Current Search: storage (x)
Pages
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Title
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Freestanding Holey Thin Films for Renewable Energy Storage.
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Creator
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Marcus, Kyle, Yang, Yang, Zhai, Lei, Dong, Yajie, University of Central Florida
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Abstract / Description
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The rapid advancement of portable and wearable technologies has challenged research to improve upon current renewable battery energy storage systems. By using nanotechnology, it is now possible to access more of the energy storage theoretical values that have been unattainable thus far. We have developed a method to create freestanding holey thin films through combinations of electrochemical and chemical vapor deposition (CVD) techniques to be used in renewable energy storage systems....
Show moreThe rapid advancement of portable and wearable technologies has challenged research to improve upon current renewable battery energy storage systems. By using nanotechnology, it is now possible to access more of the energy storage theoretical values that have been unattainable thus far. We have developed a method to create freestanding holey thin films through combinations of electrochemical and chemical vapor deposition (CVD) techniques to be used in renewable energy storage systems. Freestanding thin films promote excellent contact between the residual conductive framework and any functionalized active component specific to the designed material. Without requiring any other additives, the as-prepared freestanding thin films can be mechanically and chemically tuned to allow for use in a wide range of applications. Incorporation of micro- and nano-sized holey structures dramatically enhances the electrochemically active surface area, which is essential for facilitating appropriate reactions in conversion type energy storage systems. Combining the freestanding and holey components with an active layer effectively enhances conductivity and reduces the electron transfer distance at the electrode-electrolyte interface. Herein, two separately designed freestanding holey thin films were successfully used as cathode materials for lithium-sulfur battery (Li-S) and magnesium-ion battery (MIB) energy storage systems.
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Date Issued
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2017
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Identifier
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CFE0007127, ucf:52304
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007127
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Title
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Propagation of Unit Location Uncertainty in Dense Storage Environments.
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Creator
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Reilly, Patrick, Pazour, Jennifer, Zheng, Qipeng, Schneider, Kellie, University of Central Florida
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Abstract / Description
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Effective space utilization is an important consideration in logistics systems and is especially important in dense storage environments. Dense storage systems provide high-space utilization; however, because not all items are immediately accessible, storage and retrieval operations often require shifting of other stored items in order to access the desired item, which results in item location uncertainty when asset tracking is insufficient. Given an initial certainty in item location, we use...
Show moreEffective space utilization is an important consideration in logistics systems and is especially important in dense storage environments. Dense storage systems provide high-space utilization; however, because not all items are immediately accessible, storage and retrieval operations often require shifting of other stored items in order to access the desired item, which results in item location uncertainty when asset tracking is insufficient. Given an initial certainty in item location, we use Markovian principles to quantify the growth of uncertainty as a function of retrieval requests and discover that the steady state probability distribution for any communicating class of storage locations approaches uniform. Using this result, an expected search time model is developed and applied to the systems analyzed. We also develop metrics that quantify and characterize uncertainty in item location to aid in understanding the nature of that uncertainty. By incorporating uncertainty into our logistics model and conducting numerical experiments, we gain valuable insights into the uncertainty problem such as the benefit of multiple item copies in reducing expected search time and the varied response to different retrieval policies in otherwise identical systems.
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Date Issued
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2015
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Identifier
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CFE0006052, ucf:50972
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0006052
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Title
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METADATA AND DATA MANAGEMENT IN HIGH PERFORMANCE FILE AND STORAGE SYSTEMS.
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Creator
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Gu, Peng, Wang, Jun, University of Central Florida
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Abstract / Description
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With the advent of emerging "e-Science" applications, today's scientific research increasingly relies on petascale-and-beyond computing over large data sets of the same magnitude. While the computational power of supercomputers has recently entered the era of petascale, the performance of their storage system is far lagged behind by many orders of magnitude. This places an imperative demand on revolutionizing their underlying I/O systems, on which the management of both metadata and data...
Show moreWith the advent of emerging "e-Science" applications, today's scientific research increasingly relies on petascale-and-beyond computing over large data sets of the same magnitude. While the computational power of supercomputers has recently entered the era of petascale, the performance of their storage system is far lagged behind by many orders of magnitude. This places an imperative demand on revolutionizing their underlying I/O systems, on which the management of both metadata and data is deemed to have significant performance implications. Prefetching/caching and data locality awareness optimizations, as conventional and effective management techniques for metadata and data I/O performance enhancement, still play their crucial roles in current parallel and distributed file systems. In this study, we examine the limitations of existing prefetching/caching techniques and explore the untapped potentials of data locality optimization techniques in the new era of petascale computing. For metadata I/O access, we propose a novel weighted-graph-based prefetching technique, built on both direct and indirect successor relationship, to reap performance benefit from prefetching specifically for clustered metadata serversan arrangement envisioned necessary for petabyte scale distributed storage systems. For data I/O access, we design and implement Segment-structured On-disk data Grouping and Prefetching (SOGP), a combined prefetching and data placement technique to boost the local data read performance for parallel file systems, especially for those applications with partially overlapped access patterns. One high-performance local I/O software package in SOGP work for Parallel Virtual File System in the number of about 2000 C lines was released to Argonne National Laboratory in 2007 for potential integration into the production mode.
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Date Issued
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2008
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Identifier
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CFE0002251, ucf:47826
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002251
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Title
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Polyelectrolyte complexes based on poly(acrylic acid): mechanics and applications.
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Creator
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Lu, Xiaoyan, Zhai, Lei, Zou, Shengli, Chumbimuni Torres, Karin, Kolpashchikov, Dmitry, Dong, Yajie, University of Central Florida
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Abstract / Description
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Poly(acrylic acid) (PAA) is a weak polyelectrolyte presenting negative charge at basic conditionwhen the carboxylic group loses a proton. These carboxylate group can interact with polycationsand metal ions to form stable polyelectrolyte complexes (PECs), leading to tunable propertiesand multifunctional nanoscale structures through chemical reactions. This research focuses onnanofiber and nanoparticle fabricated by PAA-based PECs. We demonstrated the effect of ferricion concentration on the...
Show morePoly(acrylic acid) (PAA) is a weak polyelectrolyte presenting negative charge at basic conditionwhen the carboxylic group loses a proton. These carboxylate group can interact with polycationsand metal ions to form stable polyelectrolyte complexes (PECs), leading to tunable propertiesand multifunctional nanoscale structures through chemical reactions. This research focuses onnanofiber and nanoparticle fabricated by PAA-based PECs. We demonstrated the effect of ferricion concentration on the mechanical properties of PAA-based single naonofiber by using dark fieldmicroscopy imaging and persistence length analysis. The application of PAA-based nanofibermats loaded with MnO2 for supercapacitors was also explored. As a free-standing and flexiblesupercapacitor electrode, the nanofiber mat exhibited outstanding properties including high specificcapacitance, excellent reversible redox reactions, and fast charge/discharge ability. Since PAA is abiocompatible polymer, PAA-based PEC was applied as a drug-carrier in a drug delivery system.In this project, core-shell nanoparticles were fabricated with chitosan as the core and PAA as theshell to incorporate with the drug gemcitabine. Several parameters were investigated to obtainthe optimal nanoparticle size. The as-prepared drug delivery system shows prolonged releasingprofile.
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Date Issued
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2018
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Identifier
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CFE0007045, ucf:52004
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007045
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Title
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Large Scale Cryogenic Storage With Active Refrigeration.
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Creator
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Swanger, Adam, Chow, Louis, Kapat, Jayanta, Notardonato, William, University of Central Florida
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Abstract / Description
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Storage and transfer of cryogenic liquefied gases on volume scales from under 10 liters for lab use, up to hundreds of millions of liters for industrial applications is of paramount importance across a vast range of industries. Traditionally, these commodities have been stored at or near the normal boiling point due to relative ease of operation and safety-related considerations; however, this also means that some percentage will always be lost due to environmental heat leaking into the...
Show moreStorage and transfer of cryogenic liquefied gases on volume scales from under 10 liters for lab use, up to hundreds of millions of liters for industrial applications is of paramount importance across a vast range of industries. Traditionally, these commodities have been stored at or near the normal boiling point due to relative ease of operation and safety-related considerations; however, this also means that some percentage will always be lost due to environmental heat leaking into the vessel and causing boiloff. These losses become more concerning as scales increase, and are of particular importance for high-cost commodities such helium and hydrogen. Additionally, the normal boiling point has typically marked the highest liquid density achievable, which became a strong driver of end-use system designs such as space launch vehicles. Recent development and testing of an Integrated Refrigeration and Storage (IRAS) system for liquid hydrogen has proven that next generation cryogenic storage operations such as zero boiloff and densification are feasible on a large scale. This IRAS system married an 850 Watt at 20 Kelvin reverse-Brayton cycle commercial cryogenic refrigerator with a 125,000 liter LH2 storage tank via an internal tubular heat exchanger; thereby allowing heat to be removed directly from the hydrogen, and by extension, providing a means to control the bulk thermodynamic state. Tests of zero boiloff, in-situ liquefaction, and densification down to the triple point were performed, and data including fluid temperature profiles and tank pressure were gathered. Details regarding the design, setup, and testing of the IRAS system are discussed herein, and the data are used to anchor various physics models created to predict the behavior of the system during both transient and steady state operations. Hopefully these efforts will provide a useful basis for the design and implementation of future large scale IRAS systems across numerous industries.
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Date Issued
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2018
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Identifier
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CFE0007588, ucf:52530
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007588
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Title
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ASSESSMENT OF AQUIFER STORAGE AND RECOVERY IMPACT ON PHOSPHORUS STABILITY IN LAKE SEDIMENT.
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Creator
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Liu, Sha, Chang, Ni-bin, University of Central Florida
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Abstract / Description
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Lake Okeechobee, the second largest natural freshwater lake in the United States, had experienced a historical drought in 2007-2008 and the inflow to Lake Okeechobee has been reduced by 40% of the average daily mean between warm phase and cold phase due to the impact of Atlantic Multidecadal Oscillation in the past six decades. To cope with this water resources management problem, the US Army Corps of Engineers (USACE) proposed the largest national implementation plan of aquifer storage and...
Show moreLake Okeechobee, the second largest natural freshwater lake in the United States, had experienced a historical drought in 2007-2008 and the inflow to Lake Okeechobee has been reduced by 40% of the average daily mean between warm phase and cold phase due to the impact of Atlantic Multidecadal Oscillation in the past six decades. To cope with this water resources management problem, the US Army Corps of Engineers (USACE) proposed the largest national implementation plan of aquifer storage and recovery (ASR) project in the Kissimmee River Basin. Routine operation of ASR will deliver recovered water from ASR wells into the lake with different water quality parameters resulting in some concerns about the phosphorus stability issues at the sediment bed, which may lead to eutrophication problems. To explore the potential impacts of ASR operation on phosphorus stability in terms of adsorption, desorption, and diffusion processes, this research presented a systematic assessment based on five different mixing ratios between ASR water and lake water, and explored the sensitivity with respect to the chemical equilibrium between lake water and ASR water to predict the phosphorus stability changes in lake sediment. A series of lab-scale batch and column tests in support of a mechanistic modeling analysis provided a holistic chemical assessment as to how the phosphorus stability may be influenced by different mixing ratios. It led to an observation that the ratio of 1:10 between ASR water and lake water proved to be an optical ratio to avoid eutrophication and bring ecological benefits based on a suite of criteria.
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Date Issued
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2010
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Identifier
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CFE0003277, ucf:48527
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003277
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Title
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VARIABILITY OF CARBON STOCK IN FLORIDA FLATWOODS ECOSYSTEMS UNDERGOING RESTORATION AND MANAGEMENT.
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Creator
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Becker, Kathryn, Hinkle, C. Ross, University of Central Florida
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Abstract / Description
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The global community is struggling with mitigating the effects of widespread habitat loss and degradation; the effects of which are being further magnified in the face of global climate change. Quality natural habitat is becoming increasingly limited and atmospheric carbon levels continue to rise. Therefore, land managers responsible for multiuse management are often faced with the dilemma of managing ecosystems for biodiversity, as well as optimizing ecosystem services such as carbon storage...
Show moreThe global community is struggling with mitigating the effects of widespread habitat loss and degradation; the effects of which are being further magnified in the face of global climate change. Quality natural habitat is becoming increasingly limited and atmospheric carbon levels continue to rise. Therefore, land managers responsible for multiuse management are often faced with the dilemma of managing ecosystems for biodiversity, as well as optimizing ecosystem services such as carbon storage and sequestration. However, some management techniques used to meet these objectives may yield conflicting results, specifically, the management tool of prescribed fire. Fire is crucial in maintaining species composition and structure in many ecosystems, but also results in high carbon emissions. Thus, it is important for land mangers to achieve the most efficient prescribed fire management regime to both preserve plant and animal communities, and optimize carbon storage. A former ranchland at the Disney Wilderness Preserve, Central Florida, USA is being restored to native ecosystems and managed to preserve biodiversity and increase carbon storage. This study quantified the carbon stocks within the aboveground biomass, litter, and top 90 cm of soil in five ecosystems at the Disney Wilderness Preserve, all of which are managed with prescribed fire every two to three years. These carbon stocks were compared in ecosystems in different stages of restoration: bahia grass pasture, pasture in restoration for longleaf pine flatwoods, and restored longleaf pine flatwoods. The carbon stocks were also compared among three restored flatwoods communities: longleaf pine flatwoods, slash pine flatwoods, and scrubby flatwoods. To determine the effects of the current prescribed fire management, carbon stocks were quantified and compared in recently burned areas (burned 4 months prior) and areas burned two to three years prior, in all ecosystems. Soil carbon properties were assessed using 13C isotope analysis. Aboveground biomass and litter carbon stocks were found to increase with higher stage of restoration, and were significantly less in areas with recent fire management. The results of this study did not provide evidence that soil carbon stock was significantly different in different stages of restoration or at different times since fire, but soil carbon stock was found to be significantly different among the flatwoods communities. In un-restored pasture and pasture in restoration sites, the soil was found to be increasingly depleted in 13C with increasing soil depth. This pattern indicated that carbon in the upper, more labile soil carbon pool had been derived from current C4 pasture or native grasses, while carbon in the deeper, more stable carbon pool is a legacy of the historical C3 forest vegetation that existed prior to conversion to pasture. Additionally, a pattern of less depletion in 13C with increasing time since deforestation was noted, indicating an increasing loss of historic forest carbon with increasing pasture age. As the pastures in restoration for longleaf pine flatwoods mature, the isotopic composition of the soil profile in the restored longleaf pine flatwoods may serve as a reference value for the soil profiles of these sites. Overall, the mean carbon stock in the aboveground biomass, litter and top 90 cm of soil in the un-restored pasture was ~13.3 kg C/m2, the carbon stock in the pasture in restoration was ~12.7 kg C/m2, the longleaf pine flatwoods had the highest carbon stock at ~17.7 kg C/m2, the scrubby flatwoods had the smallest carbon stock at ~7.7 kg C/m2, and the slash pine flatwoods had a carbon stock of ~15.8 kg C/m2.
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Date Issued
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2011
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Identifier
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CFE0003603, ucf:48870
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003603
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Title
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SIMULATION OF PHOTOCHROMIC COMPOUNDS USING DENSITY FUNCTIONAL THEORY METHODS.
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Creator
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Patel, Pansy, Masunov, Artem, University of Central Florida
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Abstract / Description
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This Thesis describes the systematic theoretical study aimed at prediction of the essential properties for the functional organic molecules that belong to diarylethene (DA) family of compounds. Diarylethenes present the distinct ability to change color under the influence of light, known as photochromism. This change is due to ultrafast chemical transition from open to closed ring isomers (photocyclization). It can be used for optical data storage, photoswitching, and other photonic...
Show moreThis Thesis describes the systematic theoretical study aimed at prediction of the essential properties for the functional organic molecules that belong to diarylethene (DA) family of compounds. Diarylethenes present the distinct ability to change color under the influence of light, known as photochromism. This change is due to ultrafast chemical transition from open to closed ring isomers (photocyclization). It can be used for optical data storage, photoswitching, and other photonic applications. In this work we apply Density Functional Theory methods to predict 6 of the related properties: (i) molecular geometry; (ii) resonant wavelength; (iii) thermal stability; (iv) fatigue resistance; (v) quantum yield and (vi) nanoscale organization of the material. In order to study sensitivity at diode laser wavelengths, we optimized geometry and calculated vertical absorption spectra for a benchmark set of 28 diarylethenes. Bond length alternation (BLA) parameters and maximum absorption wavelengths (λmax) are compared to the data presently available from X-ray diffraction and spectroscopy experiments. We conclude that TD-M05/6-31G*/PCM//M05-2X/6-31G*/PCM level of theory gives the best agreement for both the parameters. For our predictions the root mean square deviation (RMSD) are below 0.014 ÃÂ
for the BLAs and 25 nm for λmax. The polarization functions in the basis set and solvent effects are both important for this agreement. Next we consider thermal stability. Our results suggest that UB3LYP and UM05-2X functionals predict the activation barrier for the cycloreversion reaction within 3-4 kcal/mol from experimental value for a set of 7 photochromic compounds. We also study thermal fatigue, defined as the rate of undesirable photochemical side reactions. In order to predict the kinetics of photochemical fatigue, we investigate the mechanism of by-product formation. It has been established experimentally that the by-product is formed from the closed isomer; however the mechanism was not known. We found that the thermal by-product pathway involves the bicyclohexane (BCH) ring formation as a stable intermediate, while the photochemical by-product formation pathway may involve the methylcyclopentene diradical (MCPD) intermediate. At UM05-2X/6-31G* level, the calculated barrier between the closed form and the BCH intermediate is 51.2 kcal/mol and the barrier between the BCH intermediate and the by-product 16.2 kcal/mol. Next we investigate two theoretical approaches to the prediction of quantum yield (QY) for a set of 14 diarylethene derivatives at the validated M05-2X/6-31G* theory level. These include population of ground-state conformers and location of the pericycylic minimum on the potential energy surface 2-A state. Finally, we investigate the possibility of nanoscale organization of the photochromic material based on DNA template, as an alternative to the amorphous polymer matrix. Here we demonstrate that Molecular Dynamic methods are capable to describe the intercalation of π-conjugated systems between DNA base pairs and accurately reproduced the available photophysical properties of these nanocomposites. In summary, our results are in good agreement with the experimental data for the benchmark set of molecules we conclude that Density Functional Theory methods could be successfully used as an important component of material design strategy in prediction of accurate molecular geometry, absorption spectra, thermal stability of isomers, fatigue resistance, quantum yield of photocyclization and photophysical properties of nanocomposites.
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Date Issued
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2010
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Identifier
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CFE0003136, ucf:48633
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003136
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Title
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The safe removal of frozen air from the annulus of a liquid hydrogen storage tank.
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Creator
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Krenn, Angela, Bhattacharya, Aniket, Youngquist, Robert, Vasu Sumathi, Subith, University of Central Florida
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Abstract / Description
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Large Liquid Hydrogen (LH2) storage tanks are vital infrastructure for NASA. Eventually, air may leak into the evacuated and perlite filled annular region of these tanks. Although the vacuum level is monitored in this region, the extremely cold temperature causes all but the helium and neon constituents of air to freeze. A small, often unnoticeable pressure rise is the result. As the leak persists, the quantity of frozen air increases, as does the thermal conductivity of the insulation system...
Show moreLarge Liquid Hydrogen (LH2) storage tanks are vital infrastructure for NASA. Eventually, air may leak into the evacuated and perlite filled annular region of these tanks. Although the vacuum level is monitored in this region, the extremely cold temperature causes all but the helium and neon constituents of air to freeze. A small, often unnoticeable pressure rise is the result. As the leak persists, the quantity of frozen air increases, as does the thermal conductivity of the insulation system. Consequently, a notable increase in commodity boiloff is often the first indicator of an air leak. Severe damage can then result from normal draining of the tank. The warming air will sublimate which will cause a pressure rise in the annulus. When the pressure increases above the triple point, the frozen air will begin to melt and migrate downward. Collection of liquid air on the carbon steel outer shell may chill it below its ductility range, resulting in fracture. In order to avoid a structural failure, as described above, a method for the safe removal of frozen air is needed. Two potential methods for air removal are evaluated here. The first method discussed is the connection of a vacuum pump to the annulus which provides pumping in parallel with drainage of LH2. The goal is to keep the annular pressure below the triple point so that the air continues to sublimate, thus eliminating the threat that liquefaction poses. The second method discussed is the application of heat to the bottom of the outer tank during tank drain. Though liquefaction in the annular space will occur, the goal of the heater design is to keep the outer shell above the embrittlement temperature, so that cracking will not occur.In order to evaluate these methods, it is first necessary to characterize some the physical properties and changes that take place in the system. A thermal model of the storage tank was created in SINDA/FLUINT (C(&)R Technologies, 2014) to identify locations where air can freeze. This model shows the volume that is capable of freezing air under varying conditions. It is also necessary to characterize the changes in thermal conductivity of perlite which has nitrogen frozen into its interstitial spaces. The details and results of an experiment designed for that purpose is outlined. All data, including operational data from existing LH2 tanks, is compiled and a physics-based evaluation of the two proposed air removal techniques is performed.Due to small pumping capacities at low pressure and the large quantity of air inside the annulus, the pumping option is not deemed feasible. It would take many years to remove a significant amount of air by pumping while maintaining the annular pressure below the necessary triple point. Application of heating devices is a feasible option. For a specific case, it is shown that approximately 105 kilowatts of power would be required to vaporize the air in the annulus and keep the temperature of the outer tank wall above the freezing point of water. Several engineering solutions to accomplish this are also discussed. There are many unknowns and complexities in addressing the problem of safely removing frozen air from the annulus of an LH2 storage sphere. The work that follows utilized: research, modeling, experimentation, analysis, and data from existing tanks to arrive at possible solutions to the problem. Heating solutions may be implemented immediately and could result in significant savings to the user.
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Date Issued
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2015
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Identifier
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CFE0005969, ucf:50766
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0005969
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Title
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Modeling Dense Storage Systems With Location Uncertainty.
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Creator
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Awwad, Mohamed, Pazour, Jennifer, Elshennawy, Ahmad, Thompson, William, Leon, Steven, University of Central Florida
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Abstract / Description
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This dissertation focuses on developing models to study the problem of searching and retrieving items in a dense storage environment. We consider a special storage configuration called an inverted T configuration, which has one horizontal and one vertical aisle. Inverted T configurations have fewer aisles than a traditional aisle-based storage environment. This increases the storage density; however, requires that some items to be moved out of the way to gain access to other more deeply...
Show moreThis dissertation focuses on developing models to study the problem of searching and retrieving items in a dense storage environment. We consider a special storage configuration called an inverted T configuration, which has one horizontal and one vertical aisle. Inverted T configurations have fewer aisles than a traditional aisle-based storage environment. This increases the storage density; however, requires that some items to be moved out of the way to gain access to other more deeply stored items. Such movement can result in item location uncertainty. When items are requested for retrieval in a dense storage environment with item location uncertainty, searching is required. Dense storage has a practical importance as it allows for the use of available space efficiently, which is especially important with the scarce and expensive space onboard of US Navy's ships that form a sea base. A sea base acts as a floating distribution center that provides ready issue material to forces ashore participating in various types of missions. The sea basing concept and the importance of a sea base's responsiveness is our main motivation to conduct this research.In chapter 2, we review three major bodies of literature: 1) sea based logistics, 2) dense storage and 3) search theory. Sea based logistics literature mostly focuses on the concept and the architecture of a sea base, with few papers developing mathematical models to solve operational problems of a sea base, including papers handling the logistical and sustainment aspects. Literature related to dense storage can be broken down into work dealing with a dense storage environment with an inverted T configuration and other papers dealing with other dense storage configurations. It was found that some of the dense storage literature was motivated by the same application, i.e. sea based logistics. Finally, we surveyed the vast search theory literature and classification of search environments. This research contributes to the intersection of these three bodies of literature. Specifically, this research, motivated by the application of sea basing, develops search heuristics for dense storage environments that require moving items out of the way during searching. In chapter 3, we present the problem statements. We study two single-searcher search problems. The first problem is searching for a single item in an inverted T dense storage environment. The second one is searching for one or more items in an inverted T storage environment with items stacked over each other in the vertical direction.In chapter 4, we present our first contribution. In this contribution we propose a search plan heuristic to search for a single item in an inverted T, k-deep dense storage system with the objective of decreasing the expected search time in such an environment. In this contribution, we define each storage environment entirely by the accessibility constant and the storeroom length. In addition, equations are derived to calculate each component of the search time equation that we propose: travel, put-back and repositioning. Two repositioning policies are studied. We find that a repositioning policy that uses the open aisle locations as temporary storage locations and requires put-back of these items while searching is recommended. This recommendation is because such a policy results in lower expected search time and lower variability than a policy that uses available space outside the storage area and handles put-back independently of the search process. Statistical analysis is used to analyze the numerical results of the first contribution and to analyze the performances of both repositioning polices. We derive the probability distribution of search times in a storeroom with small configurations in terms of the accessibility constant and length. It was found that this distribution can be approximated using a lognormal probability distribution with a certain mean and standard deviation. Knowing the probability distribution provides the decision makers with the full range of all possible probabilities of search times, which is useful for downstream planning operations.In chapter 5, we present the second contribution, in which we propose a search plan heuristic but for multiple items in an inverted T, k-deep storage system. Additionally, we consider stacking multiple items over each other. Stacking items over each other, increases the number of stored items and allows for the utilization of the vertical space. In this second contribution, we are using the repositioning policy that proved its superiority in the first contribution. This contribution investigates a more general and a much more challenging environment than the one studied in the first contribution. In the second environment, to gain access to some items, not only may other items need to be moved out of the way, but also the overall number of movements for items within the system will be highly affected by the number of items stacked over each other. In addition, the searcher is given a task that includes searching and retrieving a set of items, rather than just one item.For the second contribution, the performance of the search heuristic is analyzed through a Statistical Design of Experiments, and it was found that searching and retrieving multiple items instead of just a single item, would decrease the variability in search times for each storeroom configuration. Finally, in chapter 6, conclusions of this research and suggestions for future research directions are presented.
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Date Issued
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2015
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Identifier
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CFE0006256, ucf:51045
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0006256
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Title
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TWO-PHOTON 3D OPTICAL DATA STORAGE VIA FLUORESCENCE MODULATION OF FLUORENE DYES BY PHOTOCHROMIC DIARYLETHENES.
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Creator
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Corredor, Claudia, Belfield, Kevin D., University of Central Florida
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Abstract / Description
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Three-dimensional (3D) optical data storage based on two-photon processes provides highly confined excitation in a recording medium and a mechanism for writing and reading data with less cross talk between multiple memory layers, due to the quadratic dependence of two photon absorption (2PA) on the incident light intensity. The capacity for highly confined excitation and intrinsic 3D resolution affords immense information storage capacity (up to 1012 bits/cm3). Recently, the use of...
Show moreThree-dimensional (3D) optical data storage based on two-photon processes provides highly confined excitation in a recording medium and a mechanism for writing and reading data with less cross talk between multiple memory layers, due to the quadratic dependence of two photon absorption (2PA) on the incident light intensity. The capacity for highly confined excitation and intrinsic 3D resolution affords immense information storage capacity (up to 1012 bits/cm3). Recently, the use of photochromic materials for 3D memory has received intense interest because of several major advantages over current optical systems, including their erasable/rewritable capability, high resolution, and high sensitivity. This work demonstrates a novel two-photon 3D optical storage system based on the modulation of the fluorescence emission of a highly efficient two-photon absorbing fluorescent dye (fluorene derivative) and a photochromic compound (diarylethene). The feasibility of using efficient intermolecular Förster Resonance Energy Transfer (RET) from the non-covalently linked two-photon absorbing fluorescent fluorene derivative to the photochromic diarylethene as a novel read-out method in a two-photon optical data storage system was explored. For the purpose of the development of this novel two-photon 3D optical storage system, linear and two-photon spectroscopic characterization of commercial diarylethenes in solution and in a polymer film and evidence of their cyclization (O→C) and cycloreversion (C→O) reactions induced by two-photon excitation were undertaken. For the development of a readout method, Resonance Energy Transfer (RET) from twophoton absorbing fluorene derivatives to photochromic compounds was investigated under one and two-photon excitation. The Förster's distances and critical acceptor concentrations were determined for non-bound donor-acceptor pairs in homogeneous molecular ensembles. To the best of my knowledge, modulation of the two-photon fluorescence emission of a dye by a photochromic diarylethene has not been reported as a mechanism to read the recorded information in a 3D optical data storage system. This system was demonstrated to be highly stable and suitable for recording data in thick storage media. The proposed RET-based readout method proved to be non-destructive (exhibiting a loss of the initial fluorescence emission less than 20% of the initial emission after 10,000 readout cycles). Potential application of this system in a rewritable-erasable optical data storage system was proved. As part of the strategy for the development of diarylethenes optimized for 3D optical data storage, derivatives containing π-conjugated fluorene molecules were synthesized and characterized. The final part of this reasearch demonstrated the photostability of fluorine derivatives showing strong molecular polarizability and high fluorescence quantum yields. These compounds are quite promising for application in RET-based two-photon 3D optical data storage. Hence, the photostability of these fluorene derivatives is a key parameter to establish, and facilitates their full utility in critical applications.
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Date Issued
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2007
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Identifier
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CFE0001662, ucf:47210
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0001662
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Title
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THE IMPLICATIONS OF FEDERAL AND STATE LAWS REGARDING THE STORAGE, USE, AND DONATION OF CORD BLOOD.
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Creator
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Miller, Rebecca, Milon, Abby, University of Central Florida
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Abstract / Description
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Cord blood storage, use, and donation is a rising trend. The cells found in the blood of the umbilical cord can be used to treat various life threatening diseases. It has been shown that the use of these cells can produce results that are just as effective as a bone marrow transfusion. The yield of cells from a sample of cord blood is not always enough to be effective for a transfusion in adults. As such children are the primary demographic for cord blood transfusions. For this reason,...
Show moreCord blood storage, use, and donation is a rising trend. The cells found in the blood of the umbilical cord can be used to treat various life threatening diseases. It has been shown that the use of these cells can produce results that are just as effective as a bone marrow transfusion. The yield of cells from a sample of cord blood is not always enough to be effective for a transfusion in adults. As such children are the primary demographic for cord blood transfusions. For this reason, prospective parents are taking notice of the trend. Currently, federal and state statutes are set up to promote the introduction of cord blood use. What current law fails to recognize is that cord blood is in use and has a lot of potential. For this reason laws need to be updated to better reflect the current market. A more proactive approach needs to be taken to better utilize the potential of cord blood. As the trend is popularized there is an increasing notion that informed consent is not uniform enough, state laws do not adequately promote cord blood use, and there is a discrepancy between the standards of public and private cord blood banks. In order to improve upon these issues it is necessary to review the laws that are currently in place and then expand upon them so that they better reflect the storage, use, and donation of the blood. If umbilical cord blood becomes more than medical waste, as is projected to happen, then there is a need for an adequate legal foundation that protects the interests of all parties involved, especially prospective parents.
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Date Issued
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2015
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Identifier
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CFH0004737, ucf:45394
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFH0004737
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Title
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SYNTHESIS OF NOVEL FLUORENE-BASED TWO-PHOTON ABSORBING MOLECULES AND THEIR APPLICATIONS IN OPTICAL DATA STORAGE, MICROFABRICATION, AND STIMULATED EMISSION DEPLETION.
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Creator
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Yanez, Ciceron, Belfield, Kevin, University of Central Florida
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Abstract / Description
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Two-photon absorption (2PA) has been used for a number of scientific and technological applications, exploiting the fact that the 2PA probability is directly proportional to the square of the incident light intensity (while one-photon absorption bears a linear relation to the incident light intensity). This intrinsic property of 2PA leads to 3D spatial localization, important in fields such as optical data storage, fluorescence microscopy, and 3D microfabrication. The spatial confinement that...
Show moreTwo-photon absorption (2PA) has been used for a number of scientific and technological applications, exploiting the fact that the 2PA probability is directly proportional to the square of the incident light intensity (while one-photon absorption bears a linear relation to the incident light intensity). This intrinsic property of 2PA leads to 3D spatial localization, important in fields such as optical data storage, fluorescence microscopy, and 3D microfabrication. The spatial confinement that 2PA enables has been used to induce photochemical and photophysical events in increasingly smaller volumes and allowed nonlinear, 2PA-based, technologies to reach sub-diffraction limit resolutions. The primary focus of this dissertation is the development of novel, efficient 2PA, fluorene-based molecules to be used either as photoacid generators (PAGs) or fluorophores. A second aim is to develop more effective methods of synthesizing these compounds. As a third and final objective, the new molecules were used to develop a write-once-read many (WORM) optical data storage system, and stimulated emission depletion probes for bioimaging. In Chapter I, the microwave-assisted synthesis of triarylsulfonium salt photoacid generators (PAGs) from their diphenyliodonium counterparts is reported. The microwave-assisted synthesis of these novel sulfonium salts afforded reaction times 90 to 420 times faster than conventional thermal conditions, with photoacid quantum yields of new sulfonium PAGs ranging from 0.01 to 0.4. These PAGs were used to develop a fluorescence readout-based, nonlinear three-dimensional (3D) optical data storage system (Chapter II). In this system, writing was achieved by acid generation upon two-photon absorption (2PA) of a PAG (at 710 or 730 nm). Readout was then performed by interrogating two-photon absorbing dyes, after protonation, at 860 nm. Two-photon recording and readout of voxels was demonstrated in five and eight consecutive, crosstalk-free layers within a polymer matrix, generating a data storage capacity of up to 1.8 x 1013 bits/cm3. The possibility of using these PAGs in microfabrication is described in Chapter III, where two-photon induced cationic ring-opening polymerization (CROP) crosslinking of an SU8 resin is employed to produce free-standing microstructures. Chapter IV describes the investigation of one- and two-photon stimulated emission transitions by the fluorescence quenching of a sulfonyl-containing fluorene compound in solution at room temperate using a picosecond pump-probe technique. The nature of stimulated transitions under various fluorescence excitation and quenching conditions were analyzed theoretically, and good agreement with experimental data was demonstrated. Two-photon stimulated transitions S1 to S0 were shown at 1064 nm. The two-photon stimulated emission cross section of the sulfonyl fluorophore was estimated as aproximately 240 - 280 GM, making this compound a good candidate for use in two-photon stimulated emission depletion (STED) microscopy.
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Date Issued
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2009
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Identifier
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CFE0002913, ucf:48003
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002913
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Title
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DESIGN AND EXPERIMENTAL STUDY OF AN INTEGRATED VAPOR CHAMBER THERMAL ENERGY STORAGE SYSTEM.
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Creator
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Kota, Krishna, CHOW, LOUIS, University of Central Florida
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Abstract / Description
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Future defense, aerospace and automotive technologies involve electronic systems that release high pulsed waste heat like during high power microwave and laser diode applications in tactical and combat aircraft, and electrical and electronic systems in hybrid electric vehicles, which will require the development of an efficient thermal management system. A key design issue is the need for fast charging so as not to overheat the key components. The goal of this work is to study the fabrication...
Show moreFuture defense, aerospace and automotive technologies involve electronic systems that release high pulsed waste heat like during high power microwave and laser diode applications in tactical and combat aircraft, and electrical and electronic systems in hybrid electric vehicles, which will require the development of an efficient thermal management system. A key design issue is the need for fast charging so as not to overheat the key components. The goal of this work is to study the fabrication and technology implementation feasibility of a novel high energy storage, high heat flux passive heat sink. Key focus is to verify by theory and experiments, the practicability of using phase change materials as a temporary storage of waste heat for heat sink applications. The reason for storing the high heat fluxes temporarily is to be able to reject the heat at the average level when the heat source is off. Accordingly, a concept of a dual latent heat sink intended for moderate to low thermal duty cycle electronic heat sink applications is presented. This heat sink design combines the features of a vapor chamber with rapid thermal energy storage employing graphite foam inside the heat storage facility along with phase change materials and is attractive owing to its passive operation unlike some of the current thermal management techniques for cooling of electronics employing forced air circulation or external heat exchangers. In addition to the concept, end-application dependent criteria to select an optimized design for this dual latent heat sink are presented. A thermal resistance concept based design tool/model has been developed to analyze and optimize the design for experiments. The model showed that it is possible to have a dual latent heat sink design capable of handling 7 MJ of thermal load at a heat flux of 500 W/cm2 (over an area of 100 cm2) with a volume of 0.072 m3 and weighing about 57.5 kg. It was also found that with such high heat flux absorption capability, the proposed conceptual design could have a vapor-to-condenser temperature difference of less than 10 0C with a volume storage density of 97 MJ/m3 and a mass storage density of 0.122 MJ/kg. The effectiveness of this heat sink depends on the rapidness of the heat storage facility in the design during the pulse heat generation period of the duty cycle. Heat storage in this heat sink involves transient simultaneous laminar film condensation of vapor and melting of an encapsulated phase change material in graphite foam. Therefore, this conjugate heat transfer problem including the wall inertia effect is numerically analyzed and the effectiveness of the heat storage mechanism of the heat sink is verified. An effective heat capacity formulation is employed for modeling the phase change problem and is solved using finite element method. The results of the developed model showed that the concept is effective in preventing undue temperature rise of the heat source. Experiments are performed to investigate the fabrication and implementation feasibility and heat transfer performance for validating the objectives of the design i.e., to show that the VCTES heat sink is practicable and using PCM helps in arresting the vapor temperature rise in the heat sink. For this purpose, a prototype version of the VCTES heat sink is fabricated and tested for thermal performance. The volume foot-print of the vapor chamber is about 6"X5"X2.5". A custom fabricated thermal energy storage setup is incorporated inside this vapor chamber. A heat flux of 40 W/cm2 is applied at the source as a pulse and convection cooling is used on the condenser surface. Experiments are done with and without using PCM in the thermal energy storage setup. It is found that using PCM as a second latent system in the setup helps in lowering the undue temperature rise of the heat sink system. It is also found that the thermal resistance between the vapor chamber and the thermal energy storage setup, the pool boiling resistance at the heat source in the vapor chamber, the condenser resistance during heat discharging were key parameters that affect the thermal performance. Some suggestions for future improvements in the design to ease its implementation and enhance the heat transfer of this novel heat sink are also presented.
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Date Issued
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2008
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Identifier
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CFE0002332, ucf:47802
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0002332
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Title
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DEVELOPMENT OF DAILY, MONTHLY, INTER-ANNUAL, AND MEAN ANNUAL HYDROLOGICAL MODELS BASED ON A UNIFIED RUNOFF GENERATION FRAMEWORK.
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Creator
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Kheimi, Marwan, Wang, Dingbao, Wahl, Thomas, Singh, Arvind, Zheng, Qipeng, University of Central Florida
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Abstract / Description
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The main goal of this dissertation develops a unified model structure for runoff generation based on observations from a large number of catchments. Furthermore, obtaining a comprehensive understanding of the physical controlling factors that control daily, monthly, and annual water balance models. Meanwhile, applying the developed Unified model on different climate conditions, and comparing it with different well-known models.The proposed model was compared with a similar timescale model ...
Show moreThe main goal of this dissertation develops a unified model structure for runoff generation based on observations from a large number of catchments. Furthermore, obtaining a comprehensive understanding of the physical controlling factors that control daily, monthly, and annual water balance models. Meanwhile, applying the developed Unified model on different climate conditions, and comparing it with different well-known models.The proposed model was compared with a similar timescale model (HyMOD, and abcd) and applied on 92 catchments from MOPEX dataset across the United States. The HyMOD and abcd are a well-known daily and monthly hydrological model used on a variety of researchers. The differences between the new model and HyMOD, and abcd include 1) the distribution function for soil water storage capacity is different and the new distribution function leads to the SCS curve number method; and 2) the computation of evaporation is also based on the distribution function considering the spatial variability of available water evaporation. The performance of all models along with parameters used is examined to understand the controlling factors. The generated results were calibrated and validated using the Nash-Sutcliffe efficiency coefficient (NSE), indicating that the Unified model has a moderate better performance against the HyMOD at a daily time scale, and abcd model at a monthly timescale. The proposed model using the SCS-CN method shows the effect of improving the performance.
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Date Issued
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2019
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Identifier
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CFE0007478, ucf:52684
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007478
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Title
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Design and Optimization of a Wave Energy Harvester Utilizing a Flywheel Energy Storage System.
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Creator
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Helkin, Steven, Lin, Kuo-Chi, Gordon, Ali, Raghavan, Seetha, University of Central Florida
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Abstract / Description
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This thesis details the design and optimization of a buoy used to collect renewable energy from ocean waves. The proposed buoy is a point absorber(-)a device that transforms the kinetic energy of the vertical motion of surface waves into electrical energy. The focus of the research is on the mechanical system used to collect the energy, and methods to improve it for eventual use in an actual wave energy harvester. A flywheel energy storage system was utilized in order to provide an improved...
Show moreThis thesis details the design and optimization of a buoy used to collect renewable energy from ocean waves. The proposed buoy is a point absorber(-)a device that transforms the kinetic energy of the vertical motion of surface waves into electrical energy. The focus of the research is on the mechanical system used to collect the energy, and methods to improve it for eventual use in an actual wave energy harvester. A flywheel energy storage system was utilized in order to provide an improved power output from the system, even with the intermittent input of force exerted by ocean waves. A series of laboratory prototypes were developed to analyze parameters that are important to the success of the point absorb mechanical system. By introducing a velocity-based load control scheme in conjunction with flywheel energy storage, it was seen that the average power output by the prototype was increased. The generator load is controlled via a relay switch that removes electrical resistance from the generator(-)this sacrifices time during which power is drawn from the system, but also allows the buoy to move with less resistance. A simulation model was developed in order to analyze the theoretical wave absorber system and optimize the velocity threshold parameters used in the load control. Results indicate that the power output by the system can be substantially improved through the use of a flywheel energy storage control scheme that engages and disengages the electrical load based on the rotational velocity of the flywheel system. The results of the optimization are given for varying-sized generator systems input into the simulation in order to observe the associated trends.
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Date Issued
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2011
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Identifier
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CFE0004118, ucf:49113
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004118
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Title
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AN OPTIMAL CONTROL APPROACH FOR DETERMINATION OF THE HEAT LOSS COEFFICIENT IN AN ICS SOLAR DOMESTIC WATER HEATING SYSTEM.
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Creator
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Gil, Camilo, Simaan, Marwan, University of Central Florida
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Abstract / Description
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Water heating in a typical home in the U.S. accounts for a significant portion (between 14% and 25%) of the total homeÃÂÃÂÃÂÃÂ's annual energy consumption. The objective of considerably reducing the homeÃÂÃÂÃÂÃÂ's energy consumption from the utilities calls for the use of onsite renewable energy...
Show moreWater heating in a typical home in the U.S. accounts for a significant portion (between 14% and 25%) of the total homeÃÂÃÂÃÂÃÂ's annual energy consumption. The objective of considerably reducing the homeÃÂÃÂÃÂÃÂ's energy consumption from the utilities calls for the use of onsite renewable energy systems. Integral Collector Storage (ICS) solar domestic water heating systems are an alternative to help meet the hot water energy demands in a household. In order to evaluate the potential benefits and contributions from the ICS system, it is important that the parameter values included in the model used to estimate the systemÃÂÃÂÃÂÃÂ's performance are as accurate as possible. The overall heat loss coefficient (Uloss) in the model plays an important role in the performance prediction methodology of the ICS. This work presents a new and improved methodology to determine Uloss as a function of time in an ICS system using a systematic optimal control theoretic approach. This methodology is based on the derivation of a new nonlinear state space model of the system, and the formulation of a quadratic performance function whose minimization yields estimates of Uloss values that can be used in computer simulations to improve the performance prediction of the ICS system, depending on the desired time of the year and hot water draw profile. Simulation results show that predictions of the systemÃÂÃÂÃÂÃÂ's performance based on these estimates of Uloss are considerably more accurate than the predictions based on current existing methods for estimating Uloss.
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Date Issued
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2010
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Identifier
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CFE0003266, ucf:48525
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003266
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Title
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Modeling Annual Water Balance in The Seasonal Budyko Framework.
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Creator
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Alimohammadi, Negin, Wang, Dingbao, Hagen, Scott, Madani Larijani, Kaveh, University of Central Florida
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Abstract / Description
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In this thesis, the role of soil water storage change on the annual water balance is evaluated based on observations at a large number of watersheds located in a spectrum of climate regions, and an annual water balance model is developed at the seasonal scale based on Budyko hypthesis. The annual water storage change is quantified based on water balance closure given the available data of precipitation, runoff, and evaporation estimated from remote sensing data and meteorology reanalysis. The...
Show moreIn this thesis, the role of soil water storage change on the annual water balance is evaluated based on observations at a large number of watersheds located in a spectrum of climate regions, and an annual water balance model is developed at the seasonal scale based on Budyko hypthesis. The annual water storage change is quantified based on water balance closure given the available data of precipitation, runoff, and evaporation estimated from remote sensing data and meteorology reanalysis. The responses of annual runoff, evaporation, and storage change to the interannual variability of precipitation and potential evaporation are then analyzed. Both runoff and evaporation sensitivities to potential evaporation are higher under energy-limited conditions, but storage change seems to be more sensitive to potential evaporation under the conditions in which water and energy are balanced. Runoff sensitivity to precipitation is higher under energy-limited conditions; but both evaporation and storage change sensitivities to precipitation are higher under water-limited conditions. Therefore, under energy-limited conditions, most of precipitation variability is transferred to runoff variability; but under water-limited conditions, most of precipitation variability is transferred to storage change and some of precipitation variability is transferred to evaporation variability. The main finding of this part is that evaporation variability will be overestimated by assuming negligible storage change in annual water balance, particularly under water-limited conditions. Budyko framework which expresses partitioning of water supply at the mean annual scale, is adapted to be applicable in modeling water cycle in short terms i.e., seasonal and interannual scales. Seasonal aridity index is defined as the ratio of seasonal potential evaporation and the difference between precipitation and storage change. The seasonal water balance is modeled by using a Budyko-type curve with horizontal shifts which leads prediction of seasonal and annual storage changes and evaporation if precipitation, potential evaporation, and runoff data are available.
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Date Issued
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2012
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Identifier
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CFE0004509, ucf:49283
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0004509
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Title
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TWO-PHOTON CROSS SECTION ENHANCEMENT OF PHOTOCHROMIC COMPOUNDS FOR USE IN 3D OPTICAL DATA STORAGE.
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Creator
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Luchita, Gheorghe, Belfield, Kevin, University of Central Florida
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Abstract / Description
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Rewritable photochrome-based 3D optical data storage requires photochromic molecules with high two-photon absorption (2PA) cross sections. Currently, the low value of two-photon absorption cross sections of existing photochromes makes them unsuitable for practical application in 3D data storage. Worldwide attempts to increase the cross section of photochromic molecules by altering the chemical structure have yielded poor results. In this work, two ways to increase the two-photon absorption...
Show moreRewritable photochrome-based 3D optical data storage requires photochromic molecules with high two-photon absorption (2PA) cross sections. Currently, the low value of two-photon absorption cross sections of existing photochromes makes them unsuitable for practical application in 3D data storage. Worldwide attempts to increase the cross section of photochromic molecules by altering the chemical structure have yielded poor results. In this work, two ways to increase the two-photon absorption cross sections of photochromes were investigated. In the first method, partial success demonstrated by extending the conjugation of a photochromic molecule, a high two-photon absorption cross section of the closed form isomer and high photoconversion to the closed form were realized. At the same time, a decrease in photoswitching quantum yield and low photoconversion to open form was observed. A discussion is provided to explain the results, suggesting that the proposed method of extending the conjugation may not solve the problem. For this reason a new method for effective two-photon absorption cross section enhancement of photochromes was proposed. As a proof of principle, a new two-photon absorbing dye with a hydrogen bonding moiety was synthesized and used for the formation of supramolecular structures with a photochromic compound. Theoretical reasoning and experimental demonstration of energy transfer from the dye to the photochrome under one and two-photon excitation confirmed the practical value of the method. The effects of a 2PA dye on the photochromic properties of a diarylethene were investigated using a model compound to simplify data analysis. Formation of supramolecular structures was revealed using 1H NMR spectroscopic methods. The model compound, having the same hydrogen bonding moiety as 2PA dye, has been demonstrated to bind with photochrome molecules at very low concentrations. Photochromic properties of 2,3-bis(2,4,5-trimethyl-3-thienyl)maleimide, including conversions at the photostationary state, extinction coefficients, photoisomerization reaction rates and quantum yields, were shown to be affected by hydrogen bonding with the model compound - 2,6-bis-(acetamido)pyridine. The extent of this change was determined and discussed, demonstrating a balanced supramolecular strategy to modulate photochemical and photophysical properties of this important class of photochromic material.
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Date Issued
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2011
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Identifier
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CFE0003928, ucf:48695
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Format
-
Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003928
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Title
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ANALYSIS AND OPTIMIZATION OF A SOLAR THERMAL COLLECTOR WITH INTEGRATED STORAGE.
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Creator
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Bonadies, Monica, Kapat, Jay, University of Central Florida
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Abstract / Description
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Solar energy, a topic popular in the United States during the oil embargo of the 1970ÃÂ's, has become a relevant topic once more with the current focus on reducing greenhouse emissions. Solar thermal energy in particular has become popular as it uses existing steam turbine technology to produce electricity, with the benefit of using solar energy to produce steam rather than coal or nuclear heat sources. Solar thermal can also be used at lower temperatures to heat water...
Show moreSolar energy, a topic popular in the United States during the oil embargo of the 1970ÃÂ's, has become a relevant topic once more with the current focus on reducing greenhouse emissions. Solar thermal energy in particular has become popular as it uses existing steam turbine technology to produce electricity, with the benefit of using solar energy to produce steam rather than coal or nuclear heat sources. Solar thermal can also be used at lower temperatures to heat water for pools or for residential use. While this energy source has its benefits, it has the problem of being opportunistic ÃÂ the energy must be used as it is captured. With the integration of storage, a solar thermal system becomes more viable for use. In this work, a low temperature (50-70o C) thermal storage unit with a solar thermal collector is experimentally run then studied using both analytical and numerical methods. With these methods, suggestions for future developments of the storage unit are made. The prototype collector and storage combination tested worked best during the winter months, when there was low humidity. Furthermore, the heat exchanger design within the storage unit was found to work well for charging (heating) the unit, but not for discharging the storage to heat water. The best modeling method for the storage unit was the use of FLUENT, which would allow for the suggested changes to the prototype to be simulated before the next prototype was constructed.
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Date Issued
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2010
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Identifier
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CFE0003260, ucf:48548
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0003260
Pages