about the same time oxygen and nitrate reduction concluded, manganese, iron, and sulfate reduction began, with the onset of methanogenesis one month later. Reducing conditions persisted up to six months, continuing into subsequent dry periods until the next major oxidizing infiltration event. Evidence of denitrification in shallow groundwater at the site is supported by median nitrate-nitrogen less than 0.016 mg/L, excess nitrogen gas up to 3 mg/L progressively enriched in delta-15N during prolonged basin flooding, and isotopically heavy delta-15N and delta-18O of nitrate (up to 25 and 15 per mil, respectively). Isotopic enrichment of newly infiltrated stormwater suggests denitrification was partially completed within two days. Soil and water chemistry data suggest a biogeochemically active zone exists in the upper 1.4 m of soil, where organic carbon was the likely electron donor supplied by organic matter in soil solids or dissolved in infiltrating stormwater. The cyclic nature of reducing conditions effectively controlled the nitrogen cycle, switching nitrogen fate beneath the basin from nitrate leaching to reduction in the shallow saturated zone. Soil beneath the sandy stormwater infiltration basin was amended using biosorption activated media (BAM) to study the effectiveness of this technology in reducing inputs of nitrogen and phosphorus to groundwater. The functionalized soil amendment BAM consists of a 1.0:1.9:4.1 mixture (by volume) of tire crumb (to increase sorption capacity), silt and clay (to increase soil moisture retention), and sand (to promote sufficient infiltration), which was applied to develop an innovative best management practice (BMP) utilizing nutrient reduction and flood control sub-basins. Construction and materials costs, excluding profit and permit fees, for the innovative BMP were about $US 65 per square meter of basin bottom. Comparison of nitrate/chloride ratios for the shallow groundwater indicate that prior to using BAM, nitrate concentrations were substantially influenced by nitrification or variations in nitrate input. In contrast, for the new basin utilizing BAM, nitrate/chloride ratios indicate minor nitrification and nitrate losses with the exception of one summer sample that indicated a 45% loss. Biogeochemical indicators (denitrifier activity derived from real-time polymerase chain reaction and variations in major ions, nutrients, dissolved and soil gases, and stable isotopes) suggest nitrate losses are primarily attributable to denitrification, whereas dissimilatory nitrate reduction to ammonium and plant uptake are minor processes. Denitrification was likely occurring intermittently in anoxic microsites in the unsaturated zone, which was enhanced by increased soil moisture within the BAM layer and resultant reductions in surface/subsurface oxygen exchange that produced conditions conducive to increased denitrifier activity. Concentrations of total dissolved phosphorus and orthophosphate were reduced by more than 70% in unsaturated zone soil water, with the largest decreases in the BAM layer where sorption was the most likely mechanism for removal. Post-BAM orthophosphate/chloride ratios for shallow groundwater indicate predominantly minor increases and decreases in orthophosphate with the exception of one summer sample that indicated a 50% loss. Differences in nutrient variations between the unsaturated zone and shallow groundwater may be the result of the intensity and duration of nutrient removal processes and mixing ratios with water that had undergone little biogeochemical transformation. In order to quantify potential processes leading to observed nitrogen losses beneath the innovative BMP, an integrated infiltration basin(-)nitrogen reduction (IBNR) system dynamics model was developed. Based on two simulation periods, the IBNR model indicated denitrification accounted for a loss of about one-third of the total dissolved nitrogen mass inflow and was occurring predominantly in the BAM layer. The IBNR model results in combination with the field-based biogeochemical assessment demonstrated that the innovative BMP using the functionalized soil amendment BAM is a promising passive, economical, stormwater nutrient-treatment technology. Further field- and laboratory-scale research on the long-term sustainability of nutrient losses and further elucidation of causative physicochemical and biogeochemical mechanisms would contribute to improved BAM performance and green infrastructure development in the future.
Show less - Date Issued
- 2012
- Identifier
- CFE0004419, ucf:49391
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004419
- Title
- A COMPARISON OF LOAD TEST DATA AND PREDICTED BEHAVIOR OF AUGERCAST PILES IN LAYERED SOILS.
- Creator
-
Hudson, John, Kuo, Shiou-San, University of Central Florida
- Abstract / Description
-
The use of auger cast-in-place (ACIP) pilings is very common in Florida; however, there is a significant degree of uncertainty in determining the actual capacity of the pilings, especially when the pilings are installed through layers of cohesive soils. Therefore, there is a need to improve upon the existing methods of predicting the behavior of ACIP piles in layered soils. As a result, the primary objective of this study is to determine if a significant difference exists between the accepted...
Show moreThe use of auger cast-in-place (ACIP) pilings is very common in Florida; however, there is a significant degree of uncertainty in determining the actual capacity of the pilings, especially when the pilings are installed through layers of cohesive soils. Therefore, there is a need to improve upon the existing methods of predicting the behavior of ACIP piles in layered soils. As a result, the primary objective of this study is to determine if a significant difference exists between the accepted methods of pile load test analysis. Provided a significant difference is noted, the secondary objective would be to determine if an improvement could be made to enhance the existing empirical relationships used to predict pile behavior in layered soils. In order to accomplish these objectives, this study presents an evaluation of some of the most commonly used methods for predicting ACIP pile capacity based upon the results of actual field load tests. Data from twenty-five load tests were analyzed using popular methods and statistical analyses were preformed to determine and evaluate the data. These evaluations were utilized to explore correlations between predicted behavior and actual results. Based upon the results of this study, there is no statistically significant difference between the load test analyses methods examined. As a result, no improvement to the existing methods of predicting ACIP pile behavior in layered soils may be recommended at this time, and further research in this subject matter is recommended.
Show less - Date Issued
- 2008
- Identifier
- CFE0002300, ucf:47831
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0002300
- Title
- DEVELOPMENT OF DAILY, MONTHLY, INTER-ANNUAL, AND MEAN ANNUAL HYDROLOGICAL MODELS BASED ON A UNIFIED RUNOFF GENERATION FRAMEWORK.
- Creator
-
Kheimi, Marwan, Wang, Dingbao, Wahl, Thomas, Singh, Arvind, Zheng, Qipeng, University of Central Florida
- Abstract / Description
-
The main goal of this dissertation develops a unified model structure for runoff generation based on observations from a large number of catchments. Furthermore, obtaining a comprehensive understanding of the physical controlling factors that control daily, monthly, and annual water balance models. Meanwhile, applying the developed Unified model on different climate conditions, and comparing it with different well-known models.The proposed model was compared with a similar timescale model ...
Show moreThe main goal of this dissertation develops a unified model structure for runoff generation based on observations from a large number of catchments. Furthermore, obtaining a comprehensive understanding of the physical controlling factors that control daily, monthly, and annual water balance models. Meanwhile, applying the developed Unified model on different climate conditions, and comparing it with different well-known models.The proposed model was compared with a similar timescale model (HyMOD, and abcd) and applied on 92 catchments from MOPEX dataset across the United States. The HyMOD and abcd are a well-known daily and monthly hydrological model used on a variety of researchers. The differences between the new model and HyMOD, and abcd include 1) the distribution function for soil water storage capacity is different and the new distribution function leads to the SCS curve number method; and 2) the computation of evaporation is also based on the distribution function considering the spatial variability of available water evaporation. The performance of all models along with parameters used is examined to understand the controlling factors. The generated results were calibrated and validated using the Nash-Sutcliffe efficiency coefficient (NSE), indicating that the Unified model has a moderate better performance against the HyMOD at a daily time scale, and abcd model at a monthly timescale. The proposed model using the SCS-CN method shows the effect of improving the performance.
Show less - Date Issued
- 2019
- Identifier
- CFE0007478, ucf:52684
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0007478
- Title
- Use of an Activated Magnesium/cosolvent System for the Desorption and Degradation of Polycyclic Aromatic Hydrocarbons and Their Oxygenated Derivatives in Contaminated Soils.
- Creator
-
Elie, Marc, Yestrebsky, Cherie, Clausen, Christian, Elsheimer, Seth, Campiglia, Andres, Randall, Andrew, University of Central Florida
- Abstract / Description
-
The contamination of soils, with polycyclic aromatic hydrocarbons (PAHs), remains a widespread environmental concern. In the past two decades, many physical, chemical and biological methods have been developed and evaluated for the degradation of PAHs. However, due to their low aqueous solubility, high sorption affinity, hydrophobicity and recalcitrance, the environmental remediation of PAHs in soil continues to be economically challenging. In addition to PAH contamination, the presence of...
Show moreThe contamination of soils, with polycyclic aromatic hydrocarbons (PAHs), remains a widespread environmental concern. In the past two decades, many physical, chemical and biological methods have been developed and evaluated for the degradation of PAHs. However, due to their low aqueous solubility, high sorption affinity, hydrophobicity and recalcitrance, the environmental remediation of PAHs in soil continues to be economically challenging. In addition to PAH contamination, the presence of oxygenated derivatives of PAHs (OPAHs), in soils, has increasingly become a concern due to their greater toxic properties compared to parent PAH compounds. To date, no investigations on OPAH-remediation methods have been presented in the literature. The use of zero-valent metals (ZVMs) has been reported for several halogenated contaminants in solution systems, but the effectiveness of ZVM to degrade sorbed PAHs and OPAHs has been rarely addressed. This present research focuses on the development of a combined technique for the feasible desorption and degradation of PAHs and OPAHs in soils. PAH and OPAH degradation efficiency, using activated magnesium (Mg) metal combined with an ethanol-ethyl lactate cosolvent (1:1 ratio), was initially examined in soil-free systems. This metal/cosolvent system demonstrated adequate degradation (above 80%) for high-molecular-weight (HMW) PAHs, which were subsequently converted into hydroaromatic compounds; while OPAHs were degraded and converted into hydroxylated or hydrogenated derivatives. Further soil-free studies revealed that the degradation rate was affected by the surface or reactive sites of the metal and that optimum degradation efficiency were obtained with Mg ball milled with graphite (Mg/C).In a bench-scale feasibility test, the efficacy of this system was assessed on a soil spiked with a mixture of three HMW PAHs compounds and three OPAHs compounds with amounts ranging from 0.033 mmol to 0.060 mmol. The experimental results show that 2 mL of an ethanol-ethyl lactate solvent mixture resulted in 58% to 85% extraction efficiency for the selected contaminants in 1 g of spiked soil, followed by 64 - 87% degradation efficiency of the extracted contaminants with 4.11 mmol of the activated metal. This activated-Mg/cosolvent system can be considered as a promising alternative method for ex situ remediation of PAH and OPAH-contaminated soils.
Show less - Date Issued
- 2012
- Identifier
- CFE0004533, ucf:49259
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004533
- Title
- NUMERICAL COMPUTATIONS FOR PDE MODELS OF ROCKET EXHAUST FLOW IN SOIL.
- Creator
-
Brennan, Brian, Moore, Brian, University of Central Florida
- Abstract / Description
-
We study numerical methods for solving the nonlinear porous medium and Navier-Lame problems. When coupled together, these equations model the flow of exhaust through a porous medium, soil, and the effects that the pressure has on the soil in terms of spatial displacement. For the porous medium equation we use the Crank-Nicolson time stepping method with a spectral discretization in space. Since the Navier-Lame equation is a boundary value problem, it is solved using a finite element method...
Show moreWe study numerical methods for solving the nonlinear porous medium and Navier-Lame problems. When coupled together, these equations model the flow of exhaust through a porous medium, soil, and the effects that the pressure has on the soil in terms of spatial displacement. For the porous medium equation we use the Crank-Nicolson time stepping method with a spectral discretization in space. Since the Navier-Lame equation is a boundary value problem, it is solved using a finite element method where the spatial domain is represented by a triangulation of discrete points. The two problems are coupled by using approximations of solutions to the porous medium equation to define the forcing term in the Navier-Lame equation. The spatial displacement solutions can be used to approximate the strain and stress imposed on the soil. An analysis of these physical properties shows whether or not the material ceases to act as an elastic material and instead behaves like a plastic which will tell us if the soil has failed and a crater has formed. Analytical as well as experimental tests are used to find a good balance for solving the porous medium and Navier-Lame equations both accurately and efficiently.
Show less - Date Issued
- 2010
- Identifier
- CFE0003217, ucf:48565
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0003217
- Title
- Investigation of a Novel Magnesium and Acidified Ethanol System for the Degradation of Persistent Organic Pollutants.
- Creator
-
Maloney, Phillip, Yestrebsky, Cherie, Clausen, Christian, Elsheimer, Seth, Frazer, Andrew, Quinn, Jacqueline, University of Central Florida
- Abstract / Description
-
For centuries chemists have sought to improve humankind's quality of life and address many of society's most pressing needs through the development of chemical processes and synthesis of new compounds, often with phenomenal results. Unfortunately, there also are many examples where these chemicals have had unintended, detrimental consequences that are not apparent until years or decades after their initial use. There are numerous halogenated molecules in this category that are globally...
Show moreFor centuries chemists have sought to improve humankind's quality of life and address many of society's most pressing needs through the development of chemical processes and synthesis of new compounds, often with phenomenal results. Unfortunately, there also are many examples where these chemicals have had unintended, detrimental consequences that are not apparent until years or decades after their initial use. There are numerous halogenated molecules in this category that are globally dispersed, resistant to natural degradation processes, bioaccumulative, and toxic to living organisms. Chemicals such as these are classified as persistent organic pollutants (POPs), and due to their negative environmental and health effects, they require safe, effective, and inexpensive means of remediation.This research focuses on the development and optimization of a reaction matrix capable of reductively dehalogenating several POPs. Initial experiments determined that powdered magnesium and 1% V/V acetic acid in absolute ethanol was the most effective system for degrading polychlorinated biphenyl (PCB), an extraordinarily recalcitrant environmental contaminant. Further studies showed that this matrix also was capable of degrading polychlorinated dibenzo-p-dioxins (PCDDs), polybrominated diphenyl ethers (PBDEs), and four organochlorine pesticides (OCPs); dieldrin, heptachlor, heptachlor epoxide, and chlordane. During this phase of testing, field samples contaminated with chlordane were washed with ethanol and this ethanol/chlordane solution was degraded using the same reaction matrix, thereby demonstrating this technology's potential for (")real-world(") remediation projects. Finally, a set of experiments designed to provide some insight into the mechanism of dechlorination seems to indicate that two distinct processes are necessary for degradation to occur. First, the passivated outer layer of the magnesium must be removed in order to expose the zero-valent magnesium core. Next, an electron is transferred from the magnesium to the target molecule, causing the cleavage of the halide bond and the subsequent abstraction of either a hydrogen or proton from a solvent molecule. It is anticipated that an understanding of these fundamental chemical processes will allow this system to be tailored to a wide range of complex environmental media.
Show less - Date Issued
- 2013
- Identifier
- CFE0005109, ucf:50723
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005109
- Title
- Analytical And Experimental Study Of Monitoring For Chain-Like Nonlinear Dynamic Systems.
- Creator
-
Paul, Bryan, Yun, Hae-Bum, Catbas, Fikret, Chopra, Manoj, University of Central Florida
- Abstract / Description
-
Inverse analysis of nonlinear dynamic systems is an important area of research in the ?eld of structural health monitoring for civil engineering structures. Structural damage usually involves localized nonlinear behaviors of dynamic systems that evolve into different classes of nonlinearity as well as change system parameter values. Numerous parametric modal analysis techniques (e.g., eigensystem realization algorithm and subspace identification method) have been developed for system...
Show moreInverse analysis of nonlinear dynamic systems is an important area of research in the ?eld of structural health monitoring for civil engineering structures. Structural damage usually involves localized nonlinear behaviors of dynamic systems that evolve into different classes of nonlinearity as well as change system parameter values. Numerous parametric modal analysis techniques (e.g., eigensystem realization algorithm and subspace identification method) have been developed for system identification of multi-degree-of-freedom dynamic systems. However, those methods are usually limited to linear systems and known for poor sensitivity to localized damage. On the other hand, non-parametric identification methods (e.g., artificial neural networks) are advantageous to identify time-varying nonlinear systems due to unpredictable damage. However, physical interpretation of non-parametric identification results is not as straightforward as those of the parametric methods. In this study, the Multidegree-of-Freedom Restoring Force Method (MRFM) is employed as a semi-parametric nonlinear identification method to take the advantages of both the parametric and non-parametric identification methods.The MRFM is validated using two realistic experimental nonlinear dynamic tests: (i) large-scale shake table tests using building models with different foundation types, and (ii) impact test using wind blades. The large-scale shake table test was conducted at Tongji University using 1:10 scale 12-story reinforced concrete building models tested on three different foundations, including pile, box and fixed foundation. The nonlinear dynamic signatures of the building models collected from the shake table tests were processed using MRFM (i) to investigate the effects of foundation types on nonlinear behavior of the superstructure and (ii) to detect localized damage during the shake table tests. Secondly, the MRFM was applied to investigate the applicability of this method to wind turbine blades. Results are promising, showing a high level of nonlinearity of the system and how the MRFM can be applied to wind-turbine blades. Future studies were planned for the comparison of physical characteristic of this blade with blades created made of other material.
Show less - Date Issued
- 2013
- Identifier
- CFE0004734, ucf:49818
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004734
- Title
- Magnesium and Acidified Ethanol Based Treatment Systems for the Extraction and Dechlorination of Polychlorinated Biphenyls from Contaminated Oils, Paints, and Soils.
- Creator
-
Novaes-Card, Simone, Yestrebsky, Cherie, Clausen, Christian, Elsheimer, Seth, Frazer, Andrew, Duranceau, Steven, University of Central Florida
- Abstract / Description
-
Polychlorinated biphenyls (PCBs) are a class of environmentally persistent halogenated organic compounds that were once used as stabilizers to improve the properties of a variety of materials such as lubricants, heat transfer fluids, paints, and caulking materials. PCBs are also capable of migration through processes such as spillage into soils, leaching into groundwater, and volatilization into the atmosphere. Although banned in 1979 over health concerns, PCBs persist in these materials to...
Show morePolychlorinated biphenyls (PCBs) are a class of environmentally persistent halogenated organic compounds that were once used as stabilizers to improve the properties of a variety of materials such as lubricants, heat transfer fluids, paints, and caulking materials. PCBs are also capable of migration through processes such as spillage into soils, leaching into groundwater, and volatilization into the atmosphere. Although banned in 1979 over health concerns, PCBs persist in these materials to this day because they are resistant to biotic degradation and natural weathering processes. The wide variety of contaminated materials means that many existing treatment options cannot be used across all media. This research focuses on the adaptation of a reductive dehalogenation system for dechlorination of PCBs from machine oils, paints, sludges, and soils. The system utilizes magnesium, glacial acetic acid, and ethanol in order to remove the chlorine atoms from the biphenyl backbone, which is less toxic and can be broken down biotically.A treatment plan was devised for machine oil contaminated with PCBs, involving sorption of PCBs onto a column of super activated alumina followed by desorption into hexane and treatment of the hexane with magnesium and acidified ethanol to dechlorinate the PCBs. In a small-scale study, 98.5% of PCBs from an oil sample were sorbed to the column, and the PCBs that were subsequently desorbed were dechlorinated to below detectable levels within one day of magnesium and acidified ethanol treatment. Information from small-scale studies was used to design larger sorption columns intended for use at a field site.A field study was conducted to compare the effectiveness of two different treatment system pastes at removing PCBs from painted surfaces. These pastes were formulated with bulking and viscosity control agents in order to cling to vertical surfaces, and contained either acidified ethanol and magnesium (Activated Metal Treatment System, AMTS) or acidified ethanol only (Non-Metal Treatment System, NMTS). AMTS was capable of 64.8% average removal of PCBs from paint, while NMTS demonstrated 89.5% average removal but required a second step to dechlorinate the extracted PCBs. This system allows for treatment of surfaces without demolishing the structure. AMTS was also studied for in situ dechlorination of PCBs in soils, and NMTS enclosed in a polyethylene barrier was studied for extraction of PCBs from sludges.A two-step system was devised for the ex situ treatment of PCB-contaminated soils. Solvent extraction with ethanol or an ethanol/ethyl lactate cosolvent is followed by dechlorination using magnesium and glacial acetic acid. Studies included the optimization of extraction solvent, cosolvent ratio, cost, and reuse of magnesium or extraction solvent. Surface analysis of magnesium particles used in dechlorination showed a precipitate occluding part of the surface, which was thought to be a combination of magnesium ethoxide and magnesium hydroxide. This precipitate is thought to come from the reaction of magnesium ethoxide formed during the PCB dechlorination process with pore water extracted from the soil.
Show less - Date Issued
- 2013
- Identifier
- CFE0005222, ucf:50630
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0005222
- Title
- Effluent Water Quality Improvement Using Silt Fences and Stormwater Harvesting.
- Creator
-
Gogo-Abite, Ikiensinma, Chopra, Manoj, Wanielista, Martin, Nam, Boo Hyun, Weishampel, John, University of Central Florida
- Abstract / Description
-
Construction sites are among the most common areas to experience soil erosion and sediment transport due to the mandatory foundation tasks such as excavation and land grubbing. Thus, temporary sediment barriers are installed along the perimeter to prevent sediment transport from the site. Erosion and sediment transport control measures may include, but not limited to, physical and chemical processes such as the use of a silt fence and polyacrylamide product. Runoff from construction sites and...
Show moreConstruction sites are among the most common areas to experience soil erosion and sediment transport due to the mandatory foundation tasks such as excavation and land grubbing. Thus, temporary sediment barriers are installed along the perimeter to prevent sediment transport from the site. Erosion and sediment transport control measures may include, but not limited to, physical and chemical processes such as the use of a silt fence and polyacrylamide product. Runoff from construction sites and other impervious surfaces are routinely discharged into ponds for treatment before being released into a receiving water body. Stormwater harvesting from a pond for irrigation of adjacent lands is promoted as one approach to reducing pond discharge while supplementing valuable potable water used for irrigation. The reduction of pond discharge reduces the mass of pollutants in the discharge. In the dissertation, presented is the investigation of the effectiveness of temporary sediment barriers and then, development of a modeling approach to a stormwater harvesting pond to provide a comprehensive stormwater management pollution reduction assessment tool.The first part of the research presents the investigation of the performance efficiencies of silt fence fabrics in turbidity and sediment concentration removal, and the determination of flow-through-rate on simulated construction sites in real time. Two silt fence fabrics, (1) woven and the other (2) nonwoven were subjected to material index property tests and a series of field-scale tests with different rainfall intensities and events for different embankment slopes on a tilting test-bed. Collected influent and effluent samples were analyzed for sediment concentration and turbidity, and the flow-through-rate for each fabric was evaluated. Test results revealed that the woven and nonwoven silt fence achieved 11 and 56 percent average turbidity reduction efficiency, respectively. Each fabric also achieved 20 and 56 percent average sediment concentration removal efficiency, respectively. Fabric flow-through-rates were functions of the rainfall intensity and embankment slope. The nonwoven fabric exhibited higher flow-through-rates than the woven fabric in both field-scale and laboratory tests.In the second part of the study, a Stormwater Harvesting and Assessment for Reduction of Pollution (SHARP) model was developed to predict operation of wet pond used for stormwater harvesting. The model integrates the interaction of surface water and groundwater in a catchment area. The SHARP model was calibrated and validated with actual pond water elevation data from a stormwater pond at Miramar Lakes, Miramar, Florida. Model evaluation showed adequate prediction of pond water elevation with root mean square error between 0.07 and 0.12 m; mean absolute error was between 0.018 and 0.07 m; and relative index of agreement was between 0.74 and 0.98 for both calibration and validation periods. The SHARP model is capable of assessing harvesting safe-yield and discharge from a pond, including the prediction of the percentage of runoff into a harvesting pond that is not discharged.The combination of silt fence and/or polyacrylamide PAM before stormwater harvesting pond in a treatment train for the reduction of pollutants from construction sites has the potential of significantly exceeding a performance standard of 85 percent reduction typically required by local authorities. In fact, the stringent requirement of equaling pre- and post-development pollutant loading is highly achievable by the treatment train approach. The significant contribution from the integration of the SHARP model to the treatment train is that real-time assessment of pollutant loading reduction by volume can be planned and controlled to achieve target performance standards.
Show less - Date Issued
- 2012
- Identifier
- CFE0004539, ucf:49244
- Format
- Document (PDF)
- PURL
- http://purl.flvc.org/ucf/fd/CFE0004539