Current Search: tellurite -- tellurium -- glass -- crystal -- infrared -- sintering -- Bridgman (x)
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Title
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Processing of Advanced Infrared Materials.
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Creator
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Mcgill, Daniel, Richardson, Kathleen, Gaume, Romain, Christodoulides, Demetrios, Rivero Baleine, Clara, University of Central Florida
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Abstract / Description
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Infrared transparent glassy and crystalline materials often have unique and complex processing requirements but are an important class of materials for such applications as optical windows, lenses, waveplates, polarizers and beam splitters. This thesis investigates two specific materials, one amorphous and one crystalline, that are candidates for use in the short and midwave-infrared and mid and longwave infrared, respectively. It is demonstrated that an innovative uniaxial sintering process,...
Show moreInfrared transparent glassy and crystalline materials often have unique and complex processing requirements but are an important class of materials for such applications as optical windows, lenses, waveplates, polarizers and beam splitters. This thesis investigates two specific materials, one amorphous and one crystalline, that are candidates for use in the short and midwave-infrared and mid and longwave infrared, respectively. It is demonstrated that an innovative uniaxial sintering process, which uses a sacrificial pressure-transmitting medium, can be used to fully densify a 70TeO2-20WO3-10La2O3 (TWL) glass powder. The characteristics of the sintered TWL glass is compared to that of a parent glass produced through a conventional melt/quench process to ascertain the impact of process-specific property changes on the resulting material. Additionally, the design, construction and characterization of a custom-made transparent Bridgman crystal growth furnace is undertaken to enable growth of highly birefringent tellurium single crystal. The key obstacles that need to be overcome to scale up the size of the grown crystals are summarized with the end goal of producing commercial grade optical elements.
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Date Issued
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2019
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Identifier
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CFE0007894, ucf:52761
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Format
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Document (PDF)
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PURL
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http://purl.flvc.org/ucf/fd/CFE0007894
